Download or read book PHYSICOCHEMICAL PROPERTIES OF ATMOSPHERIC AEROSOLS AND THEIR EFFECT ON ICE CLOUD FORMATION written by and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract : Atmospheric aerosols play a vital role in the Earth's energy budget-directly by scattering and absorbing solar radiation and indirectly by acting as cloud condensation nuclei and ice-nucleating particles [1, 2]. The cloud formation potential of aerosol is driven by multiple factors, including surface properties, size distribution, composition, mixing state, phase state, and morphology [3]. The interaction of aerosols with clouds alters the aerosol's physicochemical properties. Those properties can also evolve during transport due to atmospheric processing, in turn, affect the aerosol's ice nucleation and cloud formation activities. This thesis presents experimental studies to understand the role of physicochemical properties of aerosol on the formation of ice. To get a detailed understanding of the aerosol effect on ice nucleation, we conducted controlled ice nucleation experiments on a known surface (muscovite mica) with controlled properties (e.g., surface cations) as well as ice nucleation experiments on complex atmospheric particles, which were characterized with multimodal microspectroscopic techniques. The results from controlled experiments suggest that the ice nucleation activity of a surface can be modified by simply changing the surface cations. In contrast, ice nucleation experiments with complex atmospheric particles indicates a more complicated dependence on the physicochemical properties.
Download or read book Atmospheric Aerosol Properties written by Kirill Ya. Kondratyev and published by Springer Science & Business Media. This book was released on 2006-08-29 with total page 595 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the first comprehensive analysis of how aerosols form in the atmosphere through in situ processes as well as via transport from the surface (dust storms, seas spray, biogenic emissions, forest fires etc.). Such an analysis has been followed by the consideration of both observation data (various field observational experiments) and numerical modeling results to assess climate impacts of aerosols bearing in mind that these impacts are the most significant uncertainty in studying natural and anthropogenic causes of climate change.
Download or read book Atmospheric Aerosols written by Hayder Abdul-Razzak and published by BoD – Books on Demand. This book was released on 2012-09-12 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is divided into two sections. The first section presents characterization of atmospheric aerosols and their impact on regional climate from East Asia to the Pacific. Ground-based, air-born, and satellite data were collected and analyzed. Detailed information about measurement techniques and atmospheric conditions were provided as well. In the second section, authors provide detailed information about the organic and inorganic constituents of atmospheric aerosols. They discuss the chemical and physical processes, temporal and spatial distribution, emissions, formation, and transportation of aerosol particles. In addition, new measurement techniques are introduced. This book hopes to serve as a useful resource to resolve some of the issues associated with the complex nature of the interaction between atmospheric aerosols and climatology.
Download or read book Atmospheric Aerosol Properties written by Kirill Ya. Kondratyev and published by Springer. This book was released on 2005-11-10 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the first comprehensive analysis of how aerosols form in the atmosphere through in situ processes as well as via transport from the surface (dust storms, seas spray, biogenic emissions, forest fires etc.). Such an analysis has been followed by the consideration of both observation data (various field observational experiments) and numerical modeling results to assess climate impacts of aerosols bearing in mind that these impacts are the most significant uncertainty in studying natural and anthropogenic causes of climate change.
Download or read book Aerosols and Atmospheric Chemistry written by Milton Kerker and published by Elsevier. This book was released on 2012-12-02 with total page 367 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosols and Atmospheric Chemistry is a collection of papers presented at the American Chemical Society Kendall Award Symposium honoring Professor Milton Kerker, held in Los Angeles, California, on March 28-April 2, 1971. Contributors focus on the physical chemistry of aerosols and their relationship to atmospheric chemistry. Topics covered range from the optical and dynamical properties of aerosols to the kinetics of growth of an aerosol in a flow reactor. The formation and chemical reactions of atmospheric particles are also discussed. This book is comprised of 30 chapters and begins with an overview of some of the optical and dynamical properties of aerosols, along with the preparation of submicron aerosols by condensation. The discussion then turns to the formation and properties of neutral ultrafine particles and small ions conditioned by gaseous impurities of the air; preparation of ultrafine metal oxide particles in a hydrogen-oxygen flame; production of aerosols by X-rays; and condensational growth of atmospheric aerosols. A comparison of synthetic and smog aerosols is also presented. The final section is devoted to the Los Angeles (Pasadena) Smog Project—its genesis, objectives, and scope—and provides a detailed description of the Minnesota Aerosol Analyzing System used in the project. This monograph will be a useful resource for chemists as well as students and researchers interested in aerosol and atmospheric chemistry.
Download or read book Regional studies of the optical chemical and microphysical properties of atmospheric aerosols written by Admir Crésio Targino and published by . This book was released on 2005 with total page 55 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Aerosol Pollution Impact on Precipitation written by Zev Levin and published by Springer Science & Business Media. This book was released on 2008-09-30 with total page 399 pages. Available in PDF, EPUB and Kindle. Book excerpt: Life on Earth is critically dependent upon the continuous cycling of water between oceans, continents and the atmosphere. Precipitation (including rain, snow, and hail) is the primary mechanism for transporting water from the atmosphere back to the Earth’s surface. It is also the key physical process that links aspects of climate, weather, and the global hydrological cycle. Changes in precipitation regimes and the frequency of extreme weather events, such as floods, droughts, severe ice/snow storms, monsoon fluctuations and hurricanes are of great potential importance to life on the planet. One of the factors that could contribute to precipitation modification is aerosol pollution from various sources such as urban air pollution and biomass burning. Natural and anthropogenic changes in atmospheric aerosols might have important implications for precipitation by influencing the hydrological cycle, which in turn could feed back to climate changes. From an Earth Science perspective, a key question is how changes expected in climate will translate into changes in the hydrological cycle, and what trends may be expected in the future. We require a much better understanding and hence predictive capability of the moisture and energy storages and exchanges among the Earth’s atmosphere, oceans, continents and biological systems. This book is a review of our knowledge of the relationship between aerosols and precipitation reaching the Earth's surface and it includes a list of recommendations that could help to advance our knowledge in this area.
Download or read book An Introduction to Clouds written by Ulrike Lohmann and published by Cambridge University Press. This book was released on 2016-06-23 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to Clouds provides a fundamental understanding of clouds, ranging from cloud microphysics to the large-scale impacts of clouds on climate. On the microscale, phase changes and ice nucleation are covered comprehensively, including aerosol particles and thermodynamics relevant for the formation of clouds and precipitation. At larger scales, cloud dynamics, mid-latitude storms and tropical cyclones are discussed leading to the role of clouds on the hydrological cycle and climate. Each chapter ends with problem sets and multiple-choice questions that can be completed online, and important equations are highlighted in boxes for ease of reference. Combining mathematical formulations with qualitative explanations of underlying concepts, this accessible book requires relatively little previous knowledge, making it ideal for advanced undergraduate and graduate students in atmospheric science, environmental sciences and related disciplines.
Download or read book Atmospheric Aerosols Their Optical Properties and Effects written by and published by . This book was released on 1976 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Final Technical Report for Award SC0008613 written by and published by . This book was released on 2017 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discovering how aerosol particles, present in the atmosphere in sizes of a few nanometers to hundred micrometers, initiate ice crystal formation represents a great challenge. Atmospheric ice nucleation is important because ice crystals alter the radiative properties of clouds and thus climate, and impact precipitation and thus the hydrological cycle. The difficulty in predicting atmospheric ice formation is attributable at least in part, to the diversity of ice nucleation pathways, the physical and chemical complexity of the ice nucleating particles (INPs), and the relatively small numbers of INPs (compared with all other aerosol particles), sometimes less than one in 100000. These factors in turn makes constraining ice nucleation parameterizations for modeling applications challenging. The majority of airborne particles are known to be organic in nature or contain organic biogenic material. The presence of organic material adds to the complexity of the particles and therefore the predictability of ice nucleation events since the organic species can display different phase states, e.g. liquid or solid, in response to temperature and humidity. The award DE-SC0008613 to PI Prof. Daniel Knopf at Stony Brook University, "Relating the Chemical and Physical Properties of Aerosols to the Water Uptake and Ice Nucleation Potential of Particles Collected During the Carbonaceous Aerosols and Radiative Effects Study (CARES)", allowed examination of laboratory generated aerosol particles and field-collected particles for their propensity to nucleate ice under typical tropospheric conditions and relate ice nucleation to the physicochemical properties of the particles including their morphology and chemical composition. This in turn allowed for development of ice nucleation parameterizations for implementation in cloud models. The award resulted in 10 peer-reviewed publications and more than 20 seminar and conference presentations. We demonstrated that the rate of immersion freezing, when a particle immersed in an aqueous droplet acts as an ice nucleus (IN), can be predicted by knowledge of the IN particle type present and the droplet's water activity which is equal to ambient relative humidity. Our water activity based immersion freezing model is successful in predicting freezing data including INPs such as mineral dusts, marine biological material, organic species, and surfactant molecules. Its mathematical simplicity makes it an ideal candidate for implementation in cloud and climate models. Furthermore, we could show that this model can reproduce many past laboratory measurements which were generated using a variety of instruments to study immersion freezing. Lastly, we have demonstrated that this model can also be applied to field collected particles. Currently, this novel physical parameterization of immersion freezing is being implemented in a cloud model. We examined the physicochemical properties and the ice nucleation potential of particles collected during CARES applying a novel experimental method that allows identification of the individual INPs within a large population of particles sampled from an ambient environment. Taking advantage of a variety of micro-spectroscopic techniques, we characterized the composition and morphology of IN and non-IN particles present in the airborne population. We developed a new parameterization for quantifying the mixing state of the entire aerosol populations by introducing a mixing state index. We found that the identified INPs belong to the most common particle-type classes observed in the CARES field samples and as such are not special or rare particles. In other words, the INPs can be shown not to be unique in contrast to the common paradigm of being rare and exceptional. Either there are differences between particles acting as IN and particles not acting as IN which are beyond our current detection limit or nucleation occurs randomly on the surface of any one of these compositionally eq ...
Download or read book Atmospheric Aerosols and Nucleation written by Paul E. Wagner and published by Springer. This book was released on 1988 with total page 764 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings give a rather complete overview of the most recent research in the areas of fundamental processes and phase transitions, cloud droplet and ice nucleation in the atmosphere, and aerosol formation and aerosol characteristics in the atmosphere. Nine review papers on topics of special importance are supplemented by about 200 summaries on topics of greatest current importance. The volume should be of interest to scientists working in the atmospheric and environmental sciences, in chemistry and in physics, as well as to engineers working in these areas.
Download or read book Atmospheric Aerosols written by Olivier Boucher and published by Springer. This book was released on 2015-05-18 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook aims to be a one stop shop for those interested in aerosols and their impact on the climate system. It starts with some fundamentals on atmospheric aerosols, atmospheric radiation and cloud physics, then goes into techniques used for in-situ and remote sensing measurements of aerosols, data assimilation, and discusses aerosol-radiation interactions, aerosol-cloud interactions and the multiple impacts of aerosols on the climate system. The book aims to engage those interested in aerosols and their impacts on the climate system: graduate and PhD students, but also post-doctorate fellows who are new to the field or would like to broaden their knowledge. The book includes exercises at the end of most chapters. Atmospheric aerosols are small (microscopic) particles in suspension in the atmosphere, which play multiple roles in the climate system. They interact with the energy budget through scattering and absorption of solar and terrestrial radiation. They also serve as cloud condensation and ice nuclei with impacts on the formation, evolution and properties of clouds. Finally aerosols also interact with some biogeochemical cycles. Anthropogenic emissions of aerosols are responsible for a cooling effect that has masked part of the warming due to the increased greenhouse effect since pre-industrial time. Natural aerosols also respond to climate changes as shown by observations of past climates and modelling of the future climate.
Download or read book Chemical and Physical Properties of Atmospheric Aerosols a a Case Study in the Unique Properties of Agricultural Aerosols b the Role of Chemical Composition in Ice Nucleation During the Arctic Spring written by Seong-Gi Moon and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This study focuses on the analysis of atmospheric particles sampled from two different field campaigns: the field study at a cattle feeding facility in the summer from 2005 to 2008 and the Indirect and Semi-Direct Aerosol Campaign (ISDAC) in 2008. A ground site field study at a representative large cattle feeding facility in the Texas Panhandle was conducted to characterize the particle size distributions, hygroscopicity, and chemical composition of agricultural aerosols. Here, a first comprehensive dataset is reported for these physical and chemical properties of agricultural aerosols appropriate for use in a site-specific emission inventory. The emission rate and transport of the aerosols are also discussed. In addition, mixing ratios of total and gaseous ammonia were measured at the same field in 2007 and 2008. Measurements such as these provide a means to determine whether the fugitive dust emitted from a typical large feedlot represents a health concern for employees of the feeding operation and the nearby community. Detailed chemical composition of aircraft-sampled particles collected during ISDAC was studied. Filter samples were collected under a variety of conditions in and out of mixed phase and ice clouds in the Arctic. Specifically, particles were sampled from a mixed-phase cloud during a period of observed high concentrations of ice nuclei (IN), a biomass plume, and under relatively clean ambient conditions. Composition of particles was studied on a particle-by-particle basis using several microspectroscopy techniques. Based on the elemental composition analysis, more magnesium was found in Arctic cloud residues relative to ambient air. Likewise, based on the carbon speciation analysis, high IN samples contained coated inorganics, carbonate, and black or brown carbon particles. In the samples collected during a flight through a biomass burning plume, water-soluble organic carbon was the dominant overall composition. Due to their hygroscopic nature, these organics may preferably act as cloud condensation nuclei (CCN) rather than IN. Other ambient samples contained relatively higher fractions of organic and inorganic mixtures and less purely water-soluble organics than found in the biomass particles. The most likely source of inorganics would be sea salt. When present, sea salt may further enhance ice nucleation.
Download or read book Atmospheric Aerosols written by S Ramachandran and published by CRC Press. This book was released on 2018-09-03 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book includes basic knowledge and understanding on the characteristics of aerosols over the continent and oceanic regions, their composition, residence times, sinks and size distributions, and their effects in the radiative transfer and climate of Earth.
Download or read book Towards an Understanding of the Cloud Formation Potential of Carbonaceous Aerosol written by Luz Teresa Padro Martinez and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: It is well known that atmospheric aerosols provide the sites for forming cloud droplets, and can affect the Earth's radiation budget through their interactions with clouds. The ability of aerosols to act as cloud condensation nuclei is a strong function of their chemical composition and size. The compositional complexity of aerosol prohibits their explicit treatment in atmospheric models of aerosol-cloud interactions. Nevertheless, the cumulative impact of organics on CCN activity is still required, as carbonaceous material can constitute up to 90% of the total aerosol, 10-70% of which is water soluble. Therefore it is necessary to characterize the water soluble organic carbon fraction by CCN activation, droplet growth kinetics, and surface tension measurements. In this thesis, we investigate the water soluble properties, such as surface tension, solubility, and molecular weight, of laboratory and ambient aerosols and their effect on CCN formation. A mechanism called Curvature Enhanced Solubility is proposed and shown to explain the apparent increased solubility of organics. A new method, called Köhler Theory Analysis, which is completely new, fast, and uses minimal amount of sample was developed to infer the molar volume (or molar mass) of organics. Due to the success of the technique in predicting the molar volume of laboratory samples, it was applied to aerosols collected in Mexico City. Additionally the surface tension, CCN activity, and droplet growth kinetics of these urban polluted aerosols were investigated. Studies performed for the water soluble components showed that the aerosols in Mexico City have surfactants present, can readily become CCN, and have growth similar to ammonium sulfate. Finally, aerosols from three different polluted sources, urban, bovine, and ship emissions, were collected and characterized. The data assembled was used to predict CCN concentrations and access our understanding of the system. From these analyses, it was evident that knowledge of the chemical composition and mixing state of the aerosol is necessary to achieve agreement between observations and predictions. The data obtained in this thesis can be introduced and used as constraints in aerosol-cloud interaction parameterizations developed for global climate models, which could lead to improvements in the indirect effect of aerosols.
Download or read book Atmospheric Aerosol Chemistry written by Hind A. Al-Abadleh and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-04-19 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosols are an important and a highly complex component of the Earth’s atmosphere that alter the radiative forcing and the chemical composition of the gas phase. These effects have impacts on local air quality and the global climate. Atmospheric Aerosol Chemistry outlines research findings to date in aerosol chemistry and advances in analytical tools used in laboratory settings for studying their surface and bulk reactivity.
Download or read book Chemistry of Atmospheric Aerosol Particles and Their Resulting Warm Cloud nucleation Properties written by Meagan Julia Kerry Moore and published by . This book was released on 2011 with total page 281 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosol particles are a major component of the troposphere and affect regional and global atmospheric chemistry and climate. The size and chemistry of these particles influences the warm and cold cloud nucleation ability and optical properties of the aerosol particles. This dissertation investigates the atmospheric chemistry of aerosol particles and their role in warm cloud nucleation through a combination of laboratory experiments and field measurements. The effect of organics on the cloud condensation nuclei (CCN) activity of sea spray aerosols is described in Chapter 2. Sea spray aerosol produced by bubbling solutions composed of simplistic mixtures of NaCl and oleic acid or SDS had a significant effect on CCN activity, even in very small amounts; while artificial seawater solutions containing microorganisms, the common cyanobacteria (Synechococcus) and DMS-producing green algae (Ostreococcus), produced particles containing ~34 times more carbon than the particles produced from pure ASW, with no significant change observed in the overall CCN activity. During the fall of 2007 and 2008, over 300,000 acres burned in San Diego County wildfires. The resulting particle chemistry and estimated hygroscopicity during these wildfire events are explored in Chapter 3. The contribution of wildfire emissions were much larger and played a more significant role in affecting cloud condensation nuclei and total particle concentrations in 2007 than in 2008. The overall particle hygroscopicity during the biomass burning dominated periods was very similar; however in 2008, the particle hygroscopicity was dominated by local sources rather than biomass burning, due to the much smaller particle size mode. Owens Lake is one of the largest sources of PM2.5 in the Western Hemisphere, producing highly soluble dust plumes, and therefore there is great potential for those particles to impact cloud formation and possibly precipitation in the region. Chapter 4 explores particle chemistry and estimated hygroscopicity at Owens Lake. No significant change in particle hygroscopicity or CCN activity occurred concurrently with the change in mixing of particle classes during two different dust events at Owens Lake; indicating that the large dust particles were most likely completely CCN active and the smaller particles are likely dictating the hygroscopicity, as most of the dust particles are large enough and would activate to become CCN regardless of their hygroscopicity. The Cloud Indirect Forcing Experiment (CIFEX) took place to study the influence of aerosols on cloud properties at Trinidad Head, a coastal site in northern California representing clean marine air with periodic long-range transport. Chapters 5 & 6 explore particle chemistry, mixing state, optical properties and estimated hygroscopicity during CIFEX. Our measurements demonstrate how changes in hygroscopicity and optical properties evolve over time in the atmosphere as a function of particle chemistry and the mixing state of the aerosol. Two distinct oxalate events with enrichment of oxalate on different particle types and sizes suggest two separate sources of oxalate.
