Download or read book Tuning Mechanics of Bio inspired Polymeric Materials Through Supramolecular Chemistry written by Seyedali Monemian and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic polymers can be designed to meet a particular mechanical criterion, but it is still a challenge to design a polymeric material, which simultaneously exhibits strength and ductility, and elasticity. However, natural materials show exceptional mechanical performance, modulated by composition, environmental triggers, and architecture. One lesson from nature is the combination of weak supramolecular interactions and strong covalent bonds. Understanding of materials, such as the muscle protein titin that exhibits these hierarchical elements, provides inspiration to design polymers with novel mechanics. We explored multiple strategies to develop hierarchical and functional bio-inspired materials: First part of this dissertation focuses on a self-complementary, hydrogen bonding linkage coupled with ultraviolet (UV) crosslinking to design supramolecular elastomers with tunable mechanical response. This interplay of dynamic hydrogen-bonded network and covalently crosslinked network resulted in a range of mechanical performance, controlled via the concentration of hydrogen bonding moieties and the UV curing time. Of particular note, this unique combination dramatically enhanced mechanical response of the UPy-functionalized elastomers, yielding toughness enhancement up to ~200×. In second part of this dissertation, a new class of "supramolecular interpenetrating polymer networks (Supramolecular IPNs)" was introduced where the phase-separated structure of IPNs with dynamic hydrogen-bond forming supramolecular associations and UV cross-linking sites led to materials with both increased extensibility and strength. Fascinatingly, the strong interphase region of the dissimilar networks, along with the dynamic nature of hydrogen bond-forming supramolecular associations yielded up to ~600× enhancement of mechanical toughness. In another effort, the interplay of dynamic hydrogen-bond forming supramolecular associations and phase-segregation - induced by UV crosslinking of pendent vinyl moieties - was exploited to generate vesicles and droplet-decorated vesicles on a submicron scale in model supramolecular IPNs. Of particular note is, these structures were formed in the bulk via combination of thermal activation above order-to-disorder transition (ODT) temperature of supramolecular polymer component and UV-crosslinking induced phase-segregation, without the aid of solvophobic interactions or a dewetting process on the substrate. This facile approach may serve as a platform for the design of self-assembled architectures utilizing dynamic polymeric materials.
Download or read book Supramolecular Design for Biological Applications written by Nobuhiko Yui and published by CRC Press. This book was released on 2002-03-11 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular chemistry is the outburst topic of the next generation of science. While the majority of biomedical research efforts to date have centered on utilizing well-known polymeric materials, the recent progress in supramolecular chemistry has introduced a fascinating new field of macromolecular architecture. Supramolecular Design fo
Download or read book Bio inspired Polymers written by Nico Bruns and published by Royal Society of Chemistry. This book was released on 2016-10-14 with total page 613 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many key aspects of life are based on naturally occurring polymers, such as polysaccharides, proteins and DNA. Unsurprisingly, their molecular functionalities, macromolecular structures and material properties are providing inspiration for designing new polymeric materials with specific functions, for example, responsive, adaptive and self-healing materials. Bio-inspired Polymers covers all aspects of the subject, ranging from the synthesis of novel polymers, to structure-property relationships, materials with advanced properties and applications of bio-inspired polymers in such diverse fields as drug delivery, tissue engineering, optical materials and lightweight structural materials. Written and edited by leading experts on the topic, the book provides a comprehensive review and essential graduate level text on bio-inspired polymers for biochemists, materials scientists and chemists working in both industry and academia.
Download or read book Supramolecular Chemistry of Biomimetic Systems written by Junbai Li and published by Springer. This book was released on 2017-10-10 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book investigates the latest developments in supramolecular assembly systems for mimicking biological structures and functions. Consisting of 14 chapters, it covers various assembly systems, such as polysaccharides, peptides, proteins, biopolymers, natural materials and various hybrid systems. Further, it focuses on different types of supramolecular systems with particular functions or structures that are relevant to living systems. A number of modern techniques used to study the supramolecular systems, such as total internal reflection fluorescence microscopy (TIRFM) and two-photon confocal microscopy, are also introduced in detail. Unlike conventional books on supramolecular assemblies, this book highlights the functions of the assembly systems, particularly their biological applications. As such, it offers a valuable resource for experienced researchers, as well as graduate students working in the field of supramolecular chemistry and biomimetic systems.
Download or read book Synthesis of Functional Hydrogels written by Weifeng Zhao and published by Frontiers Media SA. This book was released on 2020-07-28 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bio Inspired Nanotechnology written by Kaushik Pal and published by Bentham Science Publishers. This book was released on 2023-02-28 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-Inspired Nanotechnology focuses on the use of bio-inspired and biomimetic methods for the fabrication and activation of nanomaterials. It summarizes recent developments in biocompatible and biodegradable materials, including their properties, fabrication methods, synthesis protocols, and applications. This includes studies concerning the binding of the biomolecules to the surface of inorganic structures, structure/function relationships of the final materials, and unique applications of such biomimetic materials in harvesting/storage, biomedical diagnostics, and materials assembly. The book chapters also cover a range of available bio-based nanomaterials, including chitin, starch and nanocellulose. It serves as a detailed reference for learners and anyone interested in sustainable nanoscale materials, including materials scientists, biomedical engineers, environmental scientists, food and agriculture manufacturers and scientists.
Download or read book Biomimetics in Materials Science written by Michael Nosonovsky and published by Springer Science & Business Media. This book was released on 2011-12-07 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomimetics in Materials Science provides a comprehensive theoretical and practical review of biomimetic materials with self-healing, self-lubricating and self-cleaning properties. These three topics are closely related and constitute rapidly developing areas of study. The field of self-healing materials requires a new conceptual understanding of this biomimetic technology, which is in contrast to traditional engineering processes such as wear and fatigue. Biomimetics in Materials Science is the first monograph to be devoted to these materials. A new theoretical framework for these processes is presented based on the concept of multi-scale structure of entropy and non-equilibrium thermodynamics, together with a detailed review of the available technology. The latter includes experimental, modeling, and simulation results obtained on self-healing/lubricating/cleaning materials since their emergence in the past decade.
Download or read book Supramolecular Chemistry in Corrosion and Biofouling Protection written by Viswanathan S. Saji and published by CRC Press. This book was released on 2021-12-23 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular chemistry, "the chemistry beyond the molecule", is a fascinating realm of modern science. The design of novel supramolecular structures, surfaces, and techniques are at the forefront of research in different application areas, including corrosion and biofouling protection. A team of international experts provide a comprehensive view of the applications and potential of supramolecular chemistry in corrosion and biofouling prevention. Chapter topics include types and fundamentals of supramolecules, supramolecular polymers and gels, host-guest inclusion compounds, organic-inorganic hybrid materials, metallo-assemblies, cyclodextrins, crown ethers, mesoporous silica and supramolecular structures of graphene and other advances. Additional Features include: Focuses on different aspects of supramolecular chemistry in corrosion and biofouling prevention. Comprehensively covers supramolecular interactions that can provide better corrosion and biofouling protection. Provides the latest developments in self-healing coatings. Explores recent research advancements in the suggested area. Includes case studies specific to industries. The different supramolecular approaches being investigated to control corrosion and biofouling are gathered in one well-organized reference to serve senior undergraduate and graduate students, research students, engineers, and researchers in the fields of corrosion science & engineering, biofouling, and protective coatings.
Download or read book Out of Equilibrium Supra molecular Systems and Materials written by Nicolas Giuseppone and published by John Wiley & Sons. This book was released on 2021-03-30 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.
Download or read book Emerging Nanostructured Materials for Energy and Environmental Science written by Saravanan Rajendran and published by Springer. This book was released on 2019-02-07 with total page 565 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the fundamental aspects of the diverse ranges of nanostructured materials (0D, 1D, 2D and 3D) for energy and environmental applications in a comprehensive manner written by specialists who are at the forefront of research in the field of energy and environmental science. Experimental studies of nanomaterials for aforementioned applications are discussed along with their design, fabrication and their applications, with a specific focus on catalysis, energy storage and conversion systems. This work also emphasizes the challenges of past developments and directions for further research. It also looks at details pertaining to the current ground – breaking of nanotechnology and future perspectives with a multidisciplinary approach to energy and environmental science and informs readers about an efficient utilization of nanomaterials to deliver solutions for the public.
Download or read book Supramolecular Chemistry written by Peter J. Cragg and published by Springer Science & Business Media. This book was released on 2010-08-26 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to return to the biomimicry and medicinal potential that inspired many of the early supramolecular chemists and to set it in the context of current advances in the field. Following an overview of supramolecular chemistry, the first section considers the efforts made to synthesize artificial systems that mimic biological entities. The second section addresses the application of supramolecular principles to molecular diagnostics with a particular emphasis on the ‘receptor-relayreporter’ motif. Many of the examples chosen have clinical importance. The third section takes the clinical diagnostic theme further and demonstrates the therapeutic applications of supramolecular chemistry through photodynamic therapy, drug delivery, and the potential for synthetic peptides to form antibiotic tubes. The short epilogue considers the potential for supramolecular solutions to be found for further challenges in biomimetic and therapeutic chemistry.
Download or read book Hydrogen Bonded Polymers written by Wolfgang Binder and published by Springer Science & Business Media. This book was released on 2007-03-16 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt: Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic methods and thus gaining structural control over the final polymeric materials has become feasible, resulting in the field of supramolecular polymer science. Besides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes over a wide range of interactions strength ranging from several kJmol to several tens of kJmol . Central for the formation of these structures are precursor molecules of small molecular weight (usually lower than 10 000), which can assemble in solid or solution to aggregates of defined geometry.
Download or read book Core Concepts in Supramolecular Chemistry and Nanochemistry written by Jonathan W. Steed and published by John Wiley & Sons. This book was released on 2007-04-30 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles
Download or read book The Supramolecular Chemistry of Organic Inorganic Hybrid Materials written by Knut Rurack and published by John Wiley & Sons. This book was released on 2010-04-07 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt: The combination of supramolecular chemistry, inorganic solids, and nanotechnology has already led to significant advances in many areas such as sensing, controlled motion, and delivery. By making possible an unprecedented tunability of the properties of nanomaterials, these techniques open up whole new areas of application for future supramolecular concepts. The Supramolecular Chemistry of Organic–Inorganic Hybrid Materials gathers current knowledge on the subject and provides an overview of the present state and upcoming challenges in this rapidly growing, highly cross- or interdisciplinary research field. The book details how these designed materials can improve existing materials or generate novel functional features such as chemical amplification, cooperative binding and signal enhancement that are difficult or not at all achievable by classical organic supramolecular chemistry. It also discusses issues related to nanofabrication or nanotechnology such as the directed and controlled assembly or disassembly, biomimetic functions and strategies, and the gating and switching of surface functions or morphology.
Download or read book Self Healing Polymers written by Wolfgang H. Binder and published by John Wiley & Sons. This book was released on 2013-03-29 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.
Download or read book Materials Nanoarchitectonics written by Katsuhiko Ariga and published by Elsevier. This book was released on 2023-12-15 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: Materials Nanoarchitectonics: From Integrated Molecular Systems to Advanced Devices provides the latest information on the design and molecular manipulation of self-organized hierarchically structured systems using tailor-made nanoscale materials as structural and functional units. The book is organized into three main sections that focus on molecular design of building blocks and hybrid materials, formation of nanostructures, and applications and devices. Bringing together emerging materials, synthetic aspects, nanostructure strategies, and applications, the book aims to support further progress, by offering different perspectives and a strong interdisciplinary approach to this rapidly growing area of innovation. This is an extremely valuable resource for researchers, advanced students, and scientists in industry, with an interest in nanoarchitectonics, nanostructures, and nanomaterials, or across the areas of nanotechnology, chemistry, surface science, polymer science, electrical engineering, physics, chemical engineering, and materials science. Offers a nanoarchitectonic perspective on emerging fields, such as metal-organic frameworks, porous polymer materials, or biomimetic nanostructures Discusses different approaches to utilizing "soft chemistry" as a source for hierarchically organized materials Offers an interdisciplinary approach to the design and construction of integrated chemical nano systems Discusses novel approaches towards the creation of complex multiscale architectures
Download or read book Bioinspired superwettable materials from design fabrication to application written by Jingxin Meng and published by Frontiers Media SA. This book was released on 2023-05-25 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:
