Download or read book Reactive Collisions in Crossed Molecular Beams written by and published by . This book was released on 1962 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The distribution of velocity vectors of reaction products is discussed with emphasis on the restrictions imposed by the conservation laws. The recoil velocity that carries the products away from the center of mass shows how the energy of reaction is divided between internal excitation and translation. Similarly, the angular distributions, as viewed from the center of mass, reflect the partitioning of the total angular momentum between angular momenta of individual molecules and orbital angular momentum associated with their relative motion. Crossed-beam studies of several reactions of the type M + RI yields R + MI are described, where M = K, Rb, Cs, and R = CH3, C3H5, etc. The results show that most of the energy of reaction goes into internal excitation of the products and that the angular distribution is quite anisotropic, with most of the MI recoiling backward (and R forward) with respect to the incoming K beam. (auth).
Download or read book Crossed Molecular Beam Studies of Elastic Inelastic and Reactive Collisions written by James Martin Farrar and published by . This book was released on 1974 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Crossed Molecular Beam Studies of Atmospheric Chemical Reaction Dynamics written by Jingsong Zhang and published by . This book was released on 1993 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dynamics of Molecular Collisions written by W. Miller and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activity in any theoretical area is usually stimulated by new experimental techniques and the resulting opportunity of measuring phenomena that were previously inaccessible. Such has been the case in the area under consideration he re beginning about fifteen years aga when the possibility of studying chemical reactions in crossed molecular beams captured the imagination of physical chemists, for one could imagine investigating chemical kinetics at the same level of molecular detail that had previously been possible only in spectroscopic investigations of molecular stucture. This created an interest among chemists in scattering theory, the molecular level description of a bimolecular collision process. Many other new and also powerful experimental techniques have evolved to supplement the molecular be am method, and the resulting wealth of new information about chemical dynamics has generated the present intense activity in molecular collision theory. During the early years when chemists were first becoming acquainted with scattering theory, it was mainly a matter of reading the physics literature because scattering experiments have long been the staple of that field. It was natural to apply the approximations and models that had been developed for nuclear and elementary particle physics, and although some of them were useful in describing molecular collision phenomena, many were not.
Download or read book Molecular Beam Studies of Reactive Collisions written by N. J. Barry and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dynamics of Molecular Collisions written by W. Miller and published by Springer. This book was released on 1976-12 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activity in any theoretical area is usually stimulated by new experimental techniques and the resulting opportunity of measuring phenomena that were previously inaccessible. Such has been the case in the area under consideration here beginning about fifteen years ago when the possibility of studying chemical reactions in crossed molecular beams captured the imagination of physical chemists, for one could imagine investigating chemical kinetics at the same level of molecular detail that had previously been possible only in spectroscopic investigations of molecular stucture. This created an interest among chemists in scattering theory, the molecular level description of a bimolecular collision process. Many other new and also powerful experimental techniques have evolved to supplement the molecular beam method, and the resulting wealth of new information about chemical dynamics has generated the present intense activity in molecular collision theory. During the early years when chemists were first becoming acquainted with scattering theory, it was mainly a matter of reading the physics literature because scattering experiments have long been the staple of that field. It was natural to apply the approximations and models that had been developed for nuclear and elementary particle physics, and although some of them were useful in describing molecular collision phenomena, many were not. The most relevant treatise then available to students was Mott and Massey's classic The Theory of Atomic Collisions, * but, as the title implies, it dealt only sparingly with the special features that arise when at least one of the collision partners is a molecule.
Download or read book Atom Molecule Collision Theory written by Richard Barry Bernstein and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 785 pages. Available in PDF, EPUB and Kindle. Book excerpt: The broad field of molecular collisions is one of considerable current interest, one in which there is a great deal of research activity, both experi mental and theoretical. This is probably because elastic, inelastic, and reactive intermolecular collisions are of central importance in many of the fundamental processes of chemistry and physics. One small area of this field, namely atom-molecule collisions, is now beginning to be "understood" from first principles. Although the more general subject of the collisions of polyatomic molecules is of great im portance and intrinsic interest, it is still too complex from the viewpoint of theoretical understanding. However, for atoms and simple molecules the essential theory is well developed, and computational methods are sufficiently advanced that calculations can now be favorably compared with experimental results. This "coming together" of the subject (and, incidentally, of physicists and chemists !), though still in an early stage, signals that the time is ripe for an appraisal and review of the theoretical basis of atom-molecule collisions. It is especially important for the experimentalist in the field to have a working knowledge of the theory and computational methods required to describe the experimentally observable behavior of the system. By now many of the alternative theoretical approaches and computational procedures have been tested and intercompared. More-or-Iess optimal methods for dealing with each aspect are emerging. In many cases working equations, even schematic algorithms, have been developed, with assumptions and caveats delineated.
Download or read book Application of Free Jet Sources to Reactive Crossed Molecular Beam Experiments written by Dan Frazier Patch and published by . This book was released on 1972 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Crossed Molecular Beam Study of the Reactive Scattering of K I2 written by Keith Thomas Gillen and published by . This book was released on 1970 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Collision Dynamics of Methyl Radicals and Highly Vibrationally Excited Molecules Using Crossed Molecular Beams written by Pamela Mei-Ying Chu and published by . This book was released on 1991 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molecular Reaction Dynamics written by Raphael D. Levine and published by Cambridge University Press. This book was released on 2009-06-04 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular reaction dynamics is the study of chemical and physical transformations of matter at the molecular level. The understanding of how chemical reactions occur and how to control them is fundamental to chemists and interdisciplinary areas such as materials and nanoscience, rational drug design, environmental and astrochemistry. This book provides a thorough foundation to this area. The first half is introductory, detailing experimental techniques for initiating and probing reaction dynamics and the essential insights that have been gained. The second part explores key areas including photoselective chemistry, stereochemistry, chemical reactions in real time and chemical reaction dynamics in solutions and interfaces. Typical of the new challenges are molecular machines, enzyme action and molecular control. With problem sets included, this book is suitable for advanced undergraduate and graduate students, as well as being supplementary to chemical kinetics, physical chemistry, biophysics and materials science courses, and as a primer for practising scientists.
Download or read book Crossed Molecular Beam Studies written by D. R. Herschbach and published by . This book was released on 1987 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report summarizes three of investigations: 1) studies of van der Waals collision dynamics, 2) laser spectroscopy study of rotational vibrational relaxations, and 3) angular correlations in chemical reactions. A cross molecular beam apparatus was used to study several van der Waals bond exchange reactions. These collisions involving extremely weak interactions were found to have product velocity distributions which resemble those from several ion molecular reactions which occur at very high collision energy. This led to the theoretical development of a scattering model which should be applicable to a wide range of reactive and inelastic collision processes at kinetic energies higher than the bond strengths. In another effort, laser induced fluorescence experiments were performed to measure the rotational and vibrational temperatures of molecular iodine seeded in beams of helium, argon, or nitrogen expanded from a supersonic nozzle. The results demonstrated the utility of seeded iodine fluorescence as a diagnostic for pulse shape and collisional relaxation in pulsed supersonic beams. Lastly, theoretical calculations dealing with rotational orientation in molecular collisions resulted in the formulation of a correlation analysis which offers a means to obtain information about collision dynamics that would otherwise be lost by averaging over the initial impact parameters and molecular orientations.
Download or read book Theory of Molecular Collisions written by Gabriel G Balint-Kurti and published by Royal Society of Chemistry. This book was released on 2015-07-02 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost 100 years have passed since Trautz and Lewis put forward their collision theory of molecular processes. Today, knowledge of molecular collisions forms a key part of predicting and understanding chemical reactions. This book begins by setting out the classical and quantum theories of atom-atom collisions. Experimentally observable aspects of the scattering processes; their relationship to reaction rate constants and the experimental methods used to determine them are described. The quantum mechanical theory of reactive scattering is presented and related to experimental observables. The role of lasers in the measurement and analysis of reactive molecular collisions is also discussed. Written with postgraduates and newcomers to the field in mind, mathematics is kept to a minimum, and readers are guided to appendices and further reading to gain a deeper understanding of the mathematics involved.
Download or read book Molecular Beam Studies of Inelastic and Reactive Scattering written by Michael Scott Westley and published by . This book was released on 2000 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Crossed Molecular Beam Studies of Substitution and Exchange Reactions written by Gary Neil Robinson and published by . This book was released on 1988 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Crossed Molecular Beam and Tunable Laser Apparatus Applied to Reactive Scattering Studies written by Carlo Parravano and published by . This book was released on 1974 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bimolecular Collisions written by M. N. R. Ashfold and published by . This book was released on 1989 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed to provide an authoritative and timely review of advances in the field of gas-phase photochemistry and kinetics, this volume contains a collection of papers on biomolecular collisions. Contributors discuss collision processes, reactive processes and association reactions.
