Download or read book Spectroscopy and Structure of Metal Chelate Compounds written by Kazuo Nakamoto and published by . This book was released on 1968 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: X-ray and neutron diffraction / Yoshihiko Saito -- Visible and ultraviolet spectroscopy / Curtis R. Hare -- Optical rotatory dispersion and circular dichroism / Junnosuke Fujita and Yoichi Shimura -- Infrared spectroscopy / Kazuo Nakamoto -- Electron spin resonance spectroscopy / Shizuo Fujiwara -- Nuclear magnetic resonance spectroscopy / Paul J. McCarthy.
Download or read book Spectroscopy and Structure of Metal Chelate Compounds written by James Q. Wilson and published by . This book was released on 1968 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chelating Agents and Metal Chelates written by F Dwyer and published by Elsevier. This book was released on 2012-12-02 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chelating Agents and Metal Chelates focuses on the structure and properties of metal chelates, as well as bond types, stereochemistry, and optical phenomena. The selection first offers information on historical background and fundamental concepts and the nature of metal-ligand bond. Discussions focus on the structure and stability of metal chelates, bond types and characteristic properties, classes of acceptor metal atoms, and metal-metal bonds in complex compounds. The text also touches on bidentate chelates, design and stereochemistry of multidentate chelating agents, and optical phenomena in metal chelates. The publication ponders on oxidation-reduction potentials as functions of donor atom and ligand and metal chelates of ethylenediaminetetraacetic acid and related substances. Topics include liquid junction potentials, reversibility, measurement of redox potentials, ethylenediaminetetraacetato chelate couples, and metal chelates of ethylenediaminetetraacetic acid. The text also takes a look at metal chelates in biological systems and physical and coordination chemistry of tetrapyrrole pigments. The manuscript is a vital reference for senior students, research workers, biologists, and medical scientists interested in the chemistry of metal chelates.
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by N N Greenwood and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Download or read book Chemistry of Polymeric Metal Chelates written by Gulzhian I. Dzhardimalieva and published by Springer. This book was released on 2018-02-13 with total page 1036 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates
Download or read book Bonding and Spectra of Metal Chelates written by R. Linn Belford and published by . This book was released on 1955 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Spectroscopy Modeling and Computation of Metal Chelate Solubility in Supercritical CO2 written by and published by . This book was released on 2000 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The overall objectives of this project were to gain a fundamental understanding of the solubility and phase behavior of metal chelates in supercritical CO2. Extraction with CO2 is a excellent way to remove organic compounds from soils, sludges and aqueous solutions and recent research has demonstrated that together with chelating agents it is a viable way to remove metals, as well. In this project we sought to gain fundamental knowledge that is vital to computing phase behavior, and modeling and designing processes using CO2 to separate organics and metal compounds from DOE mixed wastes. Our overall program was a comprehensive one to measure, model and compute the solubility of metal chelate complexes in supercritical CO2 and CO2/cosolvent mixtures. One aspect of this work was the measurement of local solvation of metal chelates using UV-visible spectroscopy, which provided information on the solution microstructure. We also focused on the measurement of the solubility of met al chelates in supercritical CO2 and CO2/cosolvent mixtures, as well as the phase behavior of the chelating agents themselves in CO2. The purpose of these measurements was to provide information with which we could evaluate and develop thermodynamic models of the solubility behavior. Finally, we focused on the implementation of a more reliable computational technique, based on interval mathematics, to compute the phase equilibria using the thermodynamic models. These studies were undertaken because fundamental information about metal chelate solubility in supercritical CO2 is important in the design of processes using CO2 to extract components from mixed wastes and in determining the optimum operating conditions.
Download or read book Mass Spectrometry of Metal Compounds written by J. Charalambous and published by . This book was released on 1975 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Instrumentation and presentation of mass spectra; Fundamental aspects of tthe mass spectrometry of metal compounds; fragmentation of metalconntaining ions; Energetics of molecular ionisation and dissociation; Mam group organometallic and metal-metal bonded compounds; Boron compounds; Polynuclear carbonyls and related derivatives; Transition metal hydrocarbon compounds; Coordination compounds; Analytical aspects of the mass spectrometry of metal chelates.
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by and published by . This book was released on 1969 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transition Metal and Rare Earth Compounds written by Hartmut Yersin and published by Springer. This book was released on 2003-07-01 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More recently also their enormous potential for the development of new materials for photophysical and photochemical applications has been explored. Thus, it is important to focus on a deeper understanding of the elctronic energies, transition prohabilities, intermolecular interactions, etc.. This task has been accomplished by leading researchers in the field. They present introductions into, but also detailed reviews of the current state of knowledge of three different subjects.
Download or read book Photochemistry and Photophysics of Metal Complexes written by D.M. Roundhill and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.
Download or read book Spectroscopic Analysis of Metal Complexes written by Iffat Imtiaz and published by Lulu.com. This book was released on 2007-05-29 with total page 103 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the new metal complexes of sulfamethoxazole (antibiotic) with palladium (II), iron (II), iridium (III) and tin (II) cations have been synthesized and characterized using infrared and NMR.
Download or read book Chemistry of the Metal Chelate Compounds written by Arthur Earl Martell and published by . This book was released on 1952 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Transition Metal Complexes Structures and Spectra written by and published by Springer. This book was released on 2007-12-13 with total page 211 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Textbook of Inorganic Chemistry Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by D M Adams and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Download or read book Encyclopedia of Spectroscopy and Spectrometry written by and published by Academic Press. This book was released on 2016-09-22 with total page 3716 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition of the Encyclopedia of Spectroscopy and Spectrometry, Three Volume Set provides authoritative and comprehensive coverage of all aspects of spectroscopy and closely related subjects that use the same fundamental principles, including mass spectrometry, imaging techniques and applications. It includes the history, theoretical background, details of instrumentation and technology, and current applications of the key areas of spectroscopy. The new edition will include over 80 new articles across the field. These will complement those from the previous edition, which have been brought up-to-date to reflect the latest trends in the field. Coverage in the third edition includes: Atomic spectroscopy Electronic spectroscopy Fundamentals in spectroscopy High-Energy spectroscopy Magnetic resonance Mass spectrometry Spatially-resolved spectroscopic analysis Vibrational, rotational and Raman spectroscopies The new edition is aimed at professional scientists seeking to familiarize themselves with particular topics quickly and easily. This major reference work continues to be clear and accessible and focus on the fundamental principles, techniques and applications of spectroscopy and spectrometry. Incorporates more than 150 color figures, 5,000 references, and 300 articles for a thorough examination of the field Highlights new research and promotes innovation in applied areas ranging from food science and forensics to biomedicine and health Presents a one-stop resource for quick access to answers and an in-depth examination of topics in the spectroscopy and spectrometry arenas
