Download or read book NREL S Capabilities in Catalyst Development and Characterization written by and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Thermal and Catalytic Process Development Unit at NREL has state-of-the-art equipment for thermochemical process development and testing, ranging from catalyst and feedstock characterizations to bench-scale reactors to pilot plants. Within this facility is the capability to understand structure-performance relationships for advanced catalytic materials to enable improved carbon yield and reduced costs for the targeted conversion of renewable feedstocks. This fact sheet summarizes the core capabilities and applications.

Download or read book NREL s Capabilities in Bio Oil Characterization written by and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Thermal and Catalytic Process Development Unit at NREL has state-of-the-art equipment for thermochemical process development and testing, ranging from catalyst and feedstock characterizations to bench-scale reactors to pilot plants. Within this facility is the capability to provide reliable analyses for biomass-derived liquids produced from thermochemical conversion, such as pyrolysis bio-oils. This fact sheet summarizes the standardized analytical methods that provide chemical information on bio-oil samples.

Download or read book Catalyst Development and Characterization Through Gas phase Nanoparticle Synthesis in Situ X ray Absorption Spectroscopy and Machine Learning written by Brenna Marie Gibbons and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The shift towards a more sustainable energy economy is one of the imperative challenges facing humanity today, and balancing prosperity against the risks of irrevocable climate change will require policy adjustments and scientific innovations on a global scale. In particular, it is essential to move away from burning fossil fuels to meet our energy needs; rising atmospheric CO2 has already contributed to ocean acidification and record high temperatures, and the dangers only increase with every ton of CO2 emitted. Fortunately, wind and solar radiation provide vast resources for renewable energy, and remarkable progress has been made in the past several years towards incorporating these sources. As the use of renewable energy generation rises, so too does the need for efficient energy storage and conversion that are not predicated on the use of fossil fuels. Electrochemistry offers one piece of the solution through fuel cells, batteries, and other technologies. The drive to discover and refine catalysts for these electrochemical reactions is therefore of critical importance to our shared sustainable energy future. Catalyst design has benefited from the close integration of experiment and theory in a cyclical framework whereby new materials are synthesized, characterized, tested for electrochemical performance, and used to improve predictions for future catalysts. A similar framework is used in this dissertation as we delve into each part of the catalyst development cycle. We begin with materials synthesis of nanoparticles, which are of scientific interest for their unique properties compared to bulk materials. Inert gas condensation is introduced as a method for nanoparticle synthesis, and we present several systems including NiFe, Mn oxides, and other transition metals. We observe several unusual morphologies, including cubic particles and the alignment of particles on surface defects. In addition, we study catalytic activity for the oxygen evolution reaction (OER) on both NiFe of varying sizes and Mn oxide promoted with Au. We demonstrate that inert gas condensation is a highly versatile method for synthesizing nanoparticles both for fundamental studies and as electrochemical catalysts. We then focus on the details of one specific catalyst: CuAg for the oxygen reduction reaction (ORR). The ORR is a key component of fuel cells and metal-air batteries, and developing efficient and cost-effective catalysts for this reaction will entail improving our understanding of catalyst activity. We find that CuAg nanoparticles outperform either Cu or Ag nanoparticles, and that they are on par with thin films of similar compositions. To elucidate the origin of this heightened activity we use a combination of density functional theory (DFT) and in situ characterization. X-ray absorption spectroscopy (XAS) allows us to follow the electronic state of our catalyst under reaction conditions, and while we see little change in the electronic or geometric state of the Ag atoms in CuAg, the Cu atoms in CuAg are markedly different than in pure Cu. DFT predicted that Cu atoms in a Ag lattice would have dramatically different d-band states and a smaller oxygen binding energy, and our in situ experiments confirmed that Cu atoms in CuAg are more reduced than in Cu at ORR-relevant potentials. CuAg is revealed to owe its enhanced activity not to a small change in Ag, the more active metal alone, but to a substantial modification of Cu that boosts the overall performance. We hope that better understanding this system will contribute to the design of highly active non-precious catalysts for the ORR. Traditionally new catalysts for a reaction are chosen based on a combination of conventional theory calculations such as DFT and educated guesswork informed by scientific insight. However the vast search space of possible catalyst materials and the wealth of computational and experimental data for reactions studied over decades opens the possibility to use machine learning to speed the iterative design process. In the final portion of this work we consider the application of machine learning to case studies in both computational and experimental materials science. To start, we examine several algorithms for predicting metallic glasses on ternary alloys from a historical dataset based on their compositions alone. Using the two best models, we then investigate combining sparse historical data with new high-throughput data and find that more data is not always better. On the other hand, materials science encompasses many questions for which the data is much less plentiful. One strategy to maximize the value of small datasets is transfer learning, in which the outputs of one model inform subsequent models. We apply transfer learning to experimental Ni superalloy mechanical properties and nitric oxide reduction reaction computational data, and we determine that in both cases transfer learning is an effective way to improve model accuracy without collecting new data. In summary, this dissertation explores each step of the catalyst development cycle, from nanoparticle synthesis, to electrochemical testing, advanced in situ characterization, and predicting new materials via machine learning. This work aims to present fundamental insights on catalytic activity as well as several avenues for future catalyst development with the goal of contributing to a more efficient energy future.

Download or read book Hydrogen and Fuel Cells written by International Energy Agency and published by Simon and Schuster. This book was released on 2004 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen and fuel cells are vital technologies to ensure a secure and CO2-free energy future. Their development will take decades of extensive public and private effort to achieve technology breakthroughs and commercial maturity. Government research programs are indispensable for catalyzing the development process. This report maps the IEA countries' current efforts to research, develop and deploy the interlocking elements that constitute a "hydrogen economy", including CO2 capture and storage when hydrogen is produced out of fossil fuels. It provides an overview of what is being done, and by whom, covering an extensive complexity of national government R & D programs. The survey highlights the potential for exploiting the benefits of the international cooperation. This book draws primarily upon information contributed by IEA governments. In virtually all the IEA countries, important R & D and policy efforts on hydrogen and fuel cells are in place and expanding. Some are fully-integrated, government-funded programs, some are a key element in an overall strategy spread among multiple public and private efforts. The large amount of information provided in this publication reflects the vast array of technologies and logistics required to build the "hydrogen economy."--Publisher description.

Download or read book Evolution and Enabling Capabilities of Spatially Resolved Techniques for the Characterization of Heterogeneously Catalyzed Reactions written by and published by . This book was released on 2016 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development and optimization of catalysts and catalytic processes requires knowledge of reaction kinetics and mechanisms. In traditional catalyst kinetic characterization, the gas composition is known at the inlet, and the exit flow is measured to determine changes in concentration. As such, the progression of the chemistry within the catalyst is not known. Technological advances in electromagnetic and physical probes have made visualizing the evolution of the chemistry within catalyst samples a reality, as part of a methodology commonly known as spatial resolution. Herein, we discuss and evaluate the development of spatially resolved techniques, including the evolutions and achievements of this growing area of catalytic research. The impact of such techniques is discussed in terms of the invasiveness of physical probes on catalytic systems, as well as how experimentally obtained spatial profiles can be used in conjunction with kinetic modeling. Moreover, some aims and aspirations for further evolution of spatially resolved techniques are considered.

Download or read book Comprehensive Characterization of Mixed Metal Oxide Catalysts for Enhanced Catalyst Lifetime During Bio Based C2 C6 Oxygenates to Olefins Processes Cooperative Research and Development Final Report CRADA Number CRD 18 00728 written by and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Participant has developed mixed metal oxide (MMO) catalysts to selectively convert biomass-derived C2-C6 oxygenates to olefins and then hydrocarbon fuels to meet DOE 2022 fuel targets. Selective conversion ethanol to isobutylene with MMO catalysts (ZnOZrOx) requires low ethanol feeds to maintain performance. Increasing the feed results in rapid catalyst deactivation. Participant has increased catalyst stability by adding additional metal oxides. However, variations in performance based on the level and type of additive and catalytic conditions have been observed. This project will use advanced catalyst characterization methods through the ChemCatBio Advanced Catalyst Synthesis and Characterization (ACSC) project to gain insight into key catalyst features and deactivation modes with the goal of tailoring catalyst composition to improve performance.

Download or read book Characterization and Catalyst Development written by Steven A. Bradley and published by . This book was released on 1989 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: This "must-have" volume bridges the gap between catalysis science and development. It is targeted toward the catalyst scientist who needs to understand the characterization techniques as they apply to catalysts, and toward the instrumentalists who must recognize the characterization requirements of the catalyst scientist. It is the first volume to demonstrate the integrative approach for developing new catalysts, improving processes, and understanding catalysis science.

Download or read book Best Practices Handbook for the Collection and Use of Solar Resource Data for Solar Energy Applications written by M. Sengupta and published by . This book was released on 2013 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Methanol from wood waste written by A E. Hokanson and published by . This book was released on 1977 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Photoelectrochemical Hydrogen Production written by Roel van de Krol and published by Springer Science & Business Media. This book was released on 2011-11-09 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.

Download or read book Energy and Water Development Appropriations for 2012 Dept of Energy FY 2012 justifications written by United States. Congress. House. Committee on Appropriations. Subcommittee on Energy and Water Development and published by . This book was released on 2011 with total page 1436 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Energy and Water Development Appropriations for 1995 written by United States. Congress. House. Committee on Appropriations. Subcommittee on Energy and Water Development and published by . This book was released on 1994 with total page 2584 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Airborne Wind Energy written by Roland Schmehl and published by Springer. This book was released on 2018-03-31 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides in-depth coverage of the latest research and development activities concerning innovative wind energy technologies intended to replace fossil fuels on an economical basis. A characteristic feature of the various conversion concepts discussed is the use of tethered flying devices to substantially reduce the material consumption per installed unit and to access wind energy at higher altitudes, where the wind is more consistent. The introductory chapter describes the emergence and economic dimension of airborne wind energy. Focusing on “Fundamentals, Modeling & Simulation”, Part I includes six contributions that describe quasi-steady as well as dynamic models and simulations of airborne wind energy systems or individual components. Shifting the spotlight to “Control, Optimization & Flight State Measurement”, Part II combines one chapter on measurement techniques with five chapters on control of kite and ground stations, and two chapters on optimization. Part III on “Concept Design & Analysis” includes three chapters that present and analyze novel harvesting concepts as well as two chapters on system component design. Part IV, which centers on “Implemented Concepts”, presents five chapters on established system concepts and one chapter about a subsystem for automatic launching and landing of kites. In closing, Part V focuses with four chapters on “Technology Deployment” related to market and financing strategies, as well as on regulation and the environment. The book builds on the success of the first volume “Airborne Wind Energy” (Springer, 2013), and offers a self-contained reference guide for researchers, scientists, professionals and students. The respective chapters were contributed by a broad variety of authors: academics, practicing engineers and inventors, all of whom are experts in their respective fields.

Download or read book Fast Pyrolysis of Biomass written by A. V. Bridgwater and published by Cpl Press. This book was released on 1999 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited and updated version of the final report of the IEA Bioenergy Pyrolysis Task, is useful both to newcomers to the subject area and those already involved in research, development, and implementation.

Download or read book Advances in Clean Energy Technologies written by Abul Kalam Azad and published by Academic Press. This book was released on 2020-09-08 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Clean Energy Technologies presents the latest advanced approaches toward a cleaner and more sustainable energy environment. Editor Kalam Azad and his team of expert contributors focus on recent developments in the field of clean energy technologies, sustainable zero emission resources, energy efficiency and environmental sustainability, as well as clean energy policy and markets. This well-rounded reference includes an authoritative view on control and storage solutions specific to medium and large-scale industries, advanced approaches to modeling, and experimental investigations on clean energy technologies. Those working in and researching clean energy and sustainability will obtain detailed understanding of a variety of zero emission energy production and conversion approaches, as well as important socio-economic and environmental considerations that can be applied to their own unique power generation settings. - Presents an exclusive analysis on advanced approaches of modeling and experimental investigations of clean energy technologies, including solar, wind, ocean, and hybrid systems - Includes an authoritative and cross-disciplinary view on energy policy and energy markets - Helps readers develop an understanding of concepts and solutions to global issues surrounding sustainability in medium-large scale energy industries - Offers detailed understanding of a variety of zero emission energy production and conversion approaches

Download or read book Solar Hydrogen Production written by Francesco Calise and published by Academic Press. This book was released on 2019-08-15 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solar Hydrogen Production: Processes, Systems and Technologies presents the most recent developments in solar-driven hydrogen generation methods. The book covers different hydrogen production routes, from renewable sources, to solar harvesting technologies. Sections focus on solar energy, presenting the main thermal and electrical technologies suitable for possible integration into solar-based hydrogen production systems and present a thorough examination of solar hydrogen technologies, ranging from solar-driven water electrolysis and solar thermal methods, to photo-catalytic and biological processes. All hydrogen-based technologies are covered, including data regarding the state-of-the art of each process in terms of costs, efficiency, measured parameters, experimental analyses, and demonstration projects. In the last part of the book, the role of hydrogen in the integration of renewable sources in electric grids, transportation sector, and end-user applications is assessed, considering their current status and future perspectives. The book includes performance data, tables, models and references to available standards. It is thus a key-resource for engineering researchers and scientists, in both academic and industrial contexts, involved in designing, planning and developing solar hydrogen systems. - Offers a comprehensive overview of conventional and advanced solar hydrogen technologies, including simulation models, cost figures, R&D projects, demonstration projects, test standards, and safety and handling issues - Encompasses, in a single volume, information on solar energy and hydrogen systems - Includes detailed economic data on each technology for feasibility assessment of different systems

Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.