Download or read book The Reduction of Some Ammine Cobalt III Complexes by Chromous Ion written by Roy Richard Miller and published by . This book was released on 1963 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of the Reduction of alpha carbonylcarboxylatopentaamminecobalt III Complexes by Chromous Vanadous and Hexaammineruthenium II Ions written by Harry James Price and published by . This book was released on 1966 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics and Mechanisms of Reactions of Some Polymeric Cobalt III Ammines written by Alan Bruce Hoffman and published by . This book was released on 1967 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Oxidation of Stannate II Ion by Some Cobalt III Complexes written by Richard C. Pinkerton and published by . This book was released on 1951 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Metal Ion Reductions of Some Amminecobalt III Complexes written by R. Galen Miller and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Reduction of Carboxylatopentaamminecobalt III Complexes by Chromium II and Vanadium II Ions written by Martha An Barcalow Barrett and published by . This book was released on 1968 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Spectrophotometric Study of Certain Cobalt III and Chromium II Complexes written by Ronald Arlen Garber and published by . This book was released on 1964 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Preparation Characterization and Chromium II Reduction of Pentaamminecobalt III written by Robert J. Balahura and published by . This book was released on 1971 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chromium(II) reduction of a series of pentaammine- cobalt(III) complexes has been studied. A classification into inner- or outer-sphere paths has been made and the position of attack of the reductant on the ligand determined. The oxygen-bonded complexes of formamide, N,N-dimethylform- amide, dimethylsulfoxide, and urea as well as the nitrogen bonded N-cyanoguanidine complex are reduced by means of an outer-sphere mechanism. On the other hand ligand transfer was shown to occur in the reduction of (NH[subscript 3])[subscript 5]CoNHCHO[superscript 2+], (NH[subscript 3])[subscript 5]CoNCNH[superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CNH[subscript 2][superscript 2+], (NH[subscript 3])[subscript 5]CoO[subscript 2]CC[subscript 6]H[subscript 4]CN[superscript 2+], and (NH[subscript 3])[subscript 5]CoNCO[superscript 2+]. Both outer- and inner-sphere paths operate in the reduction of the nitrile bonded 4-cyanophenol complex, the inner-sphere path comprising 20% of the overall reaction. For the reduction of the terephthalonitrile complex a classification into an inner- or outer-sphere path cannot be made/ and an outer-sphere electron transfer to the ligand is postulated as the rate-determining step. A large part of the work has been concerned with the characterization of the complexes and Chapter III describes the spectroscopic measurements undertaken as well as the chemical reactions of some of the complexes. The acid dissociation constant of the N isomer of formamidopentaamine- cobalt(III), cyanamidopentaamminecobalt(III), and the nitrile bonded 4-cyanophenol have been determined. The protonation equilibrium constant for carbamatopentaammine- cobalt(III) was also obtained. A kinetic study of the acid hydrolysis of isocyanatopentaamminecobalt(III) to form hexaamminecobalt(III) and carbon dioxide was carried out. The acylation of the cyanamide and 4-cyanophenol complexes was also studied. The results of the kinetic studies of the chromium(II) reductions indicate a possible correlation between the reduction rate and the half-wave potential for the reduction of the free ligand. The studies have led to the following generalizations regarding electron transfer reactions: (1) attack of reductant at a coordinated atom does not occur, (2) the atom attached to chromium(II) in the transition state must have two lone pairs of electrons, and (3) the reducibility of the complexed ligand plays an important role in the detailed mechanism for the transfer of the electron.
Download or read book Studies on the Relative Rates of the Competitive Reductions of Cobalt III Complexes by Chromous Ion written by Michael Cabot Moore and published by . This book was released on 1967 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Study of the Thermal Decomposition of Some Chromium III and Cobalt III Ammine Complexes written by John LaRue Bear and published by . This book was released on 1960 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Competitive Reductions of Cobalt III Complexes by Tris 2 2 dipyridine chromium II Ion written by Bill Lauer and published by . This book was released on 1971 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Investigation of the Solid state Reactions of Some Cobalt III Ammine Complexes written by Feng Chih Chang and published by . This book was released on 1971 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics of the Reduction of Some Cobalt III Complexes by Iron II written by Dennis Schendel and published by . This book was released on with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Synthesis Characterization and Chromium II Reduction of Cobalt III Complexes Containing Thiolate Alcoholate and Thioether Residues written by Michael James Gilroy and published by . This book was released on 1971 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Reduction of E D T A and Related Complexes of Cobalt III by Iron II and Chromium II in Aqueous Solution written by P. B. Wood and published by . This book was released on 1964 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Reactions of Chromium III and Cobalt II Complexes written by Loretta Kiel Beutelman and published by . This book was released on 1983 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts written by and published by . This book was released on 1967 with total page 1018 pages. Available in PDF, EPUB and Kindle. Book excerpt:
