Download or read book Use of Passive Sampling to Measure the Bioavailability of Chemical Contaminants in Surface Waters and Soil written by Kelly L. O'Neal and published by . This book was released on 2015 with total page 95 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Passive Sampling Techniques in Environmental Monitoring written by Richard Greenwood and published by Elsevier. This book was released on 2007-07-03 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monitoring pollutants in air, soil and water is a routine requirement in the workplace, and in the wider environment. Passive samplers can provide a representative picture of levels of pollutants over a period of time from days to months by measuring the average concentrations to which they have been exposed. Air monitors are widely used, for instance to measure the exposure of workers to volatile compounds, but also for monitoring the fate of pollutants in the atmosphere. Passive sampling devices are now becomining increasingly used to monitor pollutants in rivers, coastal waters and ground water where contamination results from sources such as domestic and industrial discharges, and the use of agrochemicals. Passive Sampling Techniques in Environmental Monitoring provides a timely collection of information on a set of techniques that help monitor the quality of air, surface and ground waters. Passive sampling can provide an inexpensive means of obtaining a representative picture of quality over a period of time, even where levels of pollutants fluctuate due to discontinuous discharges or seasonal application of chemicals such as pesticides. Recent changes in legislation have increased the pressure to obtain better information than that provided by classical infrequent spot sampling.Brought together in one source, this book looks at the performance of a range of devices for the passive sampling of metals, and of non-polar and polar organic chemicals in air and in water. The strengths and weaknesses and the range of applicability of the technology are considered.* Comprehensive review of passive sampling - covering air, water and majority of available technologies in one volume* Chapters written by international specialist experts * Covers theory and applications, providing background information and guidelines for use in the field
Download or read book Bioavailability of Contaminants in Soils and Sediments written by National Research Council and published by National Academies Press. This book was released on 2003-05-03 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioavailability refers to the extent to which humans and ecological receptors are exposed to contaminants in soil or sediment. The concept of bioavailability has recently piqued the interest of the hazardous waste industry as an important consideration in deciding how much waste to clean up. The rationale is that if contaminants in soil and sediment are not bioavailable, then more contaminant mass can be left in place without creating additional risk. A new NRC report notes that the potential for the consideration of bioavailability to influence decision-making is greatest where certain chemical, environmental, and regulatory factors align. The current use of bioavailability in risk assessment and hazardous waste cleanup regulations is demystified, and acceptable tools and models for bioavailability assessment are discussed and ranked according to seven criteria. Finally, the intimate link between bioavailability and bioremediation is explored. The report concludes with suggestions for moving bioavailability forward in the regulatory arena for both soil and sediment cleanup.
Download or read book Advances in Passive Sampling written by Carey E. Donald and published by . This book was released on 2017 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive sampling devices have been used for decades to measure complex mixtures of bioavailable organic chemicals in a variety of environmental media. More recently passive sampler applications have expanded beyond monitoring chemical concentrations, and this dissertation continues to advance methods of passive sampling on many fronts. Despite their growing use, no practical, evidence-based guidelines exist to ensure concentrations of chemicals sequestered in passive samplers are stable in transport and storage. We demonstrated that concentrations of semivolatile chemicals sequestered within passive samplers would be stable with low-cost shipping from isolated locales by simulating in the laboratory a worst-case scenario at 35 °C for two weeks. Quantitative measures of the flux of semivolatile chemicals between soil and air have been limited by the challenges of collecting soil and estimating chemical fugacity from soil. We avoided these pitfalls by adapting passive sampling equipment to directly sample gas-phase chemicals in air above the soil. The sensitivity of the novel technique was demonstrated at three disparate sites, where volatilization was measured at a site with historically contaminated soil, and deposition was measured at another site with a recent oil spill and fire. In a related study, we deployed the same equipment on artificial turf fields to provide the first quantitative measure of semivolatile flux between artificial turf and overlying air. We detected an additional 26 compounds that have not been previously associated with artificial turf, including some that have known human health impacts. Finally, passive sampling principles were applied to measure chemicals in the human personal environment, using a newly-developed silicone passive sampler wristband. Nineteen pesticides were detected that were not reportedly used among 35 rural farmer participants, demonstrating the utility of the wristband in measuring personal exposures to pesticides. Pesticide concentrations in multiple wristbands, worn by a participant over time, were more similar to each other than to other participants, signifying the uniqueness of personal environments and the importance of taking personalized measurements when assessing risk. The advancements in this dissertation capitalize on the features of passive sampling techniques: easy, yet robust, transport capabilities were demonstrated to provide evidence-based transport criteria; ability to directly measure gas-phase chemicals led to quantitative flux measurements from soil and artificial turf; non-selective organic chemical sequestration allowed for identification of unexpected, or previously unreported chemicals; and the polymer qualities that mimic biological membranes sampled the bioavailable fraction for comparing human exposures. The advancements herein provide logistical solutions and sensitive measures of chemical transport and human exposures, and contribute to the expanding range of possibilities for passive sampling.
Download or read book Evaluation of Passive Samplers for the Monitoring of Contaminants in Sediment and Water written by Martin Larsen and published by Nordic Council of Ministers. This book was released on 2009 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive samplers spiked with performance reference compounds (PRC) were prepared in Holland, and deployed at 9 sites in the Nordic countries and Greenland. Mussels were collected at the same sites to compare passive sampler results with the mussel-watch approach usually applied in national monitoring. Sediments were sampled from 6 sites, and analysed both by total methods and passive samplers for pore water concentration. From the spiked PRCs, sampling rates was calculated, and used to determine water phase concentration of PAHs and other organic compounds with a high octanol-water partitioning coefficient. The project has shown that silicone passive samplers can be used for monitoring programmes, and development of guidelines and quality assurance of analysis are underway. Within the next 2-3 years it could become part of the monitoring strategy of OSPAR, EU and the Nordic Countries.
Download or read book Solutions Manual to Accompany Fundamentals of Environmental Sampling and Analysis written by Chunlong Zhang and published by John Wiley & Sons. This book was released on 2024-07-04 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the Solutions Manual to accompany Fundamentals of Environmental Sampling and Analysis, Second Edition. It provides solutions to the exercises and problems found in the main volume This book introduces a comprehensive overview on the fundamentals and applications of environmental sampling and analysis for students in environmental science and engineering as well as environmental professionals involved in sampling and analytical work. The book details fundamentals of sampling, selection of standard methods, QA/QC, sample preparation, chemical and instrumental principles, and method applications to various contaminants in environmental matrices (air, water, soil, waste, and biological samples). The book gives an integrated introduction to sampling and analysis – both are essential to quality environmental data. For example, contrary to other books that introduce a specific area of sampling and analysis, this text provides a balanced mix of field sampling and laboratory analysis, essential knowledge in chemistry/statistics/hydrology/regulations, wet chemical methods for conventional chemicals as well as various modern instrumental techniques for contaminants of emerging concerns. The new edition adds three standalone chapters regarding the basics of analytical and organic chemistry, environmental data analysis, mass spectrometry and other significant amounts of new materials such as time-integrated passive sampling, incremental sampling, green sample preparation, Raman spectroscopy, chiral separation, and non-target analysis. In addition, the second edition provides more examples, visual aids, case studies, and end-of-chapter exercise problems to enhance a better understanding of the fundamentals of environmental sampling and analysis while incorporating current literature (mostly peer-reviewed journal papers) regarding the applications and challenges in the field of environmental sampling and analysis.
Download or read book Encyclopedia of Aquatic Ecotoxicology written by Jean-Francois Férard and published by Springer. This book was released on 2013-06-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its 104 chapters, this Encyclopedia of aquatic ecotoxicology reveals the diversity of issues, problems and challenges that have faced, and are facing today, receiving environments. It also indicates ways by which tools, strategies and future investigations can contribute to correct, minimize, solve and prevent water quality degradation. Structured homogeneously, the chapters convey salient information on historical background, features, characteristics, uses and/or applications of treated topics, often complemented by illustrations and case studies, as well as by conclusions and prospects. This work is most suitable for teaching purposes. Academics, for example, could literally deliver comprehensive lectures to students simply based on chapter outlines and contents. Meet the Authors of the Encyclopedia! Check out 'Meet the Authors' under ADDITIONAL INFORMATION (Right menu).
Download or read book Development of Innovative Applications for Passive Sampling Devices written by Sarah E. Allan and published by . This book was released on 2011 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemicals must be bioavailable for there to be a potential for exposure and consequent risk to human or environmental health. Passive sampling devices (PSDs) are used to quantify the time-integrated concentration of bioavailable contaminants. We demonstrate that PSDs can be paired with the zebrafish developmental toxicity bioassay to produce site-specific, temporally resolved information about the toxicity of environmental samples. Furthermore, modeling associations between the chemical components of environmental mixtures and the toxic outcomes they elicit can link bioactive compounds to biological effects. This research also shows that PSDs can be used as direct biological surrogates in a risk assessment model. We were able to determine spatial and seasonal variations in exposure and risk from the consumption of polycyclic aromatic hydrocarbons (PAH) in organisms from the Portland Harbor Superfund that were not detected in the Public Health Assessment for the area. Additionally, PSDs are a tool that we were able to rapidly deploy after the Deepwater Horizon oil spill. We quantified biologically relevant PAH contamination on a large spatial scale, over a long period of time when the chemicals of concern were present at relatively low dissolved concentrations, their impact on certain areas was sporadic and their presence and toxicological significance were not easily visualized. The research presented here can be applied to improve environmental monitoring, mixture toxicity assessment and risk assessment.
Download or read book Fundamentals of Environmental Sampling written by Keith Bodger and published by Rowman & Littlefield. This book was released on 2003 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: This easy-to-use reference not only provides you with a basic understanding of environmental sampling concepts, but it also provides you with the information you need to perform your tasks with ease and efficiency. Whether you use it to train samplers or take it in the field with you for easy reference, Fundamentals of Environmental Sampling contains information all samplers need to better understand the science of their work. You will review key principles of geology and chemistry, and you will examine typical sampling techniques and their relationship to EPA and ASTM guidelines. The author discusses how these sample collection techniques affect analytical data and how data collection methods affect the validity and defensibility of data in a court of law. In addition, you will examine project management fundamentals, challenges of working in natural environments, and managing data and reporting to the client. Fundamentals of Environmental Sampling covers major sampling media--including groundwater, soil, surface water, and air--and discusses how to choose the right equipment for each job. A list of "must have" tools is included in the author's recommended "Ideal Tool Kit" along with common uses for each, descriptions of usage, and tips on buying them.
Download or read book Passive Sampling Devices PSDs as Biological Surrogates for Estimating the Bioavailability of Organic Chemicals in Soil written by JB. Wells and published by . This book was released on 2000 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic chemical exposure in soil toxicity tests and in ecological risk assessment of terrestrial systems is usually expressed as the total chemical measured. Possible alternatives to total chemical measures of organic chemical bioavailability and exposure include body residues in test organisms, soil extraction with selective solvents, and passive sampling devices (PSDs) as biological surrogates. Semipermeable membrane devices (SPMDs) offer potential as a biological surrogate in soil systems. Solid-phase microextraction (SPME) fibers are a rapid and sensitive means for detecting PAHs in soil and have the advantage of not requiring solvent extraction of soil. The objective of this study was to compare chemical uptake and residues in earthworms, SPMDs, and SPMEs exposed in artificial soil spiked with phenanthrene (PHE). Bioavailable PHE, as assessed by mortality and PHE body residues, varied dramatically with soil organic matter content. Both SPMEs and SPMDs could discriminate differences in PHE availability between treatments. However, PHE levels measured using SPMEs were more precise and allowed discrimination between toxic and non-toxic levels of PHE, while PHE levels in SPMDs were too variable for use as a predictive tool.
Download or read book Development and Evaluation of Passive Sampling Devices to Characterize the Sources Occurrence and Fate of Polar Organic Contaminants in Aquatic Systems written by Jonathan K. Challis and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The primary goal of this dissertation was to develop and evaluate an improved aquatic passive sampling device (PSD) for measurement of polar organic contaminants. Chemical uptake of current polar-PSDs (e.g., POCIS - polar organic chemical integrative sampler) is dependent on the specific environmental conditions in which the sampler is deployed (flow-rate, temperature), leading to large uncertainties when applying laboratory-derived sampling rates in-situ. A novel configuration of the diffusive gradients in thin-films (DGT) passive sampler was developed to overcome these challenges. The organic-DGT (o-DGT) configuration comprised a hydrophilic-lipophilic balance® sorbent binding phase and an outer agarose diffusive gel (thickness = 0.5-1.5 mm), notably excluding a polyethersulfone protective membrane which is used with all other polar-PSDs. Sampler calibration exhibited linear uptake and sufficient capacity for 34 pharmaceuticals and pesticides over typical environmental deployment times, with measured sampling rates ranging from 9-16 mL/d. Measured and modelled diffusion coefficients (D) through the outer agarose gel provided temperature-specific estimates of o-DGT sampling rates within 20% (measured-D) and 30% (modelled-D) compared to rates determined through full-sampler calibration. Boundary layer experiments in lab and field demonstrated that inclusion of the agarose diffusive gel negated boundary layer effects, suggesting that o-DGT uptake is largely insensitive to hydrodynamic conditions. The utility of o-DGT was evaluated under a variety of field conditions and performance was assessed in comparison to POCIS and grab samples. o-DGT was effective at measuring pharmaceuticals and pesticides in raw wastewater effluents, small creeks, large fast-flowing rivers, open-water lakes, and under ice at near-zero water temperatures. Concentrations measured by o-DGT were more accurate than POCIS when compared to grab samples, likely resulting from the influence in-situ conditions have on POCIS. Modelled sampling rates were successfully used to estimate semi-quantitative water concentrations of suspect wastewater contaminants using high-resolution mass spectrometry, demonstrating the unique utility of this o-DGT technique. This dissertation establishes o-DGT as a more accurate, user-friendly, and widely applicable passive sampler compared to current-use polar-PSDs. The o-DGT tool will help facilitate more accurate and efficient monitoring efforts and ultimately lead to more appropriate exposure data and environmental risk assessment.
Download or read book NORMAN Interlaboratory Study ILS on Passive Sampling of Emerging Pollutants written by and published by . This book was released on 2016 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt: Passive samplers can play a valuable role in monitoring water quality within a legislative framework such as the European Union's Water Framework Directive (WFD). The time-integrated data from these devices can be used to complement chemical monitoring of priority and emerging contaminants which are difficult to analyse by spot or bottle sampling methods, and to improve risk assessment of chemical pollution. In order to increase the acceptance of passive sampling technology amongst end users and to gain further information about the robustness of the calibration and analytical steps, several inter-laboratory field studies have recently been performed in Europe. Such trials are essential to further validate this sampling method and to increase the confidence of the technological approach for end users.^An inter-laboratory study on the use of passive samplers for the monitoring of emerging pollutants was organised in 2011 by the NORMAN association (Network of reference laboratories for monitoring emerging environmental pollutants; www.norman-network.net) together with the European DG Joint Research Centre to support the Common Implementation Strategy of the WFD. Thirty academic, commercial and regulatory laboratories participated in the passive sampler comparison exercise and each was allowed to select their own sampler design. All the different devices were exposed at a single sampling site to treated waste water from a large municipal treatment plant. In addition, the organisers deployed in parallel for each target analyte class multiple samplers of a single type which were subsequently distributed to the participants for analysis. This allowed an evaluation of the contribution of the different analytical laboratory procedures to the data variability.^The results obtained allow an evaluation of the potential of different passive sampling methods for monitoring selected emerging organic contaminants (pharmaceuticals, polar pesticides, steroid hormones, fluorinated surfactants, triclosan, bisphenol A and brominated flame retardants). In most cases, between laboratory variation of results from passive samplers was roughly a factor 5 larger than within laboratory variability. Similar results obtained for different passive samplers analysed by individual laboratories and also low within laboratory variability of sampler analysis indicate that the passive sampling process is causing less variability than the analysis. This points at difficulties that laboratories experienced with analysis in complex environmental matrices. Where a direct comparison was possible (not in case of brominated flame retardants) analysis of composite water samples provided results that were within the concentration range obtained by passive samplers.^However, in the future a significant improvement of the overall precision of passive sampling is needed. The results will be used to inform EU Member States about the potential application of passive sampling methods for monitoring organic chemicals within the framework of the WFD.
Download or read book Development and Application of a New Passive Sampling Device written by Lucas W. Quarles and published by . This book was released on 2010 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contaminants can exist in a wide range of states in aqueous environments, especially in surface waters. They can be freely dissolved or associated with dissolved or particulate organic matter depending on their chemical and physical characteristics. The freely dissolved fraction represents the most bioavailable fraction to an organism. These freely dissolved contaminants can cross biomembranes, potentially exerting toxic effects. Passive sampling devices (PSDs) have been developed to aid in sampling many of these contaminants by having the ability to distinguish between the freely dissolved and bound fraction of a contaminant. A new PSD, the Lipid-Free Tube (LFT) sampler was developed in response to some of the shortcomings of other current PSD that sample hydrophobic organic contaminants (HOCs). The device and laboratory methods were original modeled after a widely utilized PSD, the semipermeable membrane device (SPMD), and then improved upon. The effectiveness, efficiency, and sensitivity of not only the PSD itself, but also the laboratory methods were investigated. One requirement during LFT development was to ensure LFTs could be coupled with biological analyses without deleterious results. In an embryonic zebrafish developmental toxicity assay, embryos exposed to un-fortified LFT extracts did not show significant adverse biological response as compared to controls. Also, LFT technology lends itself to easy application in monitoring pesticides at remote sampling sites. LFTs were utilized during a series of training exchanges between Oregon State University and the Centre de Recherches en Ecotoxicologie pour le Sahel (CERES)/LOCUSTOX laboratory in Dakar, Senegal that sought to build "in country" analytical capacity. Application of LFTs as biological surrogates for predicting potential human health risk endpoints, such as those in a public health assessment was also investigated. LFT mass and accumulated contaminant masses were used directly, representing the amount of contaminants an organism would be exposed to through partitioning assuming steady state without metabolism. These exposure concentrations allow for calculating potential health risks in a human health risk model. LFT prove to be a robust tool not only for assessing bioavailable water concentrations of HOCs, but also potentially providing many insights into the toxicological significance of aquatic contaminants and mixtures.
Download or read book Passive Sampling Devices as Biological Surrogates for Evaluating Seasonal Bioavailability of Hydrophobic Organic Contaminants in Surface Water written by Doolalai Sethajintanin and published by . This book was released on 2005 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Environmental Sampling and Analysis written by Lawrence H. Keith and published by CRC Press. This book was released on 1991-03-18 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: This concise book covers all the critical aspects of environmental sampling and analysis. Extensively peer-reviewed by scientists from the U.S. Environmental Protection Agency and other government agencies, industry and academia, it is packed with practical advice and tips from renowned experts. Planning, sampling, analysis, QA/QC, and reporting are discussed for air, water, solid liquid, and biological samples, with emphasis on the interdependence between sampling and analytical activities. Special requirements for sampling devices, containers, and preservatives are provided with convenient checklists for sampling plans and protocols. New and revised recommendations involving method detection levels, reliable detection levels, and levels of quantitation are discussed in conjunction with laboratory reports and user presentations of data near analytical detection limits. This is a valuable and comprehensive reference book for chemists, technicians, consultants, lawyers, regulators, engineers, quality control officers, news and information managers, teachers, and students.
Download or read book Biophysico Chemical Processes of Anthropogenic Organic Compounds in Environmental Systems written by Baoshan Xing and published by John Wiley & Sons. This book was released on 2011-05-16 with total page 922 pages. Available in PDF, EPUB and Kindle. Book excerpt: In contrast to the classical books which largely focus on separate, individual physicochemical and biological aspects, this book aims to integrate the frontiers of knowledge on the fundamentals and the impact of physicochemical and biological interactions and processes of AOCs in soil, sediment, water and air. The specific objectives of this book are to address: (1) fundamental biophysico-chemical processes of AOCs in the environment, (2) occurrence and distribution of AOCs in air, water, and soil, and their global cycling, (3) the state-of-the-art analytical techniques of AOCs, and (4) restoration of natural environments contaminated by AOCs. The book also identifies the gaps in knowledge on the subject matter and as such provides future directions to stimulate scientific research to advance the chemical science on biophysico-chemical interfacial reactions in natural habitats. By virtue of complex nature of the interactions of AOCs with different environmental components and matrixes, no single available technique and instrument is satisfactory yet for determining their fate, transport, availability, and risk in the environment. In order to fully understand the biophysico-chemical interactions and processes of AOCs in the environment, it is critical to know chemical, physical and biological properties of AOCs and their analytical techniques. The book is unique because of its multidisciplinary approach as it provides a comprehensive and integrated coverage of biophysico-chemical reactions and processes of AOCs in various environments, associated analytical techniques, and restoration of natural environments contaminated by AOCs.
Download or read book Guidelines for the Use of the Semipermeable Membrane Device Spmd and the Polar Organic Chemical Integrative Sampler Pocis in Environmental Monitoring Studies written by David A. Alvarez and published by CreateSpace. This book was released on 2014-06-16 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt: The success of an environmental monitoring study using passive samplers, or any sampling method, begins in the office or laboratory. Regardless of the specific methods used, the general steps include the formulation of a sampling plan, training of personnel, performing the field (sampling) work, processing the collected samples to recover chemicals of inter- est, analysis of the enriched extracts, and interpretation of the data. Each of these areas will be discussed in the following sections with emphasis on specific considerations with the use of passive samplers.
