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Book A STUDY OF CORROSION AND STRESS CORROSION CRACKING OF CARBON STEEL NUCLEAR WASTE STORAGE TANKS

Download or read book A STUDY OF CORROSION AND STRESS CORROSION CRACKING OF CARBON STEEL NUCLEAR WASTE STORAGE TANKS written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Hanford reservation Tank Farms in Washington State has 177 underground storage tanks that contain approximately 50 million gallons of liquid legacy radioactive waste from cold war plutonium production. These tanks will continue to store waste until it is treated and disposed. These nuclear wastes were converted to highly alkaline pH wastes to protect the carbon steel storage tanks from corrosion. However, the carbon steel is still susceptible to localized corrosion and stress corrosion cracking. The waste chemistry varies from tank to tank, and contains various combinations of hydroxide, nitrate, nitrite, chloride, carbonate, aluminate and other species. The effect of each of these species and any synergistic effects on localized corrosion and stress corrosion cracking of carbon steel have been investigated with electrochemical polarization, slow strain rate, and crack growth rate testing. The effect of solution chemistry, pH, temperature and applied potential are all considered and their role in the corrosion behavior will be discussed.

Book Radioactive Waste Processing and Disposal

Download or read book Radioactive Waste Processing and Disposal written by U.S. Nuclear Regulatory Commission and published by . This book was released on 1980 with total page 908 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book POTENTIAL FOR STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS CONTAINING HIGHLY CAUSTIC SOLUTIONS

Download or read book POTENTIAL FOR STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS CONTAINING HIGHLY CAUSTIC SOLUTIONS written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The evaporator recycle streams of nuclear waste tanks may contain waste in a chemistry and temperature regime that exceeds the current corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history found that two of these A537 carbon steel tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved tanks of similar construction. Therefore, it appears that the efficacy of stress relief of welding residual stress is the primary corrosion-limiting mechanism. The objective of this experimental program is to test A537 carbon steel small scale welded U-bend specimens and large welded plates (30.48 x 30.38 x 2.54 cm) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in these nuclear waste tanks. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test was completed after 12 weeks of immersion in a similar solution at 125 C except that the aluminate concentration was reduced to 0.3 M. Visual inspection of the plate revealed that stress corrosion cracking had not initiated from the machined crack tips in the weld or in the heat affected zone. NDE ultrasonic testing also confirmed subsurface cracking did not occur. Based on these results, it can be concluded that the environmental condition of these tests was unable to develop stress corrosion cracking within the test periods for the small welded U-bends and for the large plates, which were welded with an identical procedure as used in the construction of the actual nuclear waste tanks in the 1960s. The absence of evidence of stress corrosion cracking and general corrosion in the laboratory-scaled specimens indicate that this type of nuclear waste tank is not susceptible to highly caustic solutions up to 12 M hydroxide at 125 C when sufficient nitrite inhibitor is present.

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1994 with total page 806 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.

Book Bombita y la Goya

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  • Pages : 18 pages

Download or read book Bombita y la Goya written by and published by . This book was released on with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Nuclear Science Abstracts

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1975 with total page 1212 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book INVESTIGATION OF THE POTENTIAL FOR CAUSTIC STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS

Download or read book INVESTIGATION OF THE POTENTIAL FOR CAUSTIC STRESS CORROSION CRACKING OF A537 CARBON STEEL NUCLEAR WASTE TANKS written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The evaporator recycle streams contain waste in a chemistry and temperature regime that may be outside of the current waste tank corrosion control program, which imposes temperature limits to mitigate caustic stress corrosion cracking (CSCC). A review of the recent service history (1998-2008) of Tanks 30 and 32 showed that these tanks were operated in highly concentrated hydroxide solution at high temperature. Visual inspections, experimental testing, and a review of the tank service history have shown that CSCC has occurred in uncooled/un-stress relieved F-Area tanks. Therefore, for the Type III/IIIA waste tanks the efficacy of the stress relief of welding residual stress is the only corrosion-limiting mechanism. The objective of this experimental program is to test carbon steel small scale welded U-bend specimens and large welded plates (12 x 12 x 1 in.) in a caustic solution with upper bound chemistry (12 M hydroxide and 1 M each of nitrate, nitrite, and aluminate) and temperature (125 C). These conditions simulate worst-case situations in Tanks 30 and 32. Both as-welded and stress-relieved specimens have been tested. No evidence of stress corrosion cracking was found in the U-bend specimens after 21 days of testing. The large plate test is currently in progress, but no cracking has been observed after 9 weeks of immersion. Based on the preliminary results, it appears that the environmental conditions of the tests are unable to develop stress corrosion cracking within the duration of these tests.

Book Corrosion Considerations for Life Management of Hanford High level Waste Tanks

Download or read book Corrosion Considerations for Life Management of Hanford High level Waste Tanks written by and published by . This book was released on 1993 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential for corrosion-related aging mechanisms to be active in the Hanford Site waste tanks is frequently questioned and there are related uncertainties. This paper considers surveillance and analyses for evaluating the potential influence of corrosion processes such as stress corrosion cracking, pitting, crevice corrosion of the reinforced concrete steel on the useful life of Hanford radioactive waste tanks. There are two types of Hanford Site underground reinforced concrete, carbon steel lined waste tank structures. They primarily store caustic nitrate wastes, some at elevated temperatures, from defense reprocessing of spent nuclear fuels. Some of the Hanford waste tanks have leaked radioactive liquid waste to the soil. These leaks are possibly due to nitrate-induced stress corrosion cracking. Major efforts prescribed to avoid nitrate-induced stress corrosion cracking in newer tank designs appear successful. A potential for pitting and crevice corrosion cracking in the carbon steel liners exists. There has been no evidence of significant uniform corrosion of the carbon steel liners and there has been no evidence of waste tank degradation caused by corrosion of the concrete reinforcing steel. A waste tank life management program is being developed to qualify the Hanford waste tanks for continued safe storage of these wastes. Corrosion evaluations, structural analyses, and surveillance are required to qualify the tanks and to promptly detect evidence of possible distress.

Book Localized Corrosion and Stress Corrosion Cracking of Candidate Materials for High level Radioactive Waste Disposal Containers in the US

Download or read book Localized Corrosion and Stress Corrosion Cracking of Candidate Materials for High level Radioactive Waste Disposal Containers in the US written by and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Container materials may undergo any of several modes of degradation in this environment, including: undesirable phase transformations due to lack of phase stability; atmospheric oxidation; general aqueous corrosion; pitting; crevice corrosion; intergranular stress corrosion cracking (IGSCC); and transgranular stress corrosion cracking (TGSCC). This paper is an analysis of data from the literature relevant to the pitting, crevice corrosion, and stress corrosion cracking (SCC) of these alloys. Though all three austenitic candidates have demonstrated pitting and crevice corrosion in chloride-containing environments, Alloy 825 has the greatest resistance to these forms of localized attack. Both types 304L and 316L stainless steels are susceptible to SCC in acidic chloride media. In contrast, SCC has not been documented for Alloy 825 under comparable conditions. Gamma irradiation has been found to enhance SCC of Types 304 and 304L stainless steels, but it has no detectable effect on the resistance of Alloy 825 to SCC. Furthermore, while microbiologically induced corrosion effects have been observed for 300-series stainless steels, nickel-based alloys such as Alloy 825 seem to be immune to such problems. Of the copper-based alloys, CDA 715 has the best overall resistance to localized attack. Its resistance to pitting is comparable to that of CDA 613 and superior to that of CDA 102. Observed rates of dealloying in CDA 715 are less than those observed in CDA 613 by orders of magnitude. The resistance of CDA 715 to SCC in tarnishing ammonical environments is comparable to that of CDA 102 and superior to that of CDA 613. Its resistance to SCC in nontarnishing ammonical environments is comparable to that of CDA 613 and superior to that of CDA 102. 22 refs., 8 figs., 4 tabs.

Book The Potential for Stress Corrosion Cracking of Copper Containers in a Canadian Nuclear Fuel Waste Disposal Vault

Download or read book The Potential for Stress Corrosion Cracking of Copper Containers in a Canadian Nuclear Fuel Waste Disposal Vault written by F. King and published by Pinawa, Man. : Whiteshell Laboratories. This book was released on 1996 with total page 82 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Localized Corrosion and Stress Corrosion Cracking of Candidate Materials for High level Radioactive Waste Disposal Containers in the US

Download or read book Localized Corrosion and Stress Corrosion Cracking of Candidate Materials for High level Radioactive Waste Disposal Containers in the US written by J. C. Farmer and published by . This book was released on 1988 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: Container materials may undergo any of several modes of degradation in this environment, including: undesirable phase transformations due to lack of phase stability; atmospheric oxidation; general aqueous corrosion; pitting; crevice corrosion; intergranular stress corrosion cracking (IGSCC); and transgranular stress corrosion cracking (TGSCC). This paper is an analysis of data from the literature relevant to the pitting, crevice corrosion, and stress corrosion cracking (SCC) of these alloys. Though all three austenitic candidates have demonstrated pitting and crevice corrosion in chloride-containing environments, Alloy 825 has the greatest resistance to these forms of localized attack. Both types 304L and 316L stainless steels are susceptible to SCC in acidic chloride media. In contrast, SCC has not been documented for Alloy 825 under comparable conditions. Gamma irradiation has been found to enhance SCC of Types 304 and 304L stainless steels, but it has no detectable effect on the resistance of Alloy 825 to SCC. Furthermore, while microbiologically induced corrosion effects have been observed for 300-series stainless steels, nickel-based alloys such as Alloy 825 seem to be immune to such problems. Of the copper-based alloys, CDA 715 has the best overall resistance to localized attack. Its resistance to pitting is comparable to that of CDA 613 and superior to that of CDA 102. Observed rates of dealloying in CDA 715 are less than those observed in CDA 613 by orders of magnitude. The resistance of CDA 715 to SCC in tarnishing ammonical environments is comparable to that of CDA 102 and superior to that of CDA 613. Its resistance to SCC in nontarnishing ammonical environments is comparable to that of CDA 613 and superior to that of CDA 102.

Book Radioactive Waste Management

Download or read book Radioactive Waste Management written by and published by . This book was released on 1981 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book TID

Download or read book TID written by and published by . This book was released on 1958 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Influence of Microstructure on Stress Corrosion Cracking of Mild Steel in Synthetic Caustic nitrate Nuclear Waste Solution

Download or read book Influence of Microstructure on Stress Corrosion Cracking of Mild Steel in Synthetic Caustic nitrate Nuclear Waste Solution written by and published by . This book was released on 1975 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The influence of alloy microstructure on stress corrosion cracking of mild steel in caustic-nitrate synthetic nuclear waste solutions was studied. An evaluation was made of the effect of heat treatment on a representative material (ASTM A 516 Grade 70) used in the construction of high activity radioactive waste storage tanks at Savannah River Plant. Several different microstructures were tested for susceptibility to stress corrosion cracking. Precracked fracture specimens loaded in either constant load or constant crack opening displacement were exposed to a variety of caustic-nitrate and nitrate solutions. Results were correlated with the mechanical and corrosion properties of the microstructures. Crack velocity and crack arrest stress intensity were found to be related to the yield strength of the steel microstructures. Fractographic evidence indicated pH depletion and corrosive crack tip chemistry conditions even in highly caustic solutions. Experimental results were compatible with crack growth by a strain- assisted anodic dissolution mechanism; however, hydrogen embrittlement also was considered possible. (auth).

Book Radioactive Waste Processing and Disposal

Download or read book Radioactive Waste Processing and Disposal written by and published by . This book was released on 1958 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Lubrication  Corrosion and Wear

Download or read book Lubrication Corrosion and Wear written by United States. National Aeronautics and Space Administration Scientific and Technical Information Division and published by . This book was released on with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: