Download or read book Some Aspects of Organotransition and Group 14 Metal Chemistry written by and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Aspects of Organotransition Metal Chemistry written by Mark Graeme Humphrey and published by . This book was released on 1987 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organotransition Metal Chemistry From Bonding to Catalysis written by John F. Hartwig and published by . This book was released on 2010-02-10 with total page 1172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.
Download or read book Organotransition Metal Chemistry A Mechanistic Approach written by Richard Heck and published by Elsevier. This book was released on 2012-12-02 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal d- and p-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.
Download or read book Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals written by Ezra Eddy Isaacs and published by . This book was released on 1974 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reaction of cycloheptatrienyltricarbonyl molybdenum cation with various main group V donor ligands (L) yielded, in general, mono-substituted complexes, [C[subscript 7]H[subscript 7]Mo(CO)[subscript 2]L][superscript +]. [superscript 31]P nmr studies on some related di-tertiary phosphine complexes provided a convenient and unequivocal determination of the stereochemistry. The reduction of the cationic cycloheptatrienyl complexes with sodium borohydride provided a suitable synthetic route to the group V derivatives of cyclo- heptatrienetricarbonylmolybdenum. The infrared, [superscript l]H and [superscript 13]C nmr, and mass spectral properties of these complexes were studied. Some main group IV ligands bonded to cycloheptatrienyldicarbonylmolybdenum were also prepared and studied by spectral means. A number of main group IV - group VI metal penta- carbonyl anionic derivatives have been prepared by the reaction of the chloropentacarbonyl anions with the organolithium compounds of the group IV elements. These compounds have the general formula, [R[subscript 3]M' -M(CO)[subscript 5]][superscript -] (where R = Me, Ph or halogen; M' = Si, Ge, Sn or Pb; M = Cr, Mo or W). Approximate carbonyl force constants were calculated from the infrared carbonyl stretching vibrations and these provided some insight into the nature of the metal-metal bonds. Transition metal nitrosyl derivatives have also been prepared by the reaction of some anionic complexes with nitrosonium hexafluorophosphate. These compounds have the general formula LM(CO)[subscript 4]NO (where L is a main group IV ligand or a halogen group and M is Mo or W). The carbonyl and nitrosyl force constants were calculated and are discussed in terms of the relative bonding properties of CO and NO ligands. Finally, the oxidation reaction of some dinuclear metal carbonyls with AgNO[subscript 2] led to the formation of metal carbonyls containing nitro ligands. Linkage isomerism involving nitro and nitrito species was encountered in solution. The [(CH[subscript 3]CN)[subscript 3]Re(CO)[subscript 3]] + cation was formed 2 - from the oxidation reaction of [Re[subscript 4](CO)[subscript 16]][superscript 2-] in acetonitrile.
Download or read book Aspects of Group 14 Element transition Metal Chemistry written by Skelte Anema and published by . This book was released on 1989 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Organometallic Chemistry written by Robert C. West and published by Elsevier. This book was released on 2011-08-09 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.Volume 56 comprises Part 1 of a themed collection of papers on "The Organotransition Metal Chemistry of Poly(pyrazolyl)borates". Provides an authoritative, definitive review addressing all aspects of organometallic chemistry Useful to researchers within this active field and is a must for every modern library of chemistry High-quality research book within this rapidly developing field
Download or read book Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the p-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.
Download or read book Published Papers on written by G. W. A. Fowles and published by . This book was released on 1964 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Some Aspects of Organo transition metal Radical Chemistry written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Download or read book The Chemistry of Carbon written by A. K. Holliday and published by Elsevier. This book was released on 2013-10-22 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Carbon: Organometallic Chemistry is a specialist's selection of certain chapters in Comprehensive Inorganic Chemistry comprising five volumes. This book contains corrections and added prefatory material and individual indices. This volume deals with carbon (Chapter 13) and describes organic chemistry of the metallic elements (Chapter 14). Carbon is unique in its ability to form strong chemical bonds with itself or other elements. Graphite and diamonds are some elementary forms of carbon. Chapter 14 discusses the basis for a qualitative, comparative description of the organic chemistry of metals and any inorganic chemistry found common in them. The book uses the covalent model in describing both bondings made in most organometallic compounds and inorganic derivatives. The text also discusses the atoms in molecules, particularly in a molecular ion, as having both ligands X and a central atom M. A table then shows the classification of some common ligands, grouping them according to the number of valence electrons that make up their bonding. The text then explains the general trends in the chemistry of the main group elements of the Periodic Table that contain ns and np orbitals in their valence shells. The book also discusses some atomic properties, their consequences, and the occurrence of unpaired electrons in organo transition metal complexes. This book will be valuable for students and professors dealing with general chemistry, gemologists, molecular scientists, and researchers.
Download or read book Organotransition Metal Chemistry Applications to Organic Synthesis written by S. G. Davies and published by Elsevier. This book was released on 2013-10-22 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.
Download or read book Some Aspects of the Organometallic Chemistry of the Early Transitions Metals written by James Anthony Stockwell and published by . This book was released on 1975 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Organometallic Chemistry written by Robert West and published by Academic Press. This book was released on 2011-08-09 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Volume 56 comprises Part 1 of a themed collection of papers on "The Organotransition Metal Chemistry of Poly(pyrazolyl)borates". * Provides an authoritative, definitive review addressing all aspects of organometallic chemistry * Useful to researchers within this active field and is a must for every modern library of chemistry * High-quality research book within this rapidly developing field
Download or read book Transition Metal Organometallic Chemistry written by R. Bruce King and published by Elsevier. This book was released on 2012-12-02 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition-Metal Organometallic Chemistry: An Introduction presents the basic facts and principles of transition-metal organometallic chemistry. The book discusses the general principles of transition-metal organometallic chemistry; the organometallic derivatives of the early transition metals; and the organometallic derivatives of chromium, molybdenum, and tungsten. The text also describes the organometallic derivatives of manganese, technetium, and rhenium; the organometallic derivatives of iron, ruthenium, and osmium; and the organometallic derivatives of cobalt, rhodium, and iridium. The organometallic derivatives of nickel, palladium, platinum, copper, silver, and gold are also considered. Chemists and chemistry students will find the book invaluable.
Download or read book Organotransition Metal Chemistry written by Akio Yamamoto and published by Wiley-Interscience. This book was released on 1986 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.
