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Book The Synthesis and Structural Characterization of Main Group and Transition Metal Complexes Supported by Nitrogen Based Ligands

Download or read book The Synthesis and Structural Characterization of Main Group and Transition Metal Complexes Supported by Nitrogen Based Ligands written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Nitrogen based monodentate and bidentate chelating ligands have captured a significant interest due to their ability to coordinate to a wide variety of elements. The â-diketimine, â-ketoiminato, formamidine, pyridineselenolate, and pyrazinecarboxamide ligands have all been employed in this study to further investigate the coordination preferences among main group and transition metals. Steric and electronic properties of these ligands can easily be altered by manipulating the substituents attached, thus leading to predictable structures with potential for many useful and significant applications. Investigations have shown that temperature, solvent, and metal halide employed are all key factors in the reaction outcomes. All of the complexes obtained throughout these studies have been characterized by X-ray crystallography along with other spectroscopic techniques, including NMR, IR, UV/Vis, and M/S. â-diketiminato ligands, [{N(R)C(Me)}2C(H)] where R = Dipp, Mes, commonly referred to as nacnac, have played an important role in the synthesis of novel pnictogenium complexes. Results show that through manipulation of the halide precursor, reaction stoichiometry, and the R substituent on the nacnac both N, N'- and N, C'-metal chelated complexes can be achieved. Additionally, â-ketiminato ligands, [RN(H)(C(Me))2C(Me)=O] where R = Dipp, and [RN(H)C(Me)CHC(Me)=O] where R = C2H4NEt2, have been studied. Both ligands were investigated with a range of d and p block metal halides and alkyls in order to compare and contrast the bulky, flexible, and even multi-dentate nature of each ligand. The preferred metal geometry remains constant for products with either ligand, but the steric protection offered by the individual ligands governs the nuclearity of the products, ranging from tetrameric cages to simple adducts. The formamidinate ligand, [RN(H)C(H)NR] where R = Dipp, was employed in synthesizing several aluminum and zinc complexes. In addition to their numerous applications as cata.

Book Synthesis and Structure of Novel Transition Metal Organometallic Complexes

Download or read book Synthesis and Structure of Novel Transition Metal Organometallic Complexes written by Dawood Afzal and published by . This book was released on 1985 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Reactivity and Structural Characterization of Transition Metal Complexes Containing Dibenzotetraaza  14  Annulene Macrocyclic Ligands

Download or read book Synthesis Reactivity and Structural Characterization of Transition Metal Complexes Containing Dibenzotetraaza 14 Annulene Macrocyclic Ligands written by Marvin Cecil Weiss and published by . This book was released on 1977 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book METAL COMPLEXATION OF NOVEL ORGANIC LIGANDS

Download or read book METAL COMPLEXATION OF NOVEL ORGANIC LIGANDS written by Piyush Desai and published by Lulu.com. This book was released on 2013-12-31 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present work is in connection with the novel ligands having structural moieties of heterocyclic rings such as benzotriazole and complex forming agent such as 8-hydroxy-quinoline and salicylic acid. Hence, both moieties have been introduced briefly.

Book Synthesis and Structural Characterization of Mono  and Dinuclear Transition Metal Complexes Containing the Tetraaza  14  Annulene Ligand

Download or read book Synthesis and Structural Characterization of Mono and Dinuclear Transition Metal Complexes Containing the Tetraaza 14 Annulene Ligand written by Joanna Czuchajowska-Wiesinger and published by . This book was released on 1991 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Characterization and X ray Structural Studies of Octahedral Transition Metal Complexes Incorporating the Novel Anionic Tridentate Ligand  Dimethyl ethanolamino   1 pyrazolyl gallate  Me2Ga OCH2CH2NH  N2C3H3

Download or read book Synthesis Characterization and X ray Structural Studies of Octahedral Transition Metal Complexes Incorporating the Novel Anionic Tridentate Ligand Dimethyl ethanolamino 1 pyrazolyl gallate Me2Ga OCH2CH2NH N2C3H3 written by Kenneth S. Chong and published by . This book was released on 1978 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Metal Mediated Template Synthesis of Ligands

Download or read book Metal Mediated Template Synthesis of Ligands written by Otilia Costisor and published by World Scientific. This book was released on 2004 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry.

Book Synthesis  Characterisation and Transition Metal Complexes of Nitrogen containing Ligands

Download or read book Synthesis Characterisation and Transition Metal Complexes of Nitrogen containing Ligands written by Stephanie Holland and published by . This book was released on 2000 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Structural Characterization of Main group Metal Complexes of a Substituted fulvalene Ligand  5 14 H bisindeno  2 3 F  H  Naphthalene

Download or read book Synthesis and Structural Characterization of Main group Metal Complexes of a Substituted fulvalene Ligand 5 14 H bisindeno 2 3 F H Naphthalene written by Dennis Malaba and published by . This book was released on 1995 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis  Characterization  and Structural Studies of the Metal Complexes with Ligands Derived from Triazacycloalkanes and Related Compounds

Download or read book Synthesis Characterization and Structural Studies of the Metal Complexes with Ligands Derived from Triazacycloalkanes and Related Compounds written by Delong Zhang and published by . This book was released on 1994 with total page 606 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Direct Synthesis of Metal Complexes

Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Book Vanadium Catalysis

    Book Details:
  • Author : Manas Sutradhar
  • Publisher : Royal Society of Chemistry
  • Release : 2020-11-05
  • ISBN : 1839160896
  • Pages : 526 pages

Download or read book Vanadium Catalysis written by Manas Sutradhar and published by Royal Society of Chemistry. This book was released on 2020-11-05 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.