Download or read book Kinetics of the Fischer Tropsch Synthesis on Iron Catalysts written by R. B. Anderson and published by . This book was released on 1963 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fischer Tropsch Synthesis Catalysts and Catalysis written by Burtron H. Davis and published by CRC Press. This book was released on 2016-04-06 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is based on a symposium held during the 248th American Chemical Society meeting that focused on use of the Fischer-Tropsch process in producing synthetic fuels. Its contents reflect the four dominant subjects of the meeting: catalyst preparation and activation, catalyst activity and reaction mechanisms, catalyst characterization and related reactions, and topics concerning commercializing the Fischer-Tropsch process. It covers recent developments related to renewable resources and green energy and provides a glimpse of the commercial potential of the Fischer-Tropsch process in synthetic fuel production.
Download or read book Factors Influencing Kinetics and Product Distribution in Fischer Tropsch Synthesis Over Iron Catalysts written by William James Cannella and published by . This book was released on 1984 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Microkinetic Model of Fischer Tropsch Synthesis on Iron Catalysts written by Uchenna Prince Paul and published by . This book was released on 2008 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fischer-Tropsch synthesis (FTS), developed in the early 1900[alpha]s, is defined as the catalytic conversion of H2 and CO to hydrocarbons and oxygenates with the production of H2O and CO2. Accurate microkinetic modeling can in principle provide insights into catalyst design and the role of promoters. This work focused on gaining an understanding of the chemistry of the kinetically relevant steps in FTS on Fe catalyst and developing a microkinetic model that describes FTS reaction kinetics.
Download or read book Fischer Tropsch Technology written by André Steynberg and published by Elsevier. This book was released on 2004-10-30 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fischer-Tropsch Technology is a unique book for its state-of-the-art approach to Fischer Tropsch (FT) technology. This book provides an explanation of the basic principles and terminology that are required to understand the application of FT technology. It also contains comprehensive references to patents and previous publications. As the first publication to focus on theory and application, it is a contemporary reference source for students studying chemistry and chemical engineering. Researchers and engineers active in the development of FT technology will also find this book an invaluable source of information. * Is the first publication to cover the theory and application for modern Fischer Tropsch technology * Contains comprehensive knowledge on all aspects relevant to the application of Fischer Tropsch technology* No other publication looks at past, present and future applications
Download or read book Bibliography of the Fischer Tropsch Synthesis and Related Processes Review and compilation of the literature on the production of synthetic liquid fuels and chemicals by the hydrogenation of carbon monoxide written by Hazel C. Anderson and published by . This book was released on 1954 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Kinetics of the Fischer Tropsch Synthesis on Iron Catalysts with List of References written by and published by . This book was released on 1964 with total page 45 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Bench scale Studies of the Fischer Tropsch Synthesis Over Iron Nickel and Nickel Cobalt Catalysts Japan written by Shiro Watanabe and published by . This book was released on 1951 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Fischer Tropsch and Related Syntheses written by Henry Herman Storch and published by . This book was released on 1951 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Fischer Tropsch Synthesis Catalysts and Catalysis written by B. H. Davis and published by CRC Press. This book was released on 2009-11-10 with total page 430 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rising oil costs have stimulated significant interest in the Fischer-Tropsch synthesis (FTS) as a method for producing a synthetic petroleum substitute. Drawn from the proceedings at a symposium held during the 236th meeting of the American Chemical Society in Philadelphia in August 2008, Advances in Fischer-Tropsch Synthesis, Catalysts, and Cataly
Download or read book Atomic Scale Design of Iron Fischer Tropsch Catalysts A Combined Computational Chemistry Experimental and Microkinetic Modeling Approach written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This work focuses on (1) searching/summarizing published Fischer-Tropsch synthesis (FTS) mechanistic and kinetic studies of FTS reactions on iron catalysts; (2) preparation and characterization of unsupported iron catalysts with/without potassium/platinum promoters; (3) measurement of H2 and CO adsorption/dissociation kinetics on iron catalysts using transient methods; (3) analysis of the transient rate data to calculate kinetic parameters of early elementary steps in FTS; (4) construction of a microkinetic model of FTS on iron, and (5) validation of the model from collection of steady-state rate data for FTS on iron catalysts. Three unsupported iron catalysts and three alumina-supported iron catalysts were prepared by non-aqueous-evaporative deposition (NED) or aqueous impregnation (AI) and characterized by chemisorption, BET, temperature-programmed reduction (TPR), extent-of-reduction, XRD, and TEM methods. These catalysts, covering a wide range of dispersions and metal loadings, are well-reduced and relatively thermally stable up to 500-600 C in H2 and thus ideal for kinetic and mechanistic studies. Kinetic parameters for CO adsorption, CO dissociation, and surface carbon hydrogenation on these catalysts were determined from temperature-programmed desorption (TPD) of CO and temperature programmed surface hydrogenation (TPSR), temperature-programmed hydrogenation (TPH), and isothermal, transient hydrogenation (ITH). A microkinetic model was constructed for the early steps in FTS on polycrystalline iron from the kinetic parameters of elementary steps determined experimentally in this work and from literature values. Steady-state rate data were collected in a Berty reactor and used for validation of the microkinetic model. These rate data were fitted to 'smart' Langmuir-Hinshelwood rate expressions derived from a sequence of elementary steps and using a combination of fitted steady-state parameters and parameters specified from the transient measurements. The results provide a platform for further development of microkinetic models of FTS on Fe and a basis for more precise modeling of FTS activity of Fe catalysts. Calculations using periodic, self-consistent Density Functional Theory (DFT) methods were performed on various realistic models of industrial, Fe-based FTS catalysts. Close-packed, most stable Fe(110) facet was analyzed and subsequently carbide formation was found to be facile leading to the choice of the FeC(110) model representing a Fe facet with a sub-surface C atom. The Pt adatom (Fe{sup Pt}(110)) was found to be the most stable model for our studies into Pt promotion and finally the role of steps was elucidated by recourse to the defected Fe(211) facet. Binding Energies(BEs), preferred adsorption sites and geometries for all FTS relevant stable species and intermediates were evaluated on each model catalyst facet. A mechanistic model (comprising of 32 elementary steps involving 19 species) was constructed and each elementary step therein was fully characterized with respect to its thermochemistry and kinetics. Kinetic calculations involved evaluation of the Minimum Energy Pathways (MEPs) and activation energies (barriers) for each step. Vibrational frequencies were evaluated for the preferred adsorption configuration of each species with the aim of evaluating entropy-changes, pre exponential factors and serving as a useful connection with experimental surface science techniques. Comparative analysis among these four facets revealed important trends in their relative behavior and roles in FTS catalysis. Overall the First Principles Calculations afforded us a new insight into FTS catalysis on Fe and modified-Fe catalysts.
Download or read book Study of Fischer Tropsch Synthesis Over Iron based Catalysts Using a Well stirred Slurry Reactor written by Ronald Alan Dictor and published by . This book was released on 1984 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book The Use of Iron Catalysts in the Fischer Tropsch Synthesis written by J. L. Wales and published by . This book was released on 1984 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Iron Catalyst Supported on Carbon Nanotubes for Fischer Tropsch Synthesis written by Mohammad Reza Malek Abbaslou and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Fischer Tropsch Oil circulation Process written by Daniel Bienstock and published by . This book was released on 1963 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book New Trends in CO Activation written by L. Guczi and published by Elsevier. This book was released on 1991-06-25 with total page 509 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this volume is to provide scientists with a comprehensive summary of new research areas in the activation of carbon monoxide, as one of the most reactive molecules, and in its applications. In order to understand the variety of the reactivity of CO, a quantum-chemical approach helps the reader to understand the binding state of CO to the solid surface (Chapter 1). The structure of the adsorbed CO can be better understood by examining its reactivity towards single crystals in the absence and in the presence of promoters (Chapter 2). The first approach in the reactivity study is that of studying catalytic activity of single crystals and structure sensitivity which are summarized in Chapter 3. One of the most prominent effects in the CO activation process is ascribed to the presence of additives, promoters which, in a real catalyst system, are far more complicated than on single crystal surfaces (Chapter 4). The original Fischer-Tropsch process applied fused iron or cobalt catalysts which were suitable for producing mainly straight chain hydrocarbons. The two most important processes involving CO activation, the new FT process and alcohol formation are discussed in Chapters 5 and 7. An important type of catalyst, the bimetallic catalysts, is discussed in Chapter 6. The role of hydrogen as one of the most frequently used partners in CO activation is discussed in Chapter 8. The field of production of specialty chemicals is an excellent example of the homogeneous catalytic activation of CO (Chapter 9). In Chapter 10 an overview is given of the industrial applications of CO chemistry and these are illustrated by working processes. The final chapter gives the reader some hints about future progress in the field.
Download or read book Bulletin written by and published by . This book was released on 1962 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt:
