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Book Synthesis and Characterization of Platinum II  Complexes with Adamantantanamine Derivatives and Related Ligands

Download or read book Synthesis and Characterization of Platinum II Complexes with Adamantantanamine Derivatives and Related Ligands written by Monique Doyon and published by . This book was released on 1991 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: "New platinum(II) complexes of the type (Pt(A$ sp prime$)Cl$ sb3 rbrack sp-$, Pt(A)(A$ sp prime$)Cl$ sb2$ and Pt(A)(A$ sp prime$)I$ sb2$, where A = methylamine, ethylamine, cyclobutylamine and cyclopentylamine and A$ sp prime$ = 1-adamantanamine, 2-adamantanamine and 1-methyladamantanamine have been synthesized. The structure of (2-adamH) (Pt(EtNH$ sb2$)Cl$ sb3$) complex has been determined by X-ray diffraction." --

Book Luminescent Platinum ii  Complexes Containing Dianionic Tetradentate Ligands Having Mixed Oxygen  Nitrogen and Carbon Donor Atoms and Platinum ii  Containing Phosphorescent Polymers

Download or read book Luminescent Platinum ii Complexes Containing Dianionic Tetradentate Ligands Having Mixed Oxygen Nitrogen and Carbon Donor Atoms and Platinum ii Containing Phosphorescent Polymers written by Wai-Yip Tong and published by Open Dissertation Press. This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Luminescent Platinum(II) Complexes Containing Dianionic Tetradentate Ligands Having Mixed Oxygen, Nitrogen and Carbon Donor Atoms and Platinum(II)-containing Phosphorescent Polymers: Synthesis, Photophysical Properties and Material Applications" by Wai-yip, Tong, 唐煒燁, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled LUMINESCENT PLATINUM(II) COMPLEXES CONTAINING DIANIONIC TETRADENTATE LIGANDS HAVING MIXED OXYGEN, NITROGEN AND CARBON DONOR ATOMS AND PLATINUM(II)-CONTAINING PHOSPHORESCENT POLYMERS: SYNTHESIS, PHOTOPHYSICAL PROPERTIES AND MATERIAL APPLICATIONS Submitted by TONG WAI YIP for the degree of Doctor of Philosophy at The University of Hong Kong in May 2014 Square planar platinum(II) complexes exhibit rich photophysical properties which are tunable through the structural variation of ligands and can be harnessed for applications in materials science. In this thesis, the great variety of spectroscopic properties of various square planar cyclometalated platinum(II) complexes supported by tetradentate (O DEGREESN DEGREESN DEGREESC and O DEGREESN DEGREESC DEGREESN) and tridentate (C DEGREESN DEGREESN) ligands containing dipyridyl moieties will be highlighted, along with their synthesis, characterization and potential application in organic light emitting diodes (OLEDs). Ind Platinum(II) complexes supported by tetradentate O DEGREESN DEGREESN DEGREESC or O DEGREESN DEGREESN DEGREESC types of ligands (O DEGREESN DEGREESN DEGREESC = 2-(4-(3,5-di-tert-butylphenyl)-6'-phenyl-2,2'- Ind bipyridin-6-yl)phenolate; O DEGREESN DEGREESN DEGREESC = 5,5-dialkyl-2-(6-phenylpyridin-2-yl) indeno[1,2-b]pyridin-9-olate) are emissive in solution at room temperature, with emission maxima tunable from 582 nm to 640 nm and quantum yields up to 0.28. Mechanochromism and the associated luminescence change in [Pt(dihexyl- Ind O DEGREESN DEGREESN DEGREESC)] (Complex 3.6) were found associated with the two different crystal packings revealed by powder X-ray diffraction (PXRD) studies. Fast vapochromic response of [Pt(3-O DEGREESN DEGREESN-2,6-difluoropyridine)] (Complex 3.3) on chloroform or dichloromethane vapours was found to be associated with structural changes in the solid state through PXRD studies. Robust and strongly emissive platinum(II) complexes supported by tetradentate O DEGREESN DEGREESC DEGREESN ligands featuring fused six-five-six membered metallacyclic ring (O DEGREESN DEGREESC DEGREESN = 2-(4-(3,5-di-tert-butylphenyl)-6-(9-(pyridin-2-yl) carbazol-2-yl)pyridin-2-yl)phenol) have been prepared. These platinum(II) complexes are among the most efficient yellow phosphors, with emission maxima ranging from 526 nm to 553 nm and luminescence quantum yields as high as -1 0.47-0.86. A yellow OLED with power efficiency (η ) up to 52 lm W is power demonstrated. In combination with the typical blue emitting iridium(III) 2' bis(4,6-difluorophenyl-pyridinato-N, C ) picolinate (FIrpic), white organic -1 light-emitting diodes (WOLEDs) displayed η up to 61 lm W and reduced power -2 efficiency roll-off at 1000 cd m . Random copolymers with photo-inert backbone poly[(N-vinylcarbazole)-co- ((R-C DEGREESN DEGREESN)Pt)] and poly[(2-(4-tert-butylphenyl)-5-(4-vinylphenyl)-1,3,4- oxadiazole)-co-((R-C DEGREESN DEGREESN)Pt)] (R-C DEGREESN DEGREESN = 3-(6-phenyl-4-(4-vinylphenyl) pyridine-2-yl)-isoquinoline or 3-(4-(4-(dec-9-enyloxy)phenyl)-6-phenylpyridin- 2-yl)isoquinoline) have been synthesized and characterized. Energy transfer between the charge transporting units and emissive (R-C DEGREESN DEGREESN)Pt units was revealed through ICP-MS inve

Book The Synthesis and Characterization of Novel Platinum II  Complexes Containing Salicylaldimine Ligands Derived from Lipophilic Amines

Download or read book The Synthesis and Characterization of Novel Platinum II Complexes Containing Salicylaldimine Ligands Derived from Lipophilic Amines written by Caeleigh Ryalls and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Characterization of Platinum  II  Complexes with Diazine Ligands

Download or read book Synthesis and Characterization of Platinum II Complexes with Diazine Ligands written by Julien Priqueler and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis of Pt II    Pt IV  Complexes of Alpha aap Acid Ligands

Download or read book Synthesis of Pt II Pt IV Complexes of Alpha aap Acid Ligands written by Georgina Giannikopoulos and published by . This book was released on 2002 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and characterization of platinum II  complexes from quinoline or pyridine functionalized benzothiophene ligands

Download or read book Synthesis and characterization of platinum II complexes from quinoline or pyridine functionalized benzothiophene ligands written by Leila Duman and published by . This book was released on 2014 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book The Synthesis and Chemistry of Platinum  II  Hydroxo and Hydroxycarbonyl Complexes Containing Tertiary Phosphine Ligands

Download or read book The Synthesis and Chemistry of Platinum II Hydroxo and Hydroxycarbonyl Complexes Containing Tertiary Phosphine Ligands written by Jin Hong and published by . This book was released on 1990 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Luminescent Platinum II  Complexes Containing Dianionic Tetradentate Ligands Having Mixed Oxygen  Nitrogen and Carbon Donor Atoms and Platinum II  containing Phosphorescent Polymers

Download or read book Luminescent Platinum II Complexes Containing Dianionic Tetradentate Ligands Having Mixed Oxygen Nitrogen and Carbon Donor Atoms and Platinum II containing Phosphorescent Polymers written by 唐煒燁 and published by . This book was released on 2014 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Synthesis and Reactivity of Pt II  and Pt IV  Cyclometallated and Tridentate Complexes Derived from Iminophosphines and Phosphinoamides

Download or read book Synthesis and Reactivity of Pt II and Pt IV Cyclometallated and Tridentate Complexes Derived from Iminophosphines and Phosphinoamides written by Terence James Maguire and published by . This book was released on 2009 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes the synthesis and reactivity of platinum(II) and platinum(IV) complexes with mixed donor ligands containing [P, N, C] and [P, N, O] donor sets derived from iminophosphines and phosphinoamides. Chapter 1 introduces the concepts and principles, like hemilability, that influence the formation of stable complexes and how this stabilisation can influence the reactivity of the complex. This is highlighted using aminophosphines and iminophosphines as examples. In order to present the application of these mixed-donor complexes, a comprehensive overview of platinum complex chemistry, including Pt(IV) complexes, trans complexes and cyclometallates, in medicine is given. Chapter 2 reports the coordination chemistry of two types of [P, N, C] donor ligands; iminophosphines HL1-4 and phosphinoamides HL5-7 to generate a novel library of monodentate, bidentate and tridentate cyclometallated Pt(II) species by a variety of methods. Chapter 3 describes the synthesis of novel ionic, monophosphine substituted Pt(II) complexes of [P, N, C] and [P, N, O] ligands. The iminophosphine ([P, N, C] and [P, N, O]) complexes underwent substitution with all three of the phosphines introduced. However, the success of the reaction of the iminolphosphine [P, N, C] complexes depended on the nature of the phosphine used. This leads to the conclusion that substitution reactions of iminolphosphine complexes are influenced by a combination of basicity and steric bulk of the incoming ligand. Chapter 4 reports the oxidation of bidentate and cyclometallated Pt(II) complexes to generate a novel series of Pt(IV) species. Additionally it reports 1H and 31P{1H} NMR investigations into the reduction of Pt(IV) by low molecular weight thiols and finally describes the reaction of the Pt(II) cyclometallates with the same low molecular weight thiols. All compounds synthesised in chapters 2-4 were characterised by elemental analysis, IR, 1H and 31P{1H} NMR spectoscopies. Selected complexes were also analysed using single X-ray crystal analyses and mass spectrometry.

Book Synthesis and Characterization of Platinum  II  Comlplexes with Diazine Ligands

Download or read book Synthesis and Characterization of Platinum II Comlplexes with Diazine Ligands written by Julien Priqueler and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Palladacycles

    Book Details:
  • Author : Jairton Dupont
  • Publisher : John Wiley & Sons
  • Release : 2008-10-13
  • ISBN : 3527317813
  • Pages : 433 pages

Download or read book Palladacycles written by Jairton Dupont and published by John Wiley & Sons. This book was released on 2008-10-13 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Book Light Emitting Electrochemical Cells

Download or read book Light Emitting Electrochemical Cells written by Rubén D. Costa and published by Springer. This book was released on 2017-07-31 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the recent achievements towards the next generation of Light-emitting electrochemical cells (LEC). Its first part focus on the definition, history and mechanism of LEC, going then to concepts and challenges and, finally, giving the reader examples of current application of new electroluminescent materials. The chapters are written by different international groups working on LEC.