Download or read book Recent progress in strategies for preparation of metal organic frameworks and their hybrids with different dimensions written by Yichun Su and published by OAE Publishing Inc.. This book was released on 2023-01-01 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: As a new kind of organic-inorganic hybrid porous material, metal-organic frameworks (MOFs) exhibit a wide application prospect in gas storage and separation, catalysis and sensing due to their characteristics of large specific surface area, high porosity and coordination unsaturation. As more and more types of MOFs were reported, the synthetic strategies of MOFs-based materials have become a hot research topic. According to the morphological dimension, MOFs can be roughly divided into one-dimensional, two-dimensional and three-dimensional structures. Herein, we summarize the synthetic methods and principles of MOFs from multi-dimensional perspectives, and explore the growth mechanism of MOFs with different morphologies based on dynamic and thermodynamic tuning. Finally, based on the above summaries, the challenges and opportunities of MOFs in the future are discussed.
Download or read book Metal Organic Frameworks with Heterogeneous Structures written by Ali Morsali and published by John Wiley & Sons. This book was released on 2021-10-12 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: METAL-ORGANIC FRAMEWORKS WITH HETEROGENEOUS STRUCTURES A unique book that sheds light on Metal-Organic Frameworks complex systems that often display behaviors that surprise and cannot be easily described. In this book, MOF-based heterostructures technology with key characteristics is completely analyzed and the current state-of-the-art is discussed. The authors focus on the complex heterostructures promoted by MOFs with advantage of their recent new advances for various applications with particular emphasis on their design. As an extension of the design and synthesis, the shaping technology of heterostructure MOFs is also of great significance to the future practical applications in industry (adsorption/desorption, gas storage, catalysis, conductivity, optical activity) of this class of complex porous materials. As this unique book covers all of the aspects of complexity in MOFs with heterogeneous structures, it serves as an essential reference to the concepts of introducing complexity to designing the future new platforms of materials with advanced and superior properties. This important compact book provides the reader with: The principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications The effects of complexities on the structure of metal-organic frameworks The roles of complexities on metal-organic frameworks applications Explanation of synthesis strategies of the complex heterostructure MOFs. Audience This book will be beneficial for chemists, materials engineers, advanced postgraduate and graduate students, researchers and specialists who are working in the area of materials design and their chemistry, porous crystalline materials, coordination polymers, hybrid and functional materials, as well as industry professionals, such as those working on selective catalysis and adsorption-separation, optics, gas capture, processes of biological and pharmaceutical.
Download or read book Recent Progress in the Synthesis of Metal organic Frameworks written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks (MOFs) have attracted considerable attention for various applications due to their tunable structure, porosity and functionality. In general, MOFs have been synthesized from isolated metal ions and organic linkers under hydrothermal or solvothermal conditions via one-spot reactions. The emerging precursor approach and kinetically tuned dimensional augmentation strategy add more diversity to this field. In addition, to speed up the crystallization process and create uniform crystals with reduced size, many alternative synthesis routes have been explored. Recent advances in microwave-assisted synthesis and electrochemical synthesis are presented in this review. In recent years, post-synthetic approaches have been shown to be powerful tools to synthesize MOFs with modified functionality, which cannot be attained via de novo synthesis. In this study, some current accomplishments of post-synthetic modification (PSM) based on covalent transformations and coordinative interactions as well as post-synthetic exchange (PSE) in robust MOFs are provided.
Download or read book Metal organic Frameworks MOFS written by Thorben van den Burg and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: "This monograph comprises six chapters, each dealing with a different aspect of metal-organic frameworks. Chapter 1 discusses recent advances based on the synthesis of multi-emissive MOF as a ratiometric sensor and their application with the mechanism of the sensing process in detail. Chapter 2 focuses on the recent advances in improving the electrochemical energy storage applications of MOFs by exploiting the combined benefits of the components constituting composites of transition metal-based compounds. Chapter 3 proposes cyclodextrin-containing metal organic frameworks (CD-MOFs) on the basis of y-cyclodextrin as carriers for leflunomide and its pharmacologically active metabolite teriflunomide. Chapter 4 discusses the origin of the MOF, their development, the different MOF prototypes and their potential, the medical advances they made and the ones in clinical use. Chapter 5 discusses the interface and mechanism of MOF for efficient photoelectrocatalysis. Finally, Chapter 6 discusses the recent development of the chemical synthesis and protocols for incorporating single metal sites with different organic units formation and properties and its prospective applications and utilization"--
Download or read book Metal Organic Frameworks for Biomedical Applications written by Masoud Mozafari and published by Woodhead Publishing. This book was released on 2020-03-17 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks for Biomedical Applications is a comprehensive, authoritative reference that offers a substantial and complete treatment of published results that have yet to be critically reviewed. It offers a summary of current research and provides in-depth understanding of the role of metal-organic frameworks in biomedical engineering. The title consists of twenty-two chapters presented by leading international researchers in the field. Chapters are arranged by target-application in biomedical engineering, allowing medical and pharmaceutic specialists to translate current materials and engineering science on metal-organic frameworks into their work. Presents the state-of-the art in metal-organic frameworks for biomedical applications Offers comprehensive treatment of metal-organic frameworks that is useful to pharmaceutic and medical experts who are non-specialists in materials science Helps materials scientists and engineers understand the needs of biomedical engineering Critically-reviews published results and current research in the field
Download or read book Metal Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Download or read book Applications of Metal Organic Frameworks and Their Derived Materials written by Inamuddin and published by John Wiley & Sons. This book was released on 2020-04-23 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal–organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.
Download or read book Metal organic Frameworks MOFs written by Priscilla Reeves and published by Novinka Books. This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks (MOFs) are porous crystalline materials, consisting of inorganic metal nodes and organic linkers. These materials possess many merits, such as light weight, high specific surface areas, well-defined porosities and open site structures. The first chapter of this book focuses on the major breakthroughs of MOFs reported to date for nanomedicine applications followed by a short commentary addressing deficient areas in the field and the future direction of MOF based therapeutics. Chapter Two provides an overview of the current state of MOFs in solidphase microextraction (SPME) together with future expectations in the field. Chapter Three reviews the methods used to fabricate MOFs and discusses the use of MOFs in sensor development. The last chapter focuses on newly emerging MOFs, MOFs-supported and MOFs-derived materials. It discusses the recent progress of preparation and applications of these MOF-based materials in the electrocatalysis for oxygen reduction reaction (ORR) and/or oxygen evolution reaction (OER).
Download or read book The Chemistry of Metal Organic Frameworks 2 Volume Set written by Stefan Kaskel and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 899 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
Download or read book Metal Organic Framework written by Xian-He Bu and published by Springer Nature. This book was released on 2020-05-28 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience.Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Download or read book Metal Organic Frameworks written by Victoria Samanidou and published by MDPI. This book was released on 2020-03-27 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.
Download or read book Metal Organic Frameworks written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2010-12-17 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Download or read book Metal Organic Frameworks written by Bhawana Jain and published by Elsevier. This book was released on 2024-04-26 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Organic Frameworks: Fundamentals to Advanced offers a substantial and complete treatment of published results. The book includes a summary of current research, along with an in- depth explanation of Metal organic frameworks (MOFs) and applications in this versatile area. Metal organic frameworks (MOFs) are structured frameworks made up of metal ions and organic molecules. These materials are similar to sponges and can absorb, retain and remove molecules from their pores. As a result, metal-organic frameworks (MOFs) are the most rapidly evolving substances in chemistry with the highest surface areas due to their well-ordered pore structure.The exciting and vast surface area allows for more chemical reactions and molecule adsorption, hence this new resource provides the newest updates on the topics covered. - Covers the synthetic advantages and versatile applications of metal-organic frameworks (MOFs) due to their organic-inorganic hybrid nature and unique porous structure - Includes energy applications such as batteries, fuel storage, fuel cells, hydrogen evaluation reactions and super capacitors - Features information on using MOFs as a replacement to conventional engineering materials as they are lightweight, less costly, environmentally-friendly and sustainable
Download or read book Metal Organic Frameworks MOFs for Environmental Applications written by Sujit K. Ghosh and published by Elsevier. This book was released on 2019-06-07 with total page 465 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. - Examines the applications of metal-organic frameworks for the remediation of environmental pollutants - Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China - Explores possible solutions to some of today's most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water - Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science
Download or read book Handbook of Advanced Ceramics written by Tadafumi Adschiri and published by Elsevier Inc. Chapters. This book was released on 2013-04-11 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Physicochemical Aspects of Metal Organic Frameworks written by Ali Maleki and published by Springer Nature. This book was released on 2023-03-03 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a both detailed and comprehensive look at metal–organic frameworks (MOFs), a relatively new class of materials with a broad application potential. The beginning chapters focus on introducing the requisite fundamental knowledge of MOFs with respect to their classification, synthesis, functionalization approaches, and various other physiochemical facets such as structural morphology and coordination chemistry. The remaining chapters cover an array of diverse applications, from areas such as energy storage and environmental remediation, to drug delivery, biosensing, and tissue engineering. Featuring chapters dedicated to the design of novel MOF structures, as well as theoretical calculations via density functional theory and machine learning techniques, this book targets a wide readership of both academic and industrial researchers interested in an in-depth understanding of the latest MOF structure–function relationships, as well as their deployment in a wide variety of coordinated engineering applications.
Download or read book Highly Stable Metal Organic Frameworks and Their Applications written by Dawei Feng and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks (MOFs) are a class of newly emerged porous materials. As inorganic-organic hybrid materials, MOFs exhibit many features such as crystalline structures, high surface areas, large porosities, and facile tunability However, the lack of high stability in harsh chemical conditions of most MOFs severely hampers MOFs' applications. This dissertation is focusing on synthesizing highly stable MOFs, developing new synthetic strategies towards single crystalline robust MOFs and their applications of catalysis, sensing as well as methane storage. In the second section, a series of highly stable porphyrinic zirconium MOFs were synthesized. PCN-222 which exhibits one of the largest one dimensional channel and extraordinary stability in acidic condition, was studied as biomimetic catalyst. PCN-224, 221, 223 and 225 were studied as CO2 fixation catalyst, alkane oxidation catalyst, catalyst for Diels Alder reaction and pH sensor respectively. In the third section, a series of highly stable mesoporous MOFs were developed. In particular, PCN-333 exhibits the largest cage (5.5nm) among all the reported MOFs while maintaining excellent stability in aqueous environment. Therefore, PCN-333(Al) was selected for enzyme immobilization. Choosing horseradish peroxidase and cytochrome c as the guest enzymes, PCN-333(Al) shows the highest immobilization amount for both enzymes among all the reported porous supports. Meanwhile, the immobilized enzymes were proved having higher catalytic activity compared to the free enzymes. In the fourth section, a new synthetic strategy towards robust Fe-MOFs, named kinetically tuned dimensional augmentation was developed. Using preformed iron carboxylate cluster, by judiciously adjusting the amount of competing reagent, 34 Fe-MOFs containing the same inorganic building block were successfully obtained with large singles crystals. Among these MOFs, PCN-250, which can be synthesized in large scale, shows one of the highest volumetric methane uptake capacity. More importantly, PCN-250 can be stable in water for more than six months without losing the porosity, which is superior to those other MOFs reported with high methane storage capacity. With its high gas uptake, extraordinary stability, and excellent scalability, PCN-250 is a viable candidate for natural gas storage for automotive applications. In summary, a series of highly stable MOFs have been synthesized for different applications. In particular, the kinetically tuned dimensional augmentation strategy has been demonstrated as a facile method to synthesize single crystalline Fe-MOFs, which greatly facilitated the development of robust Fe-MOFs for practical applications. The electronic version of this dissertation is accessible from http://hdl.handle.net/1969.1/155477
