Download or read book Physico Chemical Modifications of Block Copolymers and Their Gels for Enhanced Functionality written by Jiaqi Yan and published by . This book was released on 2021 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Physico chemical Studies of Block Copolymers in Aqueous Solution written by Jonathan Keith Armstrong and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Biodegradable Thermogels written by Xian Jun Loh and published by Royal Society of Chemistry. This book was released on 2018-09-27 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biodegradable thermogels are a promising class of stimuli-responsive polymers. This book summarizes recent developments in thermogel research with a focus on synthesis and self-assembly mechanisms, gel biodegradability, and applications for drug delivery, cell encapsulation and tissue engineering. A closing chapter on commercialisation shows the challenges faced bringing this new material to market. Edited by leading authorities on the subject, this book offers a comprehensive overview for academics and professionals across polymer science, materials science and biomedical and chemical engineering.
Download or read book Synthesis and Characterization of Ionically Bonded Diblock Copolymers written by Lei Feng (Chemical engineer) and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Block copolymers consist of two or more incompatible polymer chains linked by covalent bonds. These block copolymer can separate into nanometer sized domains whose morphology depends upon the size of the block and interactions between them. The properties of block copolymers can be modified and potentially improved by introducing noncovalent interactions to replace covalent linkages between blocks to form supramolecular block copolymers. These kinds of materials combine the microphase separation inherent to block copolymers with the facile synthesis of supramolecular materials thereby affording new and unique materials. This dissertation focuses on synthesis and characterization of PS-b-PMA block copolymers with ion-pair junctions.Firstly, the chain-end sulfonated polystyrene ([omega]-sulfonated PS) was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization and postpolymerization modification. In the postpolymerization modification two methods were investigated: in the first one, the polymer was converted to a thiol-terminated polymer by aminolysis. Then a sulfonic acid end-group was produced then by oxidation of the thiol end-group with m-chloroperoxybenzoicacid (m-CPBA); in the second method, the RAFT-polymerized polymer was directly sulfonated by oxidation with m-CPBA. After purification by column chromatography, [omega]-sulfonated PS was obtained by both methods with greater than 95% end-group functionality as measured by titration. The sulfonic acid end-group could be neutralized with various ammonium or imidazolium counter ions through acid-base or ionic metathesis reactions. These polymers with ionic end-group can be used as model supramolecular building blocks.Secondly, ammonium end functionalized polymethylacrylate (PMA) was synthesized directly by RAFT polymerization using functional RAFT agent. Then chain-end sulfonated polystyrene and ammonium end functionalized polymethylacrylate (PMA) were used to synthesize A-B block copolymers by two different methods: the first method was by mixing two oppositely charged end group functionalized polymers; the second method was to ionically bond a RAFT agent to the chain end of an end sulfonated polymer to generate a supramolecular macro RAFT agent then an A-B block copolymer was prepared by RAFT polymerization using supramolecular macro-RAFT agent. The polymerization kinetics were investigated and the molecular weight and the chemical structure of the block copolymers were characterized by 1H-NMR and SEC. The results show that the ion-bonded supramolecular block copolymer, PS-PMA, have been successfully prepared with controlled molecular weight and narrow distribution.Thirdly, the morphology of the ion-bonded supramolecular PS-PMA diblock copolymers were investigated by small-angle X-ray scattering (SAXS) and rheological techniques. Several covalently bonded PS-PMA block copolymers were synthesized by RAFT polymerization and their micro domain structures and rheology behaviors were also investigated. The results showed that the electrostatic interactions between the end ion groups are able to overcome the thermodynamic repulsion of two blocks result in the formation of diblock copolymers with similar behaviors and morphology of traditional covalent bonded diblock copolymers and their micro domain structures remain to high temperatures.
Download or read book Stimuli Responsive Gels written by Dirk Kuckling and published by MDPI. This book was released on 2018-10-11 with total page 289 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Stimuli-Responsive Gels" that was published in Gels
Download or read book Novel Fluorinated Block Copolymers by Selective Chemical Modification written by Drew Alan Davidock and published by . This book was released on 2004 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synthesis and Applications of Copolymers written by Anbanandam Parthiban and published by John Wiley & Sons. This book was released on 2014-06-23 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the reactivity of monomers is crucial in creating copolymers and determining the outcome of copolymerization. Covering the fundamental aspects of polymerization, Synthesis and Applications of Copolymers explores the reactivity of monomers and reaction conditions that ensure that the newly formed polymeric materials exhibit desired properties. Referencing a wide-range of disciplines, the book provides researchers, students, and scientists with the preparation of a diverse variety of copolymers and their recent developments, with a particular focus on copolymerization, crystallization, and techniques like nanoimprinting and micropatterning.
Download or read book Self Healing Polymers written by Wolfgang H. Binder and published by John Wiley & Sons. This book was released on 2013-03-29 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.
Download or read book Hydrogels written by Thakur Raghu Raj Singh and published by CRC Press. This book was released on 2018-02-28 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogels are crosslinked, macromolecular polymeric materials arranged in a three-dimensional network, which can absorb and retain large amounts of water. Hydrogels are commonly used in clinical practice and experimental medicine for a wide range of applications, including drug delivery, tissue engineering and regenerative medicine, diagnostics, cellular immobilization, separation of biomolecules or cells, and barrier materials to regulate biological adhesions. This book elucidates the underlying concepts and emerging applications of hydrogels and will provide key case studies and critical analysis of the existing research.
Download or read book Metal Catalysts in Olefin Polymerization written by Zhibin Guan and published by Springer Science & Business Media. This book was released on 2009-03-31 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
Download or read book Disordered Pharmaceutical Materials written by Marc Descamps and published by John Wiley & Sons. This book was released on 2016-03-28 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: A one-stop resource for researchers, developers, and post graduate students in pharmaceutical science. This handbook and ready reference provides detailed, but not overloaded information -- presenting the topic without unnecessarily complex formalism. As such, it gives a systematic and coherent overview of disordered materials for pharmaceutical applications, covering fundamental aspects, as well as preparation and characterization techniques for the target-oriented development of drug delivery systems based on disordered crystals and amorphous solids. Special attention is paid to examine the different facets and levels of disorder in their structural and dynamic aspects as well as the effect of disorder on dissolution and stability. Chapters on processing induced disorder and on patenting issues round off the book. As a result the book helps overcoming the challenges of using these materials in the pharmaceutical industry. For pharmaceutical and medicinal chemists, materials scientists, clinical physicists, and pharmaceutical laboratories looking to make better and more potent pharmaceuticals.
Download or read book Polymer Synthesis written by Elaheh Kowsari and published by . This book was released on 2011-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an overview of research on advanced synthesis polymers over the past decade. This special issue, contributed by various authors, focuses on recent advances of the field, which handle the cutting-edge aspects of the advanced technology. The contributions in these twelve chapters summarise some major efforts in this area.
Download or read book Chemical Modification of Temperature sensitive Pluronic Block Copolymers and Their Aggregation Properties written by Xiangyuan Xiong and published by . This book was released on 2005 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Poly lactic acid written by Rafael A. Auras and published by John Wiley & Sons. This book was released on 2022-06-21 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt: POLY(LACTIC ACID) The second edition of a key reference, fully updated to reflect new research and applications Poly(lactic acid)s – PLAs, biodegradable polymers derived from lactic acid, have become vital components of a sustainable society. Eco-friendly PLA polymers are used in numerous industrial applications ranging from packaging to medical implants and to wastewater treatment. The global PLA market is predicted to expand significantly over the next decade due to increasing demand for compostable and recyclable materials produced from renewable resources. Poly(lactic acid) Synthesis, Structures, Properties, Processing, Applications, and End of Life provides comprehensive coverage of the basic chemistry, production, and industrial use of PLA. Contributions from an international panel of experts review specific processing methods, characterization techniques, and various applications in medicine, textiles, packaging, and environmental engineering. Now in its second edition, this fully up-to-date volume features new and revised chapters on 3D printing, the mechanical and chemical recycling of PLA, PLA stereocomplex crystals, PLA composites, the environmental footprint of PLA, and more. Highlights the biodegradability, recycling, and sustainability benefits of PLA Describes processing and conversion technologies for PLA, such as injection molding, extrusion, blending, and thermoforming Covers various aspects of lactic acid/lactide monomers, including physicochemical properties and production Examines different condensation reactions and modification strategies for enhanced polymerization of PLA Discusses the thermal, rheological, and mechanical properties of PLA Addresses degradation and environmental issues of PLA, including photodegradation, radiolysis, hydrolytic degradation, biodegradation, and life cycle assessment Poly(lactic acid) Synthesis, Structures, Properties, Processing, Applications, and End of Life, Second Edition remains essential reading for polymer engineers, materials scientists, polymer chemists, chemical engineers, industry professionals using PLA, and scientists and advanced student engineers interested in biodegradable plastics.
Download or read book Polysaccharides written by Severian Dumitriu and published by CRC Press. This book was released on 2004-11-30 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Completely revised and expanded to reflect the latest advancements in the field, Polysaccharides: Structural Diversity and Functional Versatility, Second Edition outlines fundamental concepts in the structure, function, chemistry, and stability of polysaccharides and reveals new analytical techniques and applications currently impacting the cosmeti
Download or read book Progress in Adhesion and Adhesives written by K. L. Mittal and published by John Wiley & Sons. This book was released on 2015-07-27 with total page 515 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is based on the 13 review articles written by subject experts and published in 2014 in the Journal Reviews of Adhesion and Adhesives. The rationale for publication of this book is that currently the RAA has limited circulation, so this book provides broad exposure and dissemination of the concise, critical, illuminating, and thought-provoking review articles. The subjects of the reviews fall into 4 general areas: 1. Polymer surface modification 2. Biomedical, pharmaceutical and dental fields 3. Adhesives and adhesive joints 4. General Adhesion Aspects The topics covered include: Adhesion of condensed bodies at microscale; imparting adhesion property to silicone material; functionally graded adhesively bonded joints; synthetic adhesives for wood panels; adhesion theories in wood adhesive bonding; adhesion and surface issues in biocomposites and bionanocomposites; adhesion phenomena in pharmaceutical products and applications of AFM; cyanoacrylate adhesives in surgical applications; ways to generate monosort functionalized polyolefin surfaces; nano-enhanced adhesives; bonding dissimilar materials in dentistry; flame treatment of polymeric materials—relevance to adhesion; and mucoadhesive polymers for enhancing retention of ocular drug delivery.
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
