Download or read book Strain and Its Implications in Organic Chemistry written by Armin de Meijere and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: The topic ·Stress and Strain· of this conference was ideally constrasted by the remoteness and quiet atmosphere of the meeting place Hotel Seehof In Ratzeburg, a small medieval town situated on a peninsula in lake "Kuchensee· east of Hamburg In northern Germany. With the participation of 53 leading experts from all over the world, the workshop covered the widest possible range from the advancement of bonding theory, new mechanistic insights into chemical transformations and physical properties of highly strained compounds to their use as building blocks In organic synthesis and even as probes Into the detection of enzyme mechanisms. Because of their specific reactivities small ring units can uniquely play their role in the construction of composite functionalities. Such functionalities can increase the elegance In natural and non-natural products syntheses, since they help to develop more convergent synthetic routes and Improve the necessary chemo-, regio-and stereo-selectivity. This book presents all of the 20 Invited lectures and is complemented with short versions of 12 contributed papers and 13 poster presentations. I am convinced that it will stimulate further rapid development of this field of organic chemistry, which recently has seen extensions into the bioorganic area as well as towards new materials. In fact, several ·supra-natural" -at first sight exotic -compounds are already available In useful quantities and are being exploited to create vastly new molecular devices, i. e. compounds with unprecedented molecular functions and polymers with unconventional properties.
Download or read book Strain and Its Implications in Organic Chemistry written by Armin de Meijere and published by . This book was released on 2014-09-01 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Strain in Organic Chemistry written by Brian Halton and published by Jai Press. This book was released on 1991 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: Collected essays which provide reviews and updates on many facets of strained organic molecules, and which aim to generate ideas for future theoretical and experimental research.
Download or read book Strained Organic Molecules written by Arthur Greenberg and published by Academic Press. This book was released on 2013-10-22 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strained Organic Molecule, Volume 38 considers the vast field of strained organic molecules. The book discusses energy and entropy; cyclopropane and cyclobutane; and unique strained groupings or building blocks. The text also describes the aesthetics, rearrangements, and topology of polycycles; kinetic and thermodynamic stability; and tetrahedral tetracoordinate carbon. The inverted tetrahedra, propellanes, buttaflanes, and paddlanes; planar methane and its derivatives; and five- and six-coordinaste carbon are also considered. Chemists will find the book invaluable.
Download or read book Perspectives on Structure and Mechanism in Organic Chemistry written by Felix A. Carroll and published by John Wiley & Sons. This book was released on 2023-05-09 with total page 869 pages. Available in PDF, EPUB and Kindle. Book excerpt: PERSPECTIVES ON STRUCTURE AND MECHANISM IN ORGANIC CHEMISTRY “Beyond the basics” physical organic chemistry textbook, written for advanced undergraduates and beginning graduate students Based on the author’s first-hand classroom experience, Perspectives on Structure and Mechanism in Organic Chemistry uses complementary conceptual models to give new perspectives on the structures and reactions of organic compounds, with the overarching goal of helping students think beyond the simple models of introductory organic chemistry courses. Through this approach, the text better prepares readers to develop new ideas in the future. In the 3rd Edition, the author thoroughly updates the topics covered and reorders the contents to introduce computational chemistry earlier and to provide a more natural flow of topics, proceeding from substitution, to elimination, to addition. About 20% of the 438 problems have been either replaced or updated, with answers available in the companion solutions manual. To remind students of the human aspect of science, the text uses the names of investigators throughout the text and references material to original (or accessible secondary or tertiary) literature as a guide for students interested in further reading. Sample topics covered in Perspectives on Structure and Mechanism in Organic Chemistry include: Fundamental concepts of organic chemistry, covering atoms and molecules, heats of formation and reaction, bonding models, and double bonds Density functional theory, quantum theory of atoms in molecules, Marcus Theory, and molecular simulations Asymmetric induction in nucleophilic additions to carbonyl compounds and dynamic effects on reaction pathways Reactive intermediates, covering reaction coordinate diagrams, radicals, carbenes, carbocations, and carbanions Methods of studying organic reactions, including applications of kinetics in studying reaction mechanisms and Arrhenius theory and transition state theory A comprehensive yet accessible reference on the subject, Perspectives on Structure and Mechanism in Organic Chemistry is an excellent learning resource for students of organic chemistry, medicine, and biochemistry. The text is ideal as a primary text for courses entitled Advanced Organic Chemistry at the upper undergraduate and graduate levels.
Download or read book Advances in Strained and Interesting Organic Molecules written by Brian Halton and published by JAI Press(NY). This book was released on 1995 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Small Ring Compounds in Organic Synthesis VI written by Armin de Meijere and published by Springer. This book was released on 2003-07-01 with total page 237 pages. Available in PDF, EPUB and Kindle. Book excerpt: This current and five previous volumes (Volumes 133, 135, 144, 155, 178) convincingly demonstrate the vast applications of small rings in modern Organic Synthesis. Such applications range from total syntheses of cyclopropyl-group-containing natural products and non-natural biologically active compounds or compounds with other important properties (e.g. liquid crystalline) via syntheses of cyclopropyl analogues of natural and non-natural physiologically active compounds, e.g. peptidomimetics, to the use of cyclopropyl groups as reactive subunits in so-called composite functional groups. This current volume covers a survey of the wide range of biological activities of cyclopropyl-containing compounds, up-to-date comprehensive reviews on the multiple applicabilities of two multifunctional small ring building blocks - methyl-2-chloro-2-cyclopropylidene acetate and bicyclopropylidene - in Organic Synthesis as well as a striking new approach to cyclopentenones from easily accessible 1-ethynylcyclopropanols, which is rather general and favorably complements other cyclopentenone syntheses.
Download or read book Reactive Intermediate Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2004-01-07 with total page 1088 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
Download or read book Advances in Strained and Interesting Organic Molecules written by B. Halton and published by JAI Press. This book was released on 1999-03-31 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work provides timely essays on the many facets of strained and interesting organic molecules. Contributions from experts in the field provide insights not only for the practicing organic chemist, but also for the student at the senior undergraduate and graduate level.
Download or read book Advances in Strained and Interesting Organic Molecules written by B. Halton and published by Elsevier. This book was released on 1999-12-27 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: The eighth volume of this series comprises six chapters and describes a variety of interesting strained and not so strained molecules and their use - or abuse - in the widest sense. This volume contains a position summary of planar carbon networks, the field of strained allenesis addressed by considering the five- to- nine-membered ring derivatives and this is followed by an introduction to the nature of carbene geometry and the use of ESR spectroscopy in deducing carbene structure. The use of strained molecules in the synthesis of important new compounds of a natural and non-natural nature is a main theme in the volume. Other areas that are discussed are strained carbohydrates, stereocontrolled access to natural products and polymer systems as well as a much sought after contribution to the series on small-ring nitrogen heterocycles.
Download or read book The Chemistry of Cyclobutanes written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2005-07-08 with total page 1266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Cyclobutanes provides an in depth and comprehensive review of cyclobutanes and includes chapters on the theoretical and computational foundations; on analytical and spectroscopical aspects with dedicated chapters on Mass Spectrometry, NMR and IR/UV. There are also extensive application examples enabling the reader to collect both a theoretical and practical understanding. The Chemistry of Functional Groups Series was originally founded by Saul Patai (1918-1998) and in the 39 years of publishing has produced more than 100 volumes, providing outstanding reviews on all aspects of functional groups including analytical, physical and synthetic and applied chemistry. Saul Patai has been helped by outstanding editors, especially Zvi Rappoport who has now taken responsibility for the series to continue the tradition of producing high quality reviews with editors such as Y. Apeloig, I. Marek and J. Liebman.
Download or read book Applications of Organometallic Chemistry in the Preparation and Processing of Advanced Materials written by J.F. Harrod and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the ten years since the scientific rationale for the design, synthesis and application of inorganic and organometallic polymers (IOPs) was first conceptualised, we have witnessed the first tentative exploration of IOPs as precursors to new materials, with efforts focusing on the design and synthesis of novel ceramic precursors. Developing expertise led to precursor studies combined with the characterisation of the transformation processes that occur when IOPs are converted to ceramic materials. Now at maturity, the science presented in this volume reveals the polymer precursor approach to materials synthesis together with examples of processing ceramic shapes for a range of mechanical properties, the development of sophisticated, noninvasive analytical techniques, and IOP design rationales relying on well-defined processing-property relationships. The production of multifunctional IOPs is described, providing ion conductivity, gas sensing, bioactivity, magnetic properties, etc., combined with processability. The existence of well-defined IOPs and the exquisite control that can be exerted on sol-gel systems now provide access to such a variety of mixed organic-organometallic and/or inorganic hybrid systems that their exploitation is likely to develop into an entirely new field of materials chemistry. Future exciting avenues of research are also being opened up with the advent of buckyballs, Met-Cars, dopable preceramics, rigid-rod organometallics, and molecular tinkertoys.
Download or read book Advances in Physical Organic Chemistry written by and published by Academic Press. This book was released on 1989-06-05 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series, established by Victor Gold in 1963, brings before the chemical community substantial, authoritative, and considered reviews of areas of chemistry in which quantitative methods are used in the study of the structures of organic compounds and their relation to physical and chemical properties.Physical organic chemistry is viewed as a particular approach to scientific enquiry rather than a further intellectual specialization. Organometallic compounds are included, and relevant aspects of physical theoretical, inorganic, and biological chemistry are incorporated in reviews where appropriate.
Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2006-05-02 with total page 830 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since its original appearance in 1977, Advanced Organic Chemistry has found wide use as a text providing broad coverage of the structure, reactivity and synthesis of organic compounds. The Fourth Edition provides updated material but continues the essential elements of the previous edition. The material in Part A is organized on the basis of fundamental structural topics such as structure, stereochemistry, conformation and aromaticity and basic mechanistic types, including nucleophilic substitution, addition reactions, carbonyl chemistry, aromatic substitution and free radical reactions. The material in Part B is organized on the basis of reaction type with emphasis on reactions of importance in laboratory synthesis. As in the earlier editions, the text contains extensive references to both the primary and review literature and provides examples of data and reactions that illustrate and document the generalizations. While the text assumes completion of an introductory course in organic chemistry, it reviews the fundamental concepts for each topic that is discussed. The Fourth Edition updates certain topics that have advanced rapidly in the decade since the Third Edition was published, including computational chemistry, structural manifestations of aromaticity, enantioselective reactions and lanthanide catalysis. The two parts stand alone, although there is considerable cross-referencing. Part A emphasizes quantitative and qualitative description of structural effects on reactivity and mechanism. Part B emphasizes the most general and useful synthetic reactions. The focus is on the core of organic chemistry, but the information provided forms the foundation for future study and research in medicinal and pharmaceutical chemistry, biological chemistry and physical properties of organic compounds. The New Revised 5th Edition will be available shortly. For details, click on the link in the right-hand column.
Download or read book Interactions in Molecules written by Sigrid D. Peyerimhoff and published by John Wiley & Sons. This book was released on 2003-05-08 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: Experimentalists and theoreticians from chemistry and physics present various interactions in molecules using methods of chemical synthesis, structural analysis, spectroscopy and quantum chemical computations. This work constitutes an important basis in the investigation of increasingly more complex systems such as the study of the action of drugs in pharmaceutical research. The book gives an excellent survey for the specialist and also a welcome introduction for the advanced graduate student and the researcher in neighboring fields.
Download or read book Steric and Stereoelectronic Effects in Organic Chemistry written by Veejendra K. Yadav and published by Springer Nature. This book was released on 2021-07-01 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.
Download or read book Bibliography of Agriculture written by and published by . This book was released on 1990 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt:
