Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Download or read book Spectral Methods in Transition Metal Complexes written by K. Sridharan and published by Elsevier. This book was released on 2016-02-13 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectral Methods in Transition Metal Complexes provides a conceptual understanding on how to interpret the optical UV-vis, vibrational EPR, and NMR spectroscopy of transition metal complexes. Metal complexes have broad applications across chemistry in the areas of drug discovery, such as anticancer drugs, sensors, special materials for specific requirements, and catalysis, so a thorough knowledge in preparation and characterization of metal complexes, while niche, is critical. Accessible to both the seasoned researcher and the graduate student alike, this book provides readers with a single source of content that addresses spectral methods in transition metal complexes. Provides readers with a single reference on metal complexes and coordination compounds Contains more than 100 figures, tables, and illustrations to aid in the retention of key concepts Authored by a scientist with nearly 40 years of experience in research and instruction

Download or read book Electronic Spectra of Transitions Metal Complexes written by Vinod Jena and published by Lulu.com. This book was released on 2015-04-12 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: This books will provides a conceptual parts of Electronic spectra of various transition metal complexes, which is useful for various competitive examinations.

Download or read book Physical Inorganic Chemistry written by S. F. A. Kettle and published by Springer. This book was released on 2013-11-11 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: GEORGE CHRISTOU Indiana University, Bloomington I am no doubt representative of a large number of current inorganic chemists in having obtained my undergraduate and postgraduate degrees in the 1970s. It was during this period that I began my continuing love affair with this subject, and the fact that it happened while I was a student in an organic laboratory is beside the point. I was always enchanted by the more physical aspects of inorganic chemistry; while being captivated from an early stage by the synthetic side, and the measure of creation with a small c that it entails, I nevertheless found the application of various theoretical, spectroscopic and physicochemical techniques to inorganic compounds to be fascinating, stimulating, educational and downright exciting. The various bonding theories, for example, and their use to explain or interpret spectroscopic observations were more or less universally accepted as belonging within the realm of inorganic chemistry, and textbooks of the day had whole sections on bonding theories, magnetism, kinetics, electron-transfer mechanisms and so on. However, things changed, and subsequent inorganic chemistry teaching texts tended to emphasize the more synthetic and descriptive side of the field. There are a number of reasons for this, and they no doubt include the rise of diamagnetic organometallic chemistry as the dominant subdiscipline within inorganic chemistry and its relative narrowness vis-d-vis physical methods required for its prosecution.

Download or read book Electronic Spectra of Transition Metal Complexes written by R. K. Ray and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Electronic Spectra of Transition Metal Complexes written by B.K.Kar and published by New Central Book Agency. This book was released on 2012 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to familiarize students with the concepts , methods and applications of crystal field theory as well as ligand field theory to a point where the literature on the subject can followed with much diificulty.

Download or read book Electronic Spectra of Transition Metal Complexes written by Derek Sutton and published by . This book was released on 1968 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Optical Spectra and Chemical Bonding in Transition Metal Complexes written by Thomas Schönherr and published by Springer Science & Business Media. This book was released on 2004-09-30 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Download or read book Complexes and First row Transition Elements written by David Nicholls and published by . This book was released on 1974 with total page 215 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book The Electronic Spectra of Transition Metal Complexes written by B. D. Bird and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Electronic spectra of transition metal complex written by D. Sutton and published by . This book was released on 1968 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Electronic Absorption Spectroscopy and Related Techniques written by D. N. Sathyanarayana and published by Universities Press. This book was released on 2001 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a conceptual and experimental basis for the interpretation of electronic absorption spectroscopy and related techniques. The basic theories, instrumentation and interpretation of the spectra of organic and coordination compounds for structural studies are presented step-by-step, in an easily understandable style. related topics of emission spectroscopes are covered as well.

Download or read book Advanced Aspects of Spectroscopy written by Muhammad Akhyar Farrukh and published by BoD – Books on Demand. This book was released on 2012-08-29 with total page 551 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopy is the study of absorption and emission of electromagnetic radiation due to the interaction between matter and energy that energy depends on the specific wavelength of electromagnetic radiation. This field has proven invaluable research tool in a number of areas including chemistry, physics, biology, medicine and ecology. The spectroscopic field of research is growing day-by-day and scientists are exploring new areas in this field by introducing new techniques. The main purpose of this book is to highlight these new spectroscopic techniques like Magnetic Induction Spectroscopy, Laser-Induced Breakdown Spectroscopy, X-ray Photoelectron Spectroscopy, Low Energy Electron Loss Spectroscopy, Micro- to Macro-Raman Spectroscopy, Liquid-Immersion Raman Spectroscopy, High-Resolution Magic Angle Spinning (HR-MAS) Nuclear Magnetic Resonance (NMR) Spectroscopy, Injection and Optical Spectroscopy, and Nano Spectroscopy. This book is divided into five sections including General Spectroscopy, Advanced Spectroscopy, Nano Spectroscopy, Organic Spectroscopy, and Physical Spectroscopy which cover topics from basic to advanced levels which will provide a good source of learning for teaching and research purposes.

Download or read book Electronic Spectra of Selected 5 d Transition Metal Complexes written by Ryong K. Yoo and published by . This book was released on 1987 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Transition Metal and Rare Earth Compounds written by Hartmut Yersin and published by Springer. This book was released on 2003-07-01 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.

Download or read book Electronic and Vibronic Spectra of Transition Metal Complexes I written by Hartmut Yersin and published by Springer. This book was released on 1994-09-23 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: G. Blasse, "Vibrational Structure in the" "Luminescence Spectra of Ions in Solids."- A. Ceulemans, "The Doublet States in Chromium(III) Complexes." "A Shell-Theoretic View."- H.-H. Schmidtke, "Vibrational Progressions in Electronic" "Spectra of Complex Compounds Indicating Strong Vibronic" "Coupling."- P.E. Hoggard, "Sharp-Line Electronic Spectra and Metal-Ligand" "Geometry."- M. Colombo, A. Hauser, H.U. GA1/4del, "Competition" "Between Ligand Centered and Charge Transfer Lowest Excited" "States in bis Cyclometalated Rh3+ and Ir3+ Complexes."- D. Wexler, J.I. Zink, C. Reber, "Spectroscopic Manifestations of" "Potential" "Surface Coupling Along Normal Coordinates in " "Transition" " Metal Complexes."

Download or read book Electron Spectroscopy written by C. R. Brundle and published by Mittal Publications. This book was released on 2002 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: