Download or read book TECHNICAL ASSESSMENT OF FRACTIONAL CRYSTALLIZATION FOR TANK WASTE PRETREATMENT AT THE DOE HANFORD SITE written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Tank Closure and Waste Management for the Hanford Site written by and published by . This book was released on 2012 with total page 1098 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Use of Evaporative Fractional Crystallization in the Pretreatment Process of Multi salt Single Shell Tank Hanford Nuclear Wastes written by Laurent Nassif and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. In this thesis, experimental apparatus, procedures and results are given on scaled-down experiments of SST Early Feed for hot-cell adaptation along with operating parameters and crystallization mechanism studies on early feed multi-solute crystallization. Moreover, guidance is given regarding future steps towards adapting the technology to multi-salt crystallization kinetic parameter estimates and modeling. Crystallization, Evaporative Fractional Crystallization, Nuclear Waste Pretreatment, Cesium Removal, Hanford, SST Early and Late feed, Multi-solute, Multi-salts, Simulant Testing.
Download or read book FRACTIONAL CRYSTALLIZATION LABORATORY TESTING WITH INTERIM PRETREATMENT SYSTEM FEEDS written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The fractional crystallization process was developed as a pretreatment method for saltcake waste retrieved from Hanford single-shell tanks (SST). The process separates the retrieved SST waste into a high-level waste stream containing the bulk of the radionuclides and a low-activity waste stream containing the bulk of the nonradioactive sodium salts. The Interim Pretreatment System project shifted the focus on pretreatment planning from SST waste to double-shell tank waste.
Download or read book Cours de sens commun Prospectus written by and published by . This book was released on 17?? with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book HANFORD MEDIUM LOW CURIE WASTE PRETREATMENT ALTERNATIVES PROJECT FRACTIONAL CRYSTALLIZATION PILOT SCALE TESTING FINAL REPORT written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Fractional Crystallization Pilot Plant was designed and constructed to demonstrate that fractional crystallization is a viable way to separate the high-level and low-activity radioactive waste streams from retrieved Hanford single-shell tank saltcake. The focus of this report is to review the design, construction, and testing details of the fractional crystallization pilot plant not previously disseminated.
Download or read book FRACTIONAL CRYSTALLIZATION OF HANFORD SINGLE SHELL TANK SST WASTES LABORATORY DEVELOPMENT written by D. L. HERTING and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Laboratory studies demonstrate that fractional crystallization is a viable process for separating Hanford medium-curie waste into high-curie and low-curie fractions. The product salt from the crystallization process qualifies as low-curie feed to a supplemental treatment system (e.g., bulk vitrification). The high-curie raffinate is returned to the double-shell tank system, eventually to be sent as feed to the Waste Treatment and Immobilization Plant. Process flowsheet tests were designed with the aid of thermodynamic chemical modeling. Laboratory equipment design and test procedures were developed using simulated tank waste samples. Proof-of-concept flowsheet tests were carried out in a shielded hot cell using actual tank waste samples. Data from both simulated waste tests and actual tank waste tests demonstrate that the process exceeded all of the separation criteria established for the program.
Download or read book The Use of Carbonation and Fractional Evaporative Crystallization in the Pretreatment of Hanford Nuclear Wastes written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this work was to explore the use of fractional evaporative crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. Experimental semi-batch crystallizations of sodium salts from simulant solutions of double-shell tank (DST) feed demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium and nearly met the requirement on sodium recovery.
Download or read book FRACTIONAL CRYSTALLIZATION LABORATORY TESTING FOR INCLUSION COPRECIPITATION WITH ACTUAL TANK WASTE written by R. W. WARRANT and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Fractional crystallization is being considered as a pretreatment method to support supplemental treatment of retrieved single-shell tank (SST) saltcake waste at the Hanford Site. The goal of the fractional crystallization process is to optimize the separation of the radioactivity (radionuclides) from the saltcake waste and send it to the Waste Treatment and Immobilization Plant and send the bulk of the saltcake to the supplemental treatment plant (bulk vitrification). The primary factors that influence the separation efficiency are (1) solid/liquid separation efficiency, (2) contaminant inclusions, and (3) co-precipitation. This is a report of testing for factors (2) and (3) with actual tank waste samples. For the purposes of this report, contaminant inclusions are defined as the inclusion of supernatant, containing contaminating radionuclides, in a pocket within the precipitating saltcake crystals. Co-precipitation is defined as the simultaneous precipitation of a saltcake crystal with a contaminating radionuclide. These two factors were tested for various potential fractional crystallization product salts by spiking the composite tank waste samples (SST Early or SST Late, external letter CH2M-0600248, ''Preparation of Composite Tank Waste Samples for ME-21 Project'') with the desired target salt and then evaporating to precipitate that salt. SST Early represents the typical composition of dissolved saltcake early in the retrieval process, and SST Late represents the typical composition during the later stages of retrieval.
Download or read book Accelerating Treatment of Radioactive Waste by Evaporative Fractional Crystallization written by Laurent Nassif and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of the work described in this thesis was to explore the use of fractional crystallization as a technology that can be used to separate medium-curie waste from the Hanford Site tank farms into a high-curie waste stream, which can be sent to a Waste Treatment and Immobilization Plant (WTP), and a low-curie waste stream, which can be sent to Bulk Vitrification. The successful semi-batch crystallization of sodium salts from two single shell tank simulant solutions (SST Early Feed, SST Late Feed) demonstrated that the recovered crystalline product met the purity requirement for exclusion of cesium, sodium recovery in the crystalline product and the requirement on the sulfate-to-sodium molar ratio in the stream to be diverted to the WTP. The experimental apparatus, procedures and results obtained in this thesis on scaled-down experiments of SST Early and Late Feed simulated solutions were adapted and reproduced under hot-cell with actual wastes by our partners at Hanford. To prepare the application of the pretreatment process to pilot scale process, several varation to the feed solutions were investigated including the presence of carboxylates and amines organics compounds and solids particles. Results of the study showed that 4 organics species presented complications to the process (NTA, HEDTA, EDTA and sodium citrate) while the other species (Formate, acetate, glycolate and IDA) and solids particles did not in the conditions of the stored wastes. In this thesis, the kinetics of the crystalline species formed at the condition of the early feed certification run (66 °C and 25 g/h evaporation) were determined along with the effect of the operating temperature and evaporation rate on these kinetics. On one hand, the study of evaporation rate values ranging from 25g/h to 75g/h showed that an increase in evaporation rate increased the specific nucleation while decreasing the specific growth rate. On the other hand, experiments on operating temperature ranging from 35 °C to 75 °C displayed that the nucleation rate of all species increased with temperature at the exception of sodium carbonate monohydrate and burkeite crystals, and that the growth rate of all species increased with temperature at the exception of sodium nitrate. Furthermore, sulfate based crystals such as trisodium fluoride sulfate were only roduced at 45 °C and 75 °C.
Download or read book FRACTIONAL CRYSALLIZATION LABORATORY TESTS WITH SIMULATED TANK WASTE written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Results are presented for several simulated waste tests related to development of the fractional crystallization process. Product salt dissolution rates were measured to support pilot plant equipment design. Evaporation tests were performed to evaluate the effects of organics on slurry behavior and to determine optimum antifoam addition levels. A loss-of-power test was performed to support pilot plant accident scenario analysis. Envelope limit tests were done to address variations in feed composition.
Download or read book FRACTIONAL CRYSTALLIZATION FLOWSHEET TESTS WITH ACTUAL TANK WASTE written by D. L. HERTING and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Laboratory-scale flowsheet tests of the fractional crystallization process were conducted with actual tank waste samples in a hot cell at the 222-S Laboratory. The process is designed to separate medium-curie liquid waste into a low-curie stream for feeding to supplemental treatment and a high-curie stream for double-shell tank storage. Separations criteria (for Cs-137 sulfate, and sodium) were exceeded in all three of the flowsheet tests that were performed.
Download or read book Advice on the Department of Energy s Cleanup Technology Roadmap written by National Research Council and published by National Academies Press. This book was released on 2009-06-21 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Beginning with the Manhattan Project and continuing through the Cold War, the United States government constructed and operated a massive industrial complex to produce and test nuclear weapons and related technologies. When the Cold War ended, most of this complex was shut down permanently or placed on standby, and the United States government began a costly, long-term effort to clean up the materials, wastes, and environmental contamination resulting from its nuclear materials production. In 1989, Congress created the Office of Environmental Management (EM) within the Department of Energy (DOE) to manage this cleanup effort. Although EM has already made substantial progress, the scope of EM's future cleanup work is enormous. Advice on the Department of Energy's Cleanup Technology Roadmap: Gaps and Bridges provides advice to support the development of a cleanup technology roadmap for EM. The book identifies existing technology gaps and their priorities, strategic opportunities to leverage needed research and development programs with other organizations, needed core capabilities, and infrastructure at national laboratories and EM sites that should be maintained, all of which are necessary to accomplish EM's mission.
Download or read book Radioactive Waste Management written by and published by . This book was released on 1996-05 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy and Water Development Appropriations for 2009 written by United States. Congress. House. Committee on Appropriations. Subcommittee on Energy and Water Development and published by . This book was released on 2008 with total page 1490 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Strategy and Methodology for Radioactive Waste Characterization written by International Atomic Energy Agency and published by IAEA. This book was released on 2007 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past decade significant progress has been achieved in the development of waste characterization and control procedures and equipment as a direct response to ever-increasing requirements for quality and reliability of information on waste characteristics. Failure in control procedures at any step can have important, adverse consequences and may result in producing waste packages which are not compliant with the waste acceptance criteria for disposal, thereby adversely impacting the repository. The information and guidance included in this publication corresponds to recent achievements and reflects the optimum approaches, thereby reducing the potential for error and enhancing the quality of the end product. -- Publisher's description.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1993-10 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt:
