Download or read book Geochemical Controls Over Phosphorus Bioavailability As A Function Of Redox Sensitive Iron Oxides written by Barczok R. Maximilian and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the geochemical controls on how phosphorus (P), a limiting or co-limiting nutrient for plants and microorganisms in many ecosystems, adsorbs to iron (oxyhydr)oxides minerals (henceforth called Fe oxides) is vital to predict the bioavailability of P in a system. Orthophosphate (henceforth called phosphate), the major ion of P utilized by biota, binds strongly to Fe oxides and is removed from solution, decreasing its bioavailability. The ability of Fe oxides to adsorb phosphate and act as a geochemical control on phosphate bioavailability depends on the crystallinity and mineralogy of the Fe oxides. Changes in hydrology and resulting shifts in redox conditions, represented by field measurements of redox potential (Eh), can directly impact phosphate bioavailability by either dissolving Fe oxides and releasing phosphate or precipitating low crystallinity Fe oxides adsorbing phosphate. Additional importance of the interaction of Fe oxides and P is their impact on the stability of soil organic carbon (OC) in Arctic permafrost soils. Permafrost ecosystems store a significant amount (~60%) of the worlds soil OC that are vulnerable to emissions to the atmosphere with increasing permafrost thaw. As such I hypothesize that shifts in soil EH caused by climatic variations such as progressing permafrost thaw and will shift Fe speciation in soil towards low crystallinity Fe oxides, such as ferrihydrite, and increase the capacity of phosphate adsorption and over a longer time period decrease bioavailability of phosphate to microorganism stabilizing soil OC. In this dissertation, I investigate 1) how EH responds to hydrological change, 2) the impact of EH and Fe oxide mineralogy on Fe oxide dissolution and transformation, as well as 3) the resulting impact of changing Fe oxide mineralogy on phosphorus bioavailability to the system, and 4) the impact of thawing permafrost on soil EH and Fe crystallinity and speciation, and the resulting impact on phosphorus sorption to Fe oxides . Methods employed to address the above mentioned research goals included 1) continuous, high resolution measurements of EH with platinum electrodes, 2) sequential extractions to quantify extractable Fe and P in soils and in field-incubated minerals, and 3) x-ray absorption fine structure (XAFS) spectroscopy to evaluate changes in Fe speciation. In Chapter 2, I present research on how soil EH responds to hydrological change in and around a vernal pond . I show how Eh can vary within a small pond temporally and spatially, and how Fe reducing conditions can persist without surface water ponding. In Chapter 3 I describe how Fe oxide speciation evolves over time towards lower crystallinity in contrasting redox conditions at the same vernal pond as in Chapter 2. I also show how Fe oxides can retain phosphate and how freshly precipitated Fe oxides adsorb phosphate potentially reducing bioavailability of P. In Chapter 4 I show how Eh differs along a permafrost gradient in Sweden. I also show how Fe speciation shifts towards the poorly crystalline Fe oxide ferrihydrite as permafrost thaw progresses. Additionally, I show the strong association of P to Fe oxides along the permafrost gradient.
Download or read book Biogeochemical Cycles written by Katerina Dontsova and published by John Wiley & Sons. This book was released on 2020-04-14 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elements move through Earth's critical zone along interconnected pathways that are strongly influenced by fluctuations in water and energy. The biogeochemical cycling of elements is inextricably linked to changes in climate and ecological disturbances, both natural and man-made. Biogeochemical Cycles: Ecological Drivers and Environmental Impact examines the influences and effects of biogeochemical elemental cycles in different ecosystems in the critical zone. Volume highlights include: Impact of global change on the biogeochemical functioning of diverse ecosystems Biological drivers of soil, rock, and mineral weathering Natural elemental sources for improving sustainability of ecosystems Links between natural ecosystems and managed agricultural systems Non-carbon elemental cycles affected by climate change Subsystems particularly vulnerable to global change The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals. Book Review: http://www.elementsmagazine.org/archives/e16_6/e16_6_dep_bookreview.pdf
Download or read book Phosphorus in Action written by Else K. Bünemann and published by Springer Science & Business Media. This book was released on 2010-11-08 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phosphorus (P) is a finite resource which is essential for life. It is a limiting nutrient in many ecosystems but also a pollutant which can affect biodiversity in terrestrial ecosystems and change the ecology of water bodies. This book collects the latest information on biological processes in soil P cycling, which to date have remained much less understood than physico-chemical processes. The methods section presents spectroscopic techniques and the characterization of microbial P forms, as well as the use of tracers, molecular approaches and modeling of soil-plant systems. The section on processes deals with mycorrhizal symbioses, microbial P solubilization, soil macrofauna, phosphatase enzymes and rhizosphere processes. On the system level, P cycling is examined for grasslands, arctic and alpine soils, forest plantations, tropical forests, and dryland regions. Further, P management with respect to animal production and cropping, and the interactions between global change and P cycling, are treated.
Download or read book Bioavailability of Contaminants in Soils and Sediments written by National Research Council and published by National Academies Press. This book was released on 2003-05-03 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioavailability refers to the extent to which humans and ecological receptors are exposed to contaminants in soil or sediment. The concept of bioavailability has recently piqued the interest of the hazardous waste industry as an important consideration in deciding how much waste to clean up. The rationale is that if contaminants in soil and sediment are not bioavailable, then more contaminant mass can be left in place without creating additional risk. A new NRC report notes that the potential for the consideration of bioavailability to influence decision-making is greatest where certain chemical, environmental, and regulatory factors align. The current use of bioavailability in risk assessment and hazardous waste cleanup regulations is demystified, and acceptable tools and models for bioavailability assessment are discussed and ranked according to seven criteria. Finally, the intimate link between bioavailability and bioremediation is explored. The report concludes with suggestions for moving bioavailability forward in the regulatory arena for both soil and sediment cleanup.
Download or read book Monitored Natural Attenuation of Inorganic Contaminants in Ground Water written by and published by . This book was released on 2007 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: V.3 ... consists of individual chapters that describe 1) the conceptual background for radionuclides, including tritium, radon, strontium, technetium, uranium, iodine, radium, thorium, cesium, plutonium-americium and 2) data requirements to be met during site characterization.
Download or read book Behavior of Metals in Soils written by Joan E. McLean and published by . This book was released on 1992 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Research on Nitrification and Related Processes Part A written by Martin G. Klotz and published by Academic Press. This book was released on 2011-01-10 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: State-of-the-art update on methods and protocols dealing with the detection, isolation and characterization of macromolecules and their hosting organisms that facilitate nitrification and related processes in the nitrogen cycle as well as the challenges of doing so in very diverse environments. Provides state-of-the-art update on methods and protocols Deals with the detection, isolation and characterization of macromolecules and their hosting organisms Deals with the challenges of very diverse environments
Download or read book The Biogeochemistry of Submerged Soils written by Guy Kirk and published by John Wiley & Sons. This book was released on 2004-06-25 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Submerged soils and the wetlands they support are of huge practical importance: in global element cycles, as centres of biodiversity, in global food production. They are also uniquely interesting scientifically because of their peculiar biogeochemistry and the adaptations of plants and microbes to it. This book describes the physical, chemical and biological processes operating in submerged soils and governing their properties. It describes the transport processes controlling the fluxes of gases and solutes through the soil; the interchange of solutes between solid, liquid and gas phases; reduction and oxidation processes; biological processes in the soil and overlying water; and processes in the roots and rhizospheres of wetland plants. The dynamics of nutrients, toxins, pollutants and trace gases are then discussed in terms of these processes and in relation to wetland productivity and global element cycles. Written by a renowned expert in the field, this work will be invaluable to earth, environmental and agricultural scientists concerned with natural or man-made wetlands, and to advanced undergraduate and graduate studen ts of these topics.
Download or read book Alaska s Changing Arctic written by John E. Hobbie and published by Oxford University Press. This book was released on 2014-02-03 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this edition of the Long Term Ecological Research Network series, editors John Hobbie and George Kling and 58 co-authors synthesize the findings from the NSF-funded Arctic LTER project based at Toolik Lake, Alaska, a site that has been active since the mid-1970s. The book presents research on the core issues of climate-change science in the treeless arctic region of Alaska. As a whole, it examines both terrestrial and freshwater-aquatic ecosystems, and their three typical habitats: tundra, streams, and lakes. The book provides a history of the Toolik Lake LTER site, and discusses its present condition and future outlook. It features contributions from top scientists from many fields, creating a multidisciplinary survey of the Alaskan arctic ecosystem. Chapter topics include glacial history, climatology, land-water interactions, mercury found in the Alaskan arctic, and the response of these habitats to environmental change. The final chapter predicts the consequences that arctic Alaska faces due to global warming and climate change, and discusses the future ecology of the LTER site in the region. Alaska's Changing Arctic is the definitive scientific survey of the past, present, and future of the ecology of the Alaskan arctic.
Download or read book Trace Elmts in Soil Plants written by Alina Kabata-Pendias and published by Springer. This book was released on 1984-07-24 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Biogeochemistry in Surface water Systems written by John F. Elder and published by . This book was released on 1988 with total page 43 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Heavy Metals in Soils written by Brian J. Alloway and published by Springer Science & Business Media. This book was released on 2012-07-18 with total page 615 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition of the book has been completely re-written, providing a wider scope and enhanced coverage. It covers the general principles of the natural occurrence, pollution sources, chemical analysis, soil chemical behaviour and soil-plant-animal relationships of heavy metals and metalloids, followed by a detailed coverage of 21 individual elements, including: antimony, arsenic, barium, cadmium, chromium, cobalt, copper, gold, lead, manganese, mercury, molybdenum, nickel, selenium, silver, thallium, tin, tungsten, uranium, vanadium and zinc. The book is highly relevant for those involved in environmental science, soil science, geochemistry, agronomy, environmental health, and environmental engineering, including specialists responsible for the management and clean-up of contaminated land.
Download or read book Phosphorus Polluter and Resource of the Future written by Christian Schaum and published by IWA Publishing. This book was released on 2018-03-15 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive book provides an up-to-date and international approach that addresses the Motivations, Technologies and Assessment of the Elimination and Recovery of Phosphorus from Wastewater. This book is part of the Integrated Environmental Technology Series.
Download or read book Environmental Geochemistry of Potentially Toxic Metals written by Frederic R. Siegel and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Sediments Diagenesis and Sedimentary Rocks written by F.T. Mackenzie and published by Elsevier. This book was released on 2005-11-22 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers the formation and biogeochemistry of a variety of important sediment types from their initial formation through their conversion (diagenesis) to sedimentary rocks. The volume deals with the chemical, mineralogical, and isotopic properties of sediments and sedimentary rocks and their use in interpreting the environment of formation and subsequent events in the history of sediments, and the nature of the ocean-atmosphere system through geological time. Reprinted individual volume from the acclaimed Treatise on Geochemistry, (10 Volume Set, ISBN 0-08-043751-6, published in 2003). Comprehensive and authoritative scope and focus Reviews from renowned scientists across a range of subjects, providing both overviews and new data, supplemented by extensive bibliographies Extensive illustrations and examples from the field
Download or read book Earth s Early Atmosphere and Surface Environment written by George H. Shaw and published by Geological Society of America. This book was released on 2014 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nothing provided
Download or read book Evolution of Early Earth s Atmosphere Hydrosphere and Biosphere written by Stephen E. Kesler and published by Geological Society of America. This book was released on 2006-01-01 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The history of Earth's early atmosphere, hydrosphere, and biosphere, from Hadean through Proterozoic time, is one of geology's enduring puzzles. Ore deposits provide important insights into this history because they contain elements and minerals that are highly sensitive to the geochemical environment in which they form. Just what these minerals tell us remains a matter of considerable debate, however. When and how did life develop, an oxygen-rich atmosphere form, and sulfate dominate the ocean? This volume contains reports on these questions from both sides of the aisle for iron and manganese formations, uranium paleoplacers and hydrothermal deposits, and exhalative sulfides and oxides."--Publisher's website.
