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Book Sequestration of Arsenic by Nanoscale Zero Valent Iron  nZVI   Surface Reactions Characterized by High Resolution X Ray Photoelectron Spectroscopy  HR XPS

Download or read book Sequestration of Arsenic by Nanoscale Zero Valent Iron nZVI Surface Reactions Characterized by High Resolution X Ray Photoelectron Spectroscopy HR XPS written by Mauricio A. Valencia Ramos and published by . This book was released on 2011 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent studies have shown that nanoscale zero-valent iron (nZVI) is very effective in the removal of highly toxic arsenic species such as As(III) and As(V) from both ground and surface water. Nonetheless, little is known about the sorption reaction mechanism of the As-treated nZVI particles. The present study carries out a more detailed analysis of these particular As sorption surface reactions. In our investigation we have used nZVI with a mean diameter of 60 nm, an average shell thickness in the range of 2.3--2.8 nm, and a surface area of 30 m2/g. High Resolution X-ray Photoelectron Spectroscopy (HR-XPS) using primarily As3d spectra has provided evidence of the presence of all major As species on nZVI: As(0), As(III), and As(V). HR-XPS Fe2p and O1s spectra also confirmed the presence of an oxyhydroxide (FeOOH) layer on freshly synthesized nZVI, which forms an intrinsic shell around the reactive metallic iron nanoparticle core. We also analyzed the reactions between nZVI and As(III) demonstrating for the first time depth-dependent distributions of multiple arsenic valence states within the iron nanoparticles. The stratified concentration profiles of arsenic species in nZVI showed novel aspects of the reactions between As(III) and nZVI. The results offered clear evidence of As(III) redox reactions within the nanoparticles. The distinct layers where As(V) and As(0) reside implied that As(III) oxidation and reduction can occur at different physical fronts. We also concluded that the ability to infuse arsenic into the solid phase of the iron nanoparticles renders nZVI a more voluminous sink for arsenic compared to the commonly used iron oxides nanoparticles. Infiltration of arsenic induced by reactions with nZVI may offer an engineering methodology to encapsulate arsenic for remediation and waste disposal applications.

Book Nano Bioremediation  Fundamentals and Applications

Download or read book Nano Bioremediation Fundamentals and Applications written by Hafiz M. N. Iqbal and published by Elsevier. This book was released on 2021-11-10 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nano-Bioremediation: Fundamentals and Applications explores how nano-bioremediation is used to remedy environmental pollutants. The book's chapters focus on the design, fabrication and application of advanced nanomaterials and their integration with biotechnological processes for the monitoring and treatment of pollutants in environmental matrices. It is an important reference source for materials scientists, engineers and environmental scientists who are looking to increase their understanding of bioremediation at the nanoscale. The mitigation of environmental pollution is the biggest challenge to researchers and the scientific community, hence this book provides answers to some important questions. As an advanced hybrid technology, nano-bioremediation refers to the integration of nanomaterials and bioremediation for the remediation of pollutants. The rapid pace of urbanization, massive development of industrial sectors, and modern agricultural practices all cause a controlled or uncontrolled release of environmentally-related hazardous contaminants that are seriously threatening every key sphere, including the atmosphere, hydrosphere, biosphere, lithosphere, and anthroposphere. Explores the current and potential applications of nano-bioremediation in the remediation of hazardous pollutants Outlines the major properties and classes of nanomaterials that make them efficient bioremediation agents Assesses the major challenges of effectively implementing bioremediation techniques at the nanoscale

Book Technical Progress Report

Download or read book Technical Progress Report written by University of California (System). Salinity/Drainage Research Program and published by . This book was released on 2003 with total page 64 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Approaches in Bioremediation

Download or read book Approaches in Bioremediation written by Ram Prasad and published by Springer. This book was released on 2018-12-08 with total page 413 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioremediation refers to the clean‐up of pollution in soil, groundwater, surface water, and air using typically microbiological processes. It uses naturally occurring bacteria and fungi or plants to degrade, transform or detoxify hazardous substances to human health or the environment. For bioremediation to be effective, microorganisms must enzymatically attack the pollutants and convert them to harmless products. As bioremediation can be effective only where environmental conditions permit microbial growth and action, its application often involves the management of ecological factors to allow microbial growth and degradation to continue at a faster rate. Like other technologies, bioremediation has its limitations. Some contaminants, such as chlorinated organic or high aromatic hydrocarbons, are resistant to microbial attack. They are degraded either gradually or not at all, hence, it is not easy to envisage the rates of clean-up for bioremediation implementation. Bioremediation represents a field of great expansion due to the important development of new technologies. Among them, several decades on metagenomics expansion has led to the detection of autochthonous microbiota that plays a key role during transformation. Transcriptomic guides us to know the expression of key genes and proteomics allow the characterization of proteins that conduct specific reactions. In this book we show specific technologies applied in bioremediation of main interest for research in the field, with special attention on fungi, which have been poorly studied microorganisms. Finally, new approaches in the field, such as CRISPR-CAS9, are also discussed. Lastly, it introduces management strategies, such as bioremediation application for managing affected environment and bioremediation approaches. Examples of successful bioremediation applications are illustrated in radionuclide entrapment and retardation, soil stabilization and remediation of polycyclic aromatic hydrocarbons, phenols, plastics or fluorinated compounds. Other emerging bioremediation methods include electro bioremediation, microbe-availed phytoremediation, genetic recombinant technologies in enhancing plants in accumulation of inorganic metals, and metalloids as well as degradation of organic pollutants, protein-metabolic engineering to increase bioremediation efficiency, including nanotechnology applications are also discussed.

Book In Situ Remediation Engineering

Download or read book In Situ Remediation Engineering written by Suthan S. Suthersan and published by CRC Press. This book was released on 2004-12-28 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Situ Remediation Engineering provides a comprehensive guide to the design and implementation of reactive zone methods for treatment of all major classes of groundwater contamination. It teaches the fundamentals that underlie development of cost-effective reactive zone strategies, guides the selection of cost-effective remedial strategies and provides environmental engineers and scientists with tools to achieve optimal deployment of source area, reactive barrier, and site-wide treatments. It offers extensive coverage of remedial system operation, discussing reagent injection strategies, interpretation of process monitoring results for biological and chemical reactive zone systems, and impacts of treatment processes on aquifer hydraulic characteristics.

Book Remediation Engineering

    Book Details:
  • Author : Suthan S. Suthersan
  • Publisher : CRC Press
  • Release : 2016-11-25
  • ISBN : 1498773362
  • Pages : 628 pages

Download or read book Remediation Engineering written by Suthan S. Suthersan and published by CRC Press. This book was released on 2016-11-25 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This second edition of Remediation Engineering will continue to be the seminal handbook that regulators must have on-hand to address any of the remediation issues they are grappling with daily. The book is wide-ranging, but specific enough to address any environmental remediation challenge." —Patricia Reyes, Interstate Technology Regulatory Council, Washington, DC, USA "This book offers the researcher, teacher, practitioner, student, and regulator with state-of-the-art advances in conducting site investigations and remediation for common and emerging contaminants. It is revolutionary in its approach to conducting subsurface investigation, which greatly influences a successful and appropriate response in assessing and addressing environmental risk. This book is a giant leap forward in understanding how contaminates behave and how to reduce risk to acceptable levels in the natural world." —Daniel T. Rogers, Amsted Industries Incorporated, Chicago, Illinois, USA "This text is a superb reference and a good tool for learning about state-of-the-art techniques in remediation of soil and groundwater. [It] will become a ready reference at many companies as the engineering community creates increased value from remediation efforts around the world." —John Waites, AVX Corporation, Fountain Inn, South Carolina, USA Remediation Engineering was first published in 1996 and quickly became the go-to reference for a relatively young industry, offering the first comprehensive look at the state-of-the-science in treatment technologies of the time and the contaminants they applied to. This fully updated Second Edition will capture the fundamental advancements that have taken place during the last two decades within all the subdisciplines that form the foundation of the remediation engineering platform. It covers the entire spectrum of current technologies that are employed in the industry and also discusses future trends and how practitioners should anticipate and adapt to those needs. Features: Shares the latest paradigms in remediation design approach and contaminant hydrogeology Presents the landscape of new and emerging contaminants Details the current state of the practice for both conventional technologies, such as sparging and venting Examines newer technologies such as dynamic groundwater recirculation and injection-based remedies to address both organic and inorganic contaminants. Describes the advances in site characterization concepts such as smart investigations and digital conceptual site models. Includes all-new color photographs and figures.

Book Monitored Natural Attenuation of Inorganic Contaminants in Ground Water

Download or read book Monitored Natural Attenuation of Inorganic Contaminants in Ground Water written by and published by . This book was released on 2007 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: V.3 ... consists of individual chapters that describe 1) the conceptual background for radionuclides, including tritium, radon, strontium, technetium, uranium, iodine, radium, thorium, cesium, plutonium-americium and 2) data requirements to be met during site characterization.

Book Index Medicus

Download or read book Index Medicus written by and published by . This book was released on 2001 with total page 1736 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vols. for 1963- include as pt. 2 of the Jan. issue: Medical subject headings.

Book Advanced Magnetic Adsorbents for Water Treatment

Download or read book Advanced Magnetic Adsorbents for Water Treatment written by Lucas Meili and published by Springer Nature. This book was released on 2021-09-29 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book compiles 15 chapters about the synthesis, characterizations, and application of many kinds of magnetic adsorbents for water treatment. It is devoted to the scientific community that works with adsorption technologies for water treatment and remediation. Specifically, for professors and Ph.D. students. It is expected that this book serves as an interesting background for researchers in the field of magnetic adsorbents for water treatment.

Book Handbook of Composites from Renewable Materials  Nanocomposites

Download or read book Handbook of Composites from Renewable Materials Nanocomposites written by Vijay Kumar Thakur and published by John Wiley & Sons. This book was released on 2017-04-19 with total page 733 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique multidisciplinary 8-volume set focuses on the emerging issues concerning synthesis, characterization, design, manufacturing and various other aspects of composite materials from renewable materials and provides a shared platform for both researcher and industry. The Handbook of Composites from Renewable Materials comprises a set of 8 individual volumes that brings an interdisciplinary perspective to accomplish a more detailed understanding of the interplay between the synthesis, structure, characterization, processing, applications and performance of these advanced materials. The Handbook comprises 169 chapters from world renowned experts covering a multitude of natural polymers/ reinforcement/ fillers and biodegradable materials. Volume 8 is solely focused on the Nanocomposites: Advanced Applications. Some of the important topics include but not limited to: Virgin and recycled polymers applied to advanced nanocomposites; biodegradable polymer–carbon nanotube composites for water and wastewater treatment; eco-friendly nanocomposites of chitosan with natural extracts, antimicrobial agents, and nanometals; controllable generation of renewable nanofibrils from green materials and their application in nanocomposites; nanocellulose and nanocellulose composites; poly(lactic acid) biopolymer composites and nanocomposites for biomedical and biopackaging applications; impact of nanotechnology in water treatment: carbon nanotube and graphene; nanomaterials in energy generation; sustainable green nanocomposites from bacterial bioplastics for food-packaging applications; PLA nanocomposites: a promising material for future from renewable resources; biocomposites from renewable resources: preparation and applications of chitosan–clay nanocomposites; nanomaterials: an advanced and versatile nanoadditive for kraft and paper industries; composites and nanocomposites based on polylactic acid obtaining; cellulose-containing scaffolds fabricated by electrospinning: applications in tissue engineering and drug delivery; biopolymer-based nanocomposites for environmental applications; calcium phosphate nanocomposites for biomedical and dental applications: recent developments; chitosan–metal nanocomposites: synthesis, characterization, and applications; multi-carboxyl functionalized nanocellulose/nanobentonite composite for the effective removal and recovery of metal ions; biomimetic gelatin nanocomposite as a scaffold for bone tissue repair; natural starches-blended ionotropically gelled microparticles/beads for sustained drug release and ferrogels: smart materials for biomedical and remediation applications.

Book Investigations of Surface Redox Chemistry on Environmentally Relevant Iron Oxides and Sulfides

Download or read book Investigations of Surface Redox Chemistry on Environmentally Relevant Iron Oxides and Sulfides written by Elizabeth B. Cerkez and published by . This book was released on 2016 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Important reactions in the environment often occur at the interface between a mineral surface and aqueous phase. Reactions occurring at this interface often control the uptake or release of harmful components resulting in the geochemical cycling of elements in the environment. Additionally, minerals are commonly used in the remediation of contaminated areas, where similar chemistry occurs at their interfaces. Thus, studies of the chemistry of these interfaces are essential to our understanding of complex environments. Many of these processes are controlled by electron transfer reactions between adsorbates and the mineral interface, and it is here where this research presented will concentrate. The studies in this thesis key in on redox chemistry on various environmentally relevant iron minerals, including ferrihydrite, pyrite, and amorphous iron sulfide. A large portion of this body of work is dedicated to the understanding of the surface mediated reaction between chromate (Cr(VI)) and arsenite (As(III)). Both of these species are present in the environment and are detrimental to human health. Using in- and ex-situ experiments we have monitored the coupled redox transformation of Cr(VI) and As(III) to chromite (Cr(III)) and arsenate (As(V)). Quantum mechanical modeling was used to support the experimental studies of this novel redox chemistry. The reaction was monitored in situ, using attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), on the surface of the iron oxyhydroxide, ferrihydrite, at various solution pH values by following vibrational modes unique to Cr(VI), As(III), and As(V). At pH

Book Handbook of Nanomaterials for Wastewater Treatment

Download or read book Handbook of Nanomaterials for Wastewater Treatment written by Bharat A. Bhanvase and published by Elsevier. This book was released on 2021-05-05 with total page 1218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Nanomaterials for Wastewater Treatment: Fundamentals and Scale up Issues provides coverage of the nanomaterials used for wastewater treatment, covering photocatalytic nanocomposite materials, nanomaterials used as adsorbents, water remediation processes, and their current status and challenges. The book explores the major applications of nanomaterials for effective catalysis and adsorption, also providing in-depth information on the properties and application of new advanced nanomaterials for wastewater treatment processes. This is an important reference source for researchers who need to solve basic and advanced problems relating to the use of nanomaterials for the development of wastewater treatment processes and technologies. As nanotechnology has the potential to substantially improve current water and wastewater treatment processes, the synthesis methods and physiochemical properties of nanomaterials and noble metal nanoparticles make their performance and mechanisms efficient for the treatment of various pollutants. - Explains the properties of the most commonly used nanomaterials used for wastewater treatment - Describes the major nanoscale synthesis and processing techniques for wastewater treatment - Assesses the major challenges for using nanomaterials on a mass scale for wastewater treatment

Book Environmental Soil Remediation and Rehabilitation

Download or read book Environmental Soil Remediation and Rehabilitation written by Eric D. van Hullebusch and published by Springer Nature. This book was released on 2020-04-22 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of innovative remediation techniques and strategies for soils contaminated by heavy metals or organic compounds (e.g. petroleum hydrocarbons, NAPLs and chlorinated organic compounds). It discusses various novel chemical remediation approaches (in-situ and ex-situ) used alone and in combination with physical and/or thermal treatment. Further, it addresses the recovery of NAPLs, reuse of leaching solutions, and in-situ chemical reduction and oxidation, and explores the chemical enhancement of physical NAPLs recovery from both practical and theoretical perspectives. Also presenting the state-of-the-art in waste-assisted bioremediation to improve soil quality and the remediation of petroleum hydrocarbons, the book is a valuable resource for students, researchers and R&D professionals in industry engaged in the treatment of contaminated soils.

Book Advances in Agronomy

Download or read book Advances in Agronomy written by and published by Elsevier. This book was released on 2008-06-20 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Agronomy continues to be recognized as a leading reference and a first-rate source for the latest research in agronomy. As always, the subjects covered are varied and exemplary of the myriad of subject matter dealt with by this long-running serial. - Maintains the highest impact factor among serial publications in agriculture - Presents timely reviews on important agronomy issues - Enjoys a long-standing reputation for excellence in the field