Download or read book Synthesis and Characterization of Rationally Designed Porous Materials for Energy Storage and Carbon Capture written by Julian Patrick Sculley and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Two of the hottest areas in porous materials research in the last decade have been in energy storage, mainly hydrogen and methane, and in carbon capture and sequestration (CCS). Although these topics are intricately linked in terms of our future energy landscape, the specific materials needed to solve these problems must have significantly different properties. High pressure gas storage is most often linked with high surface areas and pore volumes, while carbon capture sorbents require high sorption enthalpies to achieve the needed selectivity. The latter typically involves separating CO2 from mixed gas streams of mostly nitrogen via a temperature swing adsorption (TSA) process. Much of the excitement has arisen because of the potential of metal-organic frameworks (MOFs) and porous polymer networks (PPNs). Both classes of materials have extremely high surface areas (upwards of 4000 m2/g) and can be modified to have specific physical properties, thus enabling high performance materials for targeted applications. This dissertation focuses on the synthesis and characterization of these novel materials for both applications by tuning framework topologies, composition, and surface properties. Specifically, two routes to synthesize a single molecule trap (SMT) highlight the flexibility of MOF design and ability to tune a framework to interact with specifically one guest molecule; computational and experimental evidence of the binding mechanism are shown as well. Furthermore, eight PPNs are synthesized and characterized for post-combustion carbon capture and direct air capture applications. In addition a high-throughput model, grounded in thermodynamics, to calculate the energy penalty associated with the carbon capture step is presented in order to evaluate all materials for TSA applications provide a comparison to the state of the art capture technologies. This includes results of working capacity and energy calculations to determine parasitic loads (per ton of CO2 captured) from readily available experimental data of any material (adsorption isotherms and heat capacities) using a few simple equations. Through various systematic investigations, trends are analyzed to form structure property relationships that will aid future material development. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/149368

Download or read book Porous Organic Frameworks written by Guangshan Zhu and published by Springer. This book was released on 2014-11-28 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the design, synthesis, characterization and applications of porous organic frameworks (POFs). Special emphasis is placed on the utilization of porous materials for CO2 capture and CH4 and H2 storage, which have promising potential for addressing the issues of environmental degradation and climate change. It also includes two chapters introducing the properties of POFs and defining the principles of synthesis, as well as a chapter dealing with post-modified POFs. This book is intended for those readers who are interested in porous materials and their applications. Guangshan Zhu is a professor at the College of Chemistry, Jilin University, China.

Download or read book Porous Metal Organic Frameworks for Energy Storage Applications written by Yangyang Liu and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The self-assembly of metal ions and organic linkers could afford 3-dimensional (3D) porous metal-organic frameworks (MOFs). They are promising materials for clean energy applications including carbon capture, hydrogen storage and methane storage. The primary goal of this research is the synthesis and characterization of new MOFs for these applications, and their structure-property relationship studies based on both experiments and simulations. Firstly, a stable magnesium MOF with 1-dimensional (1D) channel structure was synthesized. In-situ powder X-ray diffraction studies reveal its interesting phase transitions properties. After removing coordinated solvent at magnesium chains, this MOF can selectively adsorb CO2 over N2. Secondly, by varying the conditions in the solvothermal reaction, five MOFs with diverse structures were synthesized from a tetratopic ligand. Hydrogen storage properties were studied for these MOFs. A list of factors including catenation, metal nodes, charge, topology and pore size are evaluated for hydrogen storage application. In addition, four isostructural MOFs with various functionalized pore surfaces were synthesized from a series of di-isophthalate ligands. These MOFs exhibit a new network-topology and very high hydrogen uptake. They also showed reasonable adsorption selectivity of CO2 over CH4 and N2. Finally, high pressure methane uptake properties have been studied both experimentally and computationally for the series of isostructural MOFs with varying functional groups. All showed very high methane storage capacity at 298 K, 65 bar. Structure-property relationships were established for these MOFs, and simulations were employed to understand the mechanism of methane storage in MOFs. The role of copper paddlewheels and other adsorption sites for methane was evaluated. By thorough studies and careful analyses of simulation and experimental data, we proposed three novel mechanisms for methane storage in MOFs. Significantly, with the help of the mechanism studies, another two MOFs were designed, synthesized and discovered to have even higher methane storage capacities. Ligand design has been a powerful tool in synthesizing new MOFs. Besides surface area, pore size has been discovered to be a key factor for gas storage capacities of MOFs. These findings could serve as guidance for rational design of better performing materials for clean energy applications. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/152750

Download or read book Porous Materials for Environmental Applications written by Antonio Gil and published by MDPI. This book was released on 2020-06-17 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of porous materials has attracted the attention of the research community for years. Porosity characteristics have specific impacts on the material properties and materials that are applied in many areas, such as pollutant removal, CO2 capture, energy storage, catalytic oxidation and reduction processes, the conversion of biomass to biofuels, and drug delivery. Examples of porous materials are activated carbons, clays, and zeolites. The aim of this book is to collect the recent advances and progress regarding porous materials and their applications in the environmental area.

Download or read book Handbook Of Porous Materials Synthesis Properties Modeling And Key Applications In 4 Volumes written by and published by World Scientific. This book was released on 2020-10-20 with total page 1495 pages. Available in PDF, EPUB and Kindle. Book excerpt: This four-volume handbook gives a state-of-the-art overview of porous materials, from synthesis and characterization and simulation all the way to manufacturing and industrial applications. The editors, coming from academia and industry, are known for their didactic skills as well as their technical expertise. Coordinating the efforts of 37 expert authors in 14 chapters, they construct the story of porous carbons, ceramics, zeolites and polymers from varied viewpoints: surface and colloidal science, materials science, chemical engineering, and energy engineering. Volumes 1 and 2 cover the fundamentals of preparation, characterisation, and simulation of porous materials. Working from the fundamentals all the way to the practicalities of industrial production processes, the subjects include hierarchical materials, in situ and operando characterisation using NMR, X-Ray scattering and tomography, state-of-the-art molecular simulations of adsorption and diffusion in crystalline nanoporous materials, as well as the emerging areas of bio-artificing and drug delivery. Volume 3 focuses on porous materials in industrial separation applications, including adsorption separation, membrane separation, and osmotic distillation. Finally, and highly relevant to tomorrow's energy challenges, Volume 4 explains the energy engineering aspects of applying porous materials in supercapacitors, fuel cells, batteries, electrolysers and sub-surface energy applications.The text contains many high-quality colourful illustrations and examples, as well as thousands of up-to-date references to peer-reviewed articles, reports and websites for further reading. This comprehensive and well-written handbook is a must-have reference for universities, research groups and companies working with porous materials.Related Link(s)

Download or read book Studies on Porous Monolithic Materials Prepared via Sol Gel Processes written by George Hasegawa and published by Springer Science & Business Media. This book was released on 2012-10-03 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis focuses on porous monolithic materials that are not in the forms of particles, fibers, or films. In particular, the synthetic strategy of porous monolithic materials via the sol–gel method accompanied by phase separation, which is characterized as the non-templating method for tailoring well-defined macropores, is described from the basics to actual synthesis. Porous materials are attracting more and more attention in various fields such as electronics, energy storage, catalysis, sensing, adsorbents, biomedical science, and separation science. To date, many efforts have been made to synthesize porous materials in various chemical compositions—organics, inorganics including metals, glasses and ceramics, and organic-inorganic hybrids. Also demonstrated in this thesis are the potential applications of synthesized porous monolithic materials to separation media as well as to electrodes for electric double-layer capacitors (EDLCs) and Li-ion batteries (LIBs). This work is ideal for graduate students in materials science and is also useful to engineers or scientists seeking basic knowledge of porous monolithic materials.

Download or read book Porous Carbon Materials from Sustainable Precursors written by Robin J White and published by Royal Society of Chemistry. This book was released on 2015-02-11 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porous carbon materials are at the heart of many applications, including renewable energy storage and generation, due to their superior physical properties and availability. The environmentally-friendly production of these materials is crucial for a sustainable future. This book focuses on the transformation of sustainable precursors into functional, porous carbonaceous materials via the two most significant approaches: Starbon® and Hydrothermal Carbonisation. Covering cutting-edge research and emerging areas, chapters cover applications of porous carbon materials in catalysis and separation science as well as in energy science. Moreover, the challenges of characterization of these materials and their commercialization are explained by worldwide experts. The content will be accessible and valuable to post-graduate students and senior researchers alike and it will serve as a significant reference for academics and industrialists working in the areas of materials science, catalysis and separation science.

Download or read book Porous Materials written by Juan Carlos Moreno-Piraján and published by Springer Nature. This book was released on 2021-03-10 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is written in honor of Prof. Francisco Rodriguez-Reinoso, who has made significant contributions in the area of porous materials such as active carbons and graphenes. It details the preparation of porous materials, including carbonaceous, zeolitic, and siliceous materials, MOFs, aerogels, and xerogels, describing the characterization techniques and the interpretation of the results, and highlighting common errors that can occur during the process. This book subsequently presents the use of modeling based on thermodynamics to describe the materials. Lastly, it illustrates a number of current environmental protection applications in the context of both water and air.

Download or read book Submicron Porous Materials written by Paolo Bettotti and published by Springer. This book was released on 2017-02-21 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the latest research on porous materials at the submicron scale and inspires readers to better understand the porosity of materials, as well as to develop innovative new materials. A comprehensive range of materials are covered, including carbon-based and organic-based porous materials, porous anodic alumina, silica, and titania-based sol-gel materials. The fabrication, characterization, and applications of these materials are all explored, with applications ranging from sensors, thermoelectrics, catalysis, energy storage, to photovoltaics. Also of practical use for readers are chapters that describe the basics of porous silicon fabrication and its use in optical sensing and drug delivery applications; how thermal transport is affected in porous materials; how to model diffusion in porous materials; and a unique chapter on an innovative spectroscopic technique used to characterize materials' porosity. This is an ideal book for graduate students, researchers, and professionals who work with porous materials.

Download or read book Introduction to Porous Materials written by Pascal Van Der Voort and published by John Wiley & Sons. This book was released on 2019-08-19 with total page 441 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive textbook on the timely and rapidly developing topic of inorganic porous materials This is the first textbook to completely cover a broad range of inorganic porous materials. It introduces the reader to the development of functional porous inorganic materials, from the synthetic zeolites in the 50’s, to today’s hybrid materials such as metal-organic frameworks (MOFs), covalent organic frameworks (COFs) and related networks. It also provides the necessary background to understand how porous materials are organized, characterized, and applied in adsorption, catalysis, and many other domains. Additionally, the book explains characterization and application from the materials scientist viewpoint, giving the reader a practical approach on the characterization and application of the respective materials. Introduction to Inorganic Porous Materials begins by describing the basic concepts of porosity and the different types of pores, surfaces, and amorphous versus crystalline materials, before introducing readers to nature’s porous materials. It then goes on to cover everything from adsorption and catalysis to amorphous materials such as silica to inorganic carbons and Periodic Mesoporous Organosilicas (PMOs). It discusses the synthesis and applications of MOFs and the broad family of COFs. It concludes with a look at future prospects and emerging trends in the field. The only complete book of its kind to cover the wide variety of inorganic and hybrid porous materials A comprehensive reference and outstanding tool for any course on inorganic porous materials, heterogeneous catalysis, and adsorption Gives students and investigators the opportunity to learn about porous materials, how to characterize them, and understand how they can be applied in different fields Introduction to Inorganic Porous Materials is an excellent book for students and professionals of inorganic chemistry and materials science with an interest in porous materials, functional inorganic materials, heterogeneous catalysis and adsorption, and solid state characterization techniques.

Download or read book Porous Materials written by Kozo Ishizaki and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approximately four million years of human history has passed. We have been using materials to make a variety of tools. The first materials used were naturally occurring materials such as animal bones, stones, wood etc.; and some of these familiar materials are porous. Porous materials are so familiar that they are sometimes forgotten or ignored. The taste experience of ice cream is created not only by adjusting ingre dients, but also by including air as an ingredient, i.e. pores that give the smooth texture of ice cream. This book is designed to describe and explain about pores, the synthesis of materials with pores (porous materials), and applications of porous materi als. This book is intended for engineers and scientists of different disciplines and specialities, and is expected to be useful in the design and synthesis of porous materials for existing as well as potential new applications. Let us rediscover pores. K. Ishizaki, S. Komameni and M. Nanko January 1998 1 Introduction 1.1 WHAT ARE POROUS MATERIALS? Porous materials are dermed as solids containing pores. Figure 1.1 shows different porous materials. Generally speaking, porous materials have a porosity of 0.2-0.95. The porosity means the fraction of pore volume to the total volume. Porous materials have been used in various applications from daily necessities, such as purifying drinking water by activated carbon or porous ceramics, to uses in modern industries, for example removing dusts from high purity process gases for semiconductor production.

Download or read book AI Guided Design and Property Prediction for Zeolites and Nanoporous Materials written by German Sastre and published by John Wiley & Sons. This book was released on 2023-04-17 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: A cohesive and insightful compilation of resources explaining the latest discoveries and methods in the field of nanoporous materials In Artificial Intelligence for Zeolites and Nanoporous Materials: Design, Synthesis and Properties Prediction a team of distinguished researchers delivers a robust compilation of the latest knowledge and most recent developments in computational chemistry, synthetic chemistry, and artificial intelligence as it applies to zeolites, porous molecular materials, covalent organic frameworks and metal-organic frameworks. The book presents a common language that unifies these fields of research and advances the discovery of new nanoporous materials. The editors have included resources that describe strategies to synthesize new nanoporous materials, construct databases of materials, structure directing agents, and synthesis conditions, and explain computational methods to generate new materials. They also offer material that discusses AI and machine learning algorithms, as well as other, similar approaches to the field. Readers will also find a comprehensive approach to artificial intelligence applied to and written in the language of materials chemistry, guiding the reader through the fundamental questions on how far computer algorithms and numerical representations can drive our search of new nanoporous materials for specific applications. Designed for academic researchers and industry professionals with an interest in synthetic nanoporous materials chemistry, Artificial Intelligence for Zeolites and Nanoporous Materials: Design, Synthesis and Properties Prediction will also earn a place in the libraries of professionals working in large energy, chemical, and biochemical companies with responsibilities related to the design of new nanoporous materials.

Download or read book Porous Carbons written by Feiyu Kang and published by Elsevier. This book was released on 2021-11-04 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon materials form pores ranging in size and morphology, from micropores of less than 1nm, to macropores of more than 50nm, and from channel-like spaces with homogenous diameters in carbon nanotubes, to round spaces in various fullerene cages, including irregularly-shaped pores in polycrystalline carbon materials. The large quantity and rapid rate of absorption of various molecules made possible by these attributes of carbon materials are now used in the storage of foreign atoms and ions for energy storage, conversion and adsorption, and for environmental remediation. Porous Carbons: Syntheses and Applications focuses on the fabrication and application of porous carbons. It considers fabrication at three scales: micropores, mesopores, and macropores. Carbon foams, sponges, and 3D-structured carbons are detailed. The title presents applications in four key areas: energy storage, energy conversion, energy adsorption, including batteries, supercapacitors, and fuel cells and environmental remediation, emphasizing the importance of pore structures at the three scales, and the diffusion and storage of various ions and molecules. The book presents a short history of each technique and material, and assesses advantages and disadvantages. This focused book provides researchers with a comprehensive understanding of both pioneering and current synthesis techniques for porous carbons, and their modern applications. Presents modern porous carbon synthesis techniques and modern applications of porous carbons Presents current research on porous carbons in energy storage, conversion and adsorption, and in environmental remediation Provides a history and assessment of both pioneering and current cutting-edge synthesis techniques and materials Covers a significant range of precursor materials, preparation techniques, and characteristics Considers the future development of porous carbons and their various potential applications

Download or read book Nanoporous Carbons for Soft and Flexible Energy Devices written by Francesca Borghi and published by Springer. This book was released on 2022-02-01 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an interesting snapshot of new research within the fields of flexible and soft devices which use porous carbon-based materials. The increase in demand for soft and flexible electronics, electrochemical energy storage/conversion systems, piezoresistive pressure sensors has promoted the development of new strategies for the synthesis and integration of nanoporous carbon (NPC) into flexible and soft polymers and inorganic textures. The structural properties of such NPC materials combined with their mechanical, conductive and catalytic properties, show promising results for the technology they are designed for, which can be useful solutions in many other disciplines. An in-depth discussion of the use of NPC materials in different energy devices is provided in every chapter, while at the same time the knowledge of the reader on the various applications where these materials can be used will be broadened. This book sheds new light on nanoporous carbon-based materials and will be of great interest to graduate students and professionals working in this field.

Download or read book Handbook of Porous Materials written by Vitaly Gitis and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This four-volume handbook gives a state-of-the-art overview of porous materials, from synthesis and characterization all the way to manufacturing and industrial applications.

Download or read book Mechanics and Physics of Porous Materials written by Chin Hua Chia and published by CRC Press. This book was released on 2024-06-28 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porous media exist in different modern materials. It presents great surface areas with small pore size distribution. These types of materials with controllable and adjustable pore diameters are given considerable attention due to their suitable properties and applications in several fields. Porous materials have many applications in our daily life. We use different types of porous materials to clean our drinking water, for instance. This new research-oriented volume focuses on exploring the wide range of porous materials. In this new volume, original contributions from international authors along with case studies on the synthesis, design, characterization, and applications of different types of porous materials and solids are presented in detail. The book covers different types of porous materials in the broad sense by considering experimental and theoretical aspects of materials science related to porous materials and solids. The book aims to help approach characterizing a particular types of materials for more in-depth analysis. This book is divided into three parts to determine the best techniques for solving particular porous materials problems, and in each part, the fabrication and characterization of porous materials are explored with applications, describing new methodologies to gain the required information along with limitations of various methods. To make this new title a practical reference book for research students and for engineers and scientists of different disciplines working with porous materials and solids, the editors have selected a very comprehensive range of case studies as well, designed to cover the basic concepts of porosity. These case studies also describe different types of pores and surfaces for readers.

Download or read book Porosity written by Taher Ghrib and published by BoD – Books on Demand. This book was released on 2018-04-26 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses multiways in the porous materials. It involves materials with a large number of holes, and it highlights the synthesis, structure, and surface properties of porous materials closely related to more applications, such as support, catalyst, energy storage, chemical reactions, and optical applications. It studies the effect of the filling materials, the thermal treatments, and the porous density in the improvement of physical properties, electrical and energy efficiency, and the generation of new materials. Some synthetic process will be discussed with the effect of some parameters on the final characteristics of the prepared porous structures.