Download or read book Electroluminescence from Plasmonic Excitations in a Scanning Tunnelling Microscope written by Edelmann, Kevin and published by KIT Scientific Publishing. This book was released on 2019-07-03 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work presents the design and commissioning of a new low-temperature Scanning Tunnelling Microscope equipped with an innovative light collection setup using an integrated, micro-fabricated mirror tip. Commissioning experiments demonstrate the capabilities of this new instrument and reproduce known effects regarding gap plasmons on noble-metal surfaces. Furthermore, different contrasts in the plasmon-mediated light emission from Cobalt nano-islands on a Copper (111) substrate are reported.

Download or read book Light Emission from Single Self decoupled Molecules in a Scanning Tunnelling Microscope written by Rai, Vibhuti Narayan and published by KIT Scientific Publishing. This book was released on 2022-10-04 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, a clear pathway is presented to achieve well-defined electronically decoupled chromophores from metallic leads without requiring additional insulating layers. To study such self-decoupled molecules, STM equipped with an efficient light detection setup has been used. Results show that the chromophores mounted on tripodal molecular platforms adsorbed on a gold surface present well-defined and efficient electroluminescence down to the single-molecule level.

Download or read book Molecular Electronics An Introduction To Theory And Experiment 2nd Edition written by Elke Scheer and published by World Scientific. This book was released on 2017-05-19 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular Electronics is self-contained and unified in its presentation. It can be used as a textbook on nanoelectronics by graduate students and advanced undergraduates studying physics and chemistry. In addition, included in this new edition are previously unpublished material that will help researchers gain a deeper understanding into the basic concepts involved in the field of molecular electronics.

Download or read book Molecular Electronics written by Juan Carlos Cuevas and published by World Scientific. This book was released on 2010 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. The birth of molecular electronics. 1.1. Why molecular electronics?. 1.2. A brief history of molecular electronics. 1.3. Scope and structure of the book -- 2. Fabrication of metallic atomic-size contacts. 2.1. Introduction. 2.2. Techniques involving the scanning electron microscope (STM). 2.3. Methods using atomic force microscopes (AFM). 2.4. Contacts between macroscopic wires. 2.5. Transmission electron microscope. 2.6. Mechanically controllable break-junctions (MCBJ). 2.7. Electromigration technique. 2.8. Electrochemical methods. 2.9. Recent developments. 2.10. Electronic transport measurements. 2.11. Exercises -- 3. Contacting single molecules: Experimental techniques. 3.1. Introduction. 3.2. Molecules for molecular electronics. 3.3. Deposition of molecules. 3.4. Contacting single molecules. 3.5. Contacting molecular ensembles. 3.6. Exercises -- 4. The scattering approach to phase-coherent transport in nanocontacts. 4.1. Introduction. 4.2. From mesoscopic conductors to atomic-scale junctions. 4.3. Conductance is transmission : heuristic derivation of the Landauer formula. 4.4. Penetration of a potential barrier : tunnel effect. 4.5. The scattering matrix. 4.6. Multichannel Landauer formula. 4.7. Shot noise. 4.8. Thermal transport and thermoelectric phenomena. 4.9. Limitations of the scattering approach. 4.10. Exercises -- 5. Introduction to Green's function techniques for systems in equilibrium. 5.1. The Schrodinger and Heisenberg pictures. 5.2. Green's functions of a noninteracting electron system. 5.3. Application to tight-binding Hamiltonians. 5.4. Green's functions in time domain. 5.5. Exercises -- 6. Green's functions and Feynman diagrams. 6.1. The interaction picture. 6.2. The time-evolution operator. 6.3. Perturbative expansion of causal Green's functions. 6.4. Wick's theorem. 6.5. Feynman diagrams. 6.6. Feynman diagrams in energy space. 6.7. Electronic self-energy and Dyson's equation. 6.8. Self-consistent diagrammatic theory : the Hartree-Fock approximation. 6.9. The Anderson model and the Kondo effect. 6.10. Final remarks. 6.11. Exercises -- 7. Nonequilibrium Green's functions formalism. 7.1. The Keldysh formalism. 7.2. Diagrammatic expansion in the Keldysh formalism. 7.3. Basic relations and equations in the Keldysh formalism. 7.4. Application of Keldysh formalism to simple transport problems. 7.5. Exercises -- 8. Formulas of the electrical current : exploiting the Keldysh formalism. 8.1. Elastic current : microscopic derivation of the Landauer formula. 8.2. Current through an interacting atomic-scale junction. 8.3. Time-dependent transport in nanoscale junctions. 8.4. Exercises -- 9. Electronic structure I: Tight-binding approach. 9.1. Basics of the tight-binding approach. 9.2. The extended Huckel method. 9.3. Matrix elements in solid state approaches. 9.4. Slater-Koster two-center approximation. 9.5. Some illustrative examples. 9.6. The NRL tight-binding method. 9.7. The tight-binding approach in molecular electronics. 9.8. Exercises -- 10. Electronic structure II : density functional theory. 10.1. Elementary quantum mechanics. 10.2. Early density functional theories. 10.3. The Hohenberg-Kohn theorems. 10.4. The Kohn-Sham approach. 10.5. The exchange-correlation functionals. 10.6. The basic machinery of DFT. 10.7. DFT performance. 10.8. DFT in molecular electronics. 10.9. Exercises -- 11. The conductance of a single atom. 11.1. Landauer approach to conductance: brief reminder. 11.2. Conductance of atomic-scale contacts. 11.3. Conductance histograms. 11.4. Determining the conduction channels. 11.5. The chemical nature of the conduction channels of oneatom contacts. 11.6. Some further issues. 11.7. Conductance fluctuations. 11.8. Atomic chains : parity oscillations in the conductance. 11.9. Concluding remarks. 11.10. Exercises -- 12. Spin-dependent transport in ferromagnetic atomic contacts. 12.1. Conductance of ferromagnetic atomic contacts. 12.2. Magnetoresistance of ferromagnetic atomic contacts. 12.3. Anisotropic magnetoresistance in atomic contacts. 12.4. Concluding remarks and open problems -- 13. Coherent transport through molecular junctions I : basic concepts. 13.1. Identifying the transport mechanism in single-molecule junctions. 13.2. Some lessons from the resonant tunneling model. 13.3. A two-level model. 13.4. Length dependence of the conductance. 13.5. Role of conjugation in [symbol]-electron systems. 13.6. Fano resonances. 13.7. Negative differential resistance. 13.8. Final remarks. 13.9. Exercises -- 14. Coherent transport through molecular junctions II : test-bed molecules. 14.1. Coherent transport through some test-bed molecules. 14.2. Metal-molecule contact : the role of anchoring groups. 14.3. Tuning chemically the conductance : the role of side-groups. 14.4. Controlled STM-based single-molecule experiments. 14.5. Conclusions and open problems -- 15. Single-molecule transistors : Coulomb blockade and Kondo physics. 15.1. Introduction. 15.2. Charging effects in transport through nanoscale devices. 15.3. Single-molecule three-terminal devices. 15.4. Coulomb blockade theory : constant interaction model. 15.5. Towards a theory of Coulomb blockade in molecular transistors. 15.6. Intermediate coupling : cotunneling and Kondo effect. 15.7. Single-molecule transistors : experimental results. 15.8. Exercises -- 16. Vibrationally-induced inelastic current I : experiment. 16.1. Introduction. 16.2. Inelastic electron tunneling spectroscopy (IETS). 16.3. Highly conductive junctions : point-contact spectroscopy (PCS). 16.4. Crossover between PCS and IETS. 16.5. Resonant inelastic electron tunneling spectroscopy (RIETS). 16.6. Summary of vibrational signatures -- 17. Vibrationally-induced inelastic current II : theory. 17.1. Weak electron-phonon coupling regime. 17.2. Intermediate electron-phonon coupling regime. 17.3. Strong electron-phonon coupling regime. 17.4. Concluding remarks and open problems. 17.5. Exercises -- 18. The hopping regime and transport through DNA molecules. 18.1. Signatures of the hopping regime. 18.2. Hopping transport in molecular junctions : experimental examples. 18.3. DNA-based molecular junctions. 18.4. Exercises -- 19. Beyond electrical conductance : shot noise and thermal transport. 19.1. Shot noise in atomic and molecular junctions. 19.2. Heating and heat conduction. 19.3. Thermoelectricity in molecular junctions -- 20. Optical properties of current-carrying molecular junctions. 20.1. Surface-enhanced Raman spectroscopy of molecular junctions. 20.2. Transport mechanisms in irradiated molecular junctions. 20.3. Theory of photon-assisted tunneling. 20.4. Experiments on radiation-induced transport in atomic and molecular junctions. 20.5. Resonant current amplification and other transport phenomena in ac driven molecular junctions. 20.6. Fluorescence from current-carrying molecular junctions. 20.7. Molecular optoelectronic devices. 20.8. Final remarks. 20.9. Exercises -- 21. What is missing in this book?

Download or read book Optoelectronic Organic Inorganic Semiconductor Heterojunctions written by Ye Zhou and published by CRC Press. This book was released on 2021-01-20 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Optoelectronic Organic-Inorganic Semiconductor Heterojunctions summarizes advances in the development of organic-inorganic semiconductor heterojunctions, points out challenges and possible solutions for material/device design, and evaluates prospects for commercial applications. Introduces the concept and basic mechanism of semiconductor heterojunctions Describes a series of organic-inorganic semiconductor heterojunctions with desirable electrical and optical properties for optoelectronic devices Discusses typical devices such as solar cells, photo-detectors, and optoelectronic memories Outlines the materials and device challenges as well as possible strategies to promote the commercial translation of semiconductor heterojunctions-based optoelectronic devices Aimed at graduate students and researchers working in solid-state materials and electronics, this book offers a comprehensive yet accessible view of the state of the art and future directions.

Download or read book Encyclopedia of Interfacial Chemistry written by and published by Elsevier. This book was released on 2018-03-29 with total page 5276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions

Download or read book Molecular Motor Based on Single Chiral Tripodal Molecules Studied with STM written by Skolaut, Julian and published by KIT Scientific Publishing. This book was released on 2023-09-14 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work presents a single molecular motor driven by the current in an STM. Its chiral functional group is supposed to perform a rotation in a preferred direction, proven by Binomial tests to be statistically significant. The rotation is proposedly driven by the chiral-induced spin selectivity effect (CISS). However, the studies of the rotation on the dependence on the lateral tip position, voltage and current indicate that he CISS is unlikely to cause the preferred rotation direction.

Download or read book Trace Analysis with Nanomaterials written by David T. Pierce and published by John Wiley & Sons. This book was released on 2011-05-25 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presenting a wide variety of methods, this book provides a comprehensive overview of the current state -- ranging from bioanalysis to electrochemical sensing, forensics and chemistry, while also covering the toxicity aspects of nanomaterials to humans and the environment. Edited by rising stars in the field, the first section on biological analysis includes an investigation of nanoparticles and micro- and nanofluidic systems, while the second, environmental analysis, looks at the detection, monitoring, and sensing of explosives as well as pollutants, among other topics. The final part covers such advanced methods as the synthesis and characterization of gold nanorods. For analytical chemists, materials scientists, chemists working in trace analysis, and spectroscopists.

Download or read book High Resolution Imaging Spectroscopy and Nuclear Quantum Effects of Interfacial Water written by Jing Guo and published by Springer. This book was released on 2018-07-16 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents a series of experimental techniques based on scanning probe microscopy, which make it possible access the degree of freedom of protons both in real and energy space. These novel techniques and methods allow direct visualization of the concerted quantum tunneling of protons within the hydrogen-bonded network and quantification of the quantum component of a single hydrogen bond at a water–solid interface for the first time. Furthermore, the thesis demonstrates that the anharmonic quantum fluctuations of hydrogen nuclei further weaken the weak hydrogen bonds and strengthen the strong ones. However, this trend was reversed when the hydrogen bond coupled to the local environment. These pioneering findings substantially advance our understanding of the quantum nature of H bonds at the molecular level.

Download or read book Sub Kelvin scanning tunneling microscopy on magnetic molecules written by Zhang, Lei and published by KIT Scientific Publishing. This book was released on 2019-07-05 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Issues in General Physics Research 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 13957 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issues in General Physics Research / 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about General Physics Research. The editors have built Issues in General Physics Research: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about General Physics Research in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Issues in General Physics Research: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Download or read book Detection and Interaction of Single Quantum States written by Sishen Xie and published by Springer Nature. This book was released on 2023-07-25 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights the findings and achievements in the major research plan “Detection and Interaction of Single Quantum States” funded by the National Natural Science Foundation of China (NSFC). The 8-year plan started in 2011 and consisted of 107 projects conducted by Chinese universities and research institutes. The book covers the plan's research background, achievements, and follow-up prospects. The plan aimed to tackle one of the major challenges for researchers worldwide—to establish precise detection and control of single quantum states in time, space, energy, and momentum. The plan integrated precise detection means with the ultrahigh resolution of time, space, and energy, under extreme conditions such as ultrahigh vacuum, ultralow temperature, high magnetic field, and ultrahigh pressure, using interdisciplinary research methods in physics, chemistry, informatics, and materials science. The book focuses on the exploration of new phenomena, theories, and concepts of single quantum states, describes new techniques and methods of single quantum states, and presents the purification and construction of single-quantum-state systems. It is a concise and valuable source of information for researchers in quantum science and graduate students interested in the research field.

Download or read book Near field Optics Principles And Applications Proceedings Of The Second Asia pacific Workshop written by Motoichi Ohtsu and published by World Scientific. This book was released on 2000-09-05 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Near-field optics, dealing with the interaction between optical field and matter in the nanometric region, has become an interdisciplinary field spaning physics, chemistry, materials science, electrical engineering and high density data storage. This book reflects the recent status of this rapidly growing field. It discusses the basic theories, instrumentation, novel probes, theoretical simulations, and the application of near-field optics to the fields of condensed matter physics, new materials, information storage, atom photonics, etc. It provides an overview of the research on near-field optics in the 1990s.

Download or read book Plasmonic Metal Nanostructures written by Caixia Kan and published by John Wiley & Sons. This book was released on 2024-02-20 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Firsthand insights on a unique class of optoelectronic materials, covering technologies and applications in catalysis, sensing, and spectroscopy Plasmonic Metal Nanostructures provides broad coverage of the field of plasmonic technologies, from fundamentals to real-world applications such as highly sensitive spectroscopy and surface analysis techniques, summarizing the recent progress in plasmonics and their applications, with a focus on comprehensive and authoritative discussions of fabrication and characterization of the materials and their technological uses. The text also addresses current trends and advances in materials for plasmonics, such as nanostructures with novel shapes, composite nanostructures, and thin films. Starting with an overview of optical properties in materials from macro- to micro- and nanoscale, the text then moves on to discuss the fundamentals and dielectric modifications and advanced characterization methods of plasmonic nanostructures. Next, the latest development of metal nanostructures, such as core-shell and porous nanorods, nanowires for conductive films, new star-like nanoplates, different open nanostructures, and metal-semiconductor composite nanostructures, are explained in detail. The final portion of the text discusses applications of plasmonics for semiconductor optoelectronic devices, catalysis, sensing, SERS (surface-enhanced Raman Spectroscopy), and energy. Written by a highly qualified academic, Plasmonic Metal Nanostructures covers sample topics such as: Drude model for free electron gas, dielectric function of the free electron gas, surface plasmon polaritons, plasmon at metal-vacuum interface, and surface plasmon effects Drude-Lorentz model of metal nanoparticles, dielectric properties of complex nanostructures, optical property analysis of isolated nanoparticles, and numerical simulation of optical properties One-dimensional Au nanostructures, core-shell nanostructures, alloy Au/Ag nanorods, porous nanorods, and yolk-shell nanostructures FCC nanoplates, Au nanoplates with novel and well-defined shapes, metal decorated semiconductors, and optical properties of Au NBP-embedded nanostructures Providing complete coverage of plasmonic nanostructures and their applications in catalysis, sensing, spectroscopy, thin-film, analysis, optoelectronics, and a variety of other fields. The book about Plasmonic Metal Nanostructures is an essential resource for materials scientists, physics researchers and photochemists, along with catalytic, biomedical, and physical chemists.

Download or read book Recent Advances in Plasmonic Probes written by Rajib Biswas and published by Springer Nature. This book was released on 2022-06-21 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a comprehensive overview of recent advancements in both theory and practical implementation of plasmonic probes. Encompassing multiple disciplines, the field of plasmonics provides a versatile and flexible platform for nanoscale sensing and imaging. Despite being a relatively young field, plasmonic probes have come a long way, with applications in chemical, biological, civil, and architectural fields as well as enabling many analytical schemes such as immunoassay, biomarkers, environmental indexing, and water quality sensing, to name but a few. The objective of the book is to present in-depth analysis of the theory and applications of novel probes based on plasmonics, with a broad selection of specially-invited chapters on the development, fabrication, functionalization, and implementation of plasmonic probes as well as their integration with current technologies and future outlook. This book is designed to cater to the needs of novice, seasoned researchers and practitioners in academia and industry, as well as medical and environmental fields.

Download or read book Nano Structures for Optics and Photonics written by Baldassare Di Bartolo and published by Springer. This book was released on 2014-10-06 with total page 589 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contributions in this volume were presented at a NATO Advanced Study Institute held in Erice, Italy, 4-19 July 2013. Many aspects of important research into nanophotonics, plasmonics, semiconductor materials and devices, instrumentation for bio sensing to name just a few, are covered in depth in this volume. The growing connection between optics and electronics, due to the increasing important role plaid by semiconductor materials and devices, find their expression in the term photonics, which also reflects the importance of the photon aspect of light in the description of the performance of several optical systems. Nano-structures have unique capabilities that allow the enhanced performance of processes of interest in optical and photonic devices. In particular these structures permit the nanoscale manipulation of photons, electrons and atoms; they represent a very hot topic of research and are relevant to many devices and applications. The various subjects bridge over the disciplines of physics, biology and chemistry, making this volume of interest to people working in these fields. The emphasis is on the principles behind each technique and on examining the full potential of each technique.

Download or read book The Nature of the Mechanical Bond written by Carson J. Bruns and published by John Wiley & Sons. This book was released on 2016-10-10 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The story is told by THE inventor-pioneer-master in the field and is accompanied by amazing illustrations... [it] will become an absolute reference and a best seller in chemistry!" —Alberto Credi "... the great opus on the mechanical bond. A most impressive undertaking!" — Jean-Marie Lehn Congratulations to co-author J. Fraser Stoddart, a 2016 Nobel Laureate in Chemistry. In molecules, the mechanical bond is not shared between atoms—it is a bond that arises when molecular entities become entangled in space. Just as supermolecules are held together by supramolecular interactions, mechanomolecules, such as catenanes and rotaxanes, are maintained by mechanical bonds. This emergent bond endows mechanomolecules with a whole suite of novel properties relating to both form and function. They hold unlimited promise for countless applications, ranging from their presence in molecular devices and electronics to their involvement in remarkably advanced functional materials. The Nature of the Mechanical Bond is a comprehensive review of much of the contemporary literature on the mechanical bond, accessible to newcomers and veterans alike. Topics covered include: Supramolecular, covalent, and statistical approaches to the formation of entanglements that underpin mechanical bonds in molecules and macromolecules Kinetically and thermodynamically controlled strategies for synthesizing mechanomolecules Chemical topology, molecular architectures, polymers, crystals, and materials with mechanical bonds The stereochemistry of the mechanical bond (mechanostereochemistry), including the novel types of dynamic and static isomerism and chirality that emerge in mechanomolecules Artificial molecular switches and machines based on the large-amplitude translational and rotational motions expressed by suitably designed catenanes and rotaxanes. This contemporary and highly interdisciplinary field is summarized in a visually appealing, image-driven format, with more than 800 illustrations covering both fundamental and applied research. The Nature of the Mechanical Bond is a must-read for everyone, from students to experienced researchers, with an interest in chemistry’s latest and most non-canonical bond.