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Book Specific Interactions in Polyurethane Cationomers

Download or read book Specific Interactions in Polyurethane Cationomers written by Richard Joseph Goddard and published by . This book was released on 1994 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Studies have shown that addition of cationic groups to a segmented polyurethane can dramatically change physical attributes such as solution behavior, mechanical strength, and viscoelastic properties. However, the specific interactions responsible for these changes are not well understood. A series of polyether polyurethane cationomers were synthesized using chain extenders with pendant trialkylammonium groups. The morphology and properties of the cationomers were studied as a function of ion-related variables using small-angle X-ray scattering (SAXS), tensile testing, dynamic mechanical thermal analysis (DMTA), and differential scanning calorimetry (DSC). Ion content affected phase separation and mechanical properties the most; the alkyl group length was of secondary importance; and the type of neutralizing anion had essentially no effect. Further, a lamellar microstructure typical of conventional polyurethanes was evident, with no apparent aggregation of ionic groups.

Book Dissertation Abstracts International

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 946 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Polyurethane Polymers  Blends and Interpenetrating Polymer Networks

Download or read book Polyurethane Polymers Blends and Interpenetrating Polymer Networks written by Sabu Thomas and published by Elsevier. This book was released on 2017-08-15 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane Polymers: Blends and Interpenetrating Networks deals with almost all aspects of blends and IPNs formed by polyurethane, including the thermal, mechanical, morphological, and viscoelastic properties of each blend presented in the book. In addition, major applications related to these blends and IPNs are mentioned. Provides an elaborate coverage of the chemistry of polyurethane, including its synthesis and properties Includes available characterization techniques Relates types of polyurethanes to their potential properties Discusses blends options

Book American Doctoral Dissertations

Download or read book American Doctoral Dissertations written by and published by . This book was released on 2001 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Structure and Properties of Ionomers

Download or read book Structure and Properties of Ionomers written by Michel Pineri and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionomers, that is polymers containing a low concentration of charged units along the chain, have been the subject of increasing interest during the past twenty years. The presence of ionic groups in the poly mer changes some of its properties dramatically. Increases in the modu lus and the viscosity of several orders of magnitude have been observed, and changes in the glass transition of hundreds of degrees are possible. In addition, diffusion coefficients can be modified drastically. These changes are due primarily to the presence of reversible ionic cross links in these materials. Because of the low dielectric constant of most organic polymers, the ions or ionic dipoles tend to aggregate ; this aggregation process, however, is limited, because the ionic groups are covalently bonded to the organic chain. Host of the fundamental research done on these materials has been devoted to a determination of the extent of association, the structure of the aggregates, the limi ting factors, and the correlations between molecular and supermolecular structure and the resul ting properties.

Book The Physical Properties of Polyurethanes

Download or read book The Physical Properties of Polyurethanes written by Michael Wen-chien Yang and published by . This book was released on 1971 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Polyurethane Elastomers

Download or read book Polyurethane Elastomers written by Cristina Prisacariu and published by Springer Science & Business Media. This book was released on 2011-07-03 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive account of the physical / mechanical behaviour of polyurethanes (PU ́s) elastomers, films and blends of variable crystallinity. Aspects covered include the elasticity and inelasticity of amorphous to crystalline PUs, in relation to their sensitivity to chemical and physical structure. A study is made of how aspects of the constitutive responses of PUs vary with composition: the polyaddition procedure, the hard segment, soft segment and chain extender (diols and diamines) are varied systematically in a large number of systems of model and novel crosslinked andthermoplastic PUs. Results will be related to: microstructural changes, on the basis of evidence from x-ray scattering (SAXS and WAXS), and also dynamic mechanical analyses (DMA), differential scanning calorimetry (DSC) and IR dichroism. Inelastic effects will be investigated also by including quantitative correlations between the magnitude of the Mullins effect and the fractional energy dissipation by hysteresis under cyclic straining, giving common relations approached by all the materials studied. A major structural feature explored is the relationship between the nature of the hard segment (crystallising or not) and that of the soft segments. Crystallinity has been sometimes observed in the commercial PUs hard phase but this is usually limited to only a few percent for most hard segment structures when solidified from the melt. One particular diisocyanate, 4,4’-dibenzyl diisocyanate (DBDI) that, in the presence of suitable chain extenders ( diols or diamines), gives rise to significant degrees of crystallinity [i-iii] and this is included in the present work. Understanding the reaction pathways involved, in resolving the subtle morphological evolution at the nanometre level, and capturing mathematically the complex, large-deformation nonlinear viscoelastic mechanical behaviour are assumed to bring new important insights in the world basic research in polyurethanes and towards applied industrial research in this area.

Book The Physical Properties of Polyurethanes and Ionomers

Download or read book The Physical Properties of Polyurethanes and Ionomers written by Tisato Kajiyama and published by . This book was released on 1969 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Intelligent Textiles and Clothing

Download or read book Intelligent Textiles and Clothing written by H Mattila and published by Woodhead Publishing. This book was released on 2006-07-28 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of intelligent textiles in clothing is an exciting new field with wide-ranging applications. Intelligent textiles and clothing summarises some of the main types of intelligent textiles and their uses.Part one of the book reviews phase change materials (PCM), their role in such areas as thermal regulation and ways they can be integrated into outdoor and other types of clothing. The second part of the book discusses shape memory materials (SMM) and their applications in medical textiles, clothing and composite materials. Part three deals with chromic (colour change) and conductive materials and their use in such areas as sensors within clothing. The final part of the book looks at current and potential applications, including work wear and medical applications.With its distinguished editor and international team of contributors, Intelligent textiles and clothing is an essential guide for textile manufacturers in such areas as specialist clothing (for example, protective, sports and outdoor clothing) as well as medical textiles. Summarises the main types of intelligent textiles and their uses Reviews phase change materials and their role in clothing Discusses shape memory materials and their applications

Book Szycher s Handbook of Polyurethanes  Second Edition

Download or read book Szycher s Handbook of Polyurethanes Second Edition written by Michael Szycher, Ph.D and published by CRC Press. This book was released on 2012-07-13 with total page 1147 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical handbook rather than merely a chemistry reference, Szycher's Handbook of Polyurethanes, Second Edition offers an easy-to-follow compilation of crucial new information on polyurethane technology, which is irreplaceable in a wide range of applications. This new edition of a bestseller is an invaluable reference for technologists, marketers, suppliers, and academicians who require cutting-edge, commercially valuable data on the most advanced uses for polyurethane, one of the most important and complex specialty polymers. internationally recognized expert Dr. Michael Szycher updates his bestselling industry "bible" With seven entirely new chapters and five that are revised and updated, this book summarizes vital contents from U.S. patent literature—one of the most comprehensive sources of up-to-date technical information. These patents illustrate the most useful technology discovered by corporations, universities, and independent inventors. Because of the wealth of information they contain, this handbook features many full-text patents, which are carefully selected to best illustrate the complex principles involved in polyurethane chemistry and technology. Features of this landmark reference include: Hundreds of practical formulations Discussion of the polyurethane history, key terms, and commercial importance An in-depth survey of patent literature Useful stoichiometric calculations The latest "green" chemistry applications A complete assessment of medical-grade polyurethane technology Not biased toward any one supplier’s expertise, this special reference uses a simplified language and layout and provides extensive study questions after each chapter. It presents rich technical and historical descriptions of all major polyurethanes and updated sections on medical and biological applications. These features help readers better understand developmental, chemical, application, and commercial aspects of the subject.

Book Polyurethane Polymers  Composites and Nanocomposites

Download or read book Polyurethane Polymers Composites and Nanocomposites written by Sabu Thomas and published by Elsevier. This book was released on 2017-08-17 with total page 635 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyurethane Polymers: Composites and Nanocomposites concentrates on the composites and nanocomposites of polyurethane based materials. Polyurethane composites are a very important class of materials widely used in the biomedical and industrial field that offer numerous potential applications in many areas. This book discusses current research and identifies future research needs in the area. Provides an elaborate coverage of the chemistry of polyurethane, its synthesis, and properties Includes available characterization techniques Relates types of polyurethanes to their potential properties Discusses composites, nanocomposites options, and PU recycling

Book Energy Research Abstracts

Download or read book Energy Research Abstracts written by and published by . This book was released on 1978 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Linear Polyurethanes

Download or read book Linear Polyurethanes written by Piotr Król and published by CRC Press. This book was released on 2008-03-27 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes in detail the mechanisms of the diisocyanates and polyols polyaddition process as well as its kinetic and process aspects important for obtaining linear polyurethanes. General kinetics of the process and its experimental verification, using GPC chromatography as well as NMR spectroscopy and MALDI-ToF spectrometry, are presented. Accompanied by over 400 references, the author presents synthesis methods, physicochemical properties of linear polyurethanes (analyzed with DCS, TG, DMTA, Rtg, AFM microscopy methods) as semiproducts for foams, elastomers, lacquers and coatings. Research results concerning free surface energy of the polyurethane coatings are also presented. Special attention is given to the latest polyurethane applications, such as ecological waterborne dispersions, biodegradation resistant elastomers and coatings used as medical implants and binders for ceramic powder materials. Moreover, the book contains information on urethane-isocyanate prepolymers applications, which are potential semifinished products for elastomers, foams, coatings, adhesives and interpenetrating polymer network composites.

Book Physics Briefs

Download or read book Physics Briefs written by and published by . This book was released on 1993 with total page 1420 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Handbook of Polymer Research

Download or read book Handbook of Polymer Research written by Richard Arthur Pethrick and published by Nova Publishers. This book was released on 2007 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Polymer Research - Monomers. Oligomers, Polymers & Composites