Download or read book Diffusivity and Enzymatic Activity Control the Exchange of Carbonyl Sulfide COS Between Soils and the Atmosphere written by Heidi Van Diest and published by . This book was released on 2007 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Diffusivity and Enzymatic Activity Control the Exchange of Carbonyl Sulfide COS Between Soils and the Atmosphere written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS) is one of the most abundant and stable reduced sulfur trace gases found in the atmosphere with an ambient concentration around 500 ppt, which is involved in stratospheric aerosol production and the ozone cycle. COS has a variety of natural and anthropogenic sources but is well balanced by sinks as vegetation and soils. Since the sink strength of soils is poorly understood, it is important to characterize the controlling parameters. All of the soil exchange measurements done before 1990 presumed soils as a substantial source of COS (Castro and Galloway, 1991). In addition to the vegetation, soils are now regarded as an important sink (Watts, 2000). Soil samples were investigated for their exchange of COS with the atmosphere under controlled ambient conditions. Three arable soils from Germany, China and Finland and 2 forest soils from Siberia and Surinam are parameterized in relation to the ambient COS concentration, temperature and soil water content (WC). Beside ambient concentration and soil WC, soil structure and enzymatic activity seem to control the direction as well as the magnitude of the flux between soils and the atmosphere. The matching optima for boreal soils in relation to water-filled pore space (WFPS) and the linearity between deposition velocity (Vd) and bulk density suggest that the uptake of COS depends on the diffusivity dominated by WFPS, a parameter depending on soil WC, soil structure and porosity of the soil. Since carbonic anhydrase (CA) has been identified as the controlling enzyme for COS uptake in soil, we qualitatively identified the activity of CA in our soil samples, but these results are considered to be very preliminary.
Download or read book Carbonyl Sulfide Exchange Between Soils and the Atmosphere Observations and Modeling written by Wu Sun and published by . This book was released on 2017 with total page 183 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS) is a trace gas participating in key processes of the terrestrial carbon cycle. Despite its low mixing ratio in the troposphere (400-550 pmol mol-1), the amplitude of seasonal variability of COS greatly exceeds that of CO2 and is in phase with the gross photosynthesis of the terrestrial biosphere. Over the recent decade, COS has emerged as a promising tracer for quantifying terrestrial gross primary productivity (GPP) independently from respiration across the ecosystem to the global scales, because of the parallel uptake of COS and CO2 through leaf stomata. While leaf uptake of COS dominates surface COS flux on land in the absence of industrial and biomass burning emissions, soil COS flux is another smaller but significant component. Neglecting the soil component in ecosystem COS budget may bias GPP estimates derived from COS measurements. Soil may also vary from a sink to a source of COS depending on temperature and microbial sulfur metabolism. Due to the presence of potential interference from soil COS activities, using COS as a photosynthetic tracer requires soil COS flux to be separated from the net ecosystem COS exchange. This dissertation is dedicated to the mechanistic understanding of the soil-atmosphere exchange of COS using process-oriented modeling and field observations. A reactive transport model for soil COS processes is constructed to simulate soil-atmosphere COS flux from environmental variables. This model takes into account the dual-phase diffusive transport and the microbial sources and sinks of COS in the soil column. COS uptake and production rates are parameterized with enzyme kinetics and thermodynamics, consistent with lab incubation data. Leaf litter layer is explicitly resolved to account for litter COS uptake, whenever a litter layer is present. The model is evaluated against published field data of COS flux and demonstrates good skill in predicting both soil uptake and emission of COS. Model simulations further confirm that COS flux dependence on soil moisture is a result of two rivaling controls--the diffusive limitation on COS supply and the water limitation on microbial activity. Field observations on soil COS exchange have been conducted at an oak woodland in southern California and a boreal pine forest in southern Finland using automated soil chambers and mid-infrared quantum cascade laser spectrometer. Soils at both sites show consistent uptake behavior related to soil moisture and respiration. At the semi-arid oak woodland in California, microbial COS uptake is strongly limited by water availability in the dry season. The intact leaf litter layer contributes a significant portion to the overall soil COS uptake. Litter COS uptake increases with moisture content and shows a strong pulse immediately after the rain event, indicating a rapid reactivation of litter microbial activity following alleviated water stress. In the Finnish pine forest, soil COS uptake is limited by the diffusional supply of COS to soil microbes, according to the negative correlation with soil moisture. The contrasting responses of soil COS uptake to moisture in semi-arid and humid ecosystems reflect the coupling of diffusion and microbial uptake controls on COS flux. At both sites, soil COS uptake correlates well with respiration and the COS : CO2 flux ratio varies with temperature. The temperature dependence of COS : CO2 flux ratio may be a common feature of soils and indicate underlying shifts in active microbial groups. This dissertation advances knowledge of the physical and biological drivers of soil-atmosphere exchange of COS. Anticipated applications of the findings will be to better constrain global soil COS flux and derive COS-based estimates of GPP, which will be useful in understanding the responses of photosynthesis to climate variability.
Download or read book Carbonyl Sulfide Exchange in Soils for Better Estimates of Ecosystem Carbon Uptake written by and published by . This book was released on 2016 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Atmospheric Carbonyl Sulfide Sources from Anthropogenic Activity written by and published by . This book was released on 2015 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS) has recently emerged as an atmospheric tracer of gross primary production. All modeling studies of COS air-monitoring data rely on a climatological anthropogenic inventory that does not reflect present conditions or support interpretation of ice core and firn trends. Here we develop a global anthropogenic inventory for the years 1850 to 2013 based on new emission measurements and material-specific data. By applying methods from a recent regional inventory to global data, we find that the anthropogenic source is similar in magnitude to the plant sink, confounding carbon cycle applications. However, a material-specific approach results in a current anthropogenic source that is only one third of plant uptake and is concentrated in Asia, supporting carbon cycle applications of global air-monitoring data. As a result, changes in the anthropogenic source alone cannot explain the century-scale mixing ratio growth, which suggests that ice and firn data may provide the first global history of gross primary production.
Download or read book The Exchange of Reduced Sulfur Gases Between Forest Soils and the Atmosphere written by Mark Sam Castro and published by . This book was released on 1991 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Anthropogenic Sources of Carbonyl Sulfide written by and published by . This book was released on 2017 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl sulfide (COS or OCS) is emerging as a potentially important tracer of terrestrial biological carbon fluxes. Anthropogenic sources of atmospheric COS are a first order uncertainty for utilizing COS as a tracer of the carbon cycle. As anthropogenic COS is a confounding source of atmospheric COS when interpreting COS observations, incorrect estimates of anthropogenic COS sources can introduce large interpretation bias when attempting to infer carbon cycle fluxes. However, the current gridded estimate of anthropogenic sources of atmospheric COS is largely derived from data over three decades old and therefore is not likely to be representative of current atmospheric conditions. Here I address this critical knowledge gap by providing a new gridded estimate of anthropogenic COS sources derived from the most current industry activity and emissions factor data available and employ a more sophisticated approach for the spatial distribution of sources than presented in previous work. This new data set results in a very different picture of the spatial distribution of anthropogenic sources of COS and in a large upward revision in total global sources than estimated in previous work. The large missing source of atmospheric COS needed to balance the global budget of atmospheric COS has largely been attributed to an unknown ocean source in previous work. However, considering the large upward revision of anthropogenic COS sources estimated here, I present the hypothesis that anthropogenic sources may be a key component of the missing source of atmospheric COS. I present subsequent modeling scenarios to test this hypothesis and show that anthropogenic COS sources can explain observations of atmospheric COS as well as or better than enhanced ocean sources. Therefore, the data set of anthropogenic sources of COS presented here emerges as a key component of reducing interpretation bias when inferring carbon cycle fluxes using COS and for explaining the missing source of atmospheric COS and balancing the global COS budget (which has previously not been considered).
Download or read book Environmental Factors Influencing the Atmosphere soil Exchange of Some Reduced Sulfur Gases in Coniferous Forest Soils written by Jeffrey Stuart Simmons and published by . This book was released on 1994 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Soil Carbon Cycling Constrained by Oxygen dependent Enzyme Activity and Microbial Energetics written by Hannah Rose Naughton and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Soils contain up to three times as much dynamic carbon as the atmosphere, making them a critical carbon sink. Soil organic carbon (SOC) performs ecosystem services such as atmospheric carbon sequestration, retention of nutrients and water, promotion of good soil structure, and fueling microbial activity that leads to soil fertility. However, future climate and land use change endanger soil carbon stocks. An incomplete understanding of the mechanisms behind SOC degradation hinders our ability to model carbon cycling, particularly considering temporally and spatially heterogeneous soils. One key factor is the role oxygen availability plays in microbial energetics and enzyme activity, information critical to providing mechanistic predictions of SOC decay. My research explores how oxygen limitations and ensuing redox heterogeneity in soils control both the energetics of respiration, which ultimately controls greenhouse gas production of soils, and microbial access to organic substrates via oxidative enzyme depolymerization. I use both laboratory soil reactors and a floodplain field site as soil environments with spatially or temporally varying oxygen availability to test for enzymatic and thermodynamic limitations on SOC degradation and accompanying greenhouse gas production. Soil redox environment altered dissolved organic carbon (DOC) composition and chemistry over short times in the reactor setup and over short spatial scales in field soils. Oxygen-limited soils had more reduced organic C corresponding to lower thermodynamic favorability as a microbial substrate in anaerobic metabolisms. The reactors had a stark increase in relative abundance of lignin-like carbon going from aerobic to anaerobic environments, indicative of enzymatic limitations, but field soils indicated plant inputs counteract this often depth-related pattern. Aeration of soils resulted in equivalent respiration when normalized to SOC content, regardless of original microbial community or SOC composition, even in methanogenic soils lacking saprotrophic communities. This finding prompted exploration of the potential for abiotic, metal-catalyzed processes to depolymerize SOC in redox-heterogeneous floodplain soils. Ferrous iron better corresponded to phenol oxidation potential than any microbial or carbon-related predictors, highlighting the potential for rapid oxidative SOC depolymerization upon aeration of permanently or temporarily saturated soils containing reduced transition metals. Altogether, this work highlights the rapidity with which novel redox status of soils alters SOC composition, favorability as a microbial substrate, and potential for unexpected greenhouse gas release. Terrestrial carbon models are unlikely to accurately predict future stocks and fluxes of SOC if they do not account for the influence of heterogeneity of oxygen availability and ensuing effects on carbon lability.
Download or read book Sulfur in Plants written by Malcolm J. Hawkesford and published by Springer Science & Business Media. This book was released on 2007-03-07 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the latest findings on how plants respond physiologically to sulfur in their environment. It combines an ecosystems approach with new insights at the molecular and biochemical level. Key areas are explored to assess the functions and implications of this essential plant nutrient in a range of natural, semi-natural and anthropogenic environments. The result is an important new reference on the relationships between plants and sulfur.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1971 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Biological Soil Crusts Structure Function and Management written by Jayne Belnap and published by Springer Science & Business Media. This book was released on 2013-12-01 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: In arid lands, where vegetation is sparse or absent, the open ground is not bare but generally covered by a community of small, highly specialized organisms. Cyanobacteria, algae, microfungi, lichens, and bryophytes aggregate soil particles to form a coherent skin - the biological soil crust. It stabilizes and protects the soil surface from erosion by wind and water, influences water runoff and infiltration, and contributes nitrogen and carbon to desert soils. Soil surface disturbance, such as heavy livestock grazing, human trampling or off-road vehicles, breaks up the fragile soil crust, thus compromising its stability, structure, and productivity. This book is the first synthesis of the biology of soil crusts and their importance as an ecosystem component. Composition and functioning of different soil-crust types are discussed, and case studies are used to show the impact of crusts on landscape hydrology, soil stability, nutrient cycles, and land management.
Download or read book Pollution Abstracts written by and published by . This book was released on 1996 with total page 858 pages. Available in PDF, EPUB and Kindle. Book excerpt: Indexes material from conference proceedings and hard-to-find documents, in addition to journal articles. Over 1,000 journals are indexed and literature published from 1981 to the present is covered. Topics in pollution and its management are extensively covered from the standpoints of atmosphere, emissions, mathematical models, effects on people and animals, and environmental action. Major areas of coverage include: air pollution, marine pollution, freshwater pollution, sewage and wastewater treatment, waste management, land pollution, toxicology and health, noise, and radiation.
Download or read book How Tobacco Smoke Causes Disease written by United States. Public Health Service. Office of the Surgeon General and published by . This book was released on 2010 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report considers the biological and behavioral mechanisms that may underlie the pathogenicity of tobacco smoke. Many Surgeon General's reports have considered research findings on mechanisms in assessing the biological plausibility of associations observed in epidemiologic studies. Mechanisms of disease are important because they may provide plausibility, which is one of the guideline criteria for assessing evidence on causation. This report specifically reviews the evidence on the potential mechanisms by which smoking causes diseases and considers whether a mechanism is likely to be operative in the production of human disease by tobacco smoke. This evidence is relevant to understanding how smoking causes disease, to identifying those who may be particularly susceptible, and to assessing the potential risks of tobacco products.
Download or read book Toxicological Profile for Carbon Disulfide written by and published by . This book was released on 1994 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Air Emissions from Animal Feeding Operations written by National Research Council and published by National Academies Press. This book was released on 2003-04-07 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Air Emissions from Animal Feeding Operations: Current Knowledge, Future Needs discusses the need for the U.S. Environmental Protection Agency to implement a new method for estimating the amount of ammonia, nitrous oxide, methane, and other pollutants emitted from livestock and poultry farms, and for determining how these emissions are dispersed in the atmosphere. The committee calls for the EPA and the U.S. Department of Agriculture to establish a joint council to coordinate and oversee short - and long-term research to estimate emissions from animal feeding operations accurately and to develop mitigation strategies. Their recommendation was for the joint council to focus its efforts first on those pollutants that pose the greatest risk to the environment and public health.
Download or read book Bibliography of Agriculture written by and published by . This book was released on 1998 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt:
