Download or read book Onboard Hydrogen Generation for a Spark Ignition Engine Via Thermochemical Recuperation written by Isaac Alexander Silva and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A method of exhaust heat recovery from a spark-ignition internal combustion engine was explored, utilizing a steam reforming thermochemical reactor to produce a hydrogen-rich effluent, which was then consumed in the engine. The effects of hydrogen in the combustion process have been studied extensively, and it has been shown that an extension of the lean stability limit is possible through hydrogen enrichment. The system efficiency and the extension of the operational range of an internal combustion engine were explored through the use of a methane fueled naturally aspirated single cylinder engine co-fueled with syngas produced with an on board methane steam reformer. It was demonstrated that an extension of the lean stability limit is possible using this system.
Download or read book Handbook of Hydrogen Energy written by S.A. Sherif and published by CRC Press. This book was released on 2014-07-29 with total page 1058 pages. Available in PDF, EPUB and Kindle. Book excerpt: Can hydrogen and electricity supply all of the world's energy needs? Handbook of Hydrogen Energy thoroughly explores the notion of a hydrogen economy and addresses this question. The handbook considers hydrogen and electricity as a permanent energy system and provides factual information based on science. The text focuses on a large cross section o
Download or read book Diesel Emissions and Their Control 2nd Edition written by W. Addy Majewski and published by SAE International. This book was released on 2023-12-20 with total page 1135 pages. Available in PDF, EPUB and Kindle. Book excerpt: Engineers, applied scientists, students, and individuals working to reduceemissions and advance diesel engine technology will find the secondedition of Diesel Emissions and Their Control to be an indispensablereference. Whether readers are at the outset of their learning journey orseeking to deepen their expertise, this comprehensive reference bookcaters to a wide audience.In this substantial update to the 2006 classic, the authors have expandedthe coverage of the latest emission technologies. With the industryevolving rapidly, the book ensures that readers are well-informed aboutthe most recent advances in commercial diesel engines, providing acompetitive edge in their respective fields. The second edition has alsostreamlined the content to focus on the most promising technologies.This book is rooted in the wealth of information available on DieselNet.com, where the “Technology Guide” papers offer in-depth insights. Eachchapter includes links to relevant online materials, granting readers accessto even more expertise and knowledge.The second edition is organized into six parts, providing a structuredjourney through every aspect of diesel engines and emissions control: Part I: A foundational exploration of the diesel engine, combustion, andessential subsystems. Part II: An in-depth look at emission characterization, health andenvironmental impacts, testing methods, and global regulations. Part III: A comprehensive overview of diesel fuels, covering petroleumdiesel, alternative fuels, and engine lubricants. Part IV: An exploration of engine efficiency and emission controltechnologies, from exhaust gas recirculation to engine control. Part V: The latest developments in diesel exhaust aftertreatment,encompassing catalyst technologies and particulate filters. Part VI: A historical journey through the evolution of dieselengine technology, with a focus on heavy-duty engines in the NorthAmerican market. (ISBN 9781468605693, ISBN 9781468605709, ISBN 9781468605716, DOI: 10.4271/9781468605709)
Download or read book Hydrogen Enrichment and Thermochemical Recuperation in Internal Combustion Engines written by David R. Vernon and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The thermochemical recuperation process uses endothermic reformation reactions to upgrade a portion of an engine's primary fuel into a hydrogen-rich gas, thereby converting part of the exhaust heat from an internal combustion engine into chemical potential energy. Enriching the primary fuel air mixture of the internal combustion engine with this hydrogen-rich gas potentially enables combustion with very lean or dilute mixtures, resulting in higher efficiency and lower emissions as compared to standard combustion regimes. It may be possible to simplify thermochemical recuperation system architecture by directly mixing exhaust gases with the fuel in the reformation process to supply a significant portion of the heat and water required. To evaluate the effect of direct exhaust gas mixing on ethanol autothermal reformation, this work experimentally and theoretically investigated dilution with a mixture of nitrogen and carbon dioxide to simulate an exhaust composition, in combination with a range of inlet temperatures, to simulate exhaust gas temperatures, at a constant steam to carbon ratio. Parameters such as the chemical coefficient of performance, chemical energy output divided by chemical energy input, are introduced to better enable quantification of thermochemical recuperation. Trends in yield and performance metrics for ethanol autothermal reformation were observed under operating conditions across a range of oxygen to carbon ratio, a range of dilution amount, and a range of inlet temperature. For high inlet temperature cases, dilution increases hydrogen yield and chemical coefficient of performance suggesting that direct exhaust mixing would be beneficial. However, for low inlet temperatures, dilution decreased hydrogen yield and other performance metrics suggesting that direct exhaust mixing would not be beneficial. Dilution decreased methane production for many conditions. High inlet temperature conditions were found to cause homogeneous oxidation and homogenous conversion of ethanol upstream of the catalyst leading to high conversions of ethanol and high methane yields before reaching the catalyst. Coke formation rates varied over two orders of magnitude, with high coke formation rates for the high inlet temperature cases and low coke formation rates for the low inlet temperature cases. Dilution decreased the rate of coke formation. Models of intrinsic rate phenomenon were constructed in this study. The models predict that mass transport rates will be faster than the rate of chemical reaction kinetics over the range of ethanol concentrations and temperatures measured in the catalyst monolith both with and without dilution. Bounding cases for heat generation and transfer rates indicate that these phenomena could be the rate limiting mechanism or could be faster than both chemical kinetics and mass transport rates depending upon the distribution of oxidation heat between the catalyst and gas stream. Based on these results direct exhaust gas mixing is expected to be a practical method for supplying heat and water vapor for ethanol autothermal reformation in thermochemical recuperation systems when exhaust temperatures are above a certain threshold. For low exhaust temperatures direct exhaust gas mixing can supply water vapor but reduces other performance metrics.
Download or read book Hydrogen Production from Autothermal Reformation of Ethanol Iso octane Mixtures written by Jonathan M. Woolley and published by . This book was released on 2008 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fossil Energy Update written by and published by . This book was released on 1982 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book A Pathway to Higher Efficiency Internal Combustion Engines Through Thermochemical Recovery and Fuel Reforming written by Flavio Dal Forno Chuahy and published by . This book was released on 2018 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dual fuel reactivity controlled compression ignition (RCCI) combustion is a promising method to achieve high efficiency with near zero NOx and soot emissions; however, the requirement to carry two fuels on-board has limited practical applications. Advancements in catalytic reforming have demonstrated the ability to generate syngas (a mixture of CO and hydrogen) from a single hydrocarbon stream. The reformed fuel mixture can then be used as a low reactivity fuel stream to enable RCCI out of a single parent fuel. Beyond enabling dual-fuel combustion strategies out of a single parent fuel, fuel reforming can be endothermic and allow recovery of exhaust heat to drive the reforming reactions, potentially improving overall efficiency of the system. Previous works have focused on using reformed fuel to extend the lean limit of spark ignited engines, and enhancing the control of HCCI type combustion. The strategy pairs naturally with advanced dual-fuel combustion strategies, and the use of dual-fuel strategies in the context of on-board reforming and energy recovery has not been explored. Accordingly, the work presented in this dissertation attempts to fill in the gaps in the current literature and provide a pathway to "single" fuel RCCI combustion through a combination of experiments and computational fluid dynamics modeling. Initially, a system level analysis focusing on three common reforming techniques (i.e., partial oxidation, steam reforming and auto-thermal reforming) was conducted to evaluate the potential of reformed fuel. A system layout was proposed for each reforming technique and a detailed thermodynamic analysis using first- and second-law approaches were used to identify the sources of efficiency improvements. The results showed that reformed fuel combustion with a near TDC injection of diesel fuel can increase engine-only efficiency by 4% absolute when compared to a conventional diesel baseline. The efficiency improvements were a result of reduced heat transfer and shorter, more thermodynamically efficient, combustion process. For exothermic reforming processes, losses in the reformer outweigh the improvements to engine efficiency, while for endothermic processes the recovery of exhaust energy was able to allow the system efficiency to retain a large portion of the benefits to the engine combustion. Energy flow analysis showed that the reformer temperature and availability of high grade exhaust heat were the main limiting factors preventing higher efficiencies. RCCI combustion was explored experimentally for its potential to expand on the optimization results and achieve low soot and NOx emissions. The results showed that reformed fuel can be used with diesel to enable RCCI combustion and resulted in low NOx and soot emissions while achieving efficiencies similar to conventional diesel combustion. Experiments showed that the ratio H2/(H2+CO) is an important parameter for optimal engine operation. Under part-load conditions, fractions of H2/(H2+CO) higher than 60% led to pressure oscillations inside the cylinder that substantially increased heat transfer and negated any efficiency benefits. The system analysis approach was applied to the experimental results and showed that chemical equilibrium limited operation of the engine to sub-optimal operating conditions. RCCI combustion was able to achieve "diesel like" system level efficiencies without optimization of either the engine operating conditions or the combustion system. Reformed fuel RCCI was able to provide a pathway to meeting current and future emission targets with a reduction or complete elimination of aftertreatment costs. Particle size distribution experiments showed that addition of reformed fuel had a significant impact on the shape of the particle size distribution. Addition of reformed fuel reduced accumulation-mode particle concentration while increasing nucleation-mode particles. When considering the full range of particle sizes there was a significant increase in total particle concentration. However, when considering currently regulated (Dm>23nm) particles, total concentration was comparable. To address limitations identified in the system analysis of the RCCI experiments a solid oxide fuel cell was combined with the engine into a hybrid electrochemical combustion system. The addition of the fuel cell addresses the limitations by providing sufficient high grade heat to fully drive the reforming reactions. From a system level perspective, the impact of the high frequency oscillations observed in the experiments are reduced, as the system efficiency is less dependent on the engine efficiency. From an engine perspective, the high operating pressures and low reactivity of the anode gas allow reduction of the likelihood of such events. A 0-D system level code was developed and used to find representative conditions for experimental engine validation. The results showed that the system can achieve system electrical efficiencies higher than 70% at 1 MWe power level. Experimental validation showed that the engine was able to operate under both RCCI and HCCI combustion modes and resulted in low emissions and stable combustion. The potential of a hybrid electrochemical combustion system was demonstrated for high efficiency power generation
Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Download or read book Advancement in Oxygenated Fuels for Sustainable Development written by Niraj Kumar and published by Elsevier. This book was released on 2022-11-09 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Oxygenated Fuels for Sustainable Development: Feedstocks and Precursors for Catalysts Synthesis provides a roadmap to the sustainable implementation of oxygenated fuels in internal combustion engines through sustainable production, smart distribution and effective utilization. Focusing on the sustainability of feedstocks, the book assesses availability, emissions impact and reduction potential, and biodiversity and land utilization impact. Existing technologies and supply chains are reviewed, and recommendations are provided on how to sustainably implement or update these technologies, including for rural communities. Furthermore, effective supply and distribution network designs are provided alongside methods for monitoring and assessing their sustainability, accounting for social, economic, environmental and ecological factors. This book guides readers through every aspect of the production and commercialization of sustainable oxygenated fuels for internal combustion engines and their implementation across the global transport industry. Provides multilevel perspectives on how to facilitate the sustainable production of oxygenated fuel and develop new indices for measuring the effectiveness and sustainability of implementation Recommends a framework and criteria for assessing the suitability, sustainability, and environmental benefits of oxygenated biofuels Describes the fuel properties of all oxygenated fuels and their performance in unmodified and enhanced CI and SI engines
Download or read book Renewable Fuels written by Rajni Kant and published by CRC Press. This book was released on 2023-07-17 with total page 387 pages. Available in PDF, EPUB and Kindle. Book excerpt: Renewable fuels, in the present times, have become important to curb emission of greenhouse gases, which are causing damage to the environment and leading to climatic changes. Ideally, their utilization can be a zero carbon operation. Planting suitable trees on all waste lands and agro forestry on a large scale can fulfil the needs of timber, fuel, fruits, etc. All kinds of lignocellulosic biomass can be converted by several methods to useful liquid fuels like alcohols, biodiesel, methane, renewable diesel and renewable gasoline. Hydrogen can be used as a renewable fuel because of its desirable characteristics and properties for its use as a green fuel.
Download or read book Hydrogen Technology written by Aline Léon and published by Springer Science & Business Media. This book was released on 2008-07-18 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aline Leon ́ In the last years, public attention was increasingly shifted by the media and world governmentsto the conceptsof saving energy,reducingpollution,protectingthe - vironment, and developing long-term energy supply solutions. In parallel, research funding relating to alternative fuels and energy carriers is increasing on both - tional and international levels. Why has future energy supply become such a matter of concern? The reasons are the problems created by the world’s current energy supply s- tem which is mainly based on fossil fuels. In fact, the energystored in hydrocarb- based solid, liquid, and gaseous fuels was, is, and will be widely consumed for internal combustion engine-based transportation, for electricity and heat generation in residential and industrial sectors, and for the production of fertilizers in agric- ture, as it is convenient, abundant, and cheap. However, such a widespread use of fossil fuels by a constantly growing world population (from 2. 3 billion in 1939 to 6. 5 billion in 2006) gives rise to the two problems of oil supply and environmental degradation. The problemrelated to oil supply is caused by the fact that fossil fuels are not - newable primary energy sources: This means that since the rst barrel of petroleum has been pumped out from the ground, we have been exhausting a heritage given by nature.
Download or read book Integrated Gasification Combined Cycle IGCC Technologies written by Ting Wang and published by Woodhead Publishing. This book was released on 2016-11-26 with total page 929 pages. Available in PDF, EPUB and Kindle. Book excerpt: Integrated Gasification Combined Cycle (IGCC) Technologies discusses this innovative power generation technology that combines modern coal gasification technology with both gas turbine and steam turbine power generation, an important emerging technology which has the potential to significantly improve the efficiencies and emissions of coal power plants. The advantages of this technology over conventional pulverized coal power plants include fuel flexibility, greater efficiencies, and very low pollutant emissions. The book reviews the current status and future developments of key technologies involved in IGCC plants and how they can be integrated to maximize efficiency and reduce the cost of electricity generation in a carbon-constrained world. The first part of this book introduces the principles of IGCC systems and the fuel types for use in IGCC systems. The second part covers syngas production within IGCC systems. The third part looks at syngas cleaning, the separation of CO2 and hydrogen enrichment, with final sections describing the gas turbine combined cycle and presenting several case studies of existing IGCC plants. Provides an in-depth, multi-contributor overview of integrated gasification combined cycle technologies Reviews the current status and future developments of key technologies involved in IGCC plants Provides several case studies of existing IGCC plants around the world
Download or read book Hydrogen and Fuel Cells written by International Energy Agency and published by Simon and Schuster. This book was released on 2004 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen and fuel cells are vital technologies to ensure a secure and CO2-free energy future. Their development will take decades of extensive public and private effort to achieve technology breakthroughs and commercial maturity. Government research programs are indispensable for catalyzing the development process. This report maps the IEA countries' current efforts to research, develop and deploy the interlocking elements that constitute a "hydrogen economy", including CO2 capture and storage when hydrogen is produced out of fossil fuels. It provides an overview of what is being done, and by whom, covering an extensive complexity of national government R & D programs. The survey highlights the potential for exploiting the benefits of the international cooperation. This book draws primarily upon information contributed by IEA governments. In virtually all the IEA countries, important R & D and policy efforts on hydrogen and fuel cells are in place and expanding. Some are fully-integrated, government-funded programs, some are a key element in an overall strategy spread among multiple public and private efforts. The large amount of information provided in this publication reflects the vast array of technologies and logistics required to build the "hydrogen economy."--Publisher description.
Download or read book Fuel Cells and Hydrogen Production written by Timothy E. Lipman and published by Springer. This book was released on 2018-10-05 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The expected end of the “oil age” will lead to increasing focus and reliance on alternative energy conversion devices, among which fuel cells have the potential to play an important role. Not only can phosphoric acid and solid oxide fuel cells already efficiently convert today’s fossil fuels, including methane, into electricity, but other types of fuel cells, such as polymer electrolyte membrane fuel cells, have the potential to become the cornerstones of a possible future hydrogen economy. This handbook offers concise yet comprehensive coverage of the current state of fuel cell research and identifies key areas for future investigation. Internationally renowned specialists provide authoritative introductions to a wide variety of fuel cell types and hydrogen production technologies, and discuss materials and components for these systems. Sustainability and marketing considerations are also covered, including comparisons of fuel cells with alternative technologies.
Download or read book Hydrogen Energy written by and published by . This book was released on 1976 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Hydrogen and Fuel Cell written by Johannes Töpler and published by Springer. This book was released on 2015-12-20 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces readers to hydrogen as an essential energy carrier for use with renewable sources of primary energy. It provides an overview of the state of the art, while also highlighting the developmental and market potential of hydrogen in the context of energy technologies; mobile, stationary and portable applications; uninterruptible power supplies and in the chemical industry. Written by experienced practitioners, the book addresses the needs of engineers, chemists and business managers, as well as graduate students and researchers.