Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by John Wiley & Sons. This book was released on 2002-08-16 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)

Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Download or read book Organic Synthesis by Means of Transition Metal Complexes written by Jiro Tsuji and published by Springer. This book was released on 1975-11 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more comprehensively in the form of a monograph. Organometallic chemistry is a rapidly growing field of intensive research. In this field, the application of organometallic compounds to organic synthesis is an important subject and many unique synthetic methods have been discovered, especially in the last decade. Syntheses using transition-metal com pounds are now in the foreground of organic chemistry. The purpose of this monograph is to give a bird's-eye view of this field to both organic and inorganic chemists through a mechanistic approach. A systematic unification of the voluminous data accumulated in this field is now urgently required. This subject is discussed by classifying various reactions into general patterns and by illustrating them with a limited number of pertinent examples.

Download or read book Organic Synthesis by Means of Transition Metal Complexes written by Jiro Tsuji and published by Springer. This book was released on 1975 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1970 I wrote a review article for "Topics in Current Chemistry", surveying the general reaction patterns of transition-metal complexes from the standpoint of organic synthesis. The article seems to have evoked wide interest, and I therefore thought it appropriate to treat the subject more comprehensively in the form of a monograph. Organometallic chemistry is a rapidly growing field of intensive research. In this field, the application of organometallic compounds to organic synthesis is an important subject and many unique synthetic methods have been discovered, especially in the last decade. Syntheses using transition-metal com pounds are now in the foreground of organic chemistry. The purpose of this monograph is to give a bird's-eye view of this field to both organic and inorganic chemists through a mechanistic approach. A systematic unification of the voluminous data accumulated in this field is now urgently required. This subject is discussed by classifying various reactions into general patterns and by illustrating them with a limited number of pertinent examples.

Download or read book Transition Metal Arene P Complexes in Organic Synthesis and Catalysis written by E.P. Kündig and published by Springer Science & Business Media. This book was released on 2004-06-21 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï⿬ by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students

Download or read book Organic Synthesis by Means of Transition Metal Complexes written by Jiro Tsuji and published by Springer. This book was released on 1975 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Organometallic Chemistry written by R. C. Mehrotra and published by New Age International. This book was released on 2007 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Is A Revised Edition Of A Lucid And Stimulating Introductory Account Of Organometallic Chemistry, An Exciting And Rapidly Developing Interdisciplinary Branch Of Science.A Characteristic Feature Of This Book Is The Presentation Of An Integrated (Covering Different Facets Usually Dealt With Either In Organic Or/And Inorganic Texts) View Of The Rapidly Developing Field Of Organometallic Chemistry. Attempts Have Been Made To Choose The Latest Examples To Illustrate The Fundamental Properties As Well As The Synthetic Procedures Of Organometallic Chemistry. Other Features Include: (A) An Interesting Brief Historical Background Of The Subject Including Some Quotations From Relevant Nobel Lecture Accounts Of Epoch Making Advances By The Discoverers Themselves, (B) The Adoption As Far As Possible Of The Iupac Rules Of Nomenclature, (C) A Brief Account Of The Rapidly Emerging Organometallic Chemistry Of The F-Elements, And (D) Inclusion Of Study Questions At The End Of Each Chapter.During The Revision Of The Book, The Latest Examples Have Replaced The Older Ones Wherever Feasible. The Book Would Be Extremely Useful As A Basic Text For B.Sc. (Hons.) And M.Sc. Chemistry Students.

Download or read book Organic Synthesis Using Transition Metals written by Roderick Bates and published by John Wiley & Sons. This book was released on 2012-04-30 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Download or read book Organomercury Compounds in Organic Synthesis written by R.C. Larock and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal Complexes" was reviewed in the first volume of this series of monographs. This volume deals primarily with the appli cation of organomercury compounds in organic synthesis (exclusive of solvomercuration-demercuration reactions), but will of necessity involve a number of reactions of other organometallics as well. Organomercurials are among the oldest known organo metallics and were perhaps the first to have an entire book devoted to their chemistry, when Whitmore wrote an American Chemical Society monograph on the subject in 1921. Subsequently, two very detailed monographs on the subject have appeared. In 1967 "The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry" appeared and this was followed in 1974 by Houben Weyl's full volume, Band XIII/2b, devoted entirely to the organometallic compounds of mercury. These books cover the entire field of organomercury chemistry.

Download or read book Sustainable Synthesis of Pharmaceuticals written by Mariette M. Pereira and published by Royal Society of Chemistry. This book was released on 2018-03-26 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Zinc Catalysis written by Stephan Enthaler and published by John Wiley & Sons. This book was released on 2015-04-27 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Download or read book Molecular Orbitals of Transition Metal Complexes written by Yves Jean and published by Oxford University Press. This book was released on 2005-03-24 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.

Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2011-09-20 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: "One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.

Download or read book Transition metal Organometallics In Organic Synthesis written by Howard Alper and published by Elsevier. This book was released on 2012-12-02 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Download or read book Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells written by Kenneth Kam-Wing Lo and published by Academic Press. This book was released on 2016-12-30 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. - Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas - Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells - Foscuses on the fundamentals and their potential therapeutic and diagnostic applications - Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents

Download or read book Introduction to Strategies for Organic Synthesis written by Laurie S. Starkey and published by John Wiley & Sons. This book was released on 2012-01-18 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The stepping-stone text for students with a preliminary knowledge of organic chemistry looking to move into organic synthesis research and graduate-level coursework Organic synthesis is an advanced but important field of organic chemistry, however resources for advanced undergraduates and graduate students moving from introductory organic chemistry courses to organic synthesis research are scarce. Introduction to Strategies for Organic Synthesis is designed to fill this void, teaching practical skills for making logical retrosynthetic disconnections, while reviewing basic organic transformations, reactions, and reactivities. Divided into seven parts that include sections on Retrosynthesis and Protective Groups; Overview of Organic Transformations; Synthesis of Monofunctional Target Molecules; Synthesis of Target Molecules with Two Functional Groups; Synthesis of Aromatic Target Molecules; Synthesis of Compounds Containing Rings; and Predicting and Controlling Stereochemistry, the book covers everything students need to successfully perform retrosynthetic analyses of target molecule synthesis. Starting with a review of functional group transformations, reagents, and reaction mechanisms, the book demonstrates how to plan a synthesis, explaining functional group analysis and strategic disconnections. Incorporating a review of the organic reactions covered, it also demonstrates each reaction from a synthetic chemist's point of view, to provide students with a clearer understanding of how retrosynthetic disconnections are made. Including detailed solutions to over 300 problems, worked-through examples and end-of-chapter comprehension problems, Introduction to Strategies for Organic Synthesis serves as a stepping stone for students with an introductory knowledge of organic chemistry looking to progress to more advanced synthetic concepts and methodologies.