Download or read book Contemporary Problems in Carbonium Ion Chemistry I II written by C. Rees and published by Springer. This book was released on 2013-11-27 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1965 a book by P. Bartlett appeared under the title "The Nonclassical Ions" 1). The book is a collection of papers reprinted from various journals. The many reviews that have appeared since 2-22) are either antiquated (the book published in 1972 12) covers the literature mainly before 1968) or relatively biased (e.g., 3.4,10» on brief 2, 7,11). This review attempts to discuss the various points of view on the "nonclassical" carbocations. The main point is to establish the relative role of "nonclassical" and "classical" ions in various chemical processes. The author has followed P. Bartlett's advice 1) that when setting forth the achievements of the human mind one should see how we came to the modern understanding of a given problem (" ... how we know what we know"). The theory of "nonclassical" ions offers an explanation of many unique chemical, stereochemical and kinetic peculiarities of bicyclic compounds. It has expanded our knowledge on chemical bonds in carbocations by introducing electron-deficient bonds (as in boron hydrides). It has accounted for many rearrangements of stable cations. As a "side" result our knowledge has been extended about ionization processes in a solution, as well as about stereochemical methods. 2 Main Terms of Nonclassical Carbocations In 1939 Hevell, Salas and Wilson 23) assumed an intermediate, "bridge" ion 2 to be formed when camphene hydrochloride 1 is rearranged into isobornyl chloride 3. This happened 17 years after Meerwein first postulated the intermediate formation of "carbonium" ions in chemical reactions.
Download or read book Contemporary Problems in Carbonium Ion Chemistry III written by V. A. Koptyug and published by Walter de Gruyter GmbH & Co KG. This book was released on 1985-12-31 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: No detailed description available for "Contemporary Problems in Carbonium Ion Chemistry III".
Download or read book Enzyme Kinetics Catalysis and Control written by Daniel L. Purich and published by Elsevier. This book was released on 2010-06-16 with total page 915 pages. Available in PDF, EPUB and Kindle. Book excerpt: Far more than a comprehensive treatise on initial-rate and fast-reaction kinetics, this one-of-a-kind desk reference places enzyme science in the fuller context of the organic, inorganic, and physical chemical processes occurring within enzyme active sites. Drawing on 2600 references, Enzyme Kinetics: Catalysis & Control develops all the kinetic tools needed to define enzyme catalysis, spanning the entire spectrum (from the basics of chemical kinetics and practical advice on rate measurement, to the very latest work on single-molecule kinetics and mechanoenzyme force generation), while also focusing on the persuasive power of kinetic isotope effects, the design of high-potency drugs, and the behavior of regulatory enzymes. - Historical analysis of kinetic principles including advanced enzyme science - Provides both theoretical and practical measurements tools - Coverage of single molecular kinetics - Examination of force generation mechanisms - Discussion of organic and inorganic enzyme reactions
Download or read book Electron Deficient Compounds written by K. Wade and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is about compounds such as the boron hydrides and associated metal hydrides and alkyls which acquired the label 'electron deficient' when they were thought to contain too few valence electrons to hold together. Though they are now recognized as containing the numbers of bonding electrons appropriate for their structures, the term 'electron deficient' is still commonly applied to many substances that contain too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded. The study of such substances has contributed much to chemistry. Techniques for the vacuum manipulation of volatile substances were devised specifically for their study; developments in valence theory resulted from considerations of their bonding; and the reactivity of several (for example, diborane and complex metal hydrides, lithium and aluminium alkyls) has made them valuable reagents. The purpose of this book is to provide an introduction to the chemistry of these fascinating compounds. The experimental and spectroscopic methods by which they can be studied are outlined, the various types of structure they adopt are described and profusely illustrated, and the relative merits of extended valence bond and simple molecular orbital treatments of their bonding are discussed, with as liberal use of diagrams and as limited recourse to the Greek alphabet as possible. A recurring theme is the importance attached to considerations of molecular sym metry. Their reactions are treated in sufficient detail to show whether these reflect any deficiency of electrons.
Download or read book The Nature of the Chemical Bond and the Structure of Molecules and Crystals written by Linus Pauling and published by . This book was released on 1960 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advanced Chemistry Through Diagrams written by Michael Lewis and published by . This book was released on 2002 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: DT These highly successful revision guides have been brought right up-to-date for the new A Level specifications introduced in September 2000.DT Oxford Revision Guides are highly effective for both individual revision and classroom summary work. The unique visual format makes the key concepts and processes, and the links between them, easier to memorize.DT Students will save valuable revision time by using these notes instead of condensing their own.DT In fact, many students are choosing to buy their own copies so that they can colour code or highlight them as they might do with their own revision notes.
Download or read book A Textbook of Organic Chemistry 22e written by Arun Bahl & B S Bahl and published by S. Chand Publishing. This book was released on 2019 with total page 1125 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an increased focus on fundamentals, this new edition of A Textbook of Organic Chemistry continues to present the time-tested functional group approach to the subject. This examination-oriented book breaks the intricacies of Organic Chemistry into easy-to-understand steps which gives the student the necessary foundation to build upon, learn and understand Organic Chemistry in a way that is efficient as well as long-lasting.
Download or read book Onium Ions written by George A. Olah and published by John Wiley & Sons. This book was released on 1998-08-11 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Der Autor George Olah, der 1995 den Nobelpreis erhielt, stellt in seinem Buch die Anwendung von Onium-Ionen als elektrophile Reagenzien und Katalysatoren dar und erläutert diese für die chemische Synthese bedeutsamen Verbindungen. (8/98)
Download or read book Green Energy Materials Handbook written by Ming-Fa Lin and published by CRC Press. This book was released on 2019-06-18 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Green Energy Materials Handbook gives a systematic review of the development of reliable, low-cost, and high-performance green energy materials, covering mainstream computational and experimental studies as well as comprehensive literature on green energy materials, computational methods, experimental fabrication and characterization techniques, and recent progress in the field. This work presents complete experimental measurements and computational results as well as potential applications. Among green technologies, electrochemical and energy storage technologies are considered as the most practicable, environmentally friendly, and workable to make full use of renewable energy sources. This text includes 11 chapters on the field, devoted to 4 important topical areas: computational material design, energy conversion, ion transport, and electrode materials. This handbook is aimed at engineers, researchers, and those who work in the fields of materials science, chemistry, and physics. The systematic studies proposed in this book can greatly promote the basic and applied sciences.
Download or read book Proceedings of the Fifth Conference on Carbon written by S. Mrozowski and published by Elsevier. This book was released on 2013-09-17 with total page 675 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Fifth Conference on Carbon
Download or read book Organic Reaction Mechanisms written by Michael Edenborough and published by CRC Press. This book was released on 2017-12-21 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text is designed to teach students how to write organic reaction mechanisms. It starts from the absolute basics - counting the numbers of electrons around a simple atom. Then, in small steps, the text progresses to advanced mechanisms. the end, all the major mechanistic routes have been covered. The text is in the form of interactive sections, which are designed to facilitate the assimilation of the information conveyed, so that by the end the student should already know the contents without the need for extensive revision.
Download or read book Comprehensive Dissertation Index written by University Microfilms International and published by Ann Arbor, Mich. : University Microfilms International. This book was released on 1984 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Across Conventional Lines Selected Papers Of George A Olah In 2 Volumes written by George A Olah and published by World Scientific. This book was released on 2003-01-29 with total page 1503 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the course of his distinguished career spanning about half a century, George A Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance.
Download or read book Macmillan Dictionary of Chemistry written by D. Brynn Hibbert and published by Springer. This book was released on 1987-09-17 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemistry For B Sc Students Semester I Inorganic Chemistry Organic Chemistry NEP 2020 Maharashtra written by Ravin M Jugade, Vijay M Tangde and published by S. Chand Publishing. This book was released on with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is designed specifically for the B.Sc. Chemistry curriculum under the National Education Policy (NEP) in Maharashtra, provides a comprehensive and solid foundation of the subject. The chapters have been meticulously selected and structured to align with the educational objectives of fostering analytical thinking, enhancing problem-solving skills, and cultivating a deep understanding of fundamental chemistry. More than just a collection of theoretical concepts, this textbook encourages students to apply these principles. Through a wealth of examples and problems, the students are guided to develop a practical and profound understanding of chemistry, preparing them for future academic and professional pursuits. Whether you are a student aiming to excel in your studies or an educator seeking a reliable resource, this textbook is an indispensable tool on the journey to mastering the fascinating world of chemistry.
Download or read book Reaction Mechanisms in Organic Chemistry written by Metin Balcı and published by John Wiley & Sons. This book was released on 2021-12-01 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization. Along with sections covering aromaticity and the chemistry of intermediates, the book includes: A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1977 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.