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Book Synthesis and Characterization of Tris 1 ethyl isopropyl kN phosphine Cobalt II  and Nickel II  Complexes

Download or read book Synthesis and Characterization of Tris 1 ethyl isopropyl kN phosphine Cobalt II and Nickel II Complexes written by and published by . This book was released on 2013 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal complexes with biologically relevant ligands represent structural models of active sites in metalloenzymes. Imidazole groups can mimic histidine side chain residues that are present in many enzyme active sites. These active sites can be comprised of metal centers bound by three imidazole histidine residues situated in a facial triad. To model these sites, the ligand tris-imidazolyl phosphine (T1Et4iPrIP) was prepared. Chapter Two is focused on the synthesis, structure and characterization model complexes for cobalt-substituted carbonic anhydrase. Four cobalt(II) complexes bound to T1Et4iPrIP were prepared and found to possess cobalt(II) centers in distort tetrahedral, distorted square pyramidal and distorted octahedral geometries. Chapter Three is focused on the synthesis, structure and characterization of model complexes for imidazole-containing nickel metalloproteins. Two nickel(II) complexes bound to T1Et4iPrIP were prepared and found to nickel(II) centers possessing distorted square pyramidal and distorted octahedral geometries. Properties have also been examined by UV-vis, IR, and magnetic susceptometry.

Book General Science Index

Download or read book General Science Index written by and published by . This book was released on 1989 with total page 1782 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Cobalt III  and Nickel II  Complexes of Tris 3 dimethylarsinopropyl arsine and Tris 3 dimenthylarsinopropyl  Phosphine

Download or read book Cobalt III and Nickel II Complexes of Tris 3 dimethylarsinopropyl arsine and Tris 3 dimenthylarsinopropyl Phosphine written by Gereld Stokes Benner and published by . This book was released on 1966 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Cobalt  III  and Nickel  II  Compounds of Tris  3 dimethylarsinopropyl  Phosphine

Download or read book Cobalt III and Nickel II Compounds of Tris 3 dimethylarsinopropyl Phosphine written by Gereld Stokes Benner and published by . This book was released on 1963 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: