Download or read book Polymer Melt Rheology and Flow Birefringence written by Hermann Janeschitz-Kriegl and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 538 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims of this book to verify this suppo sition. The author hopes to show that the technique of the measurement of flow birefringence can fulfil an important com plementary task in polymer melt rheology. From this point it is expected that the present monograph will attract the atten tion of polymer scientists in general, and of rheologists and process engineers in particular. Certainly, the fourth chapter will appeal to the latter group. As a teacher in polymer science and technology the author wants to address also the group of the graduate students. In fact, the standard knowledge acquired during usual university studies in chemistry, physics or engineering does not enable a quick start of research activities in the field of polymer melt rheology. Certainly, in this typically interdisciplinary field everyone can lay emphasis on matters which are familar to hirn because of his preceding education. Significant research activities, however, can only be generated on the basis of a more universal knowledge. In the absence of this knowledge beginners have to rely upon the guidance of their supervisors for an unduly long period. Otherwise they take the risk of losing too much of their costly time. This holds in particular for the experimentalists who cannot be dispensed from being familiar with the necessary theoretical background.
Download or read book Polymer Melt Rheology and Flow Birefringence written by Hermann Janeschitz-Kriegl and published by Springer Verlag. This book was released on 1983 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polymer Melt Rheology written by F N Cogswell and published by Elsevier. This book was released on 1981-01-01 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores the ways in which melt flow behaviour can be exploited by the plastics engineer and technician for increased efficiency of processing operation, control of end product properties and selection and development of polymers for specific purposes. (reissued with minor corrections 1994)
Download or read book The application of flow birefringence to rheological studies of polymer melts written by J.L.S. Wales and published by Springer. This book was released on 1976-03-31 with total page 111 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. 1 Preamble The science to which this work is appended is termed rheology and rheology means the study of flow and deformation of liquids and solids with emphasis on the underlying physical processes. Characteristic for solids is that they respond to a force by deforming, and, on removal of the force, by returning to their original shape. This type of re sponse is termed elastic. Characteristic for liquids is that they deform and continue to deform as long as the force is present. This type of response is termed viscous. The two definitions just given for viscous and elastic response represent ~wo extremes of response to an external force. Materials do not always fall readily into one or the other of the above-mentioned categories. An additional parameter is needed to describe material response more fully. The extra param eter is time. As a general rule the faster the deformation the closer the re sponse is to being elastic, the slower the deformation the closer the response is to being viscous. Slow and fast . are factors relative to some natural time, T, of the material. This natural time may be thought connected with the rates of spontaneous diffusion of its molecular and atomic constituents. For every day fluids as water, the natural time is very short, of the order of 10-10s 1) and hence for most purposes is considered as being viscous.
Download or read book Constitutive Equations for Polymer Melts and Solutions written by Ronald G. Larson and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Constitutive Equations for Polymer Melts and Solutions presents a description of important constitutive equations for stress and birefringence in polymer melts, as well as in dilute and concentrated solutions of flexible and rigid polymers, and in liquid crystalline materials. The book serves as an introduction and guide to constitutive equations, and to molecular and phenomenological theories of polymer motion and flow. The chapters in the text discuss topics on the flow phenomena commonly associated with viscoelasticity; fundamental elementary models for understanding the rheology of melts, solutions of flexible polymers, and advanced constitutive equations; melts and concentrated solutions of flexible polymer; and the rheological properties of real liquid crystal polymers. Chemical engineers and physicists will find the text very useful.
Download or read book Rheology for Polymer Melt Processing written by J.-M. Piau and published by Elsevier. This book was released on 1996-10-10 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the main results obtained by different laboratories involved in the research group Rheology for polymer melt processing which is associated with French universities, schools of engineering, and the CNRS (Centre National de la Recherche Scientifique - France). The group comprises some 15 research laboratories of varied disciplines (chemistry, physics, material sciences, mechanics, mathematics), but with a common challenge viz. to enhance the understanding of the relationships between macromolecular species, their rheology and their processing. Some crucial issues of polymer science have been addressed: correlation of viscoelastic macroscopic bulk property measurements and models, slip at the wall, extrusion defects, correlation between numerical flow simulations and experiments. Features of the book: • The book is unique in that it allows one to grasp the key issues in polymer rheology and processing at once through a series of detailed state-of-the-art contributions, which were previously scattered throughout the literature. • Each paper was reviewed by experts and the book editors and some coordination was established in order to achieve a readable and easy access style. • Papers have been grouped in sections covering successively: Molecular dynamics, Constitutive equations and numerical modelling, Simple and complex flows. • Each paper can be read independently. Since the book is intended as an introduction to the main topics in polymer processing, it will be of interest to graduate students as well as to scientists in academic and industrial laboratories.
Download or read book The application of flow birefringence to rheological studies of polymer melts written by J.L.S. Wales and published by Springer. This book was released on 1976-04-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. 1 Preamble The science to which this work is appended is termed rheology and rheology means the study of flow and deformation of liquids and solids with emphasis on the underlying physical processes. Characteristic for solids is that they respond to a force by deforming, and, on removal of the force, by returning to their original shape. This type of re sponse is termed elastic. Characteristic for liquids is that they deform and continue to deform as long as the force is present. This type of response is termed viscous. The two definitions just given for viscous and elastic response represent ~wo extremes of response to an external force. Materials do not always fall readily into one or the other of the above-mentioned categories. An additional parameter is needed to describe material response more fully. The extra param eter is time. As a general rule the faster the deformation the closer the re sponse is to being elastic, the slower the deformation the closer the response is to being viscous. Slow and fast . are factors relative to some natural time, T, of the material. This natural time may be thought connected with the rates of spontaneous diffusion of its molecular and atomic constituents. For every day fluids as water, the natural time is very short, of the order of 10-10s 1) and hence for most purposes is considered as being viscous.
Download or read book Melt Rheology and Its Role in Plastics Processing written by K. Wissbrun and published by Springer Science & Business Media. This book was released on 2013-11-27 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to fulfill a dual role. On the one hand it provides a description of the rheological behavior of molten poly mers. On the other, it presents the role of rheology in melt processing operations. The account of rheology emphasises the underlying principles and presents results, but not detailed deriva tions of equations. The processing operations are described qualita tively, and wherever possible the role of rheology is discussed quantitatively. Little emphasis is given to non-rheological aspects of processes, for example, the design of machinery. The audience for which the book is intended is also dual in It includes scientists and engineers whose work in the nature. plastics industry requires some knowledge of aspects of rheology. Examples are the polymer synthetic chemist who is concerned with how a change in molecular weight will affect the melt viscosity and the extrusion engineer who needs to know the effects of a change in molecular weight distribution that might result from thermal degra dation. The audience also includes post-graduate students in polymer science and engineering who wish to acquire a more extensive background in rheology and perhaps become specialists in this area. Especially for the latter audience, references are given to more detailed accounts of specialized topics, such as constitutive relations and process simulations. Thus, the book could serve as a textbook for a graduate level course in polymer rheology, and it has been used for this purpose.
Download or read book Polymer Rheology and Processing written by A.A. Collyer and published by Springer Science & Business Media. This book was released on 1990-10-31 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Principles of Polymer Processing written by Zehev Tadmor and published by John Wiley & Sons. This book was released on 2013-12-02 with total page 1004 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thoroughly revised edition of the classic text on polymer processing The Second Edition brings the classic text on polymer processing thoroughly up to date with the latest fundamental developments in polymer processing, while retaining the critically acclaimed approach of the First Edition. Readers are provided with the complete panorama of polymer processing, starting with fundamental concepts through the latest current industry practices and future directions. All the chapters have been revised and updated, and four new chapters have been added to introduce the latest developments. Readers familiar with the First Edition will discover a host of new material, including: * Blend and alloy microstructuring * Twin screw-based melting and chaotic mixing mechanisms * Reactive processing * Devolatilization--theory, mechanisms, and industrial practice * Compounding--theory and industrial practice * The increasingly important role of computational fluid mechanics * A systematic approach to machine configuration design The Second Edition expands on the unique approach that distinguishes it from comparative texts. Rather than focus on specific processing methods, the authors assert that polymers have a similar experience in any processing machine and that these experiences can be described by a set of elementary processing steps that prepare the polymer for any of the shaping methods. On the other hand, the authors do emphasize the unique features of particular polymer processing methods and machines, including the particular elementary step and shaping mechanisms and geometrical solutions. Replete with problem sets and a solutions manual for instructors, this textbook is recommended for undergraduate and graduate students in chemical engineering and polymer and materials engineering and science. It will also prove invaluable for industry professionals as a fundamental polymer processing analysis and synthesis reference.
Download or read book Principles of Polymer Systems written by Ferdinand Rodriguez and published by CRC Press. This book was released on 2014-12-09 with total page 796 pages. Available in PDF, EPUB and Kindle. Book excerpt: A classic text in the field of chemical engineering, this revised sixth edition offers a comprehensive exploration of polymers at a level geared toward upper-level undergraduates and beginning graduate students. It contains more theoretical background for some of the fundamental concepts pertaining to polymer structure and behavior, while also providing an up-to-date discussion of the latest developments in polymerization systems. New problems have been added to several of the chapters, and a solutions manual is available upon qualifying course adoption.
Download or read book Optical Rheometry of Complex Fluids written by Gerald G. Fuller and published by Oxford University Press. This book was released on 1995-06-29 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a self-contained presentation of optical methods used to measure the structure and dynamics of complex fluids subject to the influence of external fields. Such fields--hydrodynamic, electric, and magnetic--are commonly encountered in both academic and industrial research, and can produce profound changes in the microscale properties of liquids comprised of polymers, colloids, liquid crystals, or surfactants. Starting with the basic Maxwell field equations, this book discusses the polarization properties of light, including Jones and Mueller calculus, and then covers the transmission, reflection, and scattering of light in anisotropic materials. Spectroscopic interactions with oriented systems such as absorptive dichroism, small wide angle light scattering, and Raman scattering are discussed. Applications of these methods to a wide range of problems in complex fluid dynamics and structure are presented, along with selected case studies chosen to elucidate the range of techniques and materials that can be studied. As the only book of its kind to present a self-contained description of optical methods used for the full range of complex fluids, this work will be special interest to a wide range of readers, including chemical engineers, physical chemists, physicists, polymer and colloid scientists, along with graduate and post-graduate researchers.
Download or read book Handbook of Advanced Materials Testing written by Louise Ferrante and published by CRC Press. This book was released on 1994-11-29 with total page 1036 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work discusses techniques for developing new engineering materials such as elastomers, plastic blends, composites, ceramics and high-temperature alloys. Instrumentation for evaluating their properties and identifying potential end uses are presented.;The book is intended for materials, manufacturing, mechanical, chemical and metallurgical engi
Download or read book Material Identification Using Mixed Numerical Experimental Methods written by Hugo Sol and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: Euromech 357 took place in the nice authentic monastery 'Rolduc' in Kerkrade, Holland. The objective was to bring together researchers to present their latest advancements in the relatively new domain of Material properties identification by Mixed Numerical Experimental Methods (MMM). MMM are a modem and increasingly powerful way to determine the values of unknown parameters in a numerical model by observations made on real physical test structures. Starting from the measurement of output values (like displacements, stresses, velocities, vibrations, .. ) of the real physical test structure, MMM try to update parameters in the numerical model in such a way that the computed observations match the experimental observations. It was shown clearly at the colloquium that the combined use of numerical analysing tools and sophisticated measurement techniques has created an extra degree of freedom for the design of experiments and has led to new approaches for material characterisation. The colloquium was attended by 39 participants coming from 12 different European countries. We had 23 oral presentations on the different topics of the above mentioned sessions. Each presentation was followed by an intensive discussion. Du~ to the informal atmosphere and the limited number of participants, the discussions were very lively and fruitful. The opportunity to continue to discuss common problems after dinner in a reserved place was also offered to the Euromech participants. This opportunity and the fact that the monastery was isolated (nobody could escape!) created an excellent platform for discussions and personal contacts.
Download or read book Thermoplastic Melt Rheology and Processing written by Aroon Shenoy and published by CRC Press. This book was released on 1996-08-23 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents rheological data on a number of polymers, making use of the master curve approach to determine unified curves for each generic type of polymer. The text offers a step-by-step procedure for developing a speadsheet computer program to obtain accurate thermoplastic rheograms at any tempertature without using sophisticated rheometres. It inclu
Download or read book The Mesoscopic Theory of Polymer Dynamics written by Vladimir N. Pokrovskii and published by Springer Science & Business Media. This book was released on 2009-12-16 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: The theory presented in this book explains in a consistent manner all dynamics effects observed in very concentrated solutions and melts of linear polymers from a macromolecular point of view. The presentation is compact and self-contained.
Download or read book Crystallization Modalities in Polymer Melt Processing written by Hermann Janeschitz-Kriegl and published by Springer Science & Business Media. This book was released on 2009-09-18 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure formation in crystallizing polymers, as occurring during processing, has not been treated so far in a coherent form. This fact explains, why this monograph is written as the ?rst book devoted to this subject. A quarter of a century ago the underdevelopment of this subject was obvious. Trial and error dominated. In fact, other apposite subjects as polymer melt rheology or heat transfer, had reached high levels. A great number of books has been devoted to them. Mold ?lling of amorphous polymers and the solidi?cation of these polymers by vitri?cation can nowadays be simulated numerically with a high degree of accuracy. In the solidi?ed sample even residual stresses and corresponding birefringence effects can accurately be 1 calculated . However, semicrystalline polymers, which form the majority of industrial po- mers, have been excluded from these considerations for good reasons. In fact, great uncertainties existed about the formation of quality determining crystalline str- tures. In particular, polyole?ns suffered from this shortcoming. In 1983 this fact instigated the polymer research group at the Johannes Kepler University in Linz to start with pertinent activities. The urgency of this kind of studies becomes evident, if advantages and hitches of these polymers are considered. 1. Versatility of processing: Injection molding into a great variety of shapes and sizes, from thin walled beakers to garden chairs, not to forget pipe and pro?le extrusion, cable coating, ?ber spinning, ?lm blowing. 2. Product qualities: Ductility, low density, good electric insulation, corrosion resistance, surface quality.
