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Book Growth Mechanism and Interface Effects on Microstructure of Perovskite type Barium Titanate based Epitaxial Films

Download or read book Growth Mechanism and Interface Effects on Microstructure of Perovskite type Barium Titanate based Epitaxial Films written by Jie He and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This work was motivated and focused on the growth mechanism, microstructures and interfaces of barium titanate, BaTiO3 (BTO), based epitaxial thin films. Transimission electron microscopy (TEM), high resolution TEM (HRTEM), electron diffraction (ED) have been mainly employed in this study for microstructure investigations of BTO-based epitaxial thin films with the assistance of other materials characterization methods, such as X-ray diffraction (XRD), atomic force microscopy (AFM), Nanoindentation testing, etc. As a basic studying model, epitaxial BTO films were first deposited on the (001) MgO substrate using RF magnetron sputtering to provide fundamental knowledge of the film growth for BTO based thin films. The epitaxial BTO films show a tetragonal crystal structure (a = 4.02 Å and c = 4.11 Å) with epitaxial nanodomains induced from the rough film/substrate interface due to the modification of the substrate surface characteristics (steps, terraces, and kinks) during the deposition process. Two new phases of - calculus [gamma]y (Ba10TiO26) and Hß (BaTi8O24) were formed on the MgO substrate using RF magnetron sputtering. The atomic structures of the two new phases were determined and examined. The [gamma]y phase has a monoclinic structure, Cm, a=16.49 Å̊̊, b=8.94 Å, c=3.94 Å, y=77°. The Hß phase has a monoclinic structure, Cm, a = 17.88̊Å̊, b = 7.21Å, c = 3.94 Å̊̊̊, y =82°. Both [gamma]y and Hß phases have four different oriented domains. The orientation relationship between domains and MgO substrate is discussed. Initail study shows that these new phases possess novel and interesting properties. The doped BTO films with different dopant (Sr2 and Zr4) fabricated using pulsed laser deposition (PLD) have been studied for doping effects, interface effects and film growth mechanism. The (Ba, Sr)TiO3 (BST) epitaxial films grown on 1.2° and 5.3° miscut substrates consist of lager commensurate domains, and correspondly show higher dielectric constant and dielectric tunability, and lower average modulus and hardness than those of the films grown on the 3.5° miscut substrate. The results suggest that the differences on the interfacial structure have a tremendous effect on the properties of the films. The investigation on epitaxial Ba(Zr, Ti)O3 (BZT) and 2% Mn doped Ba(Zr, Ti)O3 (Mn:BZT) thin films grown on MgO substrate revealed the formation of twin-coupled domains on the epilayer by sharing their {111}/{110} planes as common planes. The structure evolution from epilayer to nanopillars is accomplished by alternatively introducing {111} and {110} twin boundaries, resulting in gradual shrinking or enlarging of the lateral size of the epitaxial grains/twin coupled nanopillars. The formations of twin domains, sharing planes and structure transition mechasim have been discussed in detail. Eventually, the microstructures and layer interfaces of [Mn:BZT//Mn:BST]N multilayer films consisting of 2% Mn doped (Ba, Sr)TiO3 (Mn:BST) and Mn:BZT layers on MgO (001) substrates with various deposition rates, deposition period numbers N were studied to provide an integral view of the formation of multilayer films in BTO system. All the [Mn:BZT//Mn:BST]N multilayer films present epitaxial quality and induced {111}/{110} twin-coupled domains initially formed at different film thickness/layers. The film/substrate interface has an important role for the formation of twin domains and the proportion of twin domain structures in the entire films. The layer interfaces between Mn:BST and Mn:BZT with period compression and extension strains were observed and discussed. The microstructure evolution and structure-related nano-mechanical properties of the multilayer films have been systematically investigated.

Book Ceramic Abstracts

Download or read book Ceramic Abstracts written by and published by . This book was released on 1998 with total page 1040 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Chemical Abstracts

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2668 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Chemical Solution Deposition of Functional Oxide Thin Films

Download or read book Chemical Solution Deposition of Functional Oxide Thin Films written by Theodor Schneller and published by Springer Science & Business Media. This book was released on 2014-01-24 with total page 801 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first text to cover all aspects of solution processed functional oxide thin-films. Chemical Solution Deposition (CSD) comprises all solution based thin- film deposition techniques, which involve chemical reactions of precursors during the formation of the oxide films, i. e. sol-gel type routes, metallo-organic decomposition routes, hybrid routes, etc. While the development of sol-gel type processes for optical coatings on glass by silicon dioxide and titanium dioxide dates from the mid-20th century, the first CSD derived electronic oxide thin films, such as lead zirconate titanate, were prepared in the 1980’s. Since then CSD has emerged as a highly flexible and cost-effective technique for the fabrication of a very wide variety of functional oxide thin films. Application areas include, for example, integrated dielectric capacitors, ferroelectric random access memories, pyroelectric infrared detectors, piezoelectric micro-electromechanical systems, antireflective coatings, optical filters, conducting-, transparent conducting-, and superconducting layers, luminescent coatings, gas sensors, thin film solid-oxide fuel cells, and photoelectrocatalytic solar cells. In the appendix detailed “cooking recipes” for selected material systems are offered.

Book International Aerospace Abstracts

Download or read book International Aerospace Abstracts written by and published by . This book was released on 1999 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book American Doctoral Dissertations

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1993 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Advanced Nano Deposition Methods

Download or read book Advanced Nano Deposition Methods written by Yuan Lin and published by John Wiley & Sons. This book was released on 2016-08-29 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: This concise reference summarizes the latest results in nano-structured thin films, the first to discuss both deposition methods and electronic applications in detail. Following an introduction to this rapidly developing field, the authors present a variety of organic and inorganic materials along with new deposition techniques, and conclude with an overview of applications and considerations for their technology deployment.

Book The Engineering Index Annual

Download or read book The Engineering Index Annual written by and published by . This book was released on 1992 with total page 2264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its creation in 1884, Engineering Index has covered virtually every major engineering innovation from around the world. It serves as the historical record of virtually every major engineering innovation of the 20th century. Recent content is a vital resource for current awareness, new production information, technological forecasting and competitive intelligence. The world?s most comprehensive interdisciplinary engineering database, Engineering Index contains over 10.7 million records. Each year, over 500,000 new abstracts are added from over 5,000 scholarly journals, trade magazines, and conference proceedings. Coverage spans over 175 engineering disciplines from over 80 countries. Updated weekly.

Book Physics Briefs

Download or read book Physics Briefs written by and published by . This book was released on 1992 with total page 820 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Sapphire

    Book Details:
  • Author : Elena R. Dobrovinskaya
  • Publisher : Springer Science & Business Media
  • Release : 2009-04-21
  • ISBN : 0387856951
  • Pages : 493 pages

Download or read book Sapphire written by Elena R. Dobrovinskaya and published by Springer Science & Business Media. This book was released on 2009-04-21 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: By the second half of the twentieth century, a new branch of materials science had come into being — crystalline materials research. Its appearance is linked to the emergence of advanced technologies primarily based on single crystals (bulk crystals and films). At the turn of the last century, the impending onset of the “ceramic era” was forecasted. It was believed that ceramics would play a role comparable to that of the Stone or Bronze Ages in the history of civilization. Naturally, such an assumption was hypothetical, but it showed that ceramic materials had evoked keen interest among researchers. Although sapphire traditionally has been considered a gem, it has developed into a material typical of the “ceramic era.” Widening the field of sapphire application necessitated essential improvement of its homogeneity and working characteristics and extension of the range of sapphire products, especially those with stipulated properties including a preset structural defect distribution. In the early 1980s, successful attainment of crystals with predetermined char- teristics was attributed to proper choice of the growth method. At present, in view of the fact that the requirements for crystalline products have become more str- gent, such an approach tends to be insufficient. It is clear that one must take into account the physical–chemical processes that take place during the formation of the real crystal structure, i.e., the growth mechanisms and the nature and causes of crystal imperfections.

Book Polar Oxides

Download or read book Polar Oxides written by Rainer Waser and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here, more than 20 experts from leading research institutes around the world present the entire scope of this rapidly developing field. In so doing, they cover a wide range of topics, including the characterization and investigation of structural, dielectric and piezoelectric properties of ceramic materials, a well as phase transitions, electrical and optical properties and microscopic investigations. Another feature is a complete profile of the properties of polar oxides -- from their proof to their latest applications. Throughout, the authors review, discuss and assess the material properties with regard to new and advanced characterization and imaging techniques. For physicists, physicochemists, semiconductor and solid state physicists, materials scientists, and students of chemistry and physics.

Book Handbook of Nonlinear Optics

Download or read book Handbook of Nonlinear Optics written by Richard L. Sutherland and published by CRC Press. This book was released on 2003-04-22 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examining classic theories, experimental methods, and practical formulas for exploration of the core topics in nonlinear optics, the second edition of this acclaimed text was extensively revised to reflect recent advances in the analysis and modification of material properties for application in frequency conversion, optical switching and limiting,

Book Perovskite Materials

Download or read book Perovskite Materials written by Likun Pan and published by BoD – Books on Demand. This book was released on 2016-02-03 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes the current state of the know-how in the field of perovskite materials: synthesis, characterization, properties, and applications. Most chapters include a review on the actual knowledge and cutting-edge research results. Thus, this book is an essential source of reference for scientists with research fields in energy, physics, chemistry and materials. It is also a suitable reading material for graduate students.

Book Pulsed Laser Deposition of Thin Films

Download or read book Pulsed Laser Deposition of Thin Films written by Douglas B. Chrisey and published by Wiley-Interscience. This book was released on 1994-06-21 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of what is required to set up and begin research in this newly developing technology and understand the basics of the process. Internationally recognized experts in their fields cover such fundamentals as history, theory, film characteristics, surface modification, laser technology, materials and applications including excellent reviews regarding the entire areas of semiconductor buffer layers, thin-film ferroelectrics and ferrites along with the work involving films deposited by PLD.

Book Triboelectric Nanogenerators

Download or read book Triboelectric Nanogenerators written by Zhong Lin Wang and published by Springer. This book was released on 2016-08-17 with total page 537 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces an innovative and high-efficiency technology for mechanical energy harvesting. The book covers the history and development of triboelectric nanogenerators, basic structures, working principles, performance characterization, and potential applications. It is divided into three parts: Part A illustrates the fundamental working modes of triboelectric nanogenerators with their prototype structures and theoretical analysis; Part B and Part C introduce two categories of applications, namely self-powered systems and self-powered active sensors. The book will be an ideal guide to scientists and engineers beginning to study triboelectric nanogenerators or wishing to deepen their knowledge of the field. Readers will be able to place the technical details about this technology in context, and acquire the necessary skills to reproduce the experimental setups for fabrication and measurement.

Book Materials Science and Engineering Serving Society

Download or read book Materials Science and Engineering Serving Society written by R.P.H. Chang and published by Elsevier. This book was released on 1998-12-23 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: This symposium was organised with the aim of encouraging collaboration in international science and engineering communities for the benefit of human kind. It consisted of invited talks by experts on materials and poster presentation papers. Approximately 140 scientists participated and the resulting proceedings present an up-to-date review of the research in this area.

Book Laser Processing and Chemistry

Download or read book Laser Processing and Chemistry written by Dieter Bäuerle and published by Springer Science & Business Media. This book was released on 2011-09-02 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Laser Processing and Chemistry gives an overview of the fundamentals and applications of laser-matter interactions, in particular with regard to laser material processing. Special attention is given to laser-induced physical and chemical processes at gas-solid, liquid-solid, and solid-solid interfaces. Starting with the background physics, the book proceeds to examine applications of laser techniques in micro-machining, and the patterning, coating, and modification of material surfaces. This fourth edition has been revised and enlarged to cover new topics such as 3D microfabrication, advances in nanotechnology, ultrafast laser technology and laser chemical processing (LCP). Graduate students, physicists, chemists, engineers, and manufacturers alike will find this book an invaluable reference work on laser processing.