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Book Tunneling Spectroscopy on an Atomically Thin Transition Metal Dichalcogenide Superconductor

Download or read book Tunneling Spectroscopy on an Atomically Thin Transition Metal Dichalcogenide Superconductor written by Egon Sohn and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Two dimensional (2D) materials have become very popular in the last decade. Among the many available 2D materials, 2H-NbSe2, which is one compound of the transition metal dichalcogenide (TMD) family, represents the 2D superconductors. The TMDs are unique in a sense that when the bulk is thinned down to a monolayer limit, inversion symmetry is broken. Together with the strong spin-orbit coupling, spin degeneracy is broken in each band and leads to electron spins pinned in out-of-plane direction, which are opposite in direction for opposite momentum. These are called Ising spins. Unlike the conventional superconductors which freely rotating spins pair, the Cooper pairs in 2D-NbSe2 are formed by Ising spins. This results in unconventional superconducting properties. We take advantage of the unique aspect of atomically thin superconductors which is the quenched orbital depairing effect under in-plane magnetic field and study the spin properties of the superconducting state. In the first part of this dissertation (Chapter 3), we study the superconducting properties of 2D-NbSe2 under large in-plane magnetic field. We characterize the magnetic field versus temperature phase diagram of one- to three-layer NbSe2 by electrical transport measurement and find an enhanced upper critical field, several times larger than the Pauli paramagnetic limit. By fitting the results to the pair breaking equation, we confirm large spin-orbit field in 2D-NbSe2. We fabricate planer tunneling junctions and measure differential conductance spectra under in-plane magnetic field. The superconducting gap is obtained by fitting the data with the Blonder-Tinkham-Klapwijk (BTK) model. We find that there is a second-order transition in contrast to first-order transition observed in conventional superconductors. The enhanced upper critical field and the second-order phase transition both suggests finite spin susceptibility in the superconducting state which originates from the mixed spin singlet-triplet Cooper pair wave function present in noncentrosymmetric superconductors. In the second part (Chapter 4), we study the in-plane magnetic field response of the two superconducting gaps of 2D-NbSe2 and show there is a possible field driven nodal phase transition in the [gamma]-pocket superconducting order parameter. This is achieved by fabricating high-quality tunneling devices in which the differential conductance spectrum reflects the density of states. We were able to fit the data with a two-gap Bardeen-Cooper-Schrieffer density of states and identify the two superconducting gaps in 2D-NbSe2. The distinct behavior of the two superconducting gaps are explained in terms of the different spin-orbit coupling strength of the K- and [gamma]-pocket, which is also consistent with earlier theoretical studies that suggest a magnetic field driven nodal superconducting phase. We also discuss limitations in our measurement that prevents us from discerning between a nodal and a fully gapped superconducting phase in high magnetic field. In the last part (Chapter 5), we construct tunneling devices with either a magnetic barrier or a magnetic material and observe a novel two-fold symmetry in the differential conductance spectra. We fit the measured spectra with a two-gap BTK model and find that the weight of the two gaps and the superconducting order parameter depends on in-plane magnetic field direction and field strength. Our observation is explained in terms of competing superconducting channels which stabilizes by small symmetry breaking fields such as strain or external magnetic field.

Book Tunneling Spectroscopy Studies of Superconductors

Download or read book Tunneling Spectroscopy Studies of Superconductors written by Basu Dev Oli and published by . This book was released on 2021 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: In multiband superconductors, different bands at the Fermi surface contribute to the superconductivity with different magnitudes of superconducting gaps on different portions of the Fermi surface. Each band in a multiband superconductor has a condensate with an amplitude and phase that weakly interacts with the other bands' condensate. The coupling strength between the bands determines whether one or two superconducting transition temperatures are observed, and it is the key to many peculiar properties. In general, if there are two gaps of different magnitude, there are two different length scales associated with the suppression of these gaps in applied magnetic fields, for example. Therefore, effects of multigap superconductivity can be observed in superconducting vortices, which are twirls of supercurrents that are generated when a superconductor is placed in a magnetic field. Furthermore, the two superconducting order parameters in different bands are characterized by a magnitude and phase. In multiband superconductors, there are collective excitations corresponding to fluctuations of the relative phase of two order parameters, so-called the Leggett mode. The first material identified as multiband superconductor is Magnesium Diboride (MgB2) in 2001 with a critical temperature Tc of 39 K. MgB2 is a superconducting material with the highest transition temperature among all conventional BCS superconductors. It has two superconducting gaps \Delta_\pi ~ 2 meV and \Delta_\sigma\ ~ 7 meV and they arise from the existence of two bands \pi and \sigma bands of boron electrons. The discovery of superconductivity in MgB2 renewed interest in the field of multiband superconductivity. MgB2 has attracted many scientists' attention both for the fundamental importance of understanding the multiband superconductivity and possible applications such as magnets, power cables, bolometers, Josephson junction-based electronic devices, and radio-frequency cavities. Afterward, other materials have been identified as multiband superconductors such as NbSe2, the family of iron-based superconductors, heavy fermion superconductors, multilayer cuprates, borocarbides, etc. This dissertation uses tunneling experiments to highlight multiband superconductivity features in two systems, namely MgB2 thin films and ultrathin films of Pb. Further, we use multiple techniques to study a superconducting material, nitrogen-doped niobium, used for superconducting radio-frequency cavities. For the project on MgB2, MgB2/Native-Oxide/Ag planar junctions are fabricated and characterized down to 2.1 K and in the magnetic field parallel to the sample surface up to 6 Tesla. This work investigates how pairbreaking affects the magnitude and phase of the order parameter in a multiband superconductor. The tunneling spectra are analyzed in the framework of a two-band model developed by our theory collaborator Prof. Alex Gurevich, Old Dominion University. The model allows the extraction of the pair-breaking parameters among other quantities. The analysis shows that the order parameter in the ? band is quickly suppressed in the field, the ? band is cleaner than the ? band. The ratio of pairbreaking parameter in the ? band to the ? band rapidly increases at fields higher than ~0.1 T and then plateau at higher fields. This transition around 0.1 T magnetic field suggests a phase decoupling in the two bands of MgB2. Below the transition, the two bands are phase-locked, so mostly, the superconductivity in the ? band is affected, and after phase decoupling, both bands are affected by the applied field. These results are important for a basic understanding of multiband superconductors and the application implications of this material. This phase decoupling has a new and profound consequence on the superconducting state of a multiband superconductor that has been theoretically predicted and never observed experimentally. For the Pb project, ultrathin films of Pb in ultrahigh vacuum conditions are deposited by e-beam evaporation and characterized with low-temperature scanning tunneling microscopy and spectroscopy (STM/STS). The STM/STS allows measuring the electronic density of states with the highest spatial resolution down to atomic scale. The shape of a superconducting vortex core is determined by the superconducting gap and the Fermi velocity, and the STM allows to map anisotropies of these quantities spatially. The vortex cores of Pb film show a complex shape that evolves from triangular at short distances from the center to a six-fold symmetric star shape farther away from the center. These details are very subtle, and they can be highlighted only if one works within the clean limit (to avoid the averaging effect of the scattering) and by fabricating the heterostructure that pins the vortices spatially. The complex vortex core shape reflects the anisotropy of the two bands that contribute to superconductivity in this material. For the project on Niobium, cold and hot spots from nitrogen-doped Nb cutouts are characterized by low temperature scanning tunneling microscopy and spectroscopy (STM/STS) combined with X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). The radiofrequency (RF) measurements of the quality factor and temperature mapping on an N-doped Nb superconducting resonator cavity are carried out at Jefferson Laboratory before cutting out the samples. This work aims to identify possible sources of excess dissipation in hot spots and relate them to the surface chemical composition and superconducting properties. The temperature mapping revealed a strong effect of the cavity cooldown rate on the intensities of hot spots and their spatial distribution, which indicates a significant contribution of trapped vortices to the RF dissipation. SEM images acquired on the cold and hot spots using a secondary electron detector show absence of residual hydride scars and niobium nitrides on their surface. Angle-resolved XPS measurements on the native surface of these samples revealed higher oxidized Nb 3d states on the N-doped Nb cold spots, which is supported by XPS depth profiles done on the samples by Argon ion sputtering. Argon ion sputtering of oxidized Nb removes oxygen preferentially from Nb2O5 and diffuses to bulk, thickening the lower oxidation state layers. The proximity theory framework's tunneling spectra analysis suggests hot spots have stronger pairbreaking due to a weakly reduced pair potential, a thicker metallic suboxide layer, and a wide distribution of the contact resistance. STM imaging of vortex cores shows a triangular vortex lattice in both samples, and the coherence length is nearly the same in hot and cold spots. The experimental data analysis suggests weakly degraded superconducting properties at the surface of hot spot regions are not the primary sources of RF losses. Instead, they are the regions where vortices nucleate first and get trapped during cooling down. These experimental techniques and findings will be crucial in helping to qualify new recipes for SRF cavity production and to boost their performance.

Book Ultrathin Two Dimensional Semiconductors for Novel Electronic Applications

Download or read book Ultrathin Two Dimensional Semiconductors for Novel Electronic Applications written by Mohammad Karbalaei Akbari and published by CRC Press. This book was released on 2020-07-30 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering perspective on both the scientific and engineering aspects of 2D semiconductors, Ultrathin Two-Dimensional Semiconductors for Novel Electronic Applications discusses how to successfully engineer 2D materials for practical applications. It also covers several novel topics regarding 2D semiconductors which have not yet been discussed in any other publications. Features: Provides comprehensive information and data about wafer-scale deposition of 2D semiconductors, ranging from scientific discussions up to the planning of experiments and reliability testing of the fabricated samples Precisely discusses wafer-scale ALD and CVD of 2D semiconductors and investigates various aspects of deposition techniques Covers the new group of 2D materials synthesized from surface oxide of liquid metals and also explains the device fabrication and post-treatment of these 2D nanostructures Addresses a wide range of scientific and practical applications of 2D semiconductors and electronic and optoelectronic devices based on these nanostructures Offers novel coverage of 2D heterostructures and heterointerfaces and provides practical information about fabrication and application of these heterostructures Introduces the latest advancement in fabrication of novel memristors, artificial synapses and sensorimotor devices based on 2D semiconductors This work offers practical information valuable for engineering applications that will appeal to researchers, academics, and scientists working with and interested in developing an array of semiconductor electronic devices.

Book Non Centrosymmetric Superconductors

Download or read book Non Centrosymmetric Superconductors written by Ernst Bauer and published by Springer Science & Business Media. This book was released on 2012-01-10 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Superconductivity in materials without inversion symmetry in the respective crystal structures occurs in the presence of antisymmetric spin-orbit coupling as a consequence of an emerging electric field gradient. The superconducting condensate is then a superposition of spin-singlet and spin-triplet Cooper pairs. This scenario accounts for various experimental findings such as nodes in the superconducting gap or extremely large upper critical magnetic fields. Spin-triplet pairing can occur in non-centrosymmetric superconductors in spite of Anderson’s theorem that spin-triplet pairing requires a crystal structure that exhibits inversion symmetry. This book, authored and edited by leading researchers in the field, is both an introduction to and overview on this exciting branch of novel superconductors. Its self-contained and tutorial style makes it particularly suitable for self-study and as source of teaching material for special seminars and courses. At the same time it constitutes an up-to-date and authoritative reference for anyone working in this exciting field.

Book Two Dimensional Transition Metal Dichalcogenides

Download or read book Two Dimensional Transition Metal Dichalcogenides written by Narayanasamy Sabari Arul and published by Springer. This book was released on 2019-07-30 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents advanced synthesis techniques adopted to fabricate two-dimensional (2D) transition metal dichalcogenides (TMDs) materials with its enhanced properties towards their utilization in various applications such as, energy storage devices, photovoltaics, electrocatalysis, electronic devices, photocatalysts, sensing and biomedical applications. It provides detailed coverage on everything from the synthesis and properties to the applications and future prospects of research in 2D TMD nanomaterials.

Book Advanced Biosensors for Health Care Applications

Download or read book Advanced Biosensors for Health Care Applications written by Dr. Inamuddin and published by Elsevier. This book was released on 2019-06-15 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Biosensors for Health Care Applications highlights the different types of prognostic and diagnostic biomarkers associated with cancer, diabetes, Alzheimer's disease, brain and retinal diseases, cardiovascular diseases, bacterial infections, as well as various types of electrochemical biosensor techniques used for early detection of the potential biomarkers of these diseases. Many advanced nanomaterials have attracted intense interests with their unique optical and electrical properties, high stability, and good biocompatibility. Based on these properties, advanced nanoparticles have been used as biomolecular carriers, signal producers, and signal amplifiers in biosensor design. Recent studies reported that there are several diagnostic methods available, but the major issue is the sensitivity and selectivity of these approaches. This book outlines the need of novel strategies for developing new systems to retrieve health information of patients in real time. It explores the potential of nano-multidisciplinary science in the design and development of smart sensing technology using micro-nanoelectrodes, novel sensing materials, integration with MEMS, miniaturized transduction systems, novel sensing strategy, that is, FET, CMOS, System-on-a-Chip (SoC), Diagnostic-on-a-Chip (DoC), and Lab-on-a-Chip (LOC), for diagnostics and personalized health-care monitoring. It is a useful handbook for specialists in biotechnology and biochemical engineering. Describes advanced nanomaterials for biosensor applications Relates the properties of available nanomaterials to specific biomarkers applications Includes diagnosis and electrochemical studies based on biosensors Explores the potential of nano-multidisciplinary science to design and develop smart sensing technologies Describes novel strategies for developing a new class of assay systems to retrieve the desired health information

Book Two Dimensional Transition Metal Dichalcogenides

Download or read book Two Dimensional Transition Metal Dichalcogenides written by Alexander V. Kolobov and published by Springer. This book was released on 2016-07-26 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes the current status of theoretical and experimental progress in 2 dimensional graphene-like monolayers and few-layers of transition metal dichalcogenides (TMDCs). Semiconducting monolayer TMDCs, due to the presence of a direct gap, significantly extend the potential of low-dimensional nanomaterials for applications in nanoelectronics and nano-optoelectronics as well as flexible nano-electronics with unprecedented possibilities to control the gap by external stimuli. Strong quantum confinement results in extremely high exciton binding energies which forms an interesting platform for both fundamental studies and device applications. Breaking of spatial inversion symmetry in monolayers results in strong spin-valley coupling potentially leading to their use in valleytronics. Starting with the basic chemistry of transition metals, the reader is introduced to the rich field of transition metal dichalcogenides. After a chapter on three dimensional crystals and a description of top-down and bottom-up fabrication methods of few-layer and single layer structures, the fascinating world of two-dimensional TMDCs structures is presented with their unique atomic, electronic, and magnetic properties. The book covers in detail particular features associated with decreased dimensionality such as stability and phase-transitions in monolayers, the appearance of a direct gap, large binding energy of 2D excitons and trions and their dynamics, Raman scattering associated with decreased dimensionality, extraordinarily strong light-matter interaction, layer-dependent photoluminescence properties, new physics associated with the destruction of the spatial inversion symmetry of the bulk phase, spin-orbit and spin-valley couplings. The book concludes with chapters on engineered heterostructures and device applications such as a monolayer MoS2 transistor. Considering the explosive interest in physics and applications of two-dimensional materials, this book is a valuable source of information for material scientists and engineers working in the field as well as for the graduate students majoring in materials science.

Book 2D Materials

Download or read book 2D Materials written by Phaedon Avouris and published by Cambridge University Press. This book was released on 2017-06-29 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: Learn about the most recent advances in 2D materials with this comprehensive and accessible text. Providing all the necessary materials science and physics background, leading experts discuss the fundamental properties of a wide range of 2D materials, and their potential applications in electronic, optoelectronic and photonic devices. Several important classes of materials are covered, from more established ones such as graphene, hexagonal boron nitride, and transition metal dichalcogenides, to new and emerging materials such as black phosphorus, silicene, and germanene. Readers will gain an in-depth understanding of the electronic structure and optical, thermal, mechanical, vibrational, spin and plasmonic properties of each material, as well as the different techniques that can be used for their synthesis. Presenting a unified perspective on 2D materials, this is an excellent resource for graduate students, researchers and practitioners working in nanotechnology, nanoelectronics, nanophotonics, condensed matter physics, and chemistry.

Book Semiconductors

Download or read book Semiconductors written by Martin I. Pech-Canul and published by Springer. This book was released on 2019-01-17 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a practical guide to optical, optoelectronic, and semiconductor materials and provides an overview of the topic from its fundamentals to cutting-edge processing routes to groundbreaking technologies for the most recent applications. The book details the characterization and properties of these materials. Chemical methods of synthesis are emphasized by the authors throughout the publication. Describes new materials and updates to older materials that exhibit optical, optoelectronic and semiconductor behaviors; Covers the structural and mechanical aspects of the optical, optoelectronic and semiconductor materials for meeting mechanical property and safety requirements; Includes discussion of the environmental and sustainability issues regarding optical, optoelectronic, and semiconductor materials, from processing to recycling.

Book Materials Fundamentals of Molecular Beam Epitaxy

Download or read book Materials Fundamentals of Molecular Beam Epitaxy written by Jeffrey Y. Tsao and published by Academic Press. This book was released on 2012-12-02 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: The technology of crystal growth has advanced enormously during the past two decades. Among, these advances, the development and refinement of molecular beam epitaxy (MBE) has been among the msot important. Crystals grown by MBE are more precisely controlled than those grown by any other method, and today they form the basis for the most advanced device structures in solid-state physics, electronics, and optoelectronics. As an example, Figure 0.1 shows a vertical-cavity surface emitting laser structure grown by MBE. * Provides comprehensive treatment of the basic materials and surface science principles that apply to molecular beam epitaxy * Thorough enough to benefit molecular beam epitaxy researchers * Broad enough to benefit materials, surface, and device researchers * Referenes articles at the forefront of modern research as well as those of historical interest

Book 2D Monoelemental Materials  Xenes  and Related Technologies

Download or read book 2D Monoelemental Materials Xenes and Related Technologies written by Zongyu Huang and published by CRC Press. This book was released on 2022-04-19 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monoelemental 2D materials called Xenes have a graphene-like structure, intra-layer covalent bond, and weak van der Waals forces between layers. Materials composed of different groups of elements have different structures and rich properties, making Xenes materials a potential candidate for the next generation of 2D materials. 2D Monoelemental Materials (Xenes) and Related Technologies: Beyond Graphene describes the structure, properties, and applications of Xenes by classification and section. The first section covers the structure and classification of single-element 2D materials, according to the different main groups of monoelemental materials of different components and includes the properties and applications with detailed description. The second section discusses the structure, properties, and applications of advanced 2D Xenes materials, which are composed of heterogeneous structures, produced by defects, and regulated by the field. Features include: Systematically detailed single element materials according to the main groups of the constituent elements Classification of the most effective and widely studied 2D Xenes materials Expounding upon changes in properties and improvements in applications by different regulation mechanisms Discussion of the significance of 2D single-element materials where structural characteristics are closely combined with different preparation methods and the relevant theoretical properties complement each other with practical applications Aimed at researchers and advanced students in materials science and engineering, this book offers a broad view of current knowledge in the emerging and promising field of 2D monoelemental materials.

Book Introduction to Superconductivity

Download or read book Introduction to Superconductivity written by Michael Tinkham and published by Courier Corporation. This book was released on 2004-06-14 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accessible to graduate students and experimental physicists, this volume emphasizes physical arguments and minimizes theoretical formalism. Topics include the Bardeen-Cooper-Schrieffer and Ginzburg-Landau theories, magnetic properties of classic type II superconductors, the Josephson effect, fluctuation effects in classic superconductors, high-temperature superconductors, and nonequilibrium superconductivity. 109 figures. 1996 edition.

Book Density Waves In Solids

Download or read book Density Waves In Solids written by George Gruner and published by CRC Press. This book was released on 2018-03-08 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: ?Density Waves in Solids is written for graduate students and scientists interested in solid-state sciences. It discusses the theoretical and experimental state of affairs of two novel types of broken symmetry ground states of metals, charge, and spin density waves. These states arise as the consequence of electron-phonon and electron-electron interactions in low-dimensional metals.Some fundamental aspects of the one-dimensional electron gas, and of the materials with anisotropic properties, are discussed first. This is followed by the mean field theory of the phases transitions?discussed using second quantized formalism?together with the various experimental observations on the transition and on the ground states. Fluctuation effects and the collective excitations are reviewed next, using the Ginzburg-Landau formalism, followed by the review of the interaction of these states with the underlying lattice and with impurities. The final chapters are devoted to the response of the ground states to external perturbations.

Book Applied Superconductivity

Download or read book Applied Superconductivity written by Paul Seidel and published by John Wiley & Sons. This book was released on 2015-03-23 with total page 1334 pages. Available in PDF, EPUB and Kindle. Book excerpt: This wide-ranging presentation of applied superconductivity, from fundamentals and materials right up to the details of many applications, is an essential reference for physicists and engineers in academic research as well as in industry. Readers looking for a comprehensive overview on basic effects related to superconductivity and superconducting materials will expand their knowledge and understanding of both low and high Tc superconductors with respect to their application. Technology, preparation and characterization are covered for bulk, single crystals, thins fi lms as well as electronic devices, wires and tapes. The main benefit of this work lies in its broad coverage of significant applications in magnets, power engineering, electronics, sensors and quantum metrology. The reader will find information on superconducting magnets for diverse applications like particle physics, fusion research, medicine, and biomagnetism as well as materials processing. SQUIDs and their usage in medicine or geophysics are thoroughly covered, as are superconducting radiation and particle detectors, aspects on superconductor digital electronics, leading readers to quantum computing and new devices.

Book Advances in Condensed Matter and Materials Physics

Download or read book Advances in Condensed Matter and Materials Physics written by Jagannathan Thirumalai and published by BoD – Books on Demand. This book was released on 2020-05-06 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Condensed Matter and Material Physics, incorporates the work of multiple authors to enhance the theoretical as well as experimental knowledge of materials. The investigation of crystalline solids is a growing need in the electronics industry. Micro and nano transistors require an in-depth understanding of semiconductors of different groups. Amorphous materials, on the other hand, as non-equilibrium materials are widely applied in sensors and other medical and industrial applications. Superconducting magnets, composite materials, lasers, and many more applications are integral parts of our daily lives. Superfluids, liquid crystals, and polymers are undergoing active research throughout the world. Hence profound information on the nature and application of various materials is in demand. This book bestows on the reader a deep knowledge of physics behind the concepts, perspectives, characteristic properties, and prospects. The book was constructed using 10 contributions from experts in diversified fields of condensed matter and material physics and its technology from over 15 research institutes across the globe.