Download or read book Copper and Zinc Stable Isotope Ratios as Tracers of Biogeochemical Processes Sources and Transport of Cu and Zn in Soils written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Copper and Zn are essential micronutrients for plants, animals, and humans; however, they may also be pollutants if they occur at high concentrations in soil. Therefore, knowledge of Cu and Zn cycling in soils is required both for guaranteeing proper nutrition and to control possible risks arising from pollution.rnThe overall objective of my study was to test if Cu and Zn stable isotope ratios can be used to investigate into the biogeochemistry, source and transport of these metals in soils. The use of stable isotope ratios might be especially suitable to trace long-term processes occurring during soil genesis and transport of pollutants through the soil. In detail, I aimed to answer the questions, whether (1) Cu stable isotopes are fractionated during complexation with humic acid, (2) d65Cu values can be a tracer for soil genetic processes in redoximorphic soils (3) d65Cu values can help to understand soil genetic processes under oxic weathering conditions, and (4) d65Cu and d66Zn values can act as tracers of sources and transport of Cu and Zn in polluted soils.rnTo answer these questions, I ran adsorption experiments at different pH values in the laboratory and modelled Cu adsorption to humic acid. Furthermore, eight soils were sampled representing different redox and weathering regimes of which two were influenced by stagnic water, two by groundwater, two by oxic weathering (Cambisols), and two by podzolation. In all horizons of these soils, I determined selected basic soil properties, partitioned Cu into seven operationally defined fractions and determined Cu concentrations and Cu isotope ratios (d65Cu values). Finally, three additional soils were sampled along a deposition gradient at different distances to a Cu smelter in Slovakia and analyzed together with bedrock and waste material from the smelter for selected basic soil properties, Cu and Zn concentrations and d65Cu and d66Zn values.rnMy results demonstrated that (1) Copper was fractionated during adsorpti.
Download or read book Copper and Zinc Stable Isotope Ratios as Tracers of Biogeochemical Processes Sources and Transport of Cu and Zn in Soils written by Moritz Bigalke and published by . This book was released on 2010 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Copper and Iron Stable Isotope Ratios as Tracers of Redox Transformations in Soils written by and published by . This book was released on 2015 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Essential metals for plants Uptake transport regulation of homeostasis and roles in plant development written by Anja Schneider and published by Frontiers Media SA. This book was released on 2023-03-23 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Encyclopedia of Geochemistry written by William M. White and published by Springer. This book was released on 2018-07-24 with total page 1680 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.
Download or read book Investigative Strategies for Lead Source Attribution at Superfund Sites Associated with Mining Activities written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2017-12-01 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Superfund program of the US Environmental Protection Agency (EPA) was created in the 1980s to address human-health and environmental risks posed by abandoned or uncontrolled hazardous-waste sites. Identification of Superfund sites and their remediation is an expensive multistep process. As part of this process, EPA attempts to identify parties that are responsible for the contamination and thus financially responsible for remediation. Identification of potentially responsible parties is complicated because Superfund sites can have a long history of use and involve contaminants that can have many sources. Such is often the case for mining sites that involve metal contamination; metals occur naturally in the environment, they can be contaminants in the wastes generated at or released from the sites, and they can be used in consumer products, which can degrade and release the metals back to the environment. This report examines the extent to which various sources contribute to environmental lead contamination at Superfund sites that are near lead-mining areas and focuses on sources that contribute to lead contamination at sites near the Southeast Missouri Lead Mining District. It recommends potential improvements in approaches used for assessing sources of lead contamination at or near Superfund sites.
Download or read book Ore Deposits written by Sophie Decree and published by John Wiley & Sons. This book was released on 2019-04-23 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: The latest knowledge on mineral ore genesis and the exploration of ore deposits Global demand for metals has risen considerably over the past decade. Geologists are developing new approaches for studying ore deposits and discovering new sources. Ore Deposits: Origin, Exploration, and Exploitation is a compilation of diverse case studies on new prospects in ore deposit geology including atypical examples of mineral deposits and new methods for ore exploration. Volume highlights include: Presentation of the latest research on a range of ore deposit types Application of ore deposits to multiple areas of geology and geophysical exploration Emphasis on diverse methods and tools for the study of ore deposits Useful case studies for geologists in both academia and industry Ore Deposits: Origin, Exploration, and Exploitation is a valuable resource for economic geologists, mineralogists, petrologists, geochemists, mining engineers, research professionals, and advanced students in relevant areas of academic study. Read an interview with the editors to find out more: https://eos.org/editors-vox/developments-in-the-continuing-search-for-new-mineral-deposits
Download or read book Copper Transport and Isotope Fractionation in an Agrosystem written by Izabella Babcsanyi and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the end of the 19th century, the use of copper (Cu)-based fungicides has resulted in increased Cu concentrations in vineyard soils, but also in downstream aquatic ecosystems. The aim of the thesis was to better understand the fate of this Cu in an agrosystem based on assessing Cu isotope fractionation (65Cu/63Cu). The results have shown that the surface vineyard soils have become enriched in Cu from 9 to 28 times compared to the background level during 4 to 5 decades of vine-growing and that clay minerals were the major Cu sorbing phases in the soils. During rainfall, runoff mobilized ~1% of the applied Cu during the, mainly associated with clays. The stormwater wetland collecting the runoff retained in average 68% of the dissolved and more than 92% of particulate Cu. Cu isotope ratios measured in the wetland suggested dissolved Cu sorption to the sediments and in situ reduction of Cu(II) due to biogeochemical processes.
Download or read book Zinc and Copper Isotopic Fractionation During Planetary Differentiation written by Heng Chen and published by . This book was released on 2014 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zinc and copper are two important transition metal elements that are widely involved in every stage of planetary formation and differentiation. Their isotopic ratios are robust tracers used to understand the origin of the Solar System, planetary formation and differentiation processes. In this thesis, I focus on their isotopic behaviors during magmatic processes. I report the Zn isotopic compositions of representative igneous rocks to determine potential isotopic fractionations associated with magmatic processes, and to estimate the bulk silicate Earth value. I report isotopic compositions of various groups of iron meteorites (samples of which represent the core of asteroids) and discuss the data's implications for volatile history of the parent bodies of these meteorites. Chapter 1 is a short introduction to this dissertation. I summarize the geochemical properties of Zn and Cu, and discuss why their isotopes are powerful tracers in geochemistry and cosmochemistry studies. Next I introduce some basic knowledge about the meteorites with an emphasis on irons, which represent most of the meteoritic samples used in this thesis. In addition, I discuss the general concepts of mass-dependent and mass-independent isotopic fractionations, as well as Rayleigh distillation during evaporation processes. Finally, I review the isotopic analysis technique of Zn and Cu using anion-exchange chromatography and MC-ICP-MS. Chapter 2 evaluates Zn isotopic fractionation during magmatic processes and the bulk Earth value. This work has been published in Earth and Planetary Sciences Letters (Chen et al., 2013). Non-traditional stable isotopes are new and powerful proxies in the study of planetary formation and differentiation processes. However, their applications are currently limited by our knowledge of how these isotope systems are affected by igneous processes. This is particularly important because most of the materials available from planetary bodies are differentiated igneous rocks, and therefore, it is necessary to understand isotopic behavior during magmatic processes as well as to evaluate the isotopic composition of the bulk Earth for inter-planetary comparison. In order to assess the isotopic behavior of Zn, I precisely measured the Zn isotopic compositions of two suites of igneous rocks (Kilauea Iki lava lake, Hawaii, and Hekla volcano, Iceland). Results show that Zn isotopes can be fractionated as a result of fractional crystallization; however, the isotopic variation is rather limited (
Download or read book The Anthropocene as a Geological Time Unit written by Jan Zalasiewicz and published by Cambridge University Press. This book was released on 2019-03-07 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews the evidence underpinning the Anthropocene as a geological epoch written by the Anthropocene Working Group investigating it. The book discusses ongoing changes to the Earth system within the context of deep geological time, allowing a comparison between the global transition taking place today with major transitions in Earth history.
Download or read book Selected Water Resources Abstracts written by and published by . This book was released on 1990 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Non Traditional Stable Isotopes written by Fang-Zhen Teng and published by Walter de Gruyter GmbH & Co KG. This book was released on 2017-03-06 with total page 902 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) makes it possible to precisely measure non-traditional stable isotopes. This volume reviews the current status of non-traditional isotope geochemistry from analytical, theoretical, and experimental approaches to analysis of natural samples. In particular, important applications to cosmochemistry, high-temperature geochemistry, low-temperature geochemistry, and geobiology are discussed. This volume provides the most comprehensive review on non-traditional isotope geochemistry for students and researchers who are interested in both the theory and applications of non-traditional stable isotope geochemistry.
Download or read book Investigations Into Isotope Biogeochemistry of Zn in Coastal Areas and Mangroves written by Daniel Ferreira Araujo and published by . This book was released on 2016 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coastal areas worldwide are under strong pressure from anthropogenic contamination, as most of the global population and of economic activities are concentrated along the coasts and estuaries. The threaten of contaminant releasing into these ecosystems makes imperative the development of tools capable of detecting biogeochemical changes in order to help prevention, monitoring and prediction of risks in environmental studies. In this way, this thesis investigates the isotope biogeochemistry of Zinc (Zn) in order to develop a tool capable of tracing natural and anthropogenic sources, identifying biogeochemical processes and enabling the biomonitoring of metal contamination in coastal areas and mangroves. To this end, Zn isotopes compositions were determined in several natural samples collected from Sepetiba bay (southeastern Brazil), an estuarine-lagoon impacted by an industrialized coastal area near Rio de Janeiro. This bay constitutes an ideal natural laboratory for evaluating the Zn isotopic system to environmental issues, since it hosts important ecosystems of commercial and ecological interest - estuaries, mangroves and tidal flats - threaten by the metal contamination resultant of old electroplating activity and other anthropogenic diffuse sources. The collected samples include sediment cores, surface mangrove sediments, suspended particulate matter (SPM), leaves of mangrove's trees, tissues of bivalve mollusks (oysters and mussels) and rocks. Ores from Vazante deposit, Brazil were collected to represent the raw material used in the old electroplating industry. Firstly, an initial laboratory work established a method for accurate and precise determinations of Zn isotope compositions in natural samples by multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). Spatial and temporal analysis of Zn isotope compositions of sediment and rock samples fits well in a model of mixing between three main end-members: i) continental materials brought via rivers; ii) marine sources; and iii) a major anthropogenic source associated to the old electroplating wastes released into the bay. Sediment cores collected in the mud flat showed high correlation between Zn isotope compositions and Zn enrichment factors, suggesting (i) good preservation of isotopic records of natural and anthropogenic sources and (ii) no significant isotopic fractionation during sediment transport or as a result of diagenetic reactions post-deposition in the estuarine system. The sediment core sampled from a mangrove located in the zone impacted by the old electroplating activity presented levels of Zn up to 4% (dry weight) and preserved the isotopic signatures of electroplating wastes. However, there is evidence that biogeochemical processes triggered by hydrodynamics, bioturbation or rhizosphere processes slightly changed the isotopic signatures in some layers. Calculations based in this mixing model quantified contributions of the major anthropogenic source of Zn, ranging from negligible values in the pre-industrial period to nearly 80% during periods of electroplating activities between the 60's and 90's.
Download or read book Selected Water Resources Abstracts written by and published by . This book was released on 1990 with total page 1344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Compilation of Minimum and Maximum Isotope Ratios of Selected Elements in Naturally Occurring Terrestrial Materials and Reagents written by Tyler B. Coplen and published by . This book was released on 2002 with total page 112 pages. Available in PDF, EPUB and Kindle. Book excerpt: Documented variations in the isotopic compositions of some chemical elements are responsible for expanded uncertainties in the standard atomic weights published by the Commission on Atomic Weights and Isotopic Abundances of the International Union of Pure and Applied Chemistry. This report summarizes reported variations in the isotopic compositions of 20 elements that are due to physical and chemical fractionation processes (not due to radioactive decay) and their effects on the standard atomic weight uncertainties. For 11 of those elements (hydrogen, lithium, boron, carbon, nitrogen, oxygen, silicon, sulfur, chlorine, copper, and selenium), standard atomic weight uncertainties have been assigned values that are substantially larger than analytical uncertainties because of common isotope abundance variations in materials of natural terrestrial origin. For 2 elements (chromium and thallium), recently reported isotope abundance variations potentially are large enough to result in future expansion of their atomic weight uncertainties. For 7 elements (magnesium, calcium, iron, zinc, molybdenum, palladium, and tellurium), documented isotope-abundance variations in materials of natural terrestrial origin are too small to have a significant effect on their standard atomic weight uncertainties.
Download or read book Handbook of Environmental Isotope Geochemistry written by Mark Baskaran and published by Springer Science & Business Media. This book was released on 2011-10-13 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt: Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies.
Download or read book Biogeochemistry of Trace Metals written by Domy C. Adriano and published by CRC Press. This book was released on 2017-07-28 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biogeochemistry of Trace Metals is a compendium of the most recent information available on the effects of trace metals in soil quality and its potential threat on the transfer of these contaminants to consumers. Most of the chapters in the book were presented as papers during the First International Conference on the Biogeochemistry of Trace Elements (formerly Metals in Soils, Plants, Waters, and Animals) held in Orlando, Florida in May, 1990. Topics discussed include background levels of metals in soils and/or plants (covering western Europe; temperate, humid Europe; and the People's Republic of China); metal cycling and transfer in the food chain in agroecosystems; uptake and accumulation of metals by bacteria, fungi, and invertebrates; mechanistic aspects of metals; the microbial aspects of soil selenium losses; and manganese sorption on soil constituents.
