Download or read book THE IMPACT OF A TANK 40H DECANT ON THE PROJECTED OPERATING WINDOWS FOR SB4 AND GLASS SELECTION STRATEGY IN SUPPORT OF THE VARIABILITY STUDY written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Liquid Waste Organization (LWO) has requested that the Savannah River National Laboratory (SRNL) to assess the impact of a 100K gallon decant volume from Tank 40H on the existing sludge-only Sludge Batch 4 (SB4)-Frit 510 flowsheet and the coupled operations flowsheet (SB4 with the Actinide Removal Process (ARP)). Another potential SB4 flowsheet modification of interest includes the addition of 3 wt% sodium (on a calcined oxide basis) to a decanted sludge-only or coupled operations flowsheet. These potential SB4 flowsheet modifications could result in significant compositional shifts to the SB4 system. This paper study provides an assessment of the impact of these compositional changes to the projected glass operating windows and to the variability study for the Frit 510-SB4 system. The influence of the compositional changes on melt rate was not assessed in this study nor was it requested. Nominal Stage paper study assessments were completed using the projected compositions for the various flowsheet options coupled with Frit 510 (i.e., variation was not applied to the sludge and frit compositions). In order to gain insight into the impacts of sludge variation and/or frit variation (due to the procurement specifications) on the projected operating windows, three versions of the Variation Stage assessment were performed: (1) the traditional Variation Stage assessment in which the nominal Frit 510 composition was coupled with the extreme vertices (EVs) of each sludge, (2) an assessment of the impact of possible frit variation (within the accepted frit specification tolerances) on each nominal SB4 option, and (3) an assessment of the impact of possible variation in the Frit 510 composition due to the vendor's acceptance specifications coupled with the EVs of each sludge case. The results of the Nominal Stage assessment indicate very little difference among the various flowsheet options. All of the flowsheets provide DWPF with the possibility of targeting waste loadings (WLs) from the low 30s to the low 40s with Frit 510. In general, the Tank 40H decant has a slight negative impact on the operating window, but DWPF still has the ability to target current WLs (34%) and higher WLs if needed. While the decant does not affect practical WL targets in DWPF, melt rate could be reduced due to the lower Na2O content. If true, the addition of 3 wt% Na2O to the glass system may regain melt rate, assuming that the source of alkali is independent of the impact on melt rate. Coupled operations with Frit 510 via the addition of ARP to the decanted SB4 flowsheet also appears to be viable based on the projected operating windows. The addition of both ARP and 3 wt% Na2O to a decanted Tank 40H sludge may be problematic using Frit 510. Although the Nominal Stage assessments provide reasonable operating windows for the SB4 flowsheets being considered with Frit 510, introduction of potential sludge and/or frit compositional variation does have a negative impact. The magnitude of the impact on the projected operating windows is dependent on the specific flowsheet options as well as the applied variation. The results of the traditional Variation Stage assessments indicate that the three proposed Tank 40H decanted flowsheet options (Case No. 2--100K gallon decant, Case No. 3--100K gallon decant and 3 wt% Na2O addition and Case No. 4--100K gallon decant and ARP) demonstrate a relatively high degree of robustness to possible sludge variation over WLs of interest with Frit 510. However, the case where the addition of both ARP and 3 wt% Na2O is considered was problematic during the traditional Variation Stage assessment. The impact of coupling the frit specifications with the nominal SB4 flowsheet options on the projected operating windows is highly dependent on whether the upper WLs are low viscosity or liquidus temperature limited in the Nominal Stage assessments. Systems that are liquidus temperature limited exhibit a high degree of robustness to the applied frit and sludge variation, while those that are low viscosity limited show significant reductions (6 percentage points) in the upper WLs that can be obtained. When both frit and sludge variations are applied, the paper study results indicate that DWPF could be severely restricted in terms of projected operating windows for the ARP and Na2O addition options. An experimental variability study was not performed using the final SB4 composition and Frit 510 since glasses in the ComPro{trademark} data base were identified that bounded the potential operating window of this system. The bounding ARP case was not considered in that assessment. After the flowsheet cases were identified, an electronic search of ComPro{trademark} identified approximately 12 historical glasses within the compositional regions defined by at least one of the five flowsheet options, but the compositional coverage did not appear adequate to bound all cases.
Download or read book Environmental Issues and Waste Management Technologies in the Materials and Nuclear Industries XII written by Alex Cozzi and published by John Wiley & Sons. This book was released on 2009-09-24 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book documents a special collection of articles from a select group of invited prominent scientists from academia, national laboratories and industry who presented their work at the symposia on Environmental and Energy Issues at the 2008 Materials Science and Technology (MS&T’08) conference held in Pittsburgh, PA. These articles represent a summary of the presentations focusing on topics in nuclear, environmental, and green engineering were held, including a discussion of Waste Glass Leach Testing and Modeling.
Download or read book Engineering Materials 1 written by M. F. Ashby and published by . This book was released on 1996 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a broad introduction to the properties of materials used in engineering applications, and is intended to provide a course in engineering materials for students with no previous background in the subject.
Download or read book Smithells Metals Reference Book written by William F. Gale and published by Elsevier. This book was released on 2003-12-09 with total page 2072 pages. Available in PDF, EPUB and Kindle. Book excerpt: Smithells is the only single volume work which provides data on all key apsects of metallic materials. Smithells has been in continuous publication for over 50 years. This 8th Edition represents a major revision. Four new chapters have been added for this edition. these focus on; * Non conventional and emerging materials - metallic foams, amorphous metals (including bulk metallic glasses), structural intermetallic compounds and micr/nano-scale materials. * Techniques for the modelling and simulation of metallic materials. * Supporting technologies for the processing of metals and alloys. * An Extensive bibliography of selected sources of further metallurgical information, including books, journals, conference series, professional societies, metallurgical databases and specialist search tools. * One of the best known and most trusted sources of reference since its first publication more than 50 years ago * The only single volume containing all the data needed by researchers and professional metallurgists * Fully updated to the latest revisions of international standards
Download or read book Solvent Extraction and Liquid Membranes written by Manuel Aguilar and published by CRC Press. This book was released on 2008-04-07 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: The applications of solvent extraction (SX) and liquid membranes (LM) span chemistry, metallurgy, hydrometallurgy, chemical/mineral processing, and waste treatment-making it difficult to find a single resource that encompasses fundamentals as well as advanced applications. Solvent Extraction and Liquid Membranes: Fundamentals and Applicat
Download or read book Solid State Chemical Sensors written by Jiri Janata and published by Academic Press. This book was released on 2012-12-02 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid State Chemical Sensors reviews the basic chemical and physical principles involved in the construction and operation of solid state sensors. A major portion of the book is devoted to explanation of the basic mechanism of operation and the many actual and potential applications of field effect transistors for gas and solution sensing. This text is comprised of four chapters; the first of which describes the basics of device fabrication. Emphasis is placed on the physical description of semiconductor devices with catalytic metal gates, along with their drawbacks and their promise. The behavior of hydrogen in the Pd-SiO2 system is also considered, and some applications of hydrogen-sensitive transistors, such as smoke detection and biochemical reaction monitoring, are described. The second chapter focuses on chemically sensitive field effect transistors and their thermodynamics, while the third chapter explains the general fabrication procedure for solid state chemical sensors. The final chapter introduces the reader to piezoelectric and pyroelectric chemical sensors, paying particular attention to the sensor nature of piezoelectricity, the piezoelectric gravimetric sensor, and pyroelectric gas analysis. This book is intended to assist electrical engineers in understanding the chemistry involved in the construction and operation of solid state sensors and to educate chemists in solid state science.
Download or read book Avoidance of Failure written by and published by Elsevier Publishing Company. This book was released on 1970 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Engineering Materials 2 written by Michael F. Ashby and published by Elsevier. This book was released on 2014-06-28 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a thorough explanation of the basic properties of materials; of how these can be controlled by processing; of how materials are formed, joined and finished; and of the chain of reasoning that leads to a successful choice of material for a particular application. The materials covered are grouped into four classes: metals, ceramics, polymers and composites. Each class is studied in turn, identifying the families of materials in the class, the microstructural features, the processes or treatments used to obtain a particular structure and their design applications. The text is supplemented by practical case studies and example problems with answers, and a valuable programmed learning course on phase diagrams.
Download or read book Advances in Liquid Chromatography written by Toshihiko Hanai and published by World Scientific. This book was released on 1996 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a contemporary review of selected subjects in liquid chromatography, especially of the technical development, rather than the applications. The subjects are focused in the biomedical and environmental fields. This is also a troubleshooting record. Complex analytical problems such as sensitivity (sensitive detection by chemiluminescence, coulometric detection, laser based detection, necessity of degassing the system for sensitive detection), difficulty (free radical detection by Electron Spin Resonance, Polarimeter for chiral recognition) and reproducibility (packings for chiral separation and stable bonded silica gels) are solved. Theoretically and environmentally important miniaturizations are described. Individual chapters written by specialists provide information beyond what can be found in general textbooks of liquid chromatography.
Download or read book Engineering Materials 3 written by David Rayner Hunkin Jones and published by Pergamon. This book was released on 1993 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aims to provide undergraduate and graduate students with a source of practical information on the design implications of material properties, building on the basic material contained in "Engineering Materials 1 and 2". The text presents a series of case studies drawn from real situations.
Download or read book Metals and Materials written by R. E. Smallman and published by Elsevier. This book was released on 2013-10-22 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metals and Materials: Science, Processes, Applications aims to present the science of materials in a readable and concise form that leads naturally to an explanation of the ways in which materials are processed and applied. The science of metals, or physical metallurgy, has developed naturally into the wider and more diverse discipline of materials science. The study of metals and alloys still forms a large and important part of this relatively new discipline, but it’s common to find that fundamental principles and concepts of physical metallurgy can be adapted to explain the behavior of a variety of non-metallic materials. As an aid to fully study this discipline, each chapter has been supplemented with a list of specialized references. These references include images and diagrams that illustrate the subtleties of materials, such as micrographs of grain structures and fine-scale defects, phase diagrams for metals and ceramics, electron diffraction patterns revealing atomic arrangements, specific property diagrams correlating the behavior of different materials, and slip vector diagrams for deforming crystals. Throughout this book, sufficient background and theory is provided to assist students in answering questions about a large part of a typical degree course in materials science and engineering. Some sections provide a background or point of entry for postgraduate studies and courses.
Download or read book The Tribology Handbook written by Michael J Neale and published by Elsevier. This book was released on 1995-12-15 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: The renowned reference work is a practical guide to the selection and design of the components of machines and to their lubrication. It has been completely revised for this second edition by leading experts in the area.
Download or read book An Introduction to Composite Materials written by D. Hull and published by Cambridge University Press. This book was released on 1996-08-13 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edition has been greatly enlarged and updated to provide both scientists and engineers with a clear and comprehensive understanding of composite materials. In describing both theoretical and practical aspects of their production, properties and usage, the book crosses the borders of many disciplines. Topics covered include: fibres, matrices, laminates and interfaces; elastic deformation, stress and strain, strength, fatigue crack propagation and creep resistance; toughness and thermal properties; fatigue and deterioration under environmental conditions; fabrication and applications. Coverage has been increased to include polymeric, metallic and ceramic matrices and reinforcement in the form of long fibres, short fibres and particles. Designed primarily as a teaching text for final-year undergraduates in materials science and engineering, this book will also interest undergraduates and postgraduates in chemistry, physics, and mechanical engineering. In addition, it will be an excellent source book for academic and technological researchers on materials.
Download or read book Plastics Materials written by J. A. Brydson and published by . This book was released on 1975 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Materials Selection in Mechanical Design written by M. F. Ashby and published by Pergamon. This book was released on 1992-01-01 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: New materials enable advances in engineering design. This book describes a procedure for material selection in mechanical design, allowing the most suitable materials for a given application to be identified from the full range of materials and section shapes available. A novel approach is adopted not found elsewhere. Materials are introduced through their properties; materials selection charts (a new development) capture the important features of all materials, allowing rapid retrieval of information and application of selection techniques. Merit indices, combined with charts, allow optimisation of the materials selection process. Sources of material property data are reviewed and approaches to their use are given. Material processing and its influence on the design are discussed. The book closes with chapters on aesthetics and industrial design. Case studies are developed as a method of illustrating the procedure and as a way of developing the ideas further.
Download or read book Qualitative Analysis written by and published by . This book was released on 1902 with total page 910 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fatigue Mechanisms written by Jeffrey T. Fong and published by ASTM International. This book was released on 1979 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:
