Download or read book Development of Thin Films Deposited by ALD for C Si Solar Cells written by Javier Pérez Guardia and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, we have developed thin layers deposited by Atomic Layer Deposition (ALD) technique to be applied in high-efficiency crystalline silicon solar cells. In particular, we selected to study the aluminium oxide (Al2O3) as a surface passivation mechanism and the titanium dioxide (TiO2) as a selective contact for electrons. To characterize the Al2O3 we have done two studies: deposition thickness and pre-deposition cleaning process. In both studies we have measured the effective surface recombination velocity (Seff), where we get results comparable to the state of the art with Seff

Download or read book Handbook of Thin Film Deposition written by Krishna Seshan and published by William Andrew. This book was released on 2012-12-06 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Thin Film Deposition is a comprehensive reference focusing on thin film technologies and applications used in the semiconductor industry and the closely related areas of thin film deposition, thin film micro properties, photovoltaic solar energy applications, new materials for memory applications and methods for thin film optical processes. In a major restructuring, this edition of the handbook lays the foundations with an up-to-date treatment of lithography, contamination and yield management, and reliability of thin films. The established physical and chemical deposition processes and technologies are then covered, the last section of the book being devoted to more recent technological developments such as microelectromechanical systems, photovoltaic applications, digital cameras, CCD arrays, and optical thin films. A practical survey of thin film technologies aimed at engineers and managers involved in all stages of the process: design, fabrication, quality assurance and applications Covers core processes and applications in the semiconductor industry and new developments in the photovoltaic and optical thin film industries The new edition takes covers the transition taking place in the semiconductor world from Al/SiO2 to copper interconnects with low-k dielectrics Written by acknowledged industry experts from key companies in the semiconductor industry including Intel and IBM Foreword by Gordon E. Moore, co-founder of Intel and formulator of the renowned ‘Moore’s Law’ relating to the technology development cycle in the semiconductor industry

Download or read book Metal induced Growth of Microcrystalline Silicon Thin Films for Solar Cells written by and published by . This book was released on 2005 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: The research focused on the process study for deposition of device quality polycrystalline silicon (poly-Si) thin films and solar cell fabrication by using a novel technique, metal-induced growth (MIG). Cobalt (Co) is introduced in the studies as a seed layer metal for the first time, while nickel (Ni) was another candidate. To grow the poly-Si, Co or Ni seed-layers were deposited on the foreign substrates by thermal evaporation with a few nm to 50 nm thickness. Substrates were transferred into the sputtering system for Si sputtering at elevated temperature from 525°C to 625°C. The Co or Ni reacted with sputtered Si to form metal disilicides which have very small lattice mismatch with Si (0.4% lattice mismatch for NiSi2 and Si, 1.2% lattice mismatch for CoSi2 and Si). The crystalline metal disilicides provide nucleation sites for poly-Si growth. With metal-induced growth, the relatively large-grain poly-Si films can be produced at relatively low temperatures on the various foreign substrates. Compared with Ni induced Si films, Co induced poly-Si has longer minority lifetime of 0.46 [mu]s as deposited and 1.3 [mu]s after annealing. A two-step sputtering method used for film deposition showed superiority over single step sputtering by achieving Si films with larger grain size (over 1 [mu]m) and less contamination. A double seed layer (5nm Co/50nm Ni) method was developed to produce the Si film with less Ni diffusion into Si. Metal-induced Si films were deposited on flexible thin tungsten substrates for solar cell fabrication. The good back Ohmic contact (metal disilicide) was formed naturally when the Si film was deposited. In this work, the solar cells were fabricated successfully by using metal-induced grown poly-Si. With the fabricated Schottky and P/N junction solar cells, the metal-induced growth processing parameters were studied. It was found that low-pressure sputtering, oxygen control during film growth, post-annealing and Si film hydrogenation are important to produce high quality poly-Si with fewer defects. The Schottky solar cell with optimized processing parameters showed the J[sub]sc and V[sub]oc of 12 mA/cm2 and 0.2 V, respectively. By passivating the MIG [mu]c-Si surface with hydrogenated nanocrystalline Si (nc-Si:H), the V[sub]oc was improved to 0.31 V. In addition, the current transport mechanism in Schottky and P/N junction devices were studied for different film growth conditions. The results showed that two-step sputtering, oxygen control and hydrogenation improved the quality of the Si film and devices.

Download or read book Physics and Technology of Amorphous Crystalline Heterostructure Silicon Solar Cells written by Wilfried G. J. H. M. van Sark and published by Springer Science & Business Media. This book was released on 2011-11-16 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today’s solar cell multi-GW market is dominated by crystalline silicon (c-Si) wafer technology, however new cell concepts are entering the market. One very promising solar cell design to answer these needs is the silicon hetero-junction solar cell, of which the emitter and back surface field are basically produced by a low temperature growth of ultra-thin layers of amorphous silicon. In this design, amorphous silicon (a-Si:H) constitutes both „emitter“ and „base-contact/back surface field“ on both sides of a thin crystalline silicon wafer-base (c-Si) where the electrons and holes are photogenerated; at the same time, a-Si:H passivates the c-Si surface. Recently, cell efficiencies above 23% have been demonstrated for such solar cells. In this book, the editors present an overview of the state-of-the-art in physics and technology of amorphous-crystalline heterostructure silicon solar cells. The heterojunction concept is introduced, processes and resulting properties of the materials used in the cell and their heterointerfaces are discussed and characterization techniques and simulation tools are presented.

Download or read book Thin Film Solar Cells written by Qiaoer Zhou and published by . This book was released on 2011 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Development and Applications of Oxide Thin Films Using Atomic Layer Deposition and Prompt Inorganic Condensation written by Sean Weston Smith and published by . This book was released on 2015 with total page 117 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the first part of this work, thin films of Al2O3 deposited via atomic layer deposition (ALD) are demonstrated to improve the thermal stability of cellulose nanocrystal (CNC) aerogels. ALD is a chemical vapor deposition (CVD) like method in which sequential precursor exposures and self-limited surface reactions produce a conformal thin film with precise thickness control. The conformal nature of ALD is well suited to coating the porous microstructure of aerogels. SEM micrographs of coating thickness depth profiles are shown to agree with trends predicted by precursor penetration models. Thermogravimetric analysis shows samples coated with ALD Al2O3 have increased decomposition temperatures. In the second part of this work, ALD zinc tin oxide (ZTO) is used to demonstrate a technique for measuring the substrate inhibited growth in multicomponent and laminate ALD systems. The thickness control of ALD makes it attractive for multicomponent and laminate systems. However, the surface reactions of ALD mean that the first few cycles, while the film nucleates, may have a different growth per cycle (GPC) than when the film is growing on itself in a bulk growth regime. A model for the substrate inhibited ALD of ZTO is derived from two complementary sets of laminates. The thickness and composition predictions of our model are tested against the bulk GPC of ZnO and SnO2. In the final part of this work, prompt inorganic condensation (PIC) is explored as a potentially more environmentally friendly alternative to ALD for planar thin film applications. Whereas ALD requires expensive vacuum systems and has low precursor utilization, solution based methods, such as PIC, allow atmospheric processing and precursor recycling. The water based PIC solutions use nitrate counter ions which evaporate at low temperatures. Combined with the low energy required to convert the hydroxide precursor clusters into an oxide film makes PIC a promising low temperature route to dense solution processed thin films. The dielectric performance of PIC Al2O3 is shown to be comparable to ALD Al2O3 films on Si though a large interfacial SiO2 layer is found to be dominating the behavior of the PIC films. This interfacial layer is shown to form very quickly (≤ 2 min) at low temperatures (≤ 50°C). This low temperature interfacial oxide growth could be a benefit in passivating solar cells.

Download or read book Handbook of Manufacturing Engineering and Technology written by Andrew Y. C. Nee and published by Springer. This book was released on 2014-10-31 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Springer Reference Work Handbook of Manufacturing Engineering and Technology provides overviews and in-depth and authoritative analyses on the basic and cutting-edge manufacturing technologies and sciences across a broad spectrum of areas. These topics are commonly encountered in industries as well as in academia. Manufacturing engineering curricula across universities are now essential topics covered in major universities worldwide.

Download or read book Amorphous Thin Films for Solar cell Applications written by RCA Laboratories and published by . This book was released on 1979 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Atomic Layer Deposition in Energy Conversion Applications written by Julien Bachmann and published by John Wiley & Sons. This book was released on 2017-03-15 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Combining the two topics for the first time, this book begins with an introduction to the recent challenges in energy conversion devices from a materials preparation perspective and how they can be overcome by using atomic layer deposition (ALD). By bridging these subjects it helps ALD specialists to understand the requirements within the energy conversion field, and researchers in energy conversion to become acquainted with the opportunities offered by ALD. With its main focus on applications of ALD for photovoltaics, electrochemical energy storage, and photo- and electrochemical devices, this is important reading for materials scientists, surface chemists, electrochemists, electrotechnicians, physicists, and those working in the semiconductor industry.

Download or read book Thin Film Deposition written by Habib Habibur Rahman and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the details theory about Nano technology, Thin films deposition process & practical application of thin films in different types of solar cells. In chapter three, Basic structure of solids, their classifications, Lattice, Basis & Miller indices has been discussed. In chapter four, thin film deposition methods, substrates, solutions preparation, growth mechanisms, advantages, disadvantages & application has been discussed. In chapter five, detailed theory about Spin coating, Spray pyrolysis etc & their growth mechanism, advantages, disadvantages, practical applications has been discussed. In chapter six & seven, An automatic spray pyrolysis system design procedure, fabrications & characterizations of thin films has been discussed. In chapter eight, detailed theory about CVD & PVD, growth mechanism, advantages, disadvantages, practical applications has been discussed. In chapter nine, preparation of ZnO film by using Hydrothermal & Anode oxidation method has been discussed. At last, detailed theory about solar cell, application of thin films in different types of solar cells, their working principle, advantages & efficiency analysis has been discuss

Download or read book In Situ Studies of Silicon based Thin Film Growth for Crystalline Silicon Solar Cells written by Petrus Jacobus van den Oever and published by . This book was released on 2007 with total page 141 pages. Available in PDF, EPUB and Kindle. Book excerpt: First generation, crystalline silicon solar cell technology currently dominates the photovoltaic market, but several technological as well as fundamental developments are needed to sustain a leading position that enables wide-scale implementation of solar electricity. In the manufacturing technology high-throughput systems for the deposition of functional materials applied in solar cells are required, while improved solar cell concepts that yield higher conversion efficiencies or a facilitated fabrication process are crucial to further reduce the costs per unit energy produced. This theis work concentrates on two key issues in the deposition process of silicon-based thin films for crystalline silicon solar cells. First, the deposition of amorphous silicon nitride (a-SiNx:H) antireflection coatings using the expanding thermal plasma (ETP) source was addressed. The second subject of study was the deposition of ultrathin amorphous silicon (a-Si:H) films on wafer substrates, which is of eminent importance in recent applications of a-Si:H for surface passivation and in silicon heterojunction solar cells.

Download or read book Handbook of Deposition Technologies for Films and Coatings written by Peter M. Martin and published by William Andrew. This book was released on 2009-12-01 with total page 932 pages. Available in PDF, EPUB and Kindle. Book excerpt: This 3e, edited by Peter M. Martin, PNNL 2005 Inventor of the Year, is an extensive update of the many improvements in deposition technologies, mechanisms, and applications. This long-awaited revision includes updated and new chapters on atomic layer deposition, cathodic arc deposition, sculpted thin films, polymer thin films and emerging technologies. Extensive material was added throughout the book, especially in the areas concerned with plasma-assisted vapor deposition processes and metallurgical coating applications.

Download or read book The Development of CuIn1 xALSe2 Thin Films for Use in Photovoltaic Solar Cells written by Paresh S. Nasikkar and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of the work presented in this thesis was to develop CuInSe2 (CIS) and CuIni_?Al?Se2 (CIAS) thin films for application in photovoltaic (PV) solar cells. The purpose of the addition of aluminium (Al) in CIS thin films was to modify the energy band gap of the thin films to be nearer to the optimum for PV energy conversion and to replace the less abundant element, gallium (Ga) in CuIni_, Ga, Se2 (CIGS) solar cells. This also makes possible the production of tandem solar cells using CIAS to make the wide energy band gap top cell and the CIS to make the narrow energy band gap lower cell. The use of very thin CIS and CIAS absorber layers in solar cell structures was also investigated; the aim was to reduce the amount of indium (In) in cell production. The CIS and CIAS absorber films were prepared by a sequential two step method in which Cu-In and Cu-In-Al precursor layers were magnetron sputter deposited onto Mo-coated soda lime glass (SLG) substrates; the CIS or CIAS was then formed by heating in a selenium (Se) containing environment. Thin film solar cells were developed in the substrate configuration and had the structure Ni-Al/Indium tin oxide (ITO)/i-ZnO/CdS/CIAS/Mo/SLG. In order to achieve high efficiency solar cells it is an important to optimse the back contact molybdenum (Mo) layer, the absorber layer, the CdS buffer layer, the window layer and top contact layers. The work described in this thesis focused on the optimisation of the back contact and absorber layers. The thin films were characterised mainly using X-ray diffraction (XRD), energy dispersive X-ray analysis (EDS), scanning electron microscopy (SEM), secondary ion mass spectroscopy (MiniSIMS), atomic force microscopy (AFM) and using spectroscopy measurements to investigate the effect of processing conditions on the composition, crystal structure, surface morphology and the optical properties of the films. The solar cells were characterised by current-voltage (/- V) and incident photon-to-photocurrent conversion efficiency (IPCE) measurements. Both Mo single and bilayer structures were investigated. It was found that single layers had better properties than Mo bilayers. The optimisation of the Mo deposition sputtering process yielded Mo layers which had good adherence and were conformal to the glass substrates, had low resistivity (29 if .cm), were pin hole free and had good crystallinity. The influence of Cu-In precursor layers with thicknesses in the range 90-400 nm on the microstructure of the CIS thin films (thicknesses in the range 400-1600 nm) was investigated. Solar cells fabricated from the CIS films of thicknesses 500 nm and 900 nm yielded highest cell conversion efficiencies of 4.3% and 8.2%, respectively. The selenisation of the magnetron sputter deposited Cu-In-Al precursor layers was carried out at a temperature of 550?C. Films were poor in surface quality and adhesion. Films prepared from the precursor layer with n [(Al/(Al+In))] = 0.21 had a non-uniform Al depth profile towards the bottom of the film. Although the film was found to be photoactive its effective energy band gap was 0.98 eV suggesting the properties of CIS. This confirmed incomplete mixing of Al in the thin films which was considered to be segregated at the bottom of the film. The thinner layers of Cu-In-Al precursors with thicknesses in the range 0.55?1.00 gm and n [(Al/Al+In)] in the range 0.28-0.54 were magnetron sputter deposited. The precursor layers showed the prominent binary A1Cu4 compound with a uniform distribution of Al in the layer. Thin films converted from these precursor layers of thicknesses in the range 1.3-2.0 pm were fairly uniform in surface structure. Films with x 0.2 were found to have an energy bandgap of 1.10 eV and were also photoactive. Solar cells fabricated from this absorber film yielded a highest cell efficiency of 4.9%. Environmental impact assessments have been made on materials and the processes used in the fabrication of CIS and CIAS and solar cells. It was found that there is no critical environmental impact of materials and associated processes involved in the fabrication of CIS and CIAS thin film solar cells.

Download or read book Thin Films for Solar Cell Applications written by Ganesh E. Patil and published by LAP Lambert Academic Publishing. This book was released on 2011-04 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solar energy being the most important source of energy, several technologies have been developed for utilization of solar energy. Photovoltaic devices popularly known as solar cells convert solar energy into the electricity which is the most convenient form of energy. Hence thin film photovoltaic technologies are being developed. Thin film solar cell concept is being persued since the inception of photovoltaic devices. For making thin film solar cells many technologies such as CVD, Spray Pyrolysis, Glow Discharge, CBD, Electrodeposition, etc. have been used in the laboratories. The book proposes the simple Chemical Bath Deposition (CBD) technique for synthesizing thin films. The experimental results on synthesis and structural, optical, electrical properties of Cd(S, Se), CdZnS thin films and p-Cu2Se/n-CuBiSe2 hetero- junction thin films for solar cell applications by CBD are discussed. This book will be helpful for students, teachers and researchers for synthesis of thin films by using simple Chemical Bath Deposition technique.

Download or read book Chemical Vapour Deposition written by Anthony C. Jones and published by Royal Society of Chemistry. This book was released on 2009 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The book is one of the most comprehensive overviews ever written on the key aspects of chemical vapour deposition processes and it is more comprehensive, technically detailed and up-to-date than other books on CVD. The contributing authors are all practising CVD technologists and are leading international experts in the field of CVD. It presents a logical and progressive overview of the various aspects of CVD processes. Basic concepts, such as the various types of CVD processes, the design of CVD reactors, reaction modelling and CVD precursor chemistry are covered in the first few"--Jacket

Download or read book Silicon Heterojunction Solar Cells written by W.R. Fahrner and published by Trans Tech Publications Ltd. This book was released on 2006-08-15 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: The world of today must face up to two contradictory energy problems: on the one hand, there is the sharply growing consumer demand in countries such as China and India. On the other hand, natural resources are dwindling. Moreover, many of those countries which still possess substantial gas and oil supplies are politically unstable. As a result, renewable natural energy sources have received great attention. Among these, solar-cell technology is one of the most promising candidates. However, there still remains the problem of the manufacturing costs of such cells. Many attempts have been made to reduce the production costs of “conventional” solar cells (manufactured from monocrystalline silicon using diffusion methods) by instead using cheaper grades of silicon, and simpler pn-junction fabrication. That is the ‘hero’ of this book; the heterojunction solar cell.

Download or read book Molecular Layer Deposition for Tailored Organic Thin Film Materials written by Tetsuzo Yoshimura and published by CRC Press. This book was released on 2023-03-14 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews various types of MLD processes including vapor-phase MLD, liquid-phase MLD, and selective MLD. Introduces organic multiple quantum dots (Organic MQDs) that are typical tailored organic thin-film materials produced by MLD. Designs light modulators/optical switches, predicts their performance, and discusses impacts of the organic MQDs on them. Discusses impacts of the organic MQDs on optical interconnects within computers and on optical switching systems. Presents proposals of MLD applications to energy conversion systems, molecular targeted drug delivery, photodynamic therapy, and laser surgery for cancer therapy.