Download or read book Unsteady Flamelet Modeling of NOx and CO Formation in Hydrocarbon Diffusion Flames written by Naif Mohammed Al-Abbadi and published by . This book was released on 1996 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book NOx Formation in Unsteady Counterflow Diffusion Flames written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The formation of NO and NO2 are sensitive indicators of both temperature and residence time. In this work, the NOx emission index is measured in an unsteady counterflow diffusion flame for methane, propane and ethylene, as a function of average strain rate and amplitude and frequency of imposed sinusoidal oscillation. The flames studied vary from non-sooting to high soot loading, and from low average strain rate to near extinction. Due to the relatively long time scales associated with NOx formation, the effect of unsteadiness on emission index is weaker than on either temperature or soot volume fraction. Time average global measurements were taken using a California Analytical Instruments Model 400 HCLD NO/NOx analyzer. Results are compared with unsteady calculations using a modified OPPDIF code included in the Chemkin package.
Download or read book Modeling of NOx Formation in Turbulent Flames written by Weizhen Zhang and published by . This book was released on 1995 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book NOx Formation in Unsteady Counterflow Diffusion Flames written by Christopher Dwayne DeBruhl and published by . This book was released on 2003 with total page 67 pages. Available in PDF, EPUB and Kindle. Book excerpt: Keywords: Counterflow diffusion flames Nox.
Download or read book Effect of Pressure on Structure and NOx Formation in CO Air Diffusion Flames written by Howard G. Maahs and published by . This book was released on 1979 with total page 62 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Unsteady Flamelet Modeling of Pollutant Emission in Diffusion Flame written by N. Al-Abbadi and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Modeling of NOx Formation in Diffusion Flame Combustors written by N. K. Rizk and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Influence of Fuel Structure on CO and NOx Formation in Lean Premixed Hydrocarbon Flames written by and published by . This book was released on 1909 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A study is made of the influence chemical structure of fuel has upon combustion performance through tracing the generation of carbon monoxide and oxides of nitrogen in lean, premixed, hydrocarbon-air flames. The study includes both analytical and experimental investi- gations. On the analytical side, a kinetic model is developed to predict both CO and NO time-histories in one-dimensional, premixed flames. The model is based upon the assumption of partial equilibrium in the post-flame zone while the fuel oxidation in the main reaction zone is allowed for by using a global oxidation rate equation. NO formation is assumed to be entirely via the Zeldovitch mechanism and to start in the post-flame zone. The utility of the model is judged through comparison between theoretical results and experimental data. On the experimental side, a simple burner system, supporting a one-dimensional premixed flame was designed and built. All fuels selected for investigation were pure hydrocarbons representing the main hydrocarbon types usually found in practical fuels; namely paraffins, olefins, naphthenes and aromatics. The hydrogen-to-carbon ratio ranged from 1 to 2.67 and the carbon number from 3 to 12. The experiments were performed at 1,2 and 3 atm pressure levels and 140°C inlet temperature, while the equivalence ratio was in the range 0.6 to 0.9. Flames were sampled for most stable species by a water- cooled stainless steel sampling probe. The experimental results show that the fuel structure signifi- cantly affects CO time-histories in the investigated flames mainly through influencing its generation rather than its burnout. CO burnout is shown to be mainly controlled by radical recombination processes, and the experimentally derived CO global oxidation rate equations are found not to be universally applicable. The results also show that the fuel structure influences prompt NOx formation within, and very near, the main reaction zone but that it does not influence post-equilibriu.
Download or read book Dissertation Abstracts International written by and published by . This book was released on 1996 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Emission Modeling in Turbulent Premixed Flames written by Hongtao Yang and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Turbulent lean premixed combustion now plays a predominant role in reducing emission of pollutants such as NOx. For turbulent premixed flames located in the thin-reaction-zones regime, small-scale eddies could penetrate into the preheat zone of the flames and enhance the mixing process. In this study, the effects of small-scale turbulence on emission (NOx and CO) formation in premixed flame fronts are investigated through the incorporation of turbulence induced diffusion in the preheat zone of one-dimensional premixed flames. One-dimensional methane/air premixed flames are simulated with the 53-species GRI-Mech 3.0 mechanism at both atmospheric and engine conditions with different turbulence intensities. It is found that the NO generated in flame fronts deceases with increasing intensity of small-scale turbulence and the effect is more profound at high pressures. At high pressures, the turbulence induced diffusion in the preheat zone can reduce the NOx formation in flame fronts by more than 40%. On the other hand, the CO mass fraction in flame fronts increases with increasing intensity of small-scale turbulence. In the cases considered, the CO mass fraction in the flame fronts can increase by more than 55%. In addition, a flamelet-based approach that accounts for the flame thickening effects has been formulated to simulate NOx and CO formation in turbulent lean premixed combustion. In this approach, the species NO and CO are transported and solved in a simulation with chemical source terms being pre-calculated from 1-D premixed flames with detailed chemical kinetics and turbulence induced diffusion. The NO source term can be quantified by its formation in flame fronts and its formation rate in post-flame region. The CO source term can be calculated through its mass fraction at flame fronts, its mass fraction in the post-flame region and an oxidation time scale. The effect of heat loss on NO formation has been studied by investigate the relation between post-flame NO formation rate and flame temperature. Meanwhile, the effect of turbulent-chemistry interaction on NO were studied. The flamelet-based emission model has been implemented into Fluent and 3-Dimensional simulations were conducted in a combustion rig.
Download or read book Effect of Pressure on Structure and NO Sub X Formation in CO air Diffusion Flames written by and published by . This book was released on 1979 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Turbulent Reactive Flows written by R. Borghi and published by Springer Science & Business Media. This book was released on 2013-03-08 with total page 958 pages. Available in PDF, EPUB and Kindle. Book excerpt: Turbulent reactive flows are of common occurrance in combustion engineering, chemical reactor technology and various types of engines producing power and thrust utilizing chemical and nuclear fuels. Pollutant formation and dispersion in the atmospheric environment and in rivers, lakes and ocean also involve interactions between turbulence, chemical reactivity and heat and mass transfer processes. Considerable advances have occurred over the past twenty years in the understanding, analysis, measurement, prediction and control of turbulent reactive flows. Two main contributors to such advances are improvements in instrumentation and spectacular growth in computation: hardware, sciences and skills and data processing software, each leading to developments in others. Turbulence presents several features that are situation-specific. Both for that reason and a number of others, it is yet difficult to visualize a so-called solution of the turbulence problem or even a generalized approach to the problem. It appears that recognition of patterns and structures in turbulent flow and their study based on considerations of stability, interactions, chaos and fractal character may be opening up an avenue of research that may be leading to a generalized approach to classification and analysis and, possibly, prediction of specific processes in the flowfield. Predictions for engineering use, on the other hand, can be foreseen for sometime to come to depend upon modeling of selected features of turbulence at various levels of sophistication dictated by perceived need and available capability.
Download or read book Modeling of NOx Formation in Circular Laminar Jet Flames written by Vivek Siwatch and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Emissions of oxides of nitrogen (NOx) from combustion devices is a topic of tremendous current importance. The bulk of the review of NOx emissions has been in the field of turbulent jet flames. However laminar jet flames have provided much insight into the relative importance of NOx reaction pathways in non premixed combustion for various flame conditions. The existing models include detailed chemistry kinetics for various species involved in the flame. These detailed models involve very complex integration of hundreds of chemical reactions of various species and their intermediates. Hence such models are highly time consuming and also normally involve heavy computational costs. This work proposes a numerical model to compute the total production of NOx in a non-premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount of air entrainment by jet depends upon the Sc number of fuel. The higher the Sc number, the higher is the air entrained which lowers the flame temperature and hence NOx formation. With increasing Sc number, flame volume increases which leads to an increase in the NOx formation. The effect of the Sc number variation on the net production of NOx and flame structure is also investigated. The effect of equilibrium chemistry for CO2 - CO + 1/2 O2 and H2O - H2 +1/2 O2 on total NOx emission is studied. Also the effect of both CO2 and H2O equilibrium is considered simultaneously and the net NOx formation for propane is 45 ppm. The splitbetween pre-flame and post-flame regions is also investigated. For Propane, 96% of NOx emissions occur in the pre-flame region and about 4% in the post-flame region. The model predictions are compared with experimental values of NOx missions reported elsewhere.
Download or read book 30th AIAA ASME SAE ASEE Joint Propulsion Conference written by and published by . This book was released on 1994 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Cleaner Combustion written by Frédérique Battin-Leclerc and published by Springer Science & Business Media. This book was released on 2013-09-06 with total page 657 pages. Available in PDF, EPUB and Kindle. Book excerpt: This overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons, mechanism reduction and uncertainty analysis, and elementary reactions. This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field.
Download or read book Ammonia Conversion and NOx Formation in Laminar Coflowing Nonpremixed Methane air Flames written by and published by . This book was released on 2002 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: This paper reports on a combined experimental and modeling investigation of NOx formation in nitrogen-diluted laminar methane diffusion flames seeded with ammonia. The methane-ammonia mixture is a surrogate for biomass fuels which contain significant fuel-bound nitrogen. The experiments use flue-gas sampling to measure the concentration of stable species in the exhaust gas, including NO, O2, CO, and CO2. The computations evolve a two-dimensional low Mach number model using a solution-adaptive projection algorithm to capture fine-scale features of the flame. The model includes detailed thermodynamics and chemical kinetics, differential diffusion, buoyancy, and radiative losses. The model shows good agreement with the measurements over the full range of experimental NH3 seeding amounts. As more NH3 is added, a greater percentage is converted to N2 rather than to NO. The simulation results are further analyzed to trace the changes in NO formation mechanisms with increasing amounts of ammonia in the fuel.
Download or read book Turbulent Combustion written by Norbert Peters and published by Cambridge University Press. This book was released on 2000-08-15 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: The combustion of fossil fuels remains a key technology for the foreseeable future. It is therefore important that we understand the mechanisms of combustion and, in particular, the role of turbulence within this process. Combustion always takes place within a turbulent flow field for two reasons: turbulence increases the mixing process and enhances combustion, but at the same time combustion releases heat which generates flow instability through buoyancy, thus enhancing the transition to turbulence. The four chapters of this book present a thorough introduction to the field of turbulent combustion. After an overview of modeling approaches, the three remaining chapters consider the three distinct cases of premixed, non-premixed, and partially premixed combustion, respectively. This book will be of value to researchers and students of engineering and applied mathematics by demonstrating the current theories of turbulent combustion within a unified presentation of the field.
