Download or read book Kinetic Study of Ligand Substitution Reactions of Five coordinate Nickel II Complexes written by Tsong-Dsu Chang Li and published by . This book was released on 1975 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanism of Ligand Substitution of Five coordinate Ni II Complexes written by Harvest Leroy Collier and published by . This book was released on 1977 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of Ligand Substitution Reactions in the Five Coordinate Complexes Cu TREN OH2 2 Cu Me6 TREN OH2 2 and Cu Me6 TREN OH written by Peter Ralph Collins and published by . This book was released on 1979 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ligand Substitution Processes written by Cooper Harold Langford and published by . This book was released on 1966 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the mechanistic study of ligand substitution reactions is currently undergoing an exciting growth. New fast-reaction techniques have removed the upper limit on rates that can be measured, and extension to less familiar central metal atoms has begun in earnest. This might seem the wrong moment for review of the field. As yet, definitive treatment is possible only for those complexes involving monodentate ligands with cobalt(III) and platinurn(II). But, because information is so extensive for these systems, it is clear that they are functioning as models from which concepts and experiments are generated for application over the fast-growing range of the subject. We believe that this is an important moment to reopen debate on fundamentals so that concepts will be most felicitously formulated to aid growth of understanding. This monograph is centrally concerned with three aspects of those fundamentals. We have attempted to develop an approach to classification of ligand substitution reactions that is adapted to what seem to have emerged as the characteristic features of these reactions and is susceptible to operational tests. (We do recognize that any such scheme of ideas is necessarily obsolescent once it is formulated since new experiments will certainly follow immediately.) We have tried to evaluate the basis for making generalizations about ligand substitution processes and to formulate tests to show whether new reactions fall within familiar patterns. Finally, we have sought to base the models of ligand substitution processes in the language of molecular-orbital theory. We believe that MO theory is most useful, because it may be used to correlate rate data on complexes with the extensive information available from spectral and magnetic studies, yet differs from crystal-field theory in providing a natural place for consideration of the bonding electrons, which must be a principal determinant of reaction processes. To keep this essay within bounds, we assume familiarity with the elements of experimental kinetics, transition-state theory, and the simple molecular-orbital theory of complexes. Introductory physical chemistry, some familiarity with the study of reaction mechanisms, and mastery of one of the qualitative treatments of MO theory as applied to transition-metal complexes should provide sufficient background. Thus, we hope that this book will be useful to students, relatively early in their careers, who wish to explore this field.
Download or read book Ligand Exchange and Substitution on Five coordinate Complexes of Copper II Nickel II and Cobalt II written by Bruce Germein Doddridge and published by . This book was released on 1986 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Kinetics of Substitution Reactions of Some Nickel II Complexes written by Lloyd Mark Smith and published by . This book was released on 1971 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reactions of Coordinated Ligands written by P.S. Braterman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This, the second and final volume of Reactions of Coordinated Ligands, describes the chemistry of ligands bound through non-carbon atoms, and of coordinated carbon dioxide. As before, emphasis is on the underlying mechanisms, which provide a unity of understanding for superficially disparate processes. The wide range of topics covered illustrates well both the versatility and the usefulness of coordination chemistry in the controlled activation of ligands. Looking to the future, carbon dioxide is the feedstock of last resort. The homogeneous reduction of dinitrogen to ammonia now seems unlikely to replace the Haber process, but solution reactions also lead to more complex, varied, and valuable products. Nitrogen monoxide, a "non innocent" ligand, impinges as pollutant and reagent. Its rich chemistry stems from its linked roles as three-electron donor, and as extremely powerful -acceptor. In the hydrolysis and condensation of complexed amides, esters etc. , metals act both as templates and as tunable and poly functional Lewis acids. Here the control of hydrophobic and steric interactions begins to model the subtle mechanisms of biological specificity. Finally, phosphorus and sulfur are imporant both as ligand atoms in themselves, and as anchors for other functionalities. I would like to thank all those who have been involved in the writing and production of this work, and also my colleagues old and new, at Glasgow and the University of North Texas, for their support. Paul S. Braterman v CONTENTS 1. Reactions of Coordinated Carbon Dioxide 1 J. D. Miller 1.
Download or read book Exchange Reactions of Five coordinate Nickel II Complexes written by Carol Jane Galles Grimes and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reaction Mechanisms of Metal Complexes written by R W Hay and published by Elsevier. This book was released on 2000-03-01 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands
Download or read book Kinetic Studies of the Ligand Substitution Reactions of Square Planar Platinum II Complexes Containing Ligands with Group IV Elements written by Daniel Patrick McDonald and published by . This book was released on 1974 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Relative Donor Strengths of Solvents Toward Nickel II Ion and Their Effect on the Kinetics of Ligand Substitution Reactions at Nickel II Ion written by Dominick Frollini and published by . This book was released on 1980 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Kinetics of the Exchange Reactions of Various 4 substituted 3 picoline N oxides with Their Six coordinate Nickel II Complexes written by Mark Lee Yount and published by . This book was released on 1971 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Kinetic Study of Some Ligand Substitution Reactions written by Chin-tung Lin and published by . This book was released on 1967 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Chemical Kinetic Study of Substitution Reaction in Coordination Compounds Involving Transition metal Ions Having the D8 Electronic Configuration written by David J. MacDonald and published by . This book was released on 1968 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Detailed studies were completed of the kinetics and mechanisms of the acid hydrolyses of the Ni(II) and Pd(II) complexes with ethylenebisbiguanide. The stability constant for the Ni(II) complex with ethylenebisbiguanidde was determined. Employing a computer program developed from evaluating the ionization constants of ethylene bisbiguanidinium ion, the two acid dissociation constants of squaric acid were redetermined. (Author).
Download or read book Mechanisms of Reactions of Metal Complexes written by Debabrata Banerjea and published by Royal Society of Chemistry. This book was released on 2022-09-21 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
Download or read book Annual Reports on NMR Spectroscopy written by and published by Academic Press. This book was released on 1975-12-03 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annual Reports on NMR Spectroscopy
