Download or read book Measurements of Size Resolved Atmospheric Aerosol Chemical Composition with Impactors written by Xinqiu Zhang and published by . This book was released on 1990 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Atmospheric Chemistry and Physics written by John H. Seinfeld and published by John Wiley & Sons. This book was released on 2012-12-18 with total page 1249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thoroughly restructured and updated with new findings and new features The Second Edition of this internationally acclaimed text presents the latest developments in atmospheric science. It continues to be the premier text for both a rigorous and a complete treatment of the chemistry of the atmosphere, covering such pivotal topics as: * Chemistry of the stratosphere and troposphere * Formation, growth, dynamics, and properties of aerosols * Meteorology of air pollution * Transport, diffusion, and removal of species in the atmosphere * Formation and chemistry of clouds * Interaction of atmospheric chemistry and climate * Radiative and climatic effects of gases and particles * Formulation of mathematical chemical/transport models of the atmosphere All chapters develop results based on fundamental principles, enabling the reader to build a solid understanding of the science underlying atmospheric processes. Among the new material are three new chapters: Atmospheric Radiation and Photochemistry, General Circulation of the Atmosphere, and Global Cycles. In addition, the chapters Stratospheric Chemistry, Tropospheric Chemistry, and Organic Atmospheric Aerosols have been rewritten to reflect the latest findings. Readers familiar with the First Edition will discover a text with new structures and new features that greatly aid learning. Many examples are set off in the text to help readers work through the application of concepts. Advanced material has been moved to appendices. Finally, many new problems, coded by degree of difficulty, have been added. A solutions manual is available. Thoroughly updated and restructured, the Second Edition of Atmospheric Chemistry and Physics is an ideal textbook for upper-level undergraduate and graduate students, as well as a reference for researchers in environmental engineering, meteorology, chemistry, and the atmospheric sciences. Click here to Download the Solutions Manual for Academic Adopters: http://www.wiley.com/WileyCDA/Section/id-292291.html

Download or read book Measurements to Evaluate the Benchmark Properties of Atmospheric Aerosols written by Bernard G. Mendonça and published by . This book was released on 1976 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report was adapted from a Master's thesis supported by an ERL long-term University assignment at Colorado State University Fort Collins, Colorado pg. ii

Download or read book Chemical Characterization and Source Apportionment of Atmospheric Aerosols in Urban and Rural Regions written by Caroline Parworth and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosols, or particulate matter (PM), can affect climate through scattering and absorption of radiation and influence the radiative properties, precipitation efficiency, thickness, and lifetime of clouds. Aerosols are one of the greatest sources of uncertainty in climate model predictions of radiative forcing. To fully understand the sources of uncertainty contributing to the radiative properties of aerosols, measurements of PM mass, composition, and size distribution are needed globally and seasonally. To add to the current understanding of the seasonal and temporal variations in aerosol composition and chemistry, this study has focused on the quantification, speciation, and characterization of atmospheric PM in urban and rural regions of the United States (US) for short and long periods of time. In the first two chapters, we focus on 1 month of aerosol and gas-phase measurements taken in Fresno, CA, an urban and agricultural area, during the National Aeronautics and Space Administration's (NASA) field study called DISCOVER-AQ. This air quality measurement supersite included a plethora of highly detailed chemical measurements of aerosols and gases, which were made at the same time as similar aircraft column measurements of aerosols and gases. The goal of DISCOVER-AQ is to improve the interpretation of satellite observations to approximate surface conditions relating to air quality, which can be achieved by making concurrent ground- and aircraft-based measurements of aerosols and gases. We begin in chapter 2 by exploring the urban aerosol and gas-phase dataset from the NASA DISCOVER-AQ study in California. Specifically, we discuss the chemical composition and mass concentration of water-soluble PM2.5 that were measured using a particle-into-liquid sampler with ion chromatography (PILS-IC) in Fresno, California from January 13–February 10, 2013. This data was analyzed for ionic inorganic species, organic acids and amines. Gas-phase species including HNO3 and NH3 were collected with annular denuders and analyzed using ion chromatography. Using the thermodynamic E-AIM model, inorganic particle water mass concentration and pH were calculated for the first time in this area. Organic particle water mass concentration was calculated from [kappa]-Köhler theory. In chapter 3 further analysis of the aerosol- and gas-phase data measured during DISCOVER-AQ was performed to determine the effectiveness of a local residential wood burning curtailment program in improving air quality. Using aerosol speciation and concentration measurements from the 2013 winter DISCOVER-AQ study in Fresno, CA, we investigate the impact of residential wood burning restrictions on fine particulate mass concentration and composition. Key species associated with biomass burning in this region include K+, acetonitrile, black carbon, and biomass burning organic aerosol (BBOA), which represents primary organic aerosol associated with residential wood burning. Reductions in acetonitrile associated with wood burning restrictions even at night were not observed and most likely associated with stagnant conditions during curtailment periods that led to the buildup of this long-lived gas. In chapter 4 we transition to the rural aerosol dataset from the DOE SGP site. We discuss the chemical composition and mass concentration of non-refractory submicron aerosols (NR-PM1) that were measured with an aerosol chemical speciation monitor (ACSM) at the DOE SGP site from November 2010 through June 2012. Positive matrix factorization (PMF) was performed on the measured organic aerosol (OA) mass spectral matrix using a newly developed rolling window technique to derive factors associated with distinct sources, evolution processes, and physiochemical properties. The rolling window approach captured the dynamic variations of the chemical properties of the OA factors over time. Three OA factors were obtained including two oxygenated OA (OOA) factors, differing in degrees of oxidation, and a BBOA factor. Sources of NR-PM1 species at the SGP site were determined from back trajectory analyses. NR-PM1 mass concentration was dominated by organics for the majority of the study with the exception of winter, when NH4N33 increased due to transport of precursor species from surrounding urban and agricultural regions and also due to cooler temperatures. Chapter 5 is a continuation of chapter 4, where we will explore the use of the multilinear engine (ME-2) as a factor analysis technique, which is an algorithm used for solving the bilinear model called positive matrix factorization (PMF). The importance of ME-2 and its potential application on the long-term aerosol chemical speciation monitor (ACSM) data collected from the Department of Energy (DOE) Southern Great Plains (SPG) site will be discussed. ME-2 was performed on 19 months of OA mass spectral data obtained from the ACSM at the SGP site. Evaluation of ME-2 results are presented, followed by comparison of ME-2 factor results with corresponding OACOMP factor results reported in chapter 4. We show that ME-2 can determine a biomass burning organic aerosol (BBOA) factor during periods when OACOMP cannot. (Abstract shortened by ProQuest.)

Download or read book Atmospheric Aerosols written by Hayder Abdul-Razzak and published by BoD – Books on Demand. This book was released on 2012-09-12 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is divided into two sections. The first section presents characterization of atmospheric aerosols and their impact on regional climate from East Asia to the Pacific. Ground-based, air-born, and satellite data were collected and analyzed. Detailed information about measurement techniques and atmospheric conditions were provided as well. In the second section, authors provide detailed information about the organic and inorganic constituents of atmospheric aerosols. They discuss the chemical and physical processes, temporal and spatial distribution, emissions, formation, and transportation of aerosol particles. In addition, new measurement techniques are introduced. This book hopes to serve as a useful resource to resolve some of the issues associated with the complex nature of the interaction between atmospheric aerosols and climatology.

Download or read book Aerosol Measurement written by Pramod Kulkarni and published by John Wiley & Sons. This book was released on 2011-07-12 with total page 920 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol Measurement: Principles, Techniques, and Applications Third Edition is the most detailed treatment available of the latest aerosol measurement methods. Drawing on the know-how of numerous expert contributors; it provides a solid grasp of measurement fundamentals and practices a wide variety of aerosol applications. This new edition is updated to address new and developing applications of aerosol measurement, including applications in environmental health, atmospheric science, climate change, air pollution, public health, nanotechnology, particle and powder technology, pharmaceutical research and development, clean room technology (integrated circuit manufacture), and nuclear waste management.

Download or read book Atmospheric Aerosols written by Claudio Tomasi and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ein Blick auf die morphologischen, physikalischen und chemischen Eigenschaften von Aerosolen aus den unterschiedlichsten natürlichen und anthropogenen Quellen trägt zum besseren Verständnis der Rolle bei, die Aerosolpartikel bei der Streuung und Absorption kurz- und langwelliger Strahlung spielen. Dieses Fachbuch bietet Informationen, die sonst schwer zu finden sind, und vermittelt ausführlich die Kenntnisse, die erforderlich sind, um die mikrophysikalischen, chemischen und Strahlungsparameter zu charakterisieren, die bei der Wechselwirkung von Sonnen- und Erdstrahlen so überaus wichtig sind. Besonderes Augenmerk liegt auf den indirekten Auswirkungen von Aerosolen auf das Klima im Rahmen des komplexen Systems aus Aerosolen, Wolken und der Atmosphäre. Auch geht es vorrangig um die Wirkungen natürlicher und anthropogener Aerosole auf die Luftqualität und die Umwelt, auf die menschliche Gesundheit und unser kulturelles Erbe. Mit einem durchgängig lösungsorientierten Ansatz werden nicht nur die Probleme und Gefahren dieser Aerosole behandelt, sondern auch praktikable Lösungswege aufgezeigt.

Download or read book Urban Aerosols and Their Impacts written by Jeffrey S. Gaffney and published by . This book was released on 2006 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Urban aerosols have been identified as important species of concern due to their potential health and environmental impacts. This symposium series book will describe the basic chemistry and physics determining the impacts of aerosol species and will highlight the research results from the measurements that were taken following the collapse of the World Trade Center (WTC) on 9/11/01. The WTC tragedy led to the release of millions of pounds of debris aside from the structural steel, part of which was widely dissipated as aerosols and particulates in the debris cloud over lower Manhattan. Additionally, continuing fires under the debris led to the release of fine combustion related aerosols for a considerable time period in this urban environment. Held during the week of the second anniversary of the WTC tragedy in NYC, the symposium book will describe various aspects of the event, aerosol and gas exposures, and the related impacts of these aerosols. The book contributions will highlight efforts work from atmospheric chemists, meteorologists, health workers, and biologists for a timely compilation of what is known and not known about the composition and transport of tropospheric aerosols in urban environs, particularly those from the WTC collapse. Particular interest is in the acute and chronic environmental effects of these aerosols as they impact human health. Chapters included in the book will also address aerosol lifetimes, aerosol transport and removal processes, acute and chronic health effects to fine aerosol and particulate exposures, and the environmental impacts of aerosols.

Download or read book New Insights Into Single particle Mixing State Using Aircraft Aerosol Time of flight Mass Spectrometry written by Kerri Anne Pratt and published by . This book was released on 2009 with total page 387 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosols strongly influence the energy balance of the Earth and the hydrological cycle by scattering and absorbing radiation and acting as cloud condensation and ice nuclei. The climate and human health impacts of aerosols are strongly dependent on particle size, chemical composition, and mixing state. During transport in the atmosphere, aerosol particles undergo physical and chemical transformations (atmospheric aging) through heterogeneous reactions with trace gases and gas-particle partitioning of semivolatile species. The size-resolved chemical composition of individual particles may be examined in real-time using aerosol time-of-flight mass spectrometry (ATOFMS). A smaller ATOFMS with increased data acquisition capabilities was developed for aircraft-based studies. Particle volatility was examined through ground-based measurements during the Study of Organic Aerosols in Riverside, CA (SOAR), and vertical mixing state profiles and cloud residues were examined through flight-based measurements during the Ice in Clouds Experiment - Layer Clouds (ICE-L). An automated thermodenuder (TD) was coupled to the aircraft (A)-ATOFMS to provide the first real-time, individual-particle size and volatility-resolved chemical composition measurements. This work provided insight into the volatility of secondary species, as well as the sources and chemistry of ambient particle cores. Seasonal differences in the volatility of amine species were attributed to the formation of aminium sulfate and nitrate salts in the summer. Oligomeric species were detected in real-time for the first time in individual ambient aerosol particles; increased oligomer ion intensities were associated with increased particle acidity and heating. During ICE-L, vertical profiles of particle types, such as soot, mixed with secondary species, such as sulfuric acid, were examined. For cloud sampling, a counterflow virtual impactor was utilized in series with the A-ATOFMS to examine the residues of cloud droplets and ice crystals. This resulted in the first in-situ detection of biological particles in high altitude ice clouds influenced by long-range transported dust. Playa salts were observed to serve as cloud condensation nuclei and were preferentially observed as residues of large droplets.

Download or read book Atmospheric Aerosol Chemistry written by Hind A. Al-Abadleh and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-04-19 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atmospheric aerosols are an important and a highly complex component of the Earth’s atmosphere that alter the radiative forcing and the chemical composition of the gas phase. These effects have impacts on local air quality and the global climate. Atmospheric Aerosol Chemistry outlines research findings to date in aerosol chemistry and advances in analytical tools used in laboratory settings for studying their surface and bulk reactivity.

Download or read book Size resolved Chemical Composition and Water soluble Fraction of Atmospheric Aerosols Collected from the Asian Continent written by Rachelle Monique Duvall and published by . This book was released on 2002 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Measurements of the Chemical Physical and Optical Properties of Single Aerosol Particles written by Ryan Christopher Moffet and published by . This book was released on 2007 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Knowledge of aerosol physical, chemical, optical properties is essential for judging the effect that particulates have on human health, climate and visibility. The aerosol time-of-flight mass spectrometer (ATOFMS) is capable of measuring, in real-time, the size and chemical composition of atmospheric aerosols. This was exemplified by the recent deployments of the ATOFMS to Mexico City and Riverside. The ATOFMS provided rapid information about the major particle types present in the atmosphere. Industrial sources of particles, such as fine mode particles containing lead, zinc and chloride were detected in Mexico City. The rapid time response of the ATOFMS was also exploited to characterize a coarse particle concentrator used in human health effects studies. The ATOFMS showed the ability to detect changes in particle composition with a time resolution of 15 min during short 2 hour human exposure studies.

Download or read book Advances and Applications of Mass Spectral Techniques for the Characterization of Atmospheric Aerosol Particles written by Lindsay Erighn Hatch and published by . This book was released on 2012 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol particles are ubiquitous in the atmosphere and induce significant impacts on human health and climate that depend on their physical and chemical properties, such as size, composition, and mixing state (chemical associations). Measurements of aerosol composition at the single-particle level are necessary to better understand these effects. Aerosol time-of-flight mass spectrometry (ATOFMS) is able to monitor the size and chemical composition of individual particles in real time. In this doctoral research, ATOFMS analysis was extended to identify new mass spectral markers and improve the potential for quantitative measurements. Development of novel instrumentation was also undertaken. Ion markers indicative of organosulfate compounds were identified in ATOFMS mass spectra collected in Atlanta, GA. In this study, the mixing state and temporal behavior of particulate organosulfate compounds were observed for the first time. Organosulfates were overwhelmingly detected in carbonaceous submicron particles and the temporal trends indicated that they likely formed by the daytime oxidation of isoprene followed by aqueous reaction with sulfate overnight. These results highlight the roles of mixing state and multi-phase reactivity on the formation of secondary organic aerosols. ATOFMS measurements of thermally-conditioned aerosol residuals obtained during the 2005 Study of Organic Aerosols in Riverside, CA were analyzed to determine the impacts of atmospheric aging on the laser desorption/ionization process. Coatings of secondary species suppressed the ionization efficiency, thereby impacting the mass spectral peak areas; however, a novel analysis method was found to correct these artifacts and produced strong agreement with collocated quantitative instrumentation. This new analysis technique was then applied to investigate the mixing-state dependence of aerosol volatility observed in Riverside. It was observed that particulate nitrate evaporated at different temperatures from different particle types (e.g., organic vs. biomass burning), which may influence the regional transport of nitrate species. ATOFMS provides important insights into size-resolved particle sources; however it heavily fragments most organic species, resulting in loss of the molecular information. Therefore, a novel chemical ionization mass spectrometer was developed to better characterize the molecular organic aerosol constituents. In particular, an ion funnel was incorporated into a home-built proton-transfer-reaction mass spectrometer. Initial characterization studies and ion simulations indicated that the ion funnel can provide high-efficiency ion transfer from the ionization region to the mass spectrometer. These results demonstrate the potential for this instrument to ultimately achieve highly sensitive analyses of organic aerosols.

Download or read book Advances in Measurements of the Properties of Aerosol Particles written by Emma Tackman and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol particles are a diverse class of materials that permeate the atmosphere with implications for global climate and human health. Atmospheric aerosols are released into the environment from many sources and continue to undergo atmospheric processing which introduces further variation into particle populations. This surfeit of sources and atmospheric trajectories leads to a wide variety in the properties in aerosol particles such as composition, shape, size, morphology, and reactivity. The methods measuring properties of aerosol particles is itself an important and developing field of study with direct applications in bettering our understanding of aerosol behaviors and atmospheric chemical systems. This work presents a critical analysis of existing microscopy-based measurements and provides new methods, applications, and recommendations for improving the assessment of aerosol properties. Chemical properties of aerosol particles include aqueous particle acidity and the O:C ratio of organic constituents. A new method for measuring the internal pH of aqueous aerosol microdroplets was developed and presented here using carbon quantum dots as a pH sensitive fluorophore. This technique was validated using a complex organic mixture representing various functional groups found in atmospheric organic material. The influence of organic O:C ratio on phase separation for proxy organic/inorganic mixed aerosol particles was assessed for microdroplets and nanoparticles. For optical microscope experiments, sucrose was added to organic/inorganic mixtures to systematically increase the O:C ratio of the system and was observed to suppress phase separation. Similarly, particles made up of combinations of carboxylic acids at particular O:C ratios and inorganic salts are analyzed using TEM for size dependence of phase separation at the nanoscale. Generally, large particles are able to phase separate while small particles remain homogeneous, or well mixed, and the transition region between the two regimes was examined. TEM is used in several studies to consider aerosol particle spreading and morphology at atmospherically relevant sizes. Inorganic particles were found to spread along the surface of a substrate. Particles with an organic coating also spread on the substrate but additionally lost volume, possibly due to outgassing of residual volatile species in storage or physical deformation during the impaction process. Results were compared to measurements of the same particles suspended in a gas flow and sizing discrepancies between the two methods were found, mostly attributed to the presence of a substrate in microscope assays. Further, the influence of generation parameters on the final morphologies of particles was determined for particles made under low and high relative humidity conditions with wet and dry seed particles. Wet seeds were found to restructure due to humidity cycling and spread less on the surface than dry seeds, while wet and dry coated particles were influenced similarly by the impaction process. Wet seeded organic particles also showed a new textured morphology, emphasizing the utility of microscope measurements of individual aerosol particles.

Download or read book The Application of Size Resolved Hygroscopicity Measurements to Understand the Physical and Chemical Properties of Ambient Aerosol written by Joshua L. Santarpia and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: During the summer of 2002, a modified tandem differential mobility analyzer (TDMA) was used to examine the size-resolved hydration state of the ambient aerosol in Southeast Texas. Although there were slight variations in the measured properties over the course of the study, the deliquescent particles observed were almost always present as metastable aqueous solutions. A relative humidity (RH) scanning TDMA system was used to measure the deliquescence/crystallization properties of ambient aerosol populations in the same region. During August, sampling was conducted at a rural site in College Station, and in September at an urban site near the Houston ship channel. Measurements from both sites indicate cyclical changes in the composition of the soluble fraction of the aerosol, which are not strongly linked to the local aerosol source. The observations show that as temperature increases and RH decreases, the hysteresis loop describing the RH-dependence of aerosol hygroscopic growth collapses. It is proposed that this collapse is due to a decrease in the ammonium to sulfate ratio in the aerosol particles, which coincides with increasing temperature and decreasing RH. This cyclical change in aerosol acidity may influence secondary organic aerosol (SOA) production and may exaggerate the impact of the aerosol on human health. The compositional changes also result in a daily cycle in crystallization RH that is in phase with that of the ambient RH, which reduces the probability that hygroscopic particles will crystallize in the afternoon when the ambient RH is a minimum. During June and July of 2004 airborne measurements of size-resolved aerosol hygroscopic properties were made near Monterey, California. These were used to examine the change in soluble mass after the aerosol had been processed by cloud. The calculated change in soluble mass after cloud-processingranged from 0.66 [mu]g m−3 to 1.40 [mu]g m−3. Model calculations showed these values to be within the theoretical bounds for the aerosols measured. Mass light-scattering efficiencies were calculated from both an averaged aerosol size distribution and from distributions modified to reflect the effects of cloud. These calculations show that the increase in mass light-scattering efficiency should be between 6% and 14%.

Download or read book Atmospheric Aerosols Their Optical Properties and Effects written by and published by . This book was released on 1976 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Download or read book Springer Handbook of Atmospheric Measurements written by Thomas Foken and published by Springer Nature. This book was released on 2021-11-09 with total page 1761 pages. Available in PDF, EPUB and Kindle. Book excerpt: This practical handbook provides a clearly structured, concise and comprehensive account of the huge variety of atmospheric and related measurements relevant to meteorologists and for the purpose of weather forecasting and climate research, but also to the practitioner in the wider field of environmental physics and ecology. The Springer Handbook of Atmospheric Measurements is divided into six parts: The first part offers instructive descriptions of the basics of atmospheric measurements and the multitude of their influencing factors, fundamentals of quality control and standardization, as well as equations and tables of atmospheric, water, and soil quantities. The subsequent parts present classical in-situ measurements as well as remote sensing techniques from both ground-based as well as airborn or satellite-based methods. The next part focusses on complex measurements and methods that integrate different techniques to establish more holistic data. Brief discussions of measurements in soils and water, at plants, in urban and rural environments and for renewable energies demonstrate the potential of such applications. The final part provides an overview of atmospheric and ecological networks. Written by distinguished experts from academia and industry, each of the 64 chapters provides in-depth discussions of the available devices with their specifications, aspects of quality control, maintenance as well as their potential for the future. A large number of thoroughly compiled tables of physical quantities, sensors and system characteristics make this handbook a unique, universal and useful reference for the practitioner and absolutely essential for researchers, students, and technicians.