Download or read book Synthesis of Group 4 Metal diketimine Complexes written by William James Scanlon and published by . This book was released on 1998 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Group IV Imido Complexes Supported by diketiminate Ligands written by Jie Fang and published by . This book was released on 2001 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Novel beta diketiminates and beta diketiminate Derivatives for the Synthesis of Main Group Complexes written by Brant James Maitland and published by . This book was released on 2015 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is primarily concerned with the synthesis of low oxidation state alkaline earth metal complexes featuring novel [beta]-diketiminate ligands and their derivatives. The syntheses of a variety of different [beta]-diketiminates possessing extreme steric bulk, as well as those that have been electronically modified are detailed. These ligands have been used to produce a variety of different alkali metal, alkaline earth metal and lanthanide complexes.Chapter 1 provides a general introduction to low oxidation state alkaline earth metal chemistry. Particular attention is given to metal complexes featuring [beta]-diketiminates, given their central role in the research making up this thesis.Chapter 2 deals with the synthesis of a range of novel, sterically hindered [beta]-diketimines. These pro-ligands were targeted in the belief that their extreme bulk would allow the synthesis of currently unknown structural motifs.Chapter 3 is primary concerned with the exploitation of the developed sterically hindered [beta]-diketimines in the synthesis of a variety of alkali metal, alkaline earth metal and lanthanide complexes. A range of three coordinate magnesium complexes were produced using the developed ligands, most notably, the first crystallographically characterised [beta]-diketiminato magnesium hydride. In our quest for a calcium(I) dimer, a complex type which is currently unknown, a variety of [beta]-diketiminato calcium iodides were produced. The attempted reduction of these heteroleptic metal iodide complexes resulted not in the targeted low oxidation state complexes, but in two different calcium(II) dimers.In Chapter 4, the [beta]-diketimine ligand was adapted, resulting in two separate classes of pro-ligands. The first, a 1,3,5-triazapentadiene, has had the central carbon replaced by nitrogen. The second, instead of having the typical methyl groups on the ligand backbone, has dialkylamino groups. In each instance, it was envisaged that the ligands would donate additional electron density, and bind more strongly to the metal centre in coordination complexes, when compared to the standard [beta]-diketiminate ligand class. Six separate heteroleptic magnesium(II) iodide complexes have been developed from these ligands, the majority of which show promise as precursors to low oxidation state magnesium complexes.Chapter 5 details several new secondary amines which have been produced as pro-ligands for low oxidation state main group chemistry. In addition, preliminary studies have shown that these ligands have potential in coordination chemistry.

Download or read book Synthesis and Characterization of Electrophilic Group 4 Metal Complexes written by Paul W. Kletzly and published by . This book was released on 1998 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Direct Synthesis of Metal Complexes written by B.I. Kharisov and published by Elsevier. This book was released on 2018-04-19 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Download or read book The Study and Synthesis of Group 4 Transition Metal Complexes in Ziegler Natta Catalysis written by Jonathan P. Corden and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Group IV Transition Metal Complexes and Their Applications as Catalysts for Ethylene Polymerization written by Khalil Ahmad and published by . This book was released on 2010 with total page 111 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis Structures Bonding and Reactivity of Group 4 Metal Alkyl Complexes Incorporating 8 quinolinolato Ligands written by Xiaohong Bei and published by . This book was released on 1997 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Group IV Metal Complexes Employing a Newly Developed Orthometallated Imine Ligand System written by Tamam Issa Baiz and published by . This book was released on 2007 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of New Zirconium Diketiminate Complexes and Catalytic Applications written by Ibrahim EL-Zoghbi and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Group 4 Metal Octahedral Bis phenolate Complexes for Propylene Polymerization written by Madalyn Radlauer and published by . This book was released on 2008 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis and Chemistry of Cationic D Sup 0 Metal Alkyl Complexes written by and published by . This book was released on 1990 with total page 2 pages. Available in PDF, EPUB and Kindle. Book excerpt: The long term goals of this project are to design and synthesize highly unsaturated, electrophilic metal complexes and to explore their use as catalysts, reagents, and/or model systems for olefin polymerization and C-H activation chemistry. During the 1990 budget year we have focused our attention on (i) the ligand C-H activation chemistry of Cp2Zr(CH3)(THF) and related cationic, d{sup o} Zr alkyl complexes, and (ii) the synthesis of new classes of group 4 metal alkyl complexes with non-Cp2M ligand environments.

Download or read book Synthesis of Beta diketiminate Group 2 12 Metal Cyclopentadienyl Complexes written by Thomas D. Rogers (B.Sc.) and published by . This book was released on 2010 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Synthesis of Group 10 Metal Complexes for Potential Electronic Applications written by Octavia Ann Blackburn and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Titanium and Zirconium in Organic Synthesis written by Ilan Marek and published by Wiley-VCH Verlag GmbH. This book was released on 2002-01-01 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last years, the role of titanium and zirconium in organic synthesis has dramatically increased and nowadays, no synthetic chemist can afford to be without a sound knowledge of this fascinating organometal chemistry. This unique book, edited by Ilan Marek, thus summarizes the numerous applications and developments of these two group 4 early transition metal complexes. A plethora of internationally renowned experts and leading scientists in this field cover all the significant aspects of this increasingly important part of organic chemistry and bring the reader up to date. A particularly attractive and useful feature is the inclusion of typical experimental procedures, chosen for broad utility and application. This comprehensive demonstrates the diversity and the applications of these important compounds and is a must-have for all chemists working in organometallic or synthetic organic chemistry.

Download or read book Chelating Group 4 Transition Metal Amido and Alkoxide Complexes written by Brian Stephen Kimberley and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Inorganic Syntheses Volume 35 written by and published by John Wiley & Sons. This book was released on 2010-08-13 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. Includes complete, up-to-date procedures involving important inorganic substances Contains subject, contributor, and formula indexes