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Book Mechanism and Kinetics of Fischer Tropsch Synthesis Over Supported Ruthenium Catalysts

Download or read book Mechanism and Kinetics of Fischer Tropsch Synthesis Over Supported Ruthenium Catalysts written by and published by . This book was released on 1981 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A detailed study of the kinetics of the Fischer-Tropsch synthesis of hydrocarbons, methanol, and acetaldehyde, over alumina- and silica-supported ruthenium catalysts has been carried out over a broad range of reaction conditions. Based on these results and information taken from the literature, mechanisms for the formation of normal paraffins, .cap alpha.-olefins, methanol, and acetaldehyde have been proposed. Rate data were obtained between 448 and 548K, 1 and 10 atm, and H2/CO ratios between 1 and 3, utilizing a micro flow reactor operated at very low conversions. In addition to the studies performed with H2/CO mixtures, a series of experiments were carried out utilizing D2/CO mixtures. These studies were used to help identify rate limited steps and steps that were at equilibrium. A complementary investigation, carried out by in situ infrared spectroscopy, was performed using a Fourier Transform spectrometer. The spectra obtained were used to identify the modes of CO adsorption, the CO coverage, and the relative reactivity of different forms of adsorbed CO. It was established that CO adsorbs on alumina-supported Ru in, at least, two forms: (i) Ru-CO and (ii) OC-Ru-CO. Only the first of these forms participates in CO hydrogenation. The coverage of this species is described by a simple Langmuir isotherm. A reaction mechanism is presented for interpreting the kinetics of hydrocarbon synthesis, the olefin to paraffin ratio for each product, and the probability of chain propagation. Rate expressions based on this mechanism are reasonably consistent with the experimental data. Acetaldehyde, obtained mainly over silica-supported Ru, appears to be formed by a mechanism related to that for hydroformulation of olefins. The effect of the dispersion of Ru/Al2O3 catalysts on their specific activity and selectivity was also investigated. The specific activity for all products decreased rapidly with increasing dispersions.

Book Transient Studies of the Fischer   Tropsch Synthesis Over a Cobalt Catalyst

Download or read book Transient Studies of the Fischer Tropsch Synthesis Over a Cobalt Catalyst written by Adesoji Adediran Adesina and published by . This book was released on 1984 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Catalysis

    Book Details:
  • Author : James J. Spivey
  • Publisher : Royal Society of Chemistry
  • Release : 2007-08-17
  • ISBN : 085404244X
  • Pages : 402 pages

Download or read book Catalysis written by James J. Spivey and published by Royal Society of Chemistry. This book was released on 2007-08-17 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series highlights major developments in catalyst research. Each volume provides systematic and detailed reviews of heterogenous and homogenous catalysis research and applications in a variety of fields.

Book Springer Handbook of Advanced Catalyst Characterization

Download or read book Springer Handbook of Advanced Catalyst Characterization written by Israel E. Wachs and published by Springer Nature. This book was released on 2023-06-12 with total page 1109 pages. Available in PDF, EPUB and Kindle. Book excerpt: Co-edited by world-renowned scientists in the field of catalysis, this book contains the cutting-edge in situ and operando spectroscopy characterization techniques operating under reaction conditions to determine a materials’ bulk, surface, and solution complex and their applications in the field of catalysis with emphasis on solid catalysts in powder form since such catalyst are relevant for industrial applications. The handbook covers from widely-used to cutting-edge techniques. The handbook is written for a broad audience of students and professionals who want to pursue the full capabilities available by the current state-of-the-art in characterization to fully understand how their catalysts really operate and guide the rational design of advanced catalysts. Individuals involved in catalysis research will be interested in this handbook because it contains a catalogue of cutting-edge methods employed in characterization of catalysts. These techniques find wide use in applications such as petroleum refining, chemical manufacture, natural gas conversion, pollution control, transportation, power generation, pharmaceuticals and food processing. fdsfds

Book Encyclopedia of Surface and Colloid Science

Download or read book Encyclopedia of Surface and Colloid Science written by P. Somasundaran and published by CRC Press. This book was released on 2006 with total page 1014 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Fundamentals of Industrial Catalytic Processes

Download or read book Fundamentals of Industrial Catalytic Processes written by C. H. Bartholomew and published by John Wiley & Sons. This book was released on 2011-11-30 with total page 1224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis is central to the chemical industry, as it is directly or involved in the production of almost all useful chemical products. In this book the authors, present the definitive account of industrial catalytic processes. Throughout Fundamentals of Industrial Catalytic Processes the information is illustrated with many case studies and problems. This book is valuable to anyone wanting a clear account of industrial catalytic processes, but is particularly useful to industrial and academic chemists and engineers and graduate working on catalysis. This book also: Covers fundamentals of catalytic processes, including chemistry, catalyst preparation, properties and reaction engineering. Addresses heterogeneous catalytic processes employed by industry. Provides detailed data on existing catalysts and catalytic reactions, process design and chemical engineering. Covers catalysts used in fuel cells.

Book Fischer Tropsch Synthesis Over Cobalt Catalysts

Download or read book Fischer Tropsch Synthesis Over Cobalt Catalysts written by Xuezhi Zhang and published by . This book was released on 1985 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Advances in Fischer Tropsch Synthesis  Catalysts  and Catalysis

Download or read book Advances in Fischer Tropsch Synthesis Catalysts and Catalysis written by B. H. Davis and published by CRC Press. This book was released on 2009-11-10 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Cataly

Book Isotopic Tracer Studies of Fischer Tropsch Synthesis Over Ru Ti02 Catalysts

Download or read book Isotopic Tracer Studies of Fischer Tropsch Synthesis Over Ru Ti02 Catalysts written by Kamala Raghunathan Krishna and published by . This book was released on 1992 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Studying the Fischer Tropsch Synthesis on Alumina Support Cobalt Base Catalyst in Fixed Bed Reactor

Download or read book Studying the Fischer Tropsch Synthesis on Alumina Support Cobalt Base Catalyst in Fixed Bed Reactor written by Adnan Khalil Oues and published by . This book was released on 2013 with total page 90 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Fischer-Tropsch catalyst composed of cobalt supported on alumina was prepared. This catalyst was cobalt/alumina (Co/AL2 O3 ). The physical characterization of the catalyst was conducted using surface area analysis through the BET method, and particle size analysis. Fischer-Tropsch experiments were conducted in a fixed bed reactor. A flow rate of 100sml/min was selected based experimentally. Two temperatures were 330, and 350°C, and three different pressures as follows 145, 217.6, and 290 psig. The results were evaluated and studied based on conversion of hydrogen and carbon monoxide, in addition to selectivity of products.

Book CJChE

Download or read book CJChE written by and published by . This book was released on 1998-02 with total page 708 pages. Available in PDF, EPUB and Kindle. Book excerpt: