Download or read book Supported Metals in Catalysis written by James Arthur Anderson and published by World Scientific. This book was released on 2012 with total page 581 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions from experts in supported metal catalysis from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as vehicle emission control, the book also includes emerging areas where supported metal catalysis will make significant contributions to future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter and, as such, it is a must-have for anyone working in the field of heterogeneous catalysis.
Download or read book Supported Metals in Catalysis written by James Arthur Anderson and published by World Scientific. This book was released on 2012 with total page 581 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.
Download or read book Supported Metal Single Atom Catalysis written by Philippe Serp and published by John Wiley & Sons. This book was released on 2022-02-09 with total page 912 pages. Available in PDF, EPUB and Kindle. Book excerpt: b”Supported Metal Single Atom CatalysisCovers all key aspects of supported metal single atom catalysts, an invaluable resource for academic researchers and industry professionals alike Single atom catalysis is one of the most innovative and dynamic research areas in catalysis science. Supported metal catalysts are used extensively across the chemical industry, ranging from fine and bulk chemical production to petrochemicals. Single atom catalysts (SACs) combine the advantages of both homogeneous and heterogeneous catalysts such as catalyst stability, activity, and high dispersion of the active phase. Supported Metal Single Atom Catalysis provides an authoritative and up-to-date overview of the emerging field, covering the synthesis, preparation, characterization, modeling, and applications of SACs. This comprehensive volume introduces the basic principles of single atom catalysis, describes metal oxide and carbon support materials for SAC preparation, presents characterization techniques and theoretical calculations, and discusses SACs in areas including selective hydrogenation, oxidation reactions, activation of small molecules, C-C bond formation, and biomedical applications. Highlights the activity, selectivity, and stability advantages of supported metal SACs compared to other heterogeneous catalysts Covers applications of SACs in thermal catalysis, electrocatalysis, and photocatalysis Includes chapters on single atom alloys and supported double and triple metal atom catalysts Discusses the prospects, challenges, and potential industrial applications of SACs Supported Metal Single Atom Catalysis is an indispensable reference for all those working in the fields of catalysis, solid-state chemistry, materials science, and spectroscopy, including catalytic chemists, organic chemists, electrochemists, theoretical chemists, and industrial chemists.
Download or read book Handbook of Transition Metal Polymerization Catalysts written by Ray Hoff and published by John Wiley & Sons. This book was released on 2018-05-08 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt: Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Download or read book Metal Support and Metal Additive Effects in Catalysis written by B. Imelik and published by Elsevier. This book was released on 2000-04-01 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Support and Metal-Additive Effects in Catalysis, Volume 11, documents the proceedings of an international symposium organized by the Institut de Recherches sur la Catalyse - CNRS – Villeurbanne and sponsored by the Centre National de la Recherche Scientifique, Ecully (Lyon), September 14-16, 1982. This volume contains 40 manuscripts that cover a wide range of topics. Among these are studies of metal-support interactions involving Pt/Al2O3, Pt/TiO2,Fe/TiO2, Pt/MgO, Rh /Al2O3, and Pt/CeO2 catalysts. There are also separate chapters dealing with ethane, n-butane, and cyclohexane hydrogenolysis; skeletal isomerization of methylpentanes; the catalytic activity and selectivity of noble metals; CO hydrogenation over supported on SiO2, Al2O3, Ti O2,and Zr O2 nickel catalysts; and the role of promoters in Pd catalysts for methanol synthesis. Subsequent chapters cover the poisoning of platinum and nickel by sulfur; C6H6 and CO chemisorption on Pt78Ni22 (111) single crystal alloy; the surface composition of industrial ammonia synthesis catalysts; and the role of alkalis and electronegative promoters on Fe and Ni catalysts.
Download or read book Catalysis by Precious Metals Past and Future written by Marcela Martinez Tejada and published by MDPI. This book was released on 2020-04-15 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.
Download or read book Catalyst Preparation written by John Regalbuto and published by CRC Press. This book was released on 2016-04-19 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text explores the optimization of catalytic materials through traditional and novel methods of catalyst preparation, characterization, and monitoring for oxides, supported metals, zeolites, and heteropolyacids. It focuses on the synthesis of bulk materials and of heterogeneous materials, particularly at the nanoscale. The final chapters examine pretreatment, drying, finishing effects, and future applications involving catalyst preparation and the technological advances necessary for continued progress. Topics also include heat and mass transfer limitations, computation methods for predicting properties, and catalyst monitoring on laboratory and industrial scales.
Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.
Download or read book Base Metal Catalysis 2 written by Naohiko Yoshikai and published by Georg Thieme Verlag. This book was released on 2023-09-06 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances in catalytic methods based on earth-abundant metals are discussed. Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis. Volume 2 is focused on recent advances in catalysis involving cobalt, iron, manganese, and chromium. Topics covered include various types of cross-coupling processes, hydrofunctionalization of alkenes and alkynes, C-H functionalizations, and catalytic Nozaki–Hiyama–Kishi-type reactions.
Download or read book Introduction To Heterogeneous Catalysis Second Edition written by Roel Prins and published by World Scientific. This book was released on 2022-06-24 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis is a multidisciplinary subject. This book introduces the chemical, materials, and engineering principles of catalysis so that both MSc and PhD students with a basic but not extensive knowledge of chemistry and physics and those with a basic understanding of chemical engineering can learn more about catalysis. Examples are taken from catalytic reactions and catalysts used in the energy, petroleum, and base-chemicals industry.The second edition differs from the first edition in the way basic topics are integrated with catalytic applications. The authors introduce two new chapters: 'Cleaning of Fuels by Hydrotreating' and 'Electrocatalysis'. Hydrotreating is a very important industrial process and offers the opportunity to discuss metal sulfide catalysts. Electrocatalysis gains more and more attention because it can be used to minimize the anthropogenic CO₂ emissions. Solar, wind, and hydroelectricity can drive water electrolysis and CO₂ electroreduction and, therefore, excess renewable electricity can be stored in chemicals.Introduction to Heterogeneous Catalysis (Second Edition) is intended for a one-semester course for master and PhD students who want to learn more about the principles of catalysis. This must-read textbook will enable students to read catalysis literature without much difficulty and presents not only the basic concepts of catalysis but integrates the chemical, materials, and engineering aspects of catalysis with industry examples.
Download or read book Metal Oxide Catalysis 2 Volume Set written by S. David Jackson and published by John Wiley & Sons. This book was released on 2008-11-24 with total page 916 pages. Available in PDF, EPUB and Kindle. Book excerpt: With its two-volume structure, this handbook and ready reference allows for comprehensive coverage of both characterization and applications, while uniform editing throughout ensures that the structure remains consistent. The result is an up-to-date review of metal oxides in catalysis. The first volume covers a range of techniques that are used to characterize oxides, with each chapter written by an expert in the field. Volume 2 goes on to cover the use of metal oxides in catalytic reactions. For all chemists and engineers working in the field of heterogeneous catalysis.
Download or read book Catalysis written by James Spivey and published by Royal Society of Chemistry. This book was released on 2020-02-05 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight reactions active under oxidative coupling of methane conditions and how they are interlinked, heterogeneous nickel catalysts and their use in laboratory and industry, the reaction mechanism of heterogeneous catalysis with the surface science probe, the concepts of electroless deposition (ED) methods for preparation of true bimetallic catalysts, the general subject of metal-support interactions occurring over ruthenium-based catalysts and benzene as the target volatile organic compound (VOC). Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.
Download or read book Catalysis By Ceria And Related Materials 2nd Edition written by Alessandro Trovarelli and published by World Scientific. This book was released on 2013-04-30 with total page 909 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book follows the 2002 edition of Catalysis by Ceria and Related Materials, which was the first book entirely devoted to ceria and its catalytic properties. In the ten years since the first edition a massive amount of work has been carried out in the field, and ceria has gained a prominent position in catalysis as one of the most valuable material for several applications. This second edition covers fundamental and applied aspects of the latest advances in ceria-based materials with a special focus on structural, redox and catalytic features. Special emphasis is given to nano-engineered and nano-shaped systems which are a key factor in the predictive and rational design of ceria with novel properties.In addition, the book presents recent advances in emerging and traditional large-scale applications of ceria in catalysis, such as the treatment of emissions from mobile sources (including diesel and gasoline engines). The primary readership includes catalysis and material science researchers from academy and industry and postdoctorate and graduate students in chemistry, chemical engineering and physics.
Download or read book Supported Molten Metal Catalysis A New Class of Catalysts written by Ravindra Datta and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: We describe a new class of heterogeneous catalysts called supported molten metal catalysis (SMMC), in which molten metal catalysts are dispersed as nanodroplets on the surface of porous supports, allowing much larger active surface area than is possible in conventional contacting techniques for catalytic metals that are molten under reaction conditions, thus greatly enhancing their activity and potential utility. Specific examples of different types of reactions are provided to demonstrate the broad applicability of the technique in designing active, selective, and stable new catalysts. It is shown that dispersing the molten metal on a support in the suggested manner can enhance the rate of a reaction by three to four orders of magnitude as a result of the concomitant increase in the active surface area. New reaction examples include {gamma}-Al{sub 2}O{sub 3} supported molten Te (melting point 450 C) and Ga (MP 30 C) catalysts for bifunctional methylcyclohexane dehydrogenation. These catalysts provide activity similar to conventional Pt-based catalysts for this with better resistance to coking. In addition, results are described for a controlled pore glass supported molten In (MP 157 C) catalyst for the selective catalytic reduction of NO with ethanol in the presence of water, demonstrating activities superior to conventional catalysts for this reaction. A discussion is also provided on the characterization of the active surface area and dispersion of these novel supported catalysts. It is clear based on the results described that the development of new active and selective supported molten metal catalysts for practical applications is entirely plausible.
Download or read book Catalysis by Metals written by Albert Jean Renouprez and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalytic reactions on metals are still nowadays involved in more than half of the chemical industrial processes. The winter school held at "I 'Ecole de in March 1996, 13 years after the first one, accounts Physique des Houches" for an evolution of the field in several directions. First, the emulation between theoretical chemistry and solid state physics has emerged on heuristic concepts, leading not only to explanations of the observed phenomena but, for the first time, to predictions of the reactivity of catalytic systems and of the reaction pathways. The second domain which during these years has become of primary importance is the abatement of the pollution. It concerns not only the conversion of polluting effluents but more and more major modifications of the processes to avoid the production of undesired products. Two striking examples are the necessary catalytic conversion of the 100 000 cubic meter of hydrogen that would be produced in a major incident of a nuclear power plant and the replacement of the CFC. The valorization of agricultural supplies can already be considered as one of the major achievement of catalysis. Indeed, the carbon of biosustainable raw materials represents more than 2 orders of magnitude the amount extracted from fossil fuels each year. Moreover, the molecules are already highly functionalised in contrast with hydrocarbons which require costly steps to be converted to the same products. They are now of current use in the elaboration of cosmetics, vitamins, polymers, etc.
Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2020-04-06 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
Download or read book Metal Catalysed Reactions of Hydrocarbons written by Geoffrey C. Bond and published by Springer Science & Business Media. This book was released on 2005-07-01 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique book, drawing on the author’s lifetime experience, critically evaluates the extensive literature on the field of Metal-Catalysed Reactions of Hydrocarbons. Emphasis is placed on reaction mechanisms involving hydrogenation, hydrogenolysis, skeletal and positional isomerisation, and exchange reactions. The motivation for fundamental research in heterogeneous catalysis is to identify the physicochemical characteristics of active centres for the reaction being studied, to learn how these may be modified or manipulated to improve the desired behavior of the catalyst, and to recognize and control those aspects of the catalyst's structure that limit its overall performance. By restricting the subject of the book to hydrocarbons, Bond has progressively developed the subject matter to include areas of importance both to researchers and to those working in the industry.