Download or read book Design and Synthesis of Novel Liquid Crystals and Organic Semiconductors written by Kunlun Wang and published by . This book was released on 2017 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquid crystals have found wide applications due to their unique properties. In order to search for new nematic liquid crystal compounds with relatively low phase transition temperatures, a series of [1,2,3]-triazole-based mesogens and LC dimers were synthesized via the "Click Reaction" under mild conditions and their phase behavior will be presented. Meanwhile, hydrogen-bonded complexes mixed by benzonitrile derivatives and aromatic acetylenes are obtained and their thermal behavior examined. In order to achieve a better understanding of the influence of difluorination on the oligophenyls, a series of partially fluorinated oligomers were obtained and some of their physical properties are compared. Organic semiconductors possess many advantages compared to conventional inorganic semiconductors. Perfluorination was utilized in our molecular design for the synthesis of 1,3,5-triphenyl benzene derivatives and self-assembled crystals via nitrogen-iodine halogen bonding and the target molecules might show some interesting semicondocting properties.
Download or read book Design And Synthesis Of Novel Organic Materials For Liquid Crystal Applications written by Pawan Nepal and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquid crystals (LCs) show unique optical and physical properties, and so these compounds are attractive for many applications, including displays, sensors, reconfigurable mirrors, photonic devices, etc. [1-5]. Due to the cost and performance limitations of devices based on existing LC materials, it is essential to develop novel systems that are cost-effective and with enhanced performance. Also, it is crucial to explore the properties of these soft matter materials with respect to the molecular modifications to better understand their broad applicability. This is especially the case if the phase types involved are recently discovered. Many chiral dopants required for cholesteric preparations are either obtained from conventional chemical synthesis or from plant extracts. So, in search for novel dopants which are of biological origin and are relatively cheaper to produce in large volume, a study has been carried out to develop chiral compounds made from the fermentation derived bio-precursors. Likewise, the recently discovered nematic ferroelectric (NF) LCs [6] have not yet gained practical utility though they have potential to be applied in next generation displays and optoelectronic devices. Although these NF LCs show response towards ultra-small driving voltage ~1V/cm [7], the realistic applications are limited due to their current shortcomings such as monotropic LC phase, high temperature phase transition, thermochemical instability, etc. Thus, to develop novel improved systems and to seek their pragmatic applications, a variety of unique NF LCs have been synthesized and studied. Similarly, to explore the synthetic challenges and the properties related to their structural features, several classic compounds such as cyanobiphenyls (CBs), CB dimers, and triphenylene discotics have been prepared and examined. Reference: [1]Geelhaar, T. Liquid Crystals for Display Applications. Liq. Cryst. 1998, 24 (1), 91-98. https://doi.org/10.1080/026782998207613. [2] White, T. J.; Freer, A. S.; Tabiryan, N. V.; Bunning, T. J. Photoinduced Broadening of Cholesteric Liquid Crystal Reflectors. J. Appl. Phys. 2010, 107 (7). https://doi.org/10.1063/1.3369437. [3] Sergeyev, S.; Pisula, W.; Geerts, Y. H. Discotic Liquid Crystals: A New Generation of Organic Semiconductors. Chem. Soc. Rev. 2007, 36 (12), 1902-1929. https://doi.org/10.1039/b417320c. [4] Kumar, M.; Kumar, S. Liquid Crystals in Photovoltaics : A New Generation of Organic Photovoltaics. 2017, No. July 2016, 85-111. https://doi.org/10.1038/pj.2016.109. [5] Beeckman, J. Liquid-Crystal Photonic Applications. Opt. Eng. 2011, 50 (8), 081202. https://doi.org/10.1117/1.3565046. [6] Chen, X.; Chen, X.; Korblova, E.; Korblova, E.; Dong, D.; Dong, D.; Wei, X.; Wei, X.; Shao, R.; Shao, R.; et al. First-Principles Experimental Demonstration of Ferroelectricity in a Thermotropic Nematic Liquid Crystal: Polar Domains and Striking Electro-Optics. Proc. Natl. Acad. Sci. U. S. A. 2020, 117 (25), 14021-14031. https://doi.org/10.1073/pnas.2002290117. [7] Nishikawa, H.; Shiroshita, K.; Higuchi, H.; Okumura, Y.; Haseba, Y.; Yamamoto, S. I.; Sago, K.; Kikuchi, H. A Fluid Liquid-Crystal Material with Highly Polar Order. Adv. Mater. 2017, 29 (43), 1-8. https://doi.org/10.1002/adma.201702354.
Download or read book Chemistry of Discotic Liquid Crystals written by Sandeep Kumar and published by CRC Press. This book was released on 2016-04-19 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: The self-contained properties of discotic liquid crystals (DLCs) render them powerful functional materials for many semiconducting device applications and models for energy and charge migration in self-organized dynamic functional soft materials. The past three decades have seen tremendous interest in this area, fueled primarily by the possibility
Download or read book Design and Synthesis of Novel Discotic Liquid Crystals written by Himadri Sekhar Kayal and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Liquid Crystalline Semiconductors written by Richard J. Bushby and published by Springer. This book was released on 2014-12-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an exciting stage in the development of organic electronics. It is no longer an area of purely academic interest as increasingly real applications are being developed, some of which are beginning to come on-stream. Areas that have already been commercially developed or which are under intensive development include organic light emitting diodes (for flat panel displays and solid state lighting), organic photovoltaic cells, organic thin film transistors (for smart tags and flat panel displays) and sensors. Within the family of organic electronic materials, liquid crystals are relative newcomers. The first electronically conducting liquid crystals were reported in 1988 but already a substantial literature has developed. The advantage of liquid crystalline semiconductors is that they have the easy processability of amorphous and polymeric semiconductors but they usually have higher charge carrier mobilities. Their mobilities do not reach the levels seen in crystalline organics but they circumvent all of the difficult issues of controlling crystal growth and morphology. Liquid crystals self-organise, they can be aligned by fields and surface forces and, because of their fluid nature, defects in liquid crystal structures readily self-heal. With these matters in mind this is an opportune moment to bring together a volume on the subject of ‘Liquid Crystalline Semiconductors’. The field is already too large to cover in a comprehensive manner so the aim has been to bring together contributions from leading researchers which cover the main areas of the chemistry (synthesis and structure/function relationships), physics (charge transport mechanisms and optical properties) and potential applications in photovoltaics, organic light emitting diodes (OLEDs) and organic field-effect transistors (OFETs). This book will provide a useful introduction to the field for those in both industry and academia and it is hoped that it will help to stimulate future developments.
Download or read book Advances in Liquid Crystals written by Yuan Ming Huang and published by Trans Tech Publications Ltd. This book was released on 2010-01-12 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume is indexed by Thomson Reuters CPCI-S (WoS). Liquid crystals are substances that have properties which are intermediate between those of a conventional liquid and those of a solid crystal. This special collection comprises peer-reviewed papers that are concerned with all aspects of liquid crystal science and technology. The volume consists of five parts: plenary lectures, the molecular design and synthesis of liquid crystals, the characterization of liquid crystals, the applications of liquid crystals, and the emerging technologies and materials relevant to information display.
Download or read book Liquid Crystals written by Tommaso Bellini and published by Springer Science & Business Media. This book was released on 2012-01-21 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluorinated Liquid Crystals: Design of Soft Nanostructures and Increased Complexity of Self-Assembly by Perfluorinated Segments, by Carsten Tschierske Liquid Crystalline Crown Ethers, by Martin Kaller and Sabine Laschat Star-Shaped Mesogens – Hekates: The Most Basic Star Structure with Three Branches, by Matthias Lehmann DNA-Based Soft Phases, by Tommaso Bellini, Roberto Cerbino and Giuliano Zanchetta Polar and Apolar Columnar Phases Made of Bent-Core Mesogens, by N. Vaupotič, D. Pociecha and E. Gorecka Spontaneous Achiral Symmetry Breaking in Liquid Crystalline Phases, by H. Takezoe Nanoparticles in Liquid Crystals and Liquid Crystalline Nanoparticles, by Oana Stamatoiu, Javad Mirzaei, Xiang Feng and Torsten Hegmann Stimuli-Responsive Photoluminescent Liquid Crystals, by Shogo Yamane, Kana Tanabe, Yoshimitsu Sagara and Takashi Kato
Download or read book Novel Chiral Liquid Crystal Organic inorganic Hybrid Nanoparticle Systems written by Ionut Cameliu Ichim and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Synthesis of Novel Liquid Crystal Materials Designed for Electro optic Displays written by N. Carr and published by . This book was released on 1984 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Design and Synthesis of Heterocyclic Discotic Liquid Crystal Materials and Their Application for N type Organic Field effect Transistors written by 朱傑 and published by . This book was released on 2007 with total page 139 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Synthesis of Novel Liquid Crystal Materials Designed for Electro optic Displays written by N. Carr and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Handbook of Liquid Crystals Fundamentals written by Dietrich Demus and published by Wiley-VCH. This book was released on 1998-03-24 with total page 960 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Liquid Crystals is a unique compendium of knowledge on all aspects of liquid crystals. In over 2000 pages the Handbook provides detailed information on the basic principles of both low- and high-molecular weight materials, as well as the synthesis, characterization, modification, and applications (such as in computer displays or as structural materials) of all types of liquid crystals. The five editors of the Handbook are internationally renowned experts from both industry and academia and have drawn together over 70 leading figures in the field as authors. The four volumes of the Handbook are designed both to be used together or as stand-alone reference sources. Some users will require the whole set, others will be best served with a selection of the volumes. Volume 1 deals with the basic physical and chemical principles of liquid crystals, including structure-property relationships, nomenclature, phase behavior, characterization methods, and general synthesis and application strategies. As such this volume provides an excellent introduction to the field and a powerful learning and teaching tool for graduate students and above. Volume 2 concentrates on low-molecular weight materials, for example those typically used in display technology. A high quality survey of the literature is provided along with full details of molecular design strategies, phase characterization and control, and applications development. This volume is therefore by far the most detailed reference source on these industrially very important materials, ideally suited for professionals in the field. Volume 3 concentrates on high-molecular weight, or polymeric, liquid crystals, some of which are found in structural applications and others occur as natural products of living systems. A high-quality literature survey is complemented by full detail of the synthesis, processing, analysis, and applications of all important materials classes. This volume is the most comprehensive reference source on these materials, and is therefore ideally suited for professionals in the field.
Download or read book Handbook of Liquid Crystals Volume 2B written by Dietrich Demus and published by John Wiley & Sons. This book was released on 2011-09-22 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook of Liquid Crystals is a unique compendium of knowledge on all aspects of liquid crystals. In over 2000 pages the Handbook provides detailed information on the basic principles of both low- and high-molecular weight materials, as well as the synthesis, characterization, modification, and applications (such as in computer displays or as structural materials) of all types of liquid crystals. The five editors of the Handbook are internationally renowned experts from both industry and academia and have drawn together over 70 leading figures in the field as authors. The four volumes of the Handbook are designed both to be used together or as stand-alone reference sources. Some users will require the whole set, others will be best served with one or two of the volumes. Volume 1 deals with the basic physical and chemical principles of liquid crystals, including structure-property relationships, nomenclature, phase behavior, characterization methods, and general synthesis and application strategies. As such this volume provides an excellent introduction to the field and a powerful learning and teaching tool for graduate students and above. Volumes 2A and 2B concentrate on low-molecular weight materials, for example those typically used in display technology. A high quality survey of the literature is provided along with full details of molecular design strategies, phase characterization and control, and applications development. These volumes are therefore by far the most detailed reference sources on these industrially very important materials, ideally suited for professionals in the field. Volume 3 concentrates on high-molecular weight, or polymeric, liquid crystals, some of which are found in structural applications and others occur as natural products of living systems. A high-quality literature survey is complemented by full detail of the synthesis, processing, analysis, and applications of all important materials classes. This volume is the most comprehensive reference source on these materials, and is therefore ideally suited for professionals in the field.
Download or read book Liquid Crystals Beyond Displays written by Quan Li and published by John Wiley & Sons. This book was released on 2012-05-29 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry, physics, and applications of liquid crystals beyond LCDs Liquid Crystals (LCs) combine order and mobility on a molecular and supramolecular level. But while these remarkable states of matter are most commonly associated with visual display technologies, they have important applications for a variety of other fields as well. Liquid Crystals Beyond Displays: Chemistry, Physics, and Applications considers these, bringing together cutting-edge research from some of the most promising areas of LC science. Featuring contributions from respected researchers from around the globe, this edited volume emphasizes the chemistry, physics, and applications of LCs in areas such as photovoltaics, light-emitting diodes, filed-effect transistors, lasers, molecular motors, nanophotonics and biosensors. Specific chapters look at magnetic LCs, lyotropic chromonic LCs, LC-based chemical sensors, LCs in metamaterials, and much more. Introducing readers to the fundamentals of LC science through the use of illustrative examples, Liquid Crystals Beyond Displays covers not only the most recent research in the myriad areas in which LCs are being utilized, but also looks ahead, addressing potential future developments. Designed for physicists, chemists, engineers, and biologists working in academia or industry, as well as graduate students specializing in LC technology, this is the first book to consider LC applications across a wide range of fields.
Download or read book Liquid Crystal Dimers written by Sandeep Kumar and published by Cambridge University Press. This book was released on 2017-03-06 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers in-depth discussion of design principles, synthesis and thermal behavior of all types of liquid crystal (LC) dimers. The text presents recent advances in the field of LC dimers consisting of different mesogenic units such as calamitic, discotic and bent-core molecules. It starts with a chapter on the introduction of liquid crystal dimers, including their odd-even behavior, basic classification of dimers and common mesophases in dimers. The text shows how the molecular architectures are being used to develop new materials to study a range of interesting phenomena such as the biaxial nematic phase containing rod-like and disc-like mesogenic units. Finally, the text presents perspectives related to technological relevance of these dimers such as dopants in LC display mixtures exhibiting faster relaxation time, strong flexoelectric coupling and others to effect control over the properties of these materials.
Download or read book The Synthesis and Properties of Liquid Crystals with Bulky Terminal Groups for Bookshelf Geometry Ferroelectric Mixtures written by Ibrahim Ali M. Radini and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The area of liquid crystals has received a substantial research effort over the last century, particularly when the beneficial applications such as Liquid Crystal Displays (LCDs) were realised and developed. The changes to the molecular structure of liquid crystals can have a significant effect upon their mesomorphism and ferroelectric properties. Most of the research in liquid crystal for display applications concentrates on the design and synthesis of novel mesogenic cores to which straight terminal alkyl or alkoxy chains are attached. However, little is known about the effects upon the mesomorphism and ferroelectric properties of varying the terminal chains. The synthesis and mesomorphic properties of a systematic range of ortho difluoroterphenyls with a bulky terminal chain are detailed. The bulky terminal chain consists of either a tertiarybutyl group or a trimethylsilyl unit, each separated from the core by a short (dimethylene) chain, with the other terminal chain being either octyloxy or heptyl. Unusually for liquid crystals with bulky terminal chains, the smectic phase stability (particularly smectic C) is upheld by more than the nematic phase stability, and in most cases the smectic C phase stability is actually higher than comparable analogues with conventional unbranched terminal chains. It is postulated that the surprisingly high smectic C phase stability results from a phase separation effect due to the incompatibility of the spherical bulky group and the conventional unbranched terminal chain, hence implying that the smectic 'layers' are well defined, and such definition of the layers bodes well for bookshelf geometry in ferroelectric mixtures. Two mono- and four trifluoroterphenyls with a bulky terminal chain were prepared in this work to study the effect on the mesomorphic behaviour of varying the degree of fluoro substituents upon the multi-ring system. Two chiral ortho difluoro-substituted terphenyl compounds were prepared also in this work for future ferroelectric mixtures.
