Download or read book Synthesis of Novel Siloxane containing Block and Graft Copolymers by Anionic Polymerization and the Macromonomer Technique written by Steven D. Smith and published by . This book was released on 1987 with total page 700 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Block and Graft Copolymers written by R. J. Ceresa and published by . This book was released on 1962 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis of Block Copolymers of Methyl Siloxane Phenyl Siloxane Vinyl Siloxane Etc written by John Akolisa Ibemesi and published by . This book was released on 1979 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthesis of homo poly(dimethylsiloxane) PDMS, homo poly(diphenylsiloxane PDPS, and di- and tri- block copolymers of PDMS and PDPS have been carried out by anionic living polymerization, using the following reagents: hexamethylcyclotrisiloxane, HMTS and hexaphenylcyclotrisiloxane, HPTS (monomers), n-BuLi and dilithium diphenyldisilanolate, DLS (initiators), DMSO and THF (promoters) and Toluene (solvent). Lithium based catalysts are used in order to minimize siloxane rearrangement (equilibration) reactions.
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2003 with total page 812 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis of Novel Siloxane Containing Block Copolymers for Impact Modification of Polybutyleneterephthalate written by Ian Walker and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1987 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Anionic Polymerization written by Nikos Hadjichristidis and published by Springer. This book was released on 2016-10-29 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.
Download or read book The Synthesis and Characterization of Polystyrene Liquid Crystalline Siloxane Block Copolymers written by Aaron J. Moment and published by . This book was released on 2000 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Macromolecular Design of Polymeric Materials written by Hatada and published by CRC Press. This book was released on 1997-01-02 with total page 900 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a range of information on polymers and polymerization techniques, this text covers the gamut of polymer science from synthesis, structure and properties to function and applications. It analyzes speciality polymers, including acrylics, fluoropolymers, polysiplanes, polyphosphazenes, and inorganic and conducting polymers. The book examines the stereochemistry of polymerization and the stereoregularity of polymers.
Download or read book Index to American Doctoral Dissertations written by and published by . This book was released on 1989 with total page 1252 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Recent Advances in Anionic Polymerization written by T.E. Hogen-Esch and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the years the field of anionic polymerization has attracted numerous outstanding scientists, and today it still is being pursued by many researchers all over the world. The exciting discovery of termination-less polymerization processes and living polymers culminating in the development of narrow molecular weight polymers, star polymers, and tailor-made block and graft copolymers, contributed immensely to the rapid expansion of polymer science. Areas of active research in anionic polymerization presently include the structure of ion pairs and their role in regulating polymer structure, ring opening polymerization of heterocyclic monomers, synthesis of well-defined block and graft copolymers including the application of macromers in such systems, telechelic polymers with functional end groups, and other topics. New developments in the organic chemistry of carbanions such as dipolar carbanions impinge on the field of anionic polymerization. More sophisticated characterization techniques have been instrumental in obtaining better correlations between the structure of polymers and that of intermediates leading to their formation. This book contains the proceedings of the international symposium on "Recent Advances in Anionic Polymerization and Related Processes" which was held at the 1986 spring meeting of the American Chemical Society. It was the first Polymer Division-sponsored meeting exclusively devoted to anionic polymerization since the Houston ACS meeting in the spring of 1980. The proceedings of that meeting were published in the book "Anionic Polymerization", ACS Symposium Series No. 166, edited by Dr. J. E. McGrath.
Download or read book Engineered Materials Abstracts written by and published by . This book was released on 1993-04 with total page 850 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Anionic Polymerization Principles and Practice written by Maurice Morton and published by Academic Press. This book was released on 1983-03-28 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anionic Polymerization: Principles and Practice describes the unique nature of the anionic mechanism of polymerization. This book is composed of two parts encompassing 11 chapters that cover the aspects of the synthetic possibilities inherent in this system. Part I deals with the various aspects of anionic polymerization mechanism, including the monomers, initiators, solvents, and the involved initiation and propagation reactions. This part also describes the copolymerization and organolithium polymerization reactions of styrene and dienes. Part II explores the applications of anionic polymerization in polymer synthesis. This part specifically tackles the synthesis of narrow molecular weight, branched and a,?-difunctional polymers, and block copolymers. Polymer chemists and researchers who work in the chemical industry and who would wish to utilize the unique features of anionic polymerization in the synthesis of new products will find this book invaluable.
Download or read book Synthesis of Novel Methacrylate containing Polymers by Anionic Polymerization written by Robert D. Allen and published by . This book was released on 1985 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Characterization of Graft Copolymers Poly isoprene g styrene of High Molecular Weight by a Combination of Anionic Polymerization and Emulsion Polymerization written by and published by . This book was released on 2015 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this study, high molecular weight "comb-shaped" graft copolymers, poly(isoprene-g-styrene), with polyisoprene as the backbone and polystyrene as side chains, were synthesized via free radical emulsion polymerization by copolymerization of isoprene with a polystyrene macromonomer synthesized using anionic polymerization. A small amount of toluene was used in order to successfully disperse the macromonomer. Both a redox and thermal initiation system were used in the emulsion polymerization, and the latex particle size and distribution were investigated by dynamic light scattering. The structural characteristics of the macromonomer and comb graft copolymers were investigated through use of size exclusion chromatography, spectroscopy, microscopy, thermal analysis, and rheology. While the macromonomer was successfully copolymerized to obtain the desired multigraft copolymers, small amounts of unreacted macromonomer remained in the products, reflecting its reduced reactivity due to steric effects. Nevertheless, the multigraft copolymers obtained were very high in molecular weight (5-12 × 105 g/mol) and up to 10 branches per chain, on average, could be incorporated. A material incorporating 29 wt% polystyrene exhibits a disordered microphase separated morphology and elastomeric properties. As a result, these materials show promise as new, highly tunable, and potentially low cost thermoplastic elastomers.
Download or read book Block and Graft Copolymerization written by R. J. Ceresa and published by . This book was released on 1976 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polysiloxane Copolymers Anionic Polymerization written by and published by Springer. This book was released on 2014-03-12 with total page 255 pages. Available in PDF, EPUB and Kindle. Book excerpt:
