Download or read book The Effect of Pressure and Organic Constituents on the Cesium Ion Exchange Performance of IONSIV IE 911 written by and published by . This book was released on 2000 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study examined cesium (137Cs) ion exchange of crystalline silicotitanate (CST) in simulated waste solution. In particular, the study focused on the effect of CST pretreatment on the kinetics and extent of cesium adsorption. The test used IONSIV{reg_sign}IE-911 (UOP LLC, Molecular Sieves Division, Des Plaines, IL), the engineered form of CST. Pretreatment steps examined include: soaking CST in 2M NaOH solution for three days, exposing CST to 50% relative humidity for one week, flowing organic-containing (saturated) salt solution through a CST packed bed (at 5 cm/min. superficial velocity), or drying CST in air at 100 C for three days. Some tests occurred under 50 and 25 psig of argon. The following conclusions summarize the results. Pretreatment of IE-911 in organic-containing (e.g., tri-n-butyl phosphate, dibutylphosphate, butanol, paraffin and Dow Corning H-10 defoamer) simulated waste or simulated waste yielded a 83% slower rate of cesium adsorption and 56% lower cesium capacity after one week. Pretreatment of IE-911 in 2M caustic solution for 48 hours yielded a slower approach to equilibrium cesium distribution in batch contact tests--7.7 mL/(g*h) during the first 48 hours and 2.4 ml/(g*h) thereafter. Carboxylates and adsorbed carbonates inside the pores likely affect the cesium transport by either increasing the path-length or reducing mass transfer rate. Heating IE-911 as received from the vendor at 100 C for 24 hours significantly degraded its cesium removal performance by a 40.7% reduction in capacity and 43% reduction in sorption rate over one week of testing. Testing determined nearly identical distribution coefficients K{sub d} between lot {number_sign} 9990-9681-0004 and 9990-9881-0005 (i.e., difference of only 5.6%). Tests measuring water insertion rates into IE-911 show that hydration of the IE-911 does not appear to limit the rate of cesium sorption. Increasing the atmospheric pressure from 0 to 50 psig had no effect on cesium sorption. Note that lower apparent capacity or slower cesium sorption rate in these limited-duration batch contact tests as a result of pretreatment do not necessarily imply reduced dynamic performance in a flowing ion-exchange application. The experiments that provided the bases for the currently proposed facility design used caustic-pretreated IE-911. Another report will assess whether the presence of the organic compounds in the waste solution impeded column performance.

Download or read book Ion Exchange Kinetics of Cesium for Various Reaction Designs Using Crystalline Silicotitanate UOP IONSIV IE 911 written by Sung Hyun Kim and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Through collaborative efforts at Texas A & M University and Sandia National Laboratories, a crystalline silicotitanate (CST), which shows extremely high selectivity for radioactive cesium removal in highly concentrated sodium solutions, was synthesized. The effect of hydrogen peroxide on a CST under cesium ion exchange conditions has been investigated. The experimental results with hydrogen peroxide showed that the distribution coefficient of cesium decreased and the tetragonal phase, the major component of CST, slowly dissolved at hydrogen peroxide concentrations greater than 1 M.A simple and novel experimental apparatus for a single-layer ion exchange column was developed to generate experimental data for estimation of the intraparticle effective diffusivity. A mathematical model is presented for estimation of effective diffusivities for a single-layer column of CST granules. The intraparticle effective diffusivity for Cs was estimated as a parameter in the analytical solution. By using the least square method, the effective diffusivities of 1.56 ł 0.14 x 10-11 m2/s and 0.68 ł 0.09x 10-11 m2/s, respectively, were obtained. The difference in the two values was due to the different viscosities of the solutions. A good fit of the experimental data was obtained which supports the use of the homogeneous model for this system. A counter-current ion exchange (CCIX) process was designed to treat nuclear waste at the Savannah River Site. A numerical method based on the orthogonal collocation method was used to simulate the concentration profile of cesium in the CCIX loaded with CST granules. To maximize cesium loading onto the CST and minimize the volume of CST, two design cases of a moving bed, where the fresh CST is pulsed into the column at certain periods or at certain concentration of cesium, were investigated. Simulation results showed that cesium removal behavior in the pilot-scale test of CCIX experiment, where the column length is 22 ft and the CST is pulsed 1 ft in every 24 hours, was well predicted by using the values of the effective diffusivities of 1.0 to 6.0 x 10-11 m2/s.

Download or read book Characterization of UOP IONSIV IE 911 written by and published by . This book was released on 2001 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: As a participating national lab in the inter-institutional effort to resolve performance issues of the non-elutable ion exchange technology for Cs extraction, they have carried out a series of characterization studies of UOP IONSIV{reg_sign} IE-911 and its component parts. IE-911 is a bound form (zirconium hydroxide-binder) of crystalline silicotitanate (CST) ion exchanger. The crystalline silicotitanate removes Cs from solutions by selective ion exchange. The performance issues of primary concern are: (1) excessive Nb leaching and subsequent precipitation of column-plugging Nb-oxide material, and (2) precipitation of aluminosilicate on IE-911 pellet surfaces, which may be initiated by dissolution of Si from the IE-911, thus creating a supersaturated solution with respect to silica. In this work, they have identified and characterized Si- and Nb-oxide based impurity phases in IE-911, which are the most likely sources of leachable Si and Nb, respectively. Furthermore, they have determined the criteria and mechanism for removal from IE-911 of the Nb-based impurity phase that is responsible for the Nb-oxide column plugging incidents.

Download or read book The Effect of Pretreatment on the Cesium Absorption Ability of IONSIV copyright Symbol IE 911 written by F. F. Fondeur and published by . This book was released on 1999 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Pilot Scale Test of Counter Current Ion Exchange CCIX Using UOP IONSIV IE 911 written by and published by . This book was released on 2001 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: A pilot-scale test of a moving-bed configuration of a UOP IONSIV? IE-911 ion-exchange column was performed over 17 days at Severn Trent Services facilities. The objectives of the test, in order of priority, were to determine if aluminosilicate precipitation caused clumping of IE-911 particles in the column, to observe the effect on aluminum-hydroxide precipitation of water added to a simulant-filled column, to evaluate the extent of particle attrition, and to measure the expansion of the mass-transfer zone under the influence of column pulsing. The IE-911 moved through the column with no apparent clumping during the test, although analytical results indicate that little if any aluminosilicate precipitated onto the particles. A precipitate of aluminum hydroxide was not produced when water was added to the simulant-filled column, indicating that this upset scenario is probably of little concern. Particle-size distributions remained relatively constant with time and position in the column, indicating that particle attrition was not significant. The expansion of the mass-transfer zone could not be accurately measured because of the slow loading kinetics of the IE-911 and the short duration of the test; however, the information obtained indicates that back-mixing of sorbent is not extensive.

Download or read book The Effect of Alkaline Earth Metal on the Cesium Loading of Ionsiv R IE 910 and IE 911 written by and published by . This book was released on 2001 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: This study investigated the effect of variances in alkaline earth metal concentrations on cesium loading of IONSIV(R) IE-911. The study focused on Savannah River Site (SRS) ''average'' solution with varying amounts of calcium, barium and magnesium.

Download or read book Register der grondboringen gedaan langs den IJsseldam en den Lekdijk benedendams in Juli en Aug 1874 written by and published by . This book was released on 1874 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Cesium Ion Exchange Using Actual Waste written by and published by . This book was released on 1996 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ion Exchange Recovery of Cesium from Alkaline Supernatant Waste written by R. P. Popovich and published by . This book was released on 1964 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Ion Exchange of Cesium by Crystalline Silico titanates written by and published by . This book was released on 1995 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: The crystalline silico-titanates developed by the Department of Chemical Engineering at Texas A & M University, Sandia National Laboratories and UOP exhibits extremely high ion exchange selectivity for removing cesium from aqueous defense wastes. Based on experimental data and structure studies, a competitive ion exchange model was proposed to predict the ion exchange performance in different simulated waste solutions. The predicted distribution coefficients were within 10% of the experimentally determined values.

Download or read book Application of Ion Exchange Processes for the Treatment of Radioactive Waste and Management of Spent Ion Exchangers written by and published by . This book was released on 2002 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ion exchange is one of the most common and effective treatment methods for liquid radioactive waste. This book reviews the current literature on the subject and reports on the existing state of the art of the application of ion exchange processes for liquid radioactive waste treatments and of the management of spent ion exchange media.

Download or read book Directory of Graduate Research written by and published by . This book was released on 2001 with total page 1846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.

Download or read book Ion Exchange Technology I written by Inamuddin Dr. and published by Springer Science & Business Media. This book was released on 2012-06-02 with total page 561 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ion-exchange Technology I: Theory and Materials describes the theoretical principles of ion-exchange processes. More specifically, this volume focuses on the synthesis, characterization, and modelling of ion-exchange materials and their associated kinetics and equilibria. This title is a highly valuable source not only to postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology as well as to engineers and industrialists.

Download or read book Nuclear Fuel Cycle Science and Engineering written by Ian Crossland and published by Elsevier. This book was released on 2012-09-21 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: The nuclear fuel cycle is characterised by the wide range of scientific disciplines and technologies it employs. The development of ever more integrated processes across the many stages of the nuclear fuel cycle therefore confronts plant manufacturers and operators with formidable challenges. Nuclear fuel cycle science and engineering describes both the key features of the complete nuclear fuel cycle and the wealth of recent research in this important field.Part one provides an introduction to the nuclear fuel cycle. Radiological protection, security and public acceptance of nuclear technology are considered, along with the economics of nuclear power. Part two goes on to explore materials mining, enrichment, fuel element design and fabrication for the uranium and thorium nuclear fuel cycle. The impact of nuclear reactor design and operation on fuel element irradiation is the focus of part three, including water and gas-cooled reactors, along with CANDU and Generation IV designs. Finally, part four reviews spent nuclear fuel and radioactive waste management.With its distinguished editor and international team of expert contributors, Nuclear fuel cycle science and engineering provides an important review for all those involved in the design, fabrication, use and disposal of nuclear fuels as well as regulatory bodies and researchers in this field. - Provides a comprehensive and holistic review of the complete nuclear fuel cycle - Reviews the issues presented by the nuclear fuel cycle, including radiological protection and security, public acceptance and economic analysis - Discusses issues at the front-end of the fuel cycle, including uranium and thorium mining, enrichment and fuel design and fabrication

Download or read book Natural Zeolites written by G. Gottardi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites form a family of minerals which have been known since the 18th century, but they remained a curiosity for scientists and collectors until 60 years ago, when their unique physicochemical properties attracted the attention of many researchers. In the past 30 years there has been an ex traordinary development in zeolite science; six International Conferences on Zeolites have been held every 3 years since 1967, and a large number of interesting contributions have been published in their proceedings. Many books, written either by individual authors or by several authors under a leading editor, have been published on these interesting silicate phases, but none has been devoted specifically to natural zeolites, even though this theme may be of interest not only to earth scientists, but also to chemists, as the in formation obtained from natural samples completes and in tegrates the characterization of many zeolites. We are trying to fill this gap on the basis of 20 years of research on natural zeolites, which we performed at the University of Modena together with many friends and colleagues. If it is in general difficult to write a scientific book with out upsetting somebody, this is particularly true for a book on natural crystals, because mineralogy is an interdisciplin ary science which covers some fields of physics, chemistry, it is almost impossible to meet every petrology, geology, and requirement.

Download or read book The Microbiology of Nuclear Waste Disposal written by Jonathan R. Lloyd and published by Elsevier. This book was released on 2020-11-08 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Microbiology of Nuclear Waste Disposal is a state-of-the-art reference featuring contributions focusing on the impact of microbes on the safe long-term disposal of nuclear waste. This book is the first to cover this important emerging topic, and is written for a wide audience encompassing regulators, implementers, academics, and other stakeholders. The book is also of interest to those working on the wider exploitation of the subsurface, such as bioremediation, carbon capture and storage, geothermal energy, and water quality. Planning for suitable facilities in the U.S., Europe, and Asia has been based mainly on knowledge from the geological and physical sciences. However, recent studies have shown that microbial life can proliferate in the inhospitable environments associated with radioactive waste disposal, and can control the long-term fate of nuclear materials. This can have beneficial and damaging impacts, which need to be quantified. Encompasses expertise from both the bio and geo disciplines, aiming to foster important collaborations across this disciplinary divide Includes reviews and research papers from leading groups in the field Provides helpful guidance in light of plans progressing worldwide for geological disposal facilities Includes timely research for planning and safety case development

Download or read book Minerals Structure Properties Methods of Investigation written by Sergei Votyakov and published by Springer. This book was released on 2019-04-23 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book comprises the proceedings of the 9th Geoscience Conference for Young Scientists co-organized by the Institute of Geology and Geochemistry and the Institute of Mineralogy (Urals Branch of Russian Academy of Sciences) and Ural Federal University and held in Ekaterinburg, Russia, on February 5-8, 2018. The book is devoted to the relevant issues of crystal chemistry and mineral typomorphism; the structure and physico-chemical and technological properties of minerals; the computational modeling of mineral structure and properties. Much attention is drawn to the latest advances and applications of physical methods of investigation of mineral structure and composition, in particular, X-Ray diffraction, spectroscopic (optical, vibrational, ESR, Moessbauer, etc.) and microscopic (SEM, TEM, AFM, etc.) studies, as well as the methods of chemical and isotopic analysis. This book presents the current research trends of space and planetary mineralogy (meteorites, regolites, tektites). The book is intended explicitly for the specialists in the earth and planetary sciences.