Download or read book The Low Temperature Oxidation Chemistry of JP 8 and Its Surrogates at High Pressure written by and published by . This book was released on 2006 with total page 37 pages. Available in PDF, EPUB and Kindle. Book excerpt: A research program to study the low temperature oxidation chemistry of JP-8 at high pressures has been conducted at Drexel University. The current program was initiated in June 2003 through a grant from the Army Research Office (Grant No. DAAD19-03-1-0070, Project No. 44458-EG) and was completed in July 2006. The objectives of this project were to determine the effects of fuel composition variations in JP-8 reactivity at low and intermediate temperatures (600 - 1000 K) and elevated pressures (2 - 20 atm), to develop a chemical surrogate for JP-8, and to obtain kinetic information of the JP-8 surrogate components neat and in blends. Fuels were oxidized in a pressurized flow reactor, with complimentary experiments conducted in a single cylinder research engine. Detailed kinetic information was obtained utilizing gas chromatography with flame ionization detection and coupling to a mass spectrometer. In addition, hydrocarbons similar to the JP-8 surrogate components but of lighter molecular weight were studied in detail to ascertain the fundamental branching pathways of hydrocarbons at low temperatures; several other potential surrogate components and blends, including for Fischer-Tropsch JP-8, were also examined.

Download or read book Low Temperature Oxidation Chemistry of JP 8 written by and published by . This book was released on 2006 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: In an effort to develop surrogate fuels for engine modeling and development, this project is examining the low and intermediate temperature oxidation chemistry of JP-8, potential JP-8 surrogates, and their components at elevated pressure. Experiments are being run in a pressurized flow reactor (PFR) and/or a single cylinder research engine. A fundamental understanding of the preignition chemistry of high molecular weight hydrocarbons, similar to, if not including, components of real fuels, is necessary to advance the development of fuel surrogates. This project is providing information necessary to determine the chemical reaction mechanisms of such hydrocarbons. In prior work, we developed a four-component JP-8 surrogate and a four-component gasoline surrogate, and we characterized their reactivity in the low and intermediate temperature regimes (600-800 K) using our PFR facility to oxidize the fuels and our gas chromatography/mass spectrometer facility to measure the intermediate species. This year, we examined the behavior of jet fuels and the JP-8 surrogate in our single cylinder engine facility, and we used our PFR to explore the autoignition of Fischer-Tropsch JP-8 and a potential Fischer-Tropsch JP-8 surrogate.

Download or read book The Oxidation of JP 8 and Its Surrogates in the Low and Intermediate Temperature Regime written by David Burton Lenhert and published by . This book was released on 2004 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Homogeneous Charge Compression Ignition Engines 2007 written by and published by . This book was released on 2007 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Measurements of Ignition Times OH Time histories and Reaction Rates in Jet Fuel and Surrogate Oxidation Systems written by Subith Vasu Sumathi and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Fossil-based hydrocarbon fuels account for over 80% of the primary energy consumed in the world - it is still expected to be about 70% in year 2050 - and nearly 60% of that amount is used in the transport sector. The basis for globalization is transportation and a driving force has been the growth in global air traffic. The current climate crisis magnifies the need for improving the performance of jet engines by introducing scientific designs in which the use of chemical kinetics will be essential and critical for better performance and reducing pollutant emissions. Most aviation fuels are jet fuels originating from crude oil and there are major gaps in our knowledge of the high-temperature chemistry of real liquid carbon-based fuels. There is a critical need for experimental kinetic databases that can be used for the validation and refinement of jet fuel surrogate mechanisms. To fill this need, experiments were performed using shock tube and laser absorption methods to investigate jet fuel and surrogate oxidation systems under engine-relevant conditions. Ignition times and OH species time-histories were measured and low-uncertainty measurements of the reactions of OH with several stable intermediates were carried out. The work presented in this study can be broken into three categories: 1) jet fuel oxidation, 2) surrogate oxidation, and 3) OH radical reactions with several stable combustion intermediates. Ignition delay times were measured for gas-phase jet fuel oxidation (Jet-A and JP-8) in air behind reflected shock waves in a heated high-pressure shock tube. Initial reflected shock conditions were as follows: temperatures of 715-1229 K, pressures of 17-51 atm, equivalence ratios (phi) of 0.5 and 1, and oxygen concentrations of 10 and 21 % in synthetic air. Ignition delay times were measured using sidewall pressure and OH* emission at 306 nm. The new experimental results were modeled using several kinetic mechanisms using various jet fuel surrogate mixtures. Normal and cyclo alkanes are the two most important chemical classes found in jet fuels. Ignition delay time experiments were conducted during high-pressure oxidation of two commonly used representative components for normal and cyclo alkanes in jet fuel surrogates, i.e., n-dodecane and methylcyclohexane (MCH), respectively. Fuel/air ignition was studied for the following shock conditions: temperatures of 727-1177 K, pressures of 17-50 atm, phi's of 0.5 and 1. OH concentration time-histories during high-pressure n-dodecane, n-heptane and MCH oxidation were measured behind reflected shock waves in a heated, high-pressure shock tube. Experimental conditions covered temperatures of 1121 to 1422 K, pressures of 14.1-16.7 atm, and initial fuel concentrations of 500 to 1000 ppm (by volume), and an equivalence ratio of 0.5 with O2 as the oxidizer in argon as the bath gas. OH concentrations were measured using narrow-linewidth ring-dye laser absorption near the R-branchhead of the OH A-X (0,0) system at 306.47 nm. Detailed comparisons of these data with the predictions of various kinetic mechanisms were made. Sensitivity and pathway analyses for these reference fuel components were performed, leading to reaction rate recommendations with improved model performance. Reactions of OH radical with two alkenes (ethylene and propene) and a diene (1,3-butadiene) were studied behind reflected shock waves. Measurements were conducted in the range of temperatures from 890-1438 K and pressures from 1.99-10.18 atm for three initial concentrations of fuels (500ppm, 751.1ppm and 1000ppm). OH radicals were produced by shock-heating tert-butyl hydroperoxide, (CH3)3-CO-OH, and monitored by narrow-line width ring dye laser absorption of the well characterized R1(5) line of the OH A-X (0, 0) band near 306.7 nm. OH time-histories were modeled by using a modified oxidation mechanism and rate constants for the reactions of OH with ethylene, propene, and 1,3-butadiene were extracted by matching modeled and measured OH concentration time histories in the reflected shock region. Detailed error analyses yielded an uncertainty estimate of " 22.8% (OH+ethylene at 1201 K), "16.5% (OH+propene at 1136 K), and "13% (OH+1,3-butadiene at 1200K). Canonical and variational transition state theory calculations using recent ab initio results gave excellent agreement with our experimental measurements and data outside our range and hence the resulting expressions can be used directly in combustion models. In the current studies, a rate measurement for the decomposition of TBHP has been obtained in the range 745-1014 K using both incident and reflected OH data.

Download or read book Automotive Fuels Reference Book written by Paul Richards and published by SAE International. This book was released on 2014-03-05 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first two editions of this title, published by SAE International in 1990 and 1995, have been best-selling definitive references for those needing technical information about automotive fuels. This long-awaited new edition has been thoroughly revised and updated, yet retains the original fundamental fuels information that readers find so useful. This book is written for those with an interest in or a need to understand automotive fuels. Because automotive fuels can no longer be developed in isolation from the engines that will convert the fuel into the power necessary to drive our automobiles, knowledge of automotive fuels will also be essential to those working with automotive engines. Small quantities of fuel additives increasingly play an important role in bridging the gap that often exists between fuel that can easily be produced and fuel that is needed by the ever-more sophisticated automotive engine. This book pulls together in a single, extensively referenced volume, the three different but related topics of automotive fuels, fuel additives, and engines, and shows how all three areas work together. It includes a brief history of automotive fuels development, followed by chapters on automotive fuels manufacture from crude oil and other fossil sources. One chapter is dedicated to the manufacture of automotive fuels and fuel blending components from renewable sources. The safe handling, transport, and storage of fuels, from all sources, are covered. New combustion systems to achieve reduced emissions and increased efficiency are discussed, and the way in which the fuels’ physical and chemical characteristics affect these combustion processes and the emissions produced are included. There is also discussion on engine fuel system development and how these different systems affect the corresponding fuel requirements. Because the book is for a global market, fuel system technologies that only exist in the legacy fleet in some markets are included. The way in which fuel requirements are developed and specified is discussed. This covers test methods from simple laboratory bench tests, through engine testing, and long-term test procedures.

Download or read book A Study of the Low and Intermediate Temperature Oxidation Chemistry of a Primary Reference Fuel Blend and Two Gasolines at High Pressure written by Stephen Kowalski and published by . This book was released on 1993 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Shock Waves written by Klaus Hannemann and published by Springer Science & Business Media. This book was released on 2009-04-01 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 26th International Symposium on Shock Waves in Göttingen, Germany was jointly organised by the German Aerospace Centre DLR and the French-German Research Institute of Saint Louis ISL. The year 2007 marked the 50th anniversary of the Symposium, which first took place in 1957 in Boston and has since become an internationally acclaimed series of meetings for the wider Shock Wave Community. The ISSW26 focused on the following areas: Shock Propagation and Reflection, Detonation and Combustion, Hypersonic Flow, Shock Boundary Layer Interaction, Numerical Methods, Medical, Biological and Industrial Applications, Richtmyer Meshkov Instability, Blast Waves, Chemically Reacting Flows, Diagnostics, Facilities, Flow Visualisation, Ignition, Impact and Compaction, Multiphase Flow, Nozzles Flows, Plasmas and Propulsion. The two Volumes contain the papers presented at the symposium and serve as a reference for the participants of the ISSW 26 and individuals interested in these fields.

Download or read book 39th AIAA ASME SAE ASEE Joint Propulsion Conference Exhibit July 20 23 2003 Huntsville Alabama 03 4900 03 4949 written by and published by . This book was released on 2003 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book 38th AIAA ASME SAE ASEE Joint Propulsion Conference Exhibit 02 3850 02 3899 written by and published by . This book was released on 2002 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Encyclopedia of Automotive Engineering written by and published by John Wiley & Sons. This book was released on 2015-03-23 with total page 3888 pages. Available in PDF, EPUB and Kindle. Book excerpt: Erstmals eine umfassende und einheitliche Wissensbasis und Grundlage für weiterführende Studien und Forschung im Bereich der Automobiltechnik. Die Encyclopedia of Automotive Engineering ist die erste umfassende und einheitliche Wissensbasis dieses Fachgebiets und legt den Grundstein für weitere Studien und tiefgreifende Forschung. Weitreichende Querverweise und Suchfunktionen ermöglichen erstmals den zentralen Zugriff auf Detailinformationen zu bewährten Branchenstandards und -verfahren. Zusammenhängende Konzepte und Techniken aus Spezialbereichen lassen sich so einfacher verstehen. Neben traditionellen Themen des Fachgebiets beschäftigt sich diese Enzyklopädie auch mit "grünen" Technologien, dem Übergang von der Mechanik zur Elektronik und den Möglichkeiten zur Herstellung sicherer, effizienterer Fahrzeuge unter weltweit unterschiedlichen wirtschaftlichen Rahmenbedingungen. Das Referenzwerk behandelt neun Hauptbereiche: (1) Motoren: Grundlagen; (2) Motoren: Design; (3) Hybrid- und Elektroantriebe; (4) Getriebe- und Antriebssysteme; (5) Chassis-Systeme; (6) Elektrische und elektronische Systeme; (7) Karosserie-Design; (8) Materialien und Fertigung; (9) Telematik. - Zuverlässige Darstellung einer Vielzahl von Spezialthemen aus dem Bereich der Automobiltechnik. - Zugängliches Nachschlagewerk für Jungingenieure und Studenten, die die technologischen Grundlagen besser verstehen und ihre Kenntnisse erweitern möchten. - Wertvolle Verweise auf Detailinformationen und Forschungsergebnisse aus der technischen Literatur. - Entwickelt in Zusammenarbeit mit der FISITA, der Dachorganisation nationaler Automobil-Ingenieur-Verbände aus 37 Ländern und Vertretung von über 185.000 Ingenieuren aus der Branche. - Erhältlich als stets aktuelle Online-Ressource mit umfassenden Suchfunktionen oder als Print-Ausgabe in sechs Bänden mit über 4.000 Seiten. Ein wichtiges Nachschlagewerk für Bibliotheken und Informationszentren in der Industrie, bei Forschungs- und Schulungseinrichtungen, Fachgesellschaften, Regierungsbehörden und allen Ingenieurstudiengängen. Richtet sich an Fachingenieure und Techniker aus der Industrie, Studenten höherer Semester und Studienabsolventen, Forscher, Dozenten und Ausbilder, Branchenanalysen und Forscher.

Download or read book The Preignition and Autoignition Oxidation of Alternatives to Petroleum Derived JP 8 and Their Surrogate Components in a Pressurized Flow Reactor and Single Cylinder Research Engine written by Matthew S. Kurman and published by . This book was released on 2009 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Initiation and Flame Propagation in Combustion of Gases and Pyrophoric Metal Nanostructures written by Nikolai M. Rubtsov and published by Springer Nature. This book was released on 2020-10-01 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents new data on combustion processes for practical applications, discussing fire safety issues in the development of flame arresters and the use of noble metals in hydrogen recombiners for nuclear power plants. It establishes the basic principles of production of metal nanostructures, namely nanopowders of metals and compact products made of them, with the preservation of the unique properties of nanoproducts.

Download or read book Mathematical Modelling of Gas Phase Complex Reaction Systems Pyrolysis and Combustion written by and published by Elsevier. This book was released on 2019-06-21 with total page 1034 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. Details thermochemical properties and "ab initio" calculations of elementary reaction rates Details kinetic mechanisms of pyrolysis and combustion processes Explains experimental data for improving reaction models and for kinetic mechanisms assessment Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures Describes pollutant formation in combustion systems Solves and validates the kinetic mechanisms using numerical and statistical methods Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces Outlines large eddy simulation of turbulent reacting flows

Download or read book Fundamentals of Combustion Processes written by Sara McAllister and published by Springer Science & Business Media. This book was released on 2011-05-10 with total page 315 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Combustion Processes is designed as a textbook for an upper-division undergraduate and graduate level combustion course in mechanical engineering. The authors focus on the fundamental theory of combustion and provide a simplified discussion of basic combustion parameters and processes such as thermodynamics, chemical kinetics, ignition, diffusion and pre-mixed flames. The text includes exploration of applications, example exercises, suggested homework problems and videos of laboratory demonstrations

Download or read book Thermochemical Kinetics written by Sidney William Benson and published by . This book was released on 1976 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book A Review of United States Air Force and Department of Defense Aerospace Propulsion Needs written by National Research Council and published by National Academies Press. This book was released on 2007-01-14 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rocket and air-breathing propulsion systems are the foundation on which planning for future aerospace systems rests. A Review of United States Air Force and Department of Defense Aerospace Propulsion Needs assesses the existing technical base in these areas and examines the future Air Force capabilities the base will be expected to support. This report also defines gaps and recommends where future warfighter capabilities not yet fully defined could be met by current science and technology development plans.