Download or read book Mixed Valence Systems written by Yu-Wu Zhong and published by John Wiley & Sons. This book was released on 2023-03-09 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.
Download or read book Mixed Valence Compounds written by D.B. Brown and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been a decade since two seminal reviews demonstrated that mixed-valence compounds share many unique and fascinating features. The insight pro vided by those early works has promoted a great deal of both experimental and theoretical study. As a result of extensive efforts, our understanding of the bonding and properties of mixed-valence compounds has advanced substantially. There has been no compre hensive treatment of mixed-valence compounds since 1967, and the meeting convened at Oxford in September, 1979, provided a unique opportunity to examine the subject and its many ramifications. Mixed-valence compounds play an important role in many fields. Although the major impact of the subject has been in chemistry, its importance has become increasingly clear in solid state physics, geology, and biology. Extensive interest and effort in the field of molecular metals has demonstrated that mixed-valency is a prerequisite for high elec trical conductivity. The intense colors of many minerals have been shown to be due to mixed-valency, and the electron-transfer properties of certain mixed-valence metalloproteins are important in biological processes. Experts from all of these areas participated in this meeting, and the truly interdisciplinary nature of the subject made it a unique learning experience for all in attendance.
Download or read book Mixed Valency Systems Applications in Chemistry Physics and Biology written by K. Prassides and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed valency is one of various names used to describe compounds which contain ions of the same element in two different formal states of oxidation. The existence of mixed valency systems goes far back into the geological evolutionary history of the earth and other planets, while a plethora of mixed valency minerals has attracted attention since antiquity. Indeed, control of the oxidation states of Fe in its oxides (FeO, Fe304' Fe203) was elegantly used in vase painting by the ancient Greeks to produce the characteristic black and red Attic ceramics (Z. Goffer, "Archaeological Chemistry", Wiley, New York, 1980). It was, however, only 25 years ago that two reviews of mixed valency appeared in the literature almost simultaneously, signalling the first attempt to treat mixed valency systems as a separate class of compounds whose properties can be correlated with the molecular and the electronic structure of their members. Then mixed valency phenomena attracted the interest of disparate classes of scientists, ranging from synthetic chemists to solid state physicists and from biologists to geologists. This activity culminated with the NATO ASI meeting in Oxford in 1979. The 1980's saw again a continuing upsurge of interest in mixed valency. Its presence is a necessary factor in the search for highly conducting materials, including molecular metals and superconductors. The highly celebrated high T c ceramic superconducting oxides are indeed mixed valency compounds.
Download or read book Mixed Valence Systems written by Yuwu Zhong and published by John Wiley & Sons. This book was released on 2023-05-30 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.
Download or read book Valence trapped to Valence delocalized Mixed valence Systems by Bridge State Modification written by Kevin P. Schultz and published by . This book was released on 2008 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Molecules into Materials written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 17046 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Download or read book Organic Redox Systems written by Tohru Nishinaga and published by John Wiley & Sons. This book was released on 2015-12-30 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. • Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties • Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems • Offers a useful guide for both academic and industrial chemists involved with organic electronic materials • Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Download or read book Correlations In Clusters And Related Systems New Perspectives On The Many body Problem written by Jean-patrick Connerade and published by World Scientific. This book was released on 1996-05-25 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: This proceedings volume describes many-body effects in highly correlated systems with special emphasis on metal clusters and transition from the free atom to the solid state limit and on strong laser field effects. The interdisciplinary nature of the subject should be stressed: clusters are a novel area of research, involving atomic, molecular, solid state and nuclear physics.
Download or read book Theory of Heavy Fermions and Valence Fluctuations written by Tadao Kasuya and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains the proceedings of the Eighth Taniguchi Interna tional Symposium on the Theory of Condensed Matter, which was held at Shima Kanko Hotel in Shima, Japan, 10-13 April 1985. The topic of the Symposium was Valence Fluctuation and Heavy Fermion Systems, one of the most fundamental problems in present-day condensed matter physics. The dilute Kondo problem, which is one of the most typical and unique many-body problems in condensed matter physics, developed recently into the dense Kondo and the coherent Kondo lattice problems in the 4f elec tron systems. It is accepted now that a large degeneracy in f-electron systems makes this latter situation possible by enhancing the single-site Kondo state relative to the inter-site magnetic interactions. Now, anoma lous behavior in f-electron systems show rich variety and are called valence fluctuation phenomena as a whole. They have, however, a common fea ture. In the lowest temperature region, they show either heavy Fermion like character or a narrow gap formation at the Fermi energy. Discovery of superconductivity in the heavy Fermion systems is attracting more in terest. Anyway, the valence fluctuating states are thought to be of fun damental importance to bridge the gap between the localized magnetic states and the delocalized nownagnetic states.
Download or read book Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions written by L.C. Gupta and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 749 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the Koln meeting (August 28-31, 1984), Irdia was chosen as the venue for the next International Conference on Valence Fluctuations. lhis was in recognition ard appreciation of the work done, both experimental ard theoretical, by the Irdian scientists in this area during the last decade. We decided to hold this Conference in the month of January, 1987 at Bangalore. lhe subject of Valence Fluctuations has kept itself alive ard active as it has provided many shocks ard suprises particularly among the Ce- ard U-based intermetallies. lhe richness of many interesting physical phenomena occurring in mixed valent materials, the flexibility of modifying their physical properties (by alloying, for example) ard the possibility of synthesizing a wide variety of new such materials seem to be the key factors in this regard. Barely six months before this Conference, an International Conference on Anomalous Rare Earths and Actinides (ICAREA) had been held at Grenoble (July, 1986) which also focussed on mixed valence ard heavy fermion phenomena. In spite of this, the response to this' Conference was very enthusiastic and encouraging. Many interesting ard important results were presented at this Conference which have been included in this volume.
Download or read book Electron Spin Resonance written by P B Ayscough and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Download or read book Moment Formation In Solids written by W. J. L. Buyers and published by Springer Science & Business Media. This book was released on 2013-12-01 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problem of moment formation in metallic systems lies at the interface of localized and itinerant magnetism. The phenomena observed correspond to destruction rather than to formation of spin-correlations. They give rise to the progression from local ized ground states through Kondo and mixed-valence behaviour to itinerant magnetic or non-magnetic systems. Somewhere in the pro gression superconductivity can occur in the presence of f-moments. To bring together the disparate ideas and methods, previously the subject of intense debate only at a number of topical confer ences, a two-week Advanced Study Institute was held August 21 - September 02, 1983, at Lester B. Pearson College of the Pacific, Vancouver Island. In the stimulating environment provided by the pines and fiord at the site of this remote United World College on the Canadian West Coast, scientists and students from around the globe gathered to hear lectures by experts. The Study Institute involved seventy-six people and followed in the tradition . of pre vious "Banff" summer schools organized by the Canadian Association of Physicists. It was made possible by grants from the North Atlantic Treaty Organization, the Natural Sciences & Engineering Research Council of Canada and Atomic Energy of Canada. The grants permitted many young scientists from Nato and non-Nato countries to learn the fundamentals as well as the latest results in the field.
Download or read book Organic Redox Systems written by Tohru Nishinaga and published by John Wiley & Sons. This book was released on 2015-11-25 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing a thorough overview of leading research from internationally-recognized contributing authors, this book describes methods for the preparation and application of redox systems for organic electronic materials like transistors, photovoltaics, and batteries. • Covers bond formation and cleavage, supramolecular systems, molecular design, and synthesis and properties • Addresses preparative methods, unique structural features, physical properties, and material applications of redox active p-conjugated systems • Offers a useful guide for both academic and industrial chemists involved with organic electronic materials • Focuses on the transition-metal-free redox systems composed of organic and organo main group compounds
Download or read book Lower Dimensional Systems and Molecular Electronics written by Robert M. Metzger and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 729 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume represents the written account of the NATO Advanced Study Institute "Lower-Dimensional Systems and Molecular Electronics" held at Hotel Spetses, Spetses Island, Greece from 12 June to 23 June 1989. The goal of the Institute was to demonstrate the breadth of chemical and physical knowledge that has been acquired in the last 20 years in inorganic and organic crystals, polymers, and thin films, which exhibit phenomena of reduced dimensionality. The interest in these systems started in the late 1960's with lower-dimensional inorganic conductors, in the early 1970's with quasi-one-dimensional crystalline organic conductors. which by 1979 led to the first organic superconductors, and, in 1977, to the fITSt conducting polymers. The study of monolayer films (Langmuir-Blodgett films) had progressed since the 1930's, but reached a great upsurge in . the early 1980's. The pursuit of non-linear optical phenomena became increasingly popular in the early 1980's, as the attention turned from inorganic crystals to organic films and polymers. And in the last few years the term "moleculw' electronics" has gained ever-increasing acceptance, although it is used in several contexts. We now have organic superconductors with critical temperatures in excess of 10 K, conducting polymers that are soluble and processable, and used commercially; we have films of a few monolayers that have high in-plane electrical conductivity, and polymers that show great promise in photonics; we even have a few devices that function almost at the molecular level.
Download or read book M ssbauer Effect Methodology written by Irwin J. Gruverman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the eighth volume of a continuing series intended to provide a forum for publication of develop ments in Mossbauer effect methodology and in spectroscopy and its applications. Mossbauer Effect Methodology, Volume 8, records the proceedings of the Eighth Symposium on Mossbauer Effect Methodology. The symposium was sponsored by the New England Nuclear Corporation, with emphasis on application and some attention to spectroscopy and methodology. The Symposium was held in the Mercury Ballroom of the New York Hilton on January 28, 1973. Dr. J. J. Zuckerman presided over the afternoon and evening sessions. Almost two hundred participants attended, despite the pressures of travel budget limitations, indicating a continuing high level of interest in the field. Contri buting Sponsors were Austin Science Associates, Elron, Nuclear Science Instruments and Ranger Electronics. The MOssbauer equipment demonstrated by these organizations continued to evolve and improve year by year, and was well received by symposium participants. A one-year break in the symposium series resulted in submission of a very large number of papers. A Selection Committee was formed and selected 16 papers for inclusion in the symposium. Regrettably, many worthwhile papers could not be included. Applications were stressed.
Download or read book EXAFS and Near Edge Structure written by A. Bianconi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of X-ray spectroscopy using synchrotron radiation is growing so rapidly and expanding into such different research areas that it is now diffi cult to keep up with the literature. EXAFS and XANES are becoming interdis ciplinary methods used in solid-state physics, biology, and chemistry, and are making impressive contributions to these branches of science. The present book gives a panorama of the research activity in this field. It contains the papers presented at the International Conference on EXAFS and Near Edge Structure held in Frascati, Italy, September 13-17, 1982. This was the first international conference devoted to EXAFS spectroscopy (Extended X-ray Ab sorption Fine Structure) and its applications. The other topic of the con ference was the new XANES (X-ray Absorption Near Edge Structure), which in of experimental and theoretical developments finally appears to have terms left its infancy. The applications of EXAFS concern the determination of local structures in complex systems; we have therefore divided the subject matter into differ ent parts on various types of materials: amorphous metals, glasses, solu tions, biological systems, catalysts, and special crystals such as mixed valence systems and ionic conductors. EXAFS provides unique information for each kind of system, but the analysis of EXAFS data also poses special prob lems in each case. General problems of EXAFS data analysis are discussed, as well as developments in instrumentation for X-ray absorption using syn chrotron radiation and laboratory EXAFS.
