Download or read book Processing and Characterization of Sol Gel Cerium Oxide Microspheres written by and published by . This book was released on 2016 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of interest to space exploration and power generation, Radioisotope Thermoelectric Generators (RTGs) can provide long-term power to remote electronic systems without the need for refueling or replacement. Plutonium-238 (Pu-238) remains one of the more promising materials for thermoelectric power generation due to its high power density, long half-life, and low gamma emissions. Traditional methods for processing Pu-238 include ball milling irregular precipitated powders before pressing and sintering into a dense pellet. The resulting submicron particulates of Pu-238 quickly accumulate and contaminate glove boxes. An alternative and dust-free method for Pu-238 processing is internal gelation via sol-gel techniques. Sol-gel methodology creates monodisperse and uniform microspheres that can be packed and pressed into a pellet. For this study cerium oxide microspheres were produced as a surrogate to Pu-238. The similar electronic orbitals between cerium and plutonium make cerium an ideal choice for non-radioactive work. Before the microspheres can be sintered and pressed they must be washed to remove the processing oil and any unreacted substituents. An investigation was performed on the washing step to find an appropriate wash solution that reduced waste and flammable risk. Cerium oxide microspheres were processed, washed, and characterized to determine the effectiveness of the new wash solution.
Download or read book Production of Cerium Oxide Microspheres by an Internal Gelation Sol gel Process written by Jeffrey John Wegener and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The experiments performed for this research were completed to produce solid cerium oxide microspheres by an internal gelation sol-gel process. The motivation for this work was to develop a process that would enable the fabrication of a storage or transmutation form for the plutonium and transuranics (TRU) from the Uranium Extraction Plus (UREX) used fuel reprocessing process. This process is being investigated by the Department of Energy (DOE) and the Advanced Fuel Cycles Initiative (AFCI) through the Nuclear Energy Research Initiative. The internal gelation production of cerium oxide involves the combination of hexamethylenetetramine (HMTA), urea, and cerium nitrate solutions at ~100°C. Microspheres were produced by injection of a broth solution into a flowing stream of hot silicone oil. The captured microspheres were aged, washed, and then underwent Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC), and XRay Diffraction (XRD) analysis. The process variables examined in this study include the concentrations of HMTA, urea and cerium nitrate, the process temperature, the postgelation aging time, and the product washing conditions. Over a series of 70 experiments, it was determined that a broth solution containing a mixture of 1.45 M cerium nitrate and 1.65 M HMTA and urea (1:1 ratio) solutions produced the best cerium oxide microspheres. The spheres were aged for 30 to 60 minutes and then washed in hexane to remove the silicone oil and a subsequent series of ammonium hydroxide washes to remove unreacted product and to fully gel the microspheres. Through DSC analysis it was determined that excess wash or unreacted product may be removed by an exothermic reaction at approximately 200°C. The XRD analysis of unheated spheres showed the presence of cerium oxide with additional cerium-bearing organics. Following heating, the microspheres were completely converted to cerium oxide.
Download or read book Preparation and Characterization of Sol gel Derived Metal Oxide Thin Films and Powders for Coatings and Catalysts written by Per A. Askeland and published by . This book was released on 1997 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Sol Gel Science and Technology written by Lisa Klein and published by Springer Nature. This book was released on 2018-05-31 with total page 3755 pages. Available in PDF, EPUB and Kindle. Book excerpt: This completely updated and expanded second edition stands as a comprehensive knowledgebase on both the fundamentals and applications of this important materials processing method. The diverse, international team of contributing authors of this reference clarify in extensive detail properties and applications of sol-gel science and technology as it pertains to the production of substances, active and non-active, including optical, electronic, chemical, sensor, bio- and structural materials. Essential to a wide range of manufacturing industries, the compilation divides into the three complementary sections: Sol-Gel Processing, devoted to general aspects of processing and recently developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, and photocatalysts; Characterization of Sol-Gel Materials and Products, presenting contributions that highlight the notion that useful materials are only produced when characterization is tied to processing, such as determination of structure by NMR, in-situ characterization of the sol-gel reaction process, determination of microstructure of oxide gels, characterization of porous structure of gels by the surface measurements, and characterization of organic-inorganic hybrid; and Applications of Sol-Gel Technology, covering applications such as the sol-gel method used in processing of bulk silica glasses, bulk porous gels prepared by sol-gel method, application of sol-gel method to fabrication of glass and ceramic fibers, reflective and antireflective coating films, application of sol-gel method to formation of photocatalytic coating films, and application of sol-gel method to bioactive coating films. The comprehensive scope and integrated treatment of topics make this reference volume ideal for R&D scientists and engineers across a wide range of disciplines and professional interests.
Download or read book Handbook of sol gel science and technology 1 Sol gel processing written by Sumio Sakka and published by Springer Science & Business Media. This book was released on 2005 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since Dr. Disiich of Germany prepared a glass lens by the sol-gel method around 1970, sol-gel science and technology has continued to develop. Since then this field has seen remarkable technical developments as well as a broadening of the applications of sol-gel science and technology. There is a growing need for a comprehensive reference that treats both the fundamentals and the applications, and this is the aim of "Handbook of Sol-Gel Science and Technology."The primary purpose of sol-gel science and technology is to produce materials, active and non-active including optical, electronic, chemical, sensor, bio- and structural materials. This means that sol-gel science and technology is related to all kinds of manufacturing industries. Thus Volume 1, "Sol-Gel Processing," is devoted to general aspects of processing. Newly developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, photocatalysts will be covered. Topics in this volume include: Volume 2, "Characterization of Sol-Gel Materials and Products, "highlights the important fact that useful materials are only produced when characterization is tied to processing. Furthermore, characterization is essential to the understanding of nanostructured materials, and sol-gel technology is a most important technology in this new field. Since nanomaterials display their functional property based on their nano- and micro-structure, "characterization" is very important. Topics found in Volume 2 include: Sol-gel technology is a versatile technology, making it possible to produce a wide variety of materials and to provide existing substances with novel properties. This technology was applied to producingnovel materials, for example organic-inorganic hybrids, which are quite difficult to make by other fabricating techniques, and it was also applied to producing materials based on high temperature superconducting oxides. "Applications of Sol-Gel Technology," (Volume 3), will cover applications such as:
Download or read book The Sol Gel Handbook written by David Levy and published by John Wiley & Sons. This book was released on 2015-08-28 with total page 1616 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive three-volume handbook brings together a review of the current state together with the latest developments in sol-gel technology to put forward new ideas. The first volume, dedicated to synthesis and shaping, gives an in-depth overview of the wet-chemical processes that constitute the core of the sol-gel method and presents the various pathways for the successful synthesis of inorganic and hybrid organic-inorganic materials, bio- and bio-inspired materials, powders, particles and fibers as well as sol-gel derived thin films, coatings and surfaces. The second volume deals with the mechanical, optical, electrical and magnetic properties of sol-gel derived materials and the methods for their characterization such as diffraction methods and nuclear magnetic resonance, infrared and Raman spectroscopies. The third volume concentrates on the various applications in the fields of membrane science, catalysis, energy research, biomaterials science, biomedicine, photonics and electronics.
Download or read book Preparation Coating Evaluation and Irradiation Testing of Sol Gel Oxide Microspheres written by and published by . This book was released on 1966 with total page 45 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sol Gel Preparation and Characterization of Metal Silica and Metal Oxide Silica Nanocomposites written by G. Piccaluga and published by Trans Tech Publications Ltd. This book was released on 2000-02-21 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials with nanometer size particles exhibit unique chemical and physical properties. In particular, nanocomposite materials, composed of nanometric metal and metal oxide particles embedded in vitreous matrices, present a variety of interesting magnetic, electric and catalytic properties, that are strongly size-dependent. Among the different preparation methods which can be used to obtain this kind of materials, the sol-gel process is particularly interesting because it is affected by several parameters which allow a versatile control of the structural, textural and chemical properties of the final products. The present volume focusses on the preparation of metal-silica and metal oxide-silica (Me=Ni, Fe, Zn) nanocomposites by the sol-gel method and the characterization of their structural and magnetic properties.
Download or read book HANDBOOK of sol gel science and technology written by and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Sol Gel Science and Technology written by S. Sakka and published by Springer. This book was released on 2004-12-17 with total page 1968 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since Dr. Disiich of Germany prepared a glass lens by the sol-gel method around 1970, sol-gel science and technology has continued to develop. Since then this field has seen remarkable technical developments as well as a broadening of the applications of sol-gel science and technology. There is a growing need for a comprehensive reference that treats both the fundamentals and the applications, and this is the aim of Handbook of Sol-Gel Science and Technology. The primary purpose of sol-gel science and technology is to produce materials, active and non-active including optical, electronic, chemical, sensor, bio- and structural materials. This means that sol-gel science and technology is related to all kinds of manufacturing industries. Thus Volume 1, Sol-Gel Processing, is devoted to general aspects of processing. Newly developed materials such as organic-inorganic hybrids, photonic crystals, ferroelectric coatings, photocatalysts will be covered. Topics in this volume include: Synthesis and reaction of sol-gel precursors, Preparation of bulk glass and ceramics, Processing of porous materials based on self-organization, Synthesis of organic-inorganic hybrid materials, Coating of plastics, Special processes used in sol-gel formation of materials (1. Non-hydrolytic sol-gel process, 2. Sonogels, and 3. UV irradiation). Volume 2, Characterization of Sol-Gel Materials and Products, highlights the important fact that useful materials are only produced when characterization is tied to processing. Furthermore, characterization is essential to the understanding of nanostructured materials, and sol-gel technology is a most important technology in this new field. Since nanomaterials display their functional property based on their nano- and micro-structure, "characterization" is very important. Topics found in Volume 2 include: Determination of structure by NMR, In-situ characterization of the sol-gel reaction process, Determination of microstructure of oxide gels, Characterization of porous structure of gels by the surface measurements, Characterization of organic-inorganic hybrid, Measurements of rheological properties, Measurements of functional properties: fluorescence, laser, non-linear optical and other properties. Sol-gel technology is a versatile technology, making it possible to produce a wide variety of materials and to provide existing substances with novel properties. This technology was applied to producing novel materials, for example organic-inorganic hybrids, which are quite difficult to make by other fabricating techniques, and it was also applied to producing materials based on high temperature superconducting oxides. Volume 3, Applications of Sol-Gel Technology, will cover applications such as: Application of sol-gel method to processing of bulk silica glasses, Bulk porous gels prepared by sol-gel method, Application of sol-gel method to fabrication of glass and ceramic fibers, Reflective and antireflective coating films, Planar waveguides prepared by sol-gel method, Films with micropatterns and two-dimensional photonic crystals, Application of sol-gel method to formation of ferroelectric films, Application of sol-gel method to formation of photocatalytic coating films, Application of sol-gel method to bioactive coating films.
Download or read book Sol Gel Method written by Guadalupe Valverde Aguilar and published by BoD – Books on Demand. This book was released on 2019-02-13 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: The sol-gel method is a powerful route of synthesis used worldwide. It produces bulk, nano- and mesostructured sol-gel materials, which can encapsulate metallic and magnetic nanoparticles, non-linear azochromophores, perovskites, organic dyes, biological molecules, etc.. This can have interesting applications for catalysis, photocatalysis; drug delivery for treatment of neurodegenerative diseases such as cancer, Parkinson's and Azheimer's. In this book, valuable contributions related to novel materials synthesized by the sol-gel route are provided. The effect of the sol-gel method to synthesize these materials with potential properties is described, and how the variation of the parameters during the synthesis influences their design and allows to adjust their properties according to the desired application is discussed.
Download or read book Sol Gel Silica written by Larry L. Hench and published by William Andrew. This book was released on 1998-12-31 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: A unique perspective of twentieth century research and development in materials science. It summarizes the fifteen years of sol-gel silica processing research leading to the commercial development of bioactive gel-glasses for medical applications. It demonstrates the combined use of quantum mechanical molecular modeling and spectroscopy to solve environmental stability problems. A final chapter addresses the topic of Technology Transfer - how to transfer technology from the laboratory to a profitable commercial enterprise using examples from various chapters in the book.
Download or read book Sol Gel Processing and Applications written by Y.A. Attia and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: During my professional career, I developed a strong interest in sol-gel technology, and worked on both xerogel and aerogel systems. My fascination with aerogels has driven me to explore their commercial potential, which is currently an important component of my company's business plan. Together with my co-workers, I have also worked on the preparation of controlled PZT and silica xerogels as well as thin film coatings of metals by the sol-gel technology, These experiences convinced me of the tremendous potentials of this technology. A conviction that is shared by many scientists, engineers, and business leaders around the globe. Many sol-gel derived products are already articles of commerce. However, to expand the commercial potential of sol-gel technology, two challenges must be met: (1) the quality of sol-gel derived products must continue to meet or exceed the quality of competing products, (2) the production cost of sol-gel products (specially aerogels) must continued to decline. A key to lowering the costs of sol-gel products is finding inexpensive precursors.
Download or read book Introduction to Sol Gel Processing written by Alain C. Pierre and published by Springer Nature. This book was released on 2020-03-10 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a broad, general introduction to the processing of Sol-Gel technologies. This updated volume serves as a general handbook for researchers and students entering the field. This new edition provides updates in fields that have undergone rapid developments, such as Ceramics, Catalysis, Chromatropgraphy, biomaterials, glass science, and optics. It provides a simple, compact resource that can also be used in graduate-level materials science courses.
Download or read book Handbook of Sol gel Science and Technology written by Lisa C. Klein and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sol Gel Technologies for Glass Producers and Users written by Michel Andre Aegerter and published by Springer Science & Business Media. This book was released on 2013-03-19 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sol-Gel Techniques for Glass Producers and Users provides technological information, descriptions and characterizations of prototypes, or products already on the market, and illustrates advantages and disadvantages of the sol-gel process in comparison to other methods. The first chapter entitled "Wet Chemical Technology" gives a summary of the basic principles of the sol-gel chemistry. The most promising applications are related to coatings. Chapter 2 describes the various "Wet Chemical Coating Technologies" from glass cleaning to many deposition and post-coating treatment techniques. These include patterning of coatings through direct or indirect techniques which have became very important and for which the sol-gel processing is particularly well adapted. Chapter 3 entitled "Bulk Glass Technologies" reports on the preparation of special glasses for different applications. Chapter 4 entitled "Coatings and Materials Properties" describes the properties of the different coatings and the sol-gel materials, fibers and powders. The chapter also includes a section dedicated to the characterization techniques especially applied to sol-gel coatings and products.
Download or read book Sol Gel Process Development and Microsphere Preparation written by and published by . This book was released on 1966 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
