Download or read book Nanocellulose written by Jin Huang and published by John Wiley & Sons. This book was released on 2019-08-05 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensively introduces readers to the production, modifications, and applications of nanocellulose This book gives a thorough introduction to the structure, properties, surface modification, theory, mechanism of composites, and functional materials derived from nanocellulose. It also provides in-depth descriptions of plastics, composites, and functional nanomaterials specifically derived from cellulose nanocrystals, cellulose nanofibrils, and bacterial cellulose. It includes the most recent progress in developing a conceptual framework of nanocellulose, as well as its numerous applications in the design and manufacture of nanocomposites and functional nanomaterials. The book also looks at the relationship between structure and properties. Featuring contributions from many noted experts in the field, Nanocellulose: From Fundamentals to Advanced Materials examines the current status of nanocomposites based on nanocelluloses. It covers surface modification of nanocellulose in the nanocomposites development; reinforcing mechanism of cellulose nanocrystals in nanocomposites; and advanced materials based on self-organization of cellulose nanocrystals. The book studies the role of cellulose nanofibrils in nanocomposites, as well as a potential application based on colloidal properties of cellulose nanocrystals. It also offers strategies to explore biomedical applications of nanocellulose. Provides comprehensive knowledge on the topic of nanocellulose, including the preparation, structure, properties, surface modification and strategy Covers new reports on the application of nanocellulose Summarizes three kinds of nanocellulose (cellulose nanocrystals, cellulose nanofibrils, and bacterial cellulose) and their production, modification, and applications Nanocellulose: From Fundamentals to Advanced Materials is a useful resource for specialist researchers of chemistry, materials, and nanotechnology science, as well as for researchers and students of the subject.
Download or read book Surface Modification of Cellulose Nanocrystal for Advanced Applications written by Zhen Zhang and published by . This book was released on 2017 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cellulose nanocrystals (CNC) are bio-based nanoparticles, which display an array of interesting properties related to their renewability, biocompatibility, high tensile strength and elastic modulus, high aspect ratio, low density, low coefficient of thermal expansion, and liquid crystal behavior. As a result, CNC can be exploited in a wide variety of applications, which include the fields of composites, catalysts, emulsions or colloidosomes. However, the engineering of innovative nanomaterials from CNC generally requires a fine control of their surface properties by chemical modification, to tailor their dispersive, interfacial and self-assembling properties, or to introduce novel functionalities. In this context, the surface functionalization of cellulose nanocrystals by esterification and Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP) reactions was envisaged, with the objective to develop novel advanced materials. The first chapter describes the state-of-the-art of the field in which the cellulose nanocrystals are presented, with their properties, methods of functionalization and potential applications. A brief overview of the SI-ATRP reaction is also given. In the second chapter, a convenient method is proposed to directly characterize the polymer grafted by SI-ATRP on the CNC surface, without cleaving the polymer from the nanoparticle. The SI-ATRP grafting of polystyrene (PS) at the CNC surface was performed from brominated CNC initiators, in the presence of a sacrificial initiator. With this work, we show that Dynamic light scattering (DLS) is a convenient tool to monitor the polymerization process, while differential scanning calorimetry (DSC) can be used to verify if the polymerization rates of the grafted and free polymers coincide. Finally, we demonstrate that thermogravimetric analysis (TGA) can be used to directly estimate the molecular weight of the PS grafted at the surface of the CNC without cleaving the polymer from the nanoparticle. In the third chapter, both SI-ATRP and Surface-Initiated Activator Re-Generated by Electron Transfer ATRP (SI-ARGET ATRP) were conducted to graft PS and P4VP on the surface of CNC. The SI-ATRP and SI-ARGET ATRP approaches were systematically compared to evaluate the potential benefit of each method. The surface initiating efficiencies (SIE) of the CNC-Br macroinitiators with regards to styrene or P4VP were evaluated by TGA and EA, respectively. The combination of analytical methods such as FT-IR, DLS, DSC, TGA, and EA demontrated that the SI-ARGET ATRP reaction favored the grafting of longer polymer chains with lower grafting densities compared with the classical SI-ATRP method. The impact of catalyst concentration and propagation rate on the differences noted was particularly discussed. In the fourth chapter, pH-responsive P4VP-g-CNC nanohybrids were prepared by SI-ATRP and subsequently used to stabilize gold nanoparticles (Au NPs) and produce recyclable catalysts. The presence of P4VP brushes at the CNC surface led to the growing of Au NPs of lower averaged diameter compared with the diameter of the Au NPs deposited on pristine CNC. The catalytic performance of pristine Au NPs, Au NPs stabilized by CNC (Au@CNC) and Au NPs stabilized by P4VP-g-CNC (Au@P4VP-g-CNC) were then compared, through the measurement of the turnover frequency (TOF) obtained after catalytic reduction of 4-nitrophenol (4NP), used as a model reaction. Compared with pristine Au NPs, the catalytic activity of Au@CNC and Au@P4VP-g-CNC were about 10 and 24 times better, respectively. Moreover, the Au@P4VP-g-CNC material could be conveniently recovered by flocculation at basic pH, and the recycled catalyst remained highly active. In the fifth chapter, Ultraviolet (UV)-responsive poly(cinnamoyloxy ethyl methacrylate) (PCEM) was grafted on CNC using SI-ATRP. The resultant PCEM-grafted CNC (PCEM-g-CNC) exhibits high UV absorption properties and undergoes crosslinking under UV irradiation. When the PCEM-g-CNC nanohybrids were incorporated in poly(vinyl chloride), transparent composite films with UV-blocking properties were obtained. The comparison of the optical and mechanical properties of the films before and after UV-irradiation allowed it to be demonstrated that the PCEM-g-CNC nanoparticles also acted as thermal and UV-stabilizers for PVC. Meanwhile, the tensile mechanical properties of the PVC film were significantly improved, and further increased after UV-irradiation. In the sixth chapter, a facile method to prepare colloidosomes at room temperature is proposed from w/o inverse Pickering emulsions containing silica precursors and stabilized by cinnamate modified CNC (Cin-CNC). Cin-CNC Pickering surfactants were prepared by acylation with an excess of cinnamoyl chloride. The Cin-CNC surface displayed partial wettability with both toluene and water, which allowed stabilization w/o inverse Pickering emulsions. The Cin-CNC particles around the droplets were subsequently locked by cross-linking TEOS or TBOS silica precursors at the water/toluene interface, leading to an intricate network of polysiloxane within the Cin-CNC shell. In optimized conditions, the Cin-CNC/silica colloidosomes obtained displayed a robust shell and slow releasing capacity with regards to encapsulated molecules such as rhodamine B or fluorescent deoxyribonucleic acid (DNA). In the last chapter, we summarized the general conclusions of the thesis and proposed some recommendations for the future work. The cellulose nanocrystals were modified by esterification and surface initiated Atom Transfer Radical Polymerization. The characterization, mechanism and advanced applications of the functionalized CNC were envisaged. Based on the research and results in this project, we also proposed some recommendations for the future work on the modification of CNC and the other advanced applications.
Download or read book Surface Modifications of Nanocellulose written by Ning Lin and published by Elsevier. This book was released on 2024-06-01 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface Modifications of Nanocellulose: Strategies, Methods, and Applications establishes the basic framework of nanocellulose. This book systemically summarizes the strategy and protocols of surface modifications on nanocellulose and comprehensively analyzes the relationship between surface modifications and their functional applications. It provides a one-stop reference for researchers engaged in biopolymer research with a commitment to the development of highly-valued functional polymers, nanomaterials, and green chemistry. Systemically summarizes the strategy and protocols of surface modifications on nanocellulose Includes a database for the modified species as a reference book for surface modification on nanocellulose Illustrates the relationship between modification and applications of nanocellulose Provides inspiration for the development of potential functional modification in this field
Download or read book Nanocellulose Extraction and Surface Modification Toward Active Packaging Applications written by Ying Wu (M.S. in Biological Engineerng) and published by . This book was released on 2017 with total page 84 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cellulose nanocrystals (CNCs) have attracted growing interest as a renewable nanomaterial. The main objective of this study was to explore the extraction of CNCs from switchgrass and surface modification of CNCs into antimicrobially active nanomaterials for active packaging application. Switchgrass was first fractionated via different pretreatment/pulping methods (i.e., acid-chlorite pretreatment, organosolv pretreatment, and deep eutectic solvent (DES) pretreatment), yielding high cellulose-enriched pulp (greater than 75.53 percent cellulose). Acid-chlorite pretreatment was the most effective for delignification, removing 97.80 percent lignin from switchgrass. In contrast, DES pretreatment was more effective for hemicellulose removal (greater than 79.55 percent xylan). Fourier transform infrared (FTIR) spectra also showed significant lignin and hemicellulose removal and enrichment of cellulose after pretreatment. Post-treatment with NaOH and H2O2 bleached organosolv and DES pulp, making them more suitable for CNCs extraction via sulfuric acid hydrolysis. The yields of CNCs extracted from the resulting pulps ranged from 30.52 to 35.82 percent (based on the dry mass of pulp loaded) via sulfuric acid hydrolysis with the highest yield observed with mildly post-treated ChCl: FA pulp. The surface charge of the prepared CNCs ranged from -20.30 to -26.70 mV. And the average particle size ranged from 63.55 to 222.20 nm. Surface modification by grafting polyethyleneimine (PEI) onto the surface of CNCs with carboxylic groups endowed CNCs with antimicrobial activity, especially toward Gram-positive bacteria Bacillus megaterium. The modified CNCs (CNCs-PEI) showed positive surface charge, indicating successful cationization. FTIR also confirmed the presence of PEI on surface modified CNCs. Incorporation of CNCs-PEI by 5 percent into PVA film improved its mechanical strength remarkably. This study demonstrated successful extraction of CNCs from switchgrass and development of antimicrobially active CNCs via surface modification toward active packaging applications. Antimicrobially active CNCs have great potential to be used as a multifunctional nanomaterial for advanced applications.
Download or read book Handbook of Nanocellulose and Cellulose Nanocomposites 2 Volume Set written by Hanieh Kargarzadeh and published by John Wiley & Sons. This book was released on 2017-06-19 with total page 914 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date and comprehensive overview summarizing recent achievements, the state of the art, and trends in research into nanocellulose and cellulose nanocomposites. Following an introduction, this ready references discusses the characterization as well surface modification of cellulose nanocomposites before going into details of the manufacturing and the self-assembly of such compounds. After a description of various alternatives, including thermoplastic, thermosetting, rubber, and fully green cellulose nanocomposites, the book continues with their mechanic and thermal properties, as well as crystallization and rheology behavior. A summary of spectroscopic and water sorption properties precedes a look at environmental health and safety of these nanocomposites. With its coverage of a wide variety of materials, important characterization tools and resulting applications, this is an essential reference for beginners as well as experienced researchers.
Download or read book Cellulose Nanocrystals written by Vimal Katiyar and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-10-12 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cellulose nanocrystals are being used more frequently as processing and nanofabrication techniques have advanced considerably. Cellulose Nanocrystals includes topics including Extraction and Fabrication Methodologies, Scale-Up Strategies and Life Cycle Assessment, Surface Modification Strategies, Nanocomposites, and Characterization and Testing Protocols. This book will appeal to physical, chemical and biological scientists as well as engineers.
Download or read book Cellulose Nanocrystals written by Maren Grunert and published by . This book was released on 2002 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Cellulose Nanocrystals written by Wadood Y. Hamad and published by John Wiley & Sons. This book was released on 2017-03-31 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research into cellulose nanocrystals is currently in an exponential growth phase, with research into potential applications now strengthened by recent advances in nanomanufacturing. The possibility of routine commercial production of these advanced materials is now becoming a reality. Cellulose Nanocrystals: Properties, Production and Applications provides an in-depth overview of the materials science, chemistry and physics of cellulose nanocrystals, and the technical development of advanced materials based on cellulose nanocrystals for industrial and medical applications. Topics covered include: • A comprehensive treatment of the structure, morphology and synthesis of cellulose nanocrystals. • The science and engineering of producing cellulose nanocrystals and the challenges involved in nanomanufacturing on a large industrial scale. • Surface/interface modifications of cellulose nanocrystals for the development of novel biomaterials with attractive structural and functional properties. • The scientific bases for developing cellulose-based nanomaterials with advanced functionalities for industrial/medical applications and consumer products. • Discussions on the (i) reinforcing potential of cellulose nanocrystals in polymer nanocomposites, (ii) utilization of these nanocrystals as efficient templates for developing tunable photonic materials, as well as (iii) applications in sustainable electronics and biomedicine. Cellulose Nanocrystals: Properties, Production and Applications will appeal to audiences in the physical, chemical and biological sciences as well as engineering disciplines. It will be of critical interest to industrialists seeking to develop sustainable new materials for the advanced industrial economies of the 21st century, ranging from adaptive “smart” packaging materials, to new chiral, mesoporous materials for optoelectronics and photonics , to high-performance nanocomposites for structural applications.
Download or read book Nanocellulose written by Alain Dufresne and published by Walter de Gruyter. This book was released on 2012-12-06 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: This specialist monograph provides an overview of the recent research on the fundamental and applied properties of nanoparticles extracted from cellulose, the most abundant polymer on the planet and an essential renewable resource. Given the rapid advancements in the field and the high level of interest within the scientific and industrial communities, this timely book will be required reading for all those working with nanocellulose in the life sciences and bio-based applications, biological, chemical and agricultural engineering, organic chemistry and materials science. The author pioneered the use of cellulose nanoparticles (cellulose nanocrystals or whiskers and cellulose microfibrils) in nanocomposite applications.The book combines a general introduction to cellulose and basic techniques with more advanced chapters on specific properties and applications of nanocellulose.
Download or read book Industrial Applications of Nanocellulose and Its Nanocomposites written by S.M. Sapuan and published by Woodhead Publishing. This book was released on 2022-03-18 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocellulose is a versatile material that has received much attention from scientists working in a broad range of application fields, such as automotive, composites, adsorbents, paints, coatings, medical implants, electronics, cosmetics, pulp and paper, tissue engineering, medical, packaging, and aerogels. Industrial Applications of Nanocellulose and Its Nanocomposites provides an extensive, up-to-date review of this fast-moving research field. The chapters cover a wide range of aspects, including synthesis, surface modification, and improvement of properties toward target applications. The main objectives of the book are to reflect on recent advancements in the design and fabrication of advanced nanocellulose and discuss important requirements for each application, as well as the challenges that might be faced. The book also includes an overview of the current economic perspectives and safety issues, as well as future directions for nanocellulose-based materials. It will serve as a valuable reference resource for academic and industrial researchers, environmental chemists, nanotechnologists, chemical engineers, polymer chemists, materials scientists, and all those working in the manufacturing industries. Comprehensively covers a broad range of industrial applications. Includes case studies on economic perspectives, safety issues, and advanced development of nanocellulose-based products. Discusses nanocellulose production from biological waste.
Download or read book Surface Modification of Cellulose Nanocrystals written by Samuel Eyley and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nanocrystals written by Sudheer Neralla and published by BoD – Books on Demand. This book was released on 2012-08-29 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocrystals research has been an area of significant interest lately, due to the wide variety of potential applications in semiconductor, optical and biomedical fields. This book consists of a collection of research work on nanocrystals processing and characterization of their structural, optical, electronic, magnetic and mechanical properties. Various methods for nanocrystals synthesis are discussed in the book. Size-dependent properties such as quantum confinement, superparamagnetism have been observed in semiconductor and magnetic nanoparticles. Nanocrystals incorporated into different material systems have proven to possess improved properties. A review of the exciting outcomes nanoparticles study has provided indicates further accomplishments in the near future.
Download or read book Cellulose written by Matheus Poletto and published by BoD – Books on Demand. This book was released on 2015-12-09 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cellulose - Fundamental Aspects and Current Trends consists of 10 chapters written by international subject matter experts investigating the characteristics and current applications of this fascinating material. This book will help the reader to develop a deeper understanding about the concepts related to cellulose and the nanocellulose structure, modification, production, dissolution, and application. Biosynthesis mechanisms and medical applications of microbial cellulose are also discussed. This book will serve as the starting point for materials science researchers, engineers, and technologists from diverse backgrounds in physics, chemistry, biology, materials science, and engineering who want to know and better understand the unique characteristics of the most abundant biopolymer on earth.
Download or read book Surface Modification and Characterization of Cellulose Nanocrystal for Biomedical Applications written by Seyedeh Parinaz Akhlaghi and published by . This book was released on 2014 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an ever-increasing desire to develop novel materials that could control the release of active compounds and increase their stability. Replacing petroleum-based synthetic polymers with sustainable materials has many advantages, such as reducing the dependence on fossil fuels, and diminishing environmental pollution. Recently, cellulose nanocrystal (CNC) obtained by acid hydrolysis of cellulose fibres has gained a lot of interest. The high mechanical strength, large and negatively charged surface area, and the presence of several hydroxyl groups that allow for modification with different functionalities make CNC an excellent candidate for various applications in the biomedical field. This thesis explores (i) the surface modification and characterization of modified CNC and (ii) the biomedical applications of these novel sustainable nanomaterials.
Download or read book Production and Applications of Cellulose Nanomaterials written by Robert J. Moon and published by . This book was released on 2013 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nanocellulose and Sustainability written by Koon-Yang Lee and published by CRC Press. This book was released on 2018-01-03 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanometre scale cellulose fibres, or nanocellulose, are emerging materials for various advanced applications. Nanocellulose and Sustainability: Production, Properties, Applications, and Case Studies provides a comprehensive overview of nanocellulose production, nanocellulose properties and nanocellulose in selected applications. This book serves as an entry level reference text for undergraduates, graduate students, researchers and professional engineers working in the area of nanocellulose and sustainability. Features: Summarises the surface and bulk properties of various types of nanocellulose Reviews the application of nanocellulose in water purification and optically transparent materials Provides an overview of nanocellulose as Pickering emulsifier, binder for loose natural fibres to produce non-woven preforms, as well as nanocellulose-based aerogels Presents a techno-economic analysis of industrial bacterial cellulose production Discusses the pilot scale production of cellulose nanocrystals
Download or read book Handbook of Nanocellulose and Cellulose Nanocomposites written by Hanieh Kargarzadeh and published by John Wiley & Sons. This book was released on 2017-03-02 with total page 897 pages. Available in PDF, EPUB and Kindle. Book excerpt: An up-to-date and comprehensive overview summarizing recent achievements, the state of the art, and trends in research into nanocellulose and cellulose nanocomposites. Following an introduction, this ready references discusses the characterization as well surface modification of cellulose nanocomposites before going into details of the manufacturing and the self-assembly of such compounds. After a description of various alternatives, including thermoplastic, thermosetting, rubber, and fully green cellulose nanocomposites, the book continues with their mechanic and thermal properties, as well as crystallization and rheology behavior. A summary of spectroscopic and water sorption properties precedes a look at environmental health and safety of these nanocomposites. With its coverage of a wide variety of materials, important characterization tools and resulting applications, this is an essential reference for beginners as well as experienced researchers.
