Download or read book Liquid Phase Oxidation via Heterogeneous Catalysis written by Mario G. Clerici and published by John Wiley & Sons. This book was released on 2013-04-26 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.
Download or read book Selective Oxidation by Heterogeneous Catalysis written by Gabriele Centi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.
Download or read book Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and published by John Wiley & Sons. This book was released on 2016-07-12 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Download or read book Heterogeneous Catalytic Oxidation written by B. K. Hodnett and published by John Wiley & Sons. This book was released on 2000-07-13 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: This authoritative and comprehensive volume presents the essence of catalytic chemistry, describing the structure of catalysts, the technology in which they are used and the chemical transformations that occur during reaction. Heterogeneous catalytic oxidation is a key technique used in the large-scale production of organic chemicals. This text uses catalytic oxidation to explain the principles of heterogeneous catalysis and includes descriptions of how reactants and products interact on the molecular scale with the active sites on the surface of these materials. Following an introduction to the principles and chemistry of catalytic oxidation, Professor Hodnett uses detailed case studies which represent and illustrate the fundamentals and technology for specific aspects of heterogeneous catalytic oxidation including: * Propene Oxidation to Acrolein * n-Butane Oxidation to Maleic Anhydride * Epoxidation over Silver Catalysts * Fundamentals and Technologies of the Catalytic Destruction of Volatile Organic Compounds * Ammoxidation for the Insertion of Nitrogen into Organic Structures * Oxidative Insertion of Chlorine into Ethylene and Catalytic Combustion of Chlorinated Hydrocarbons * Liquid Phase Oxidations with Particular Emphasis on the Use of Hydrogen Peroxide as an Oxidizing Agent
Download or read book Heterogeneous Catalysis in Organic Chemistry written by Gerard V. Smith and published by Academic Press. This book was released on 1999-06-30 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations
Download or read book Fine Chemicals through Heterogeneous Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production. With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.
Download or read book Catalytic Oxidation Principles And Applications A Course Of The Netherlands Institute For Catalysis Research Niok written by R A Sheldon and published by World Scientific. This book was released on 1995-10-30 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.
Download or read book Modern Heterogeneous Oxidation Catalysis written by Noritaka Mizuno and published by John Wiley & Sons. This book was released on 2009-11-18 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.
Download or read book Modern Applications of High Throughput R D in Heterogeneous Catalysis written by Alfred Hagemeyer and published by Bentham Science Publishers. This book was released on 2014-04-04 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: This eBook covers the application of high-throughput R&D to both fundamental and applied catalysis including catalyst synthesis, characterization, and testing in various reactor types. Chapters include topics such as applications ranging from optimizations of established industrial catalysts to the discovery of innovative new materials, examples of the development of innovative parallel characterization methods, and cases of real catalyst testing in small scale reactor systems. Readers will also find chapters that cover commodity chemicals produced using continuous gas phase processes as well as fine chemicals produced in liquid phase batch reactors. The potential of industrial chemicals production from biorenewable feedstocks is also presented. The steadily improving high throughput workflows are today being applied to relevant reactions and targets such as hydrotreating, Deacon oxidation, Fischer-Tropsch, propane dehydrogenation, C4 oxidation, methane coupling, exhaust gas catalysis, bio-based Nylon, fuel cells and vitamins. The topics presented in this eBook have been contributed by researchers from academia as well as industry, making this eBook a well-balanced reference, which could be of particular interest to professional, industrial or service R&D labs.
Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by Springer Nature. This book was released on 2019-10-02 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.
Download or read book New Developments in Selective Oxidation by Heterogeneous Catalysis written by P. Ruiz and published by Elsevier. This book was released on 1992-02-06 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.
Download or read book Catalytic Oxidation written by Roger A. Sheldon and published by World Scientific Publishing Company Incorporated. This book was released on 1995 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Liquid Phase Aerobic Oxidation Catalysis written by Shannon S. Stahl and published by John Wiley & Sons. This book was released on 2016-10-10 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Download or read book Liquid Phase Oxidation written by C.H. Bamford and published by Elsevier. This book was released on 1980-08-01 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquid Phase Oxidation
Download or read book Heterogeneous Catalysis and Fine Chemicals II written by M. Guisnet and published by Elsevier. This book was released on 1991-04-19 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recession in the traditional heavy industries along with the development of advanced technologies in all the industrial countries has meant that the impact of heterogeneous catalysis in the synthesis of fine chemicals is becoming increasingly noticeable. The second International Symposium on Heterogeneous Catalysis and Fine Chemicals is to be seen in this perspective. Organised by the Laboratory of Catalysis in Organic Chemistry of the University of Poitiers within the framework of the International Symposia of the `Centre National de la Recherche Scientifique' (CNRS), the symposium provided an opportunity for contact between academic researchers and manufacturers, users (or potential users) of solid catalysts for fine chemical synthesis. The book gives an overall view of the problems encountered by academic and industrial researchers. A large variety of reactions are described, the emphasis being on selectivity: chemo-, regio-, stereoselectivity (even enantioselectivity) and on the change of these selectivities as a function of the characteristics of the surface sites (nature, distribution, etc.). The three themes of the symposium, hydrogenation, oxidation and acid-base catalysis were introduced in four plenary lectures and two invited communications, maintaining a balance between the industrial and the academic points of view. Some 60 research papers selected by the Scientific Committee were presented. All are reproduced in full in this proceedings volume.
Download or read book Metal Oxides in Heterogeneous Catalysis written by Jacques C. Vedrine and published by Elsevier. This book was released on 2018-01-11 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications
Download or read book Perovskites and Related Mixed Oxides written by Pascal Granger and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level. The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.
