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Book Kinetic Study of Styrene maleic Anhydride Copolymers Using Succinic Anhydride as the Model Compound

Download or read book Kinetic Study of Styrene maleic Anhydride Copolymers Using Succinic Anhydride as the Model Compound written by Barbara M. Johanson Jauch and published by . This book was released on 1997 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The reaction of aniline with succinic anhydride, a low molecular weight poly[styrene-co-(maleic anhydride)], and a high molecular weight poly[styreneco-(maleic anhydride)] were used to determine if these polymer reactions are diffusion- or reaction-controlled. Kinetic study protocols were developed to determine the rate constants for the succinic anhydride/aniline model reaction and for the 50/50 and 86/14 copolymers. These protocols were then used to gather kinetic data. The succinic anhydride/aniline reaction was determined to be exothermic and to have an induction period. The succinic anhydride/aniline reaction was also determined to have an experimental rate constant of 13 L/molmin 25% at 67 +/- 1.5 degrees Celsius. For the copolymer/aniline reactions, the experimental rate constants at 67 +/- 1.5 degrees Celsius were determined to be .051 L/molmin 15% for the 50/50 polymer and .008 L/molmin 18% for the 86/14 polymer. The model reaction was found to be 250 times faster than the 50/50 polymer/aniline reaction and 1600 times faster than the 86/14 polymer/aniline reaction. The 50/50 polymer/aniline reaction was determined to be 6 times faster than the 86/14 polymer/aniline reaction. At 20 1.5 degrees Celsius, the theoretical diffusion-controlled rate constant for the succinic anhydride/aniline reaction was determined to be 7.09 x 10^11 L/molmin and the experimental rate of reaction was determined to be 0.72 L/molmin 25%. Thus, these reactions were determined to be reaction-controlled."--Abstract.

Book A Kinetic Study of the Free Radical Copolymerization of Maleic Anhydride and Ethyl Vinyl Ether Using the Rotating Sector Technique

Download or read book A Kinetic Study of the Free Radical Copolymerization of Maleic Anhydride and Ethyl Vinyl Ether Using the Rotating Sector Technique written by Raymond Eugene Pasquali and published by . This book was released on 1972 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Free Radical Copolymerization of Styrene and Maleic Anhydride

Download or read book Free Radical Copolymerization of Styrene and Maleic Anhydride written by Lubertus Klumperman and published by . This book was released on 1994 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Film Balance Studies on Styrene maleic Anhydride Copolymers

Download or read book Film Balance Studies on Styrene maleic Anhydride Copolymers written by Hans Olf Esser and published by . This book was released on 1965 with total page 74 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Handbook of Maleic Anhydride Based Materials

Download or read book Handbook of Maleic Anhydride Based Materials written by Osama M. Musa and published by Springer. This book was released on 2016-09-22 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: A handbook on syntheses and properties, production processes, and applications of maleic anhydride and maleic anhydride derived products – all in one text. This handbook provides a comprehensive overview of maleic anhydride chemistry and applications from the professional perspective. With chapters written by leading R&D scientists from the chemical industry, and edited by the Vice President and ASI Technology Chief at Ashland Specialty Ingredients (ASI), Dr. Osama M. Musa, readers will find a unique perspective and summary of the latest advancements in the field of maleic anhydride science. Maleic anhydride is produced industrially on large scale (10E3 kt/annum). Its rich chemistry makes it an important raw material for numerous products and processes (e.g. for applications in polymers and coatings), many of which are covered in this handbook for the first time in a comprehensive manner. The broad scope spans topics ranging from production techniques (including topics such as processes, catalysis, trouble-shooting), synthesis and properties of small and polymeric maleic anhydride based compounds (focusing on industrially relevant compounds as well as emerging areas of importance) and in-depth and broad discussions of commercial maleic anhydride based applications.

Book Polymer Synthesis and Characterization

Download or read book Polymer Synthesis and Characterization written by Stanley R. Sandler and published by Elsevier. This book was released on 1998-05-21 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: This laboratory manual covers important techniques for polymer synthesis and characterization, and provides newcomers with a comprehensive introduction to the basic principles of highlighted techniques. The reader will benefit from the clear writing style and straightforward approach to fairly complex ideas. The book also provides references that the more advanced reader can use to obtain in-depth explanations of techniques. Polymer Synthesis and Characterization will serve as a useful resource for industrial technicians and researchers in polymer chemistry and physics, material science, and analytical chemistry. Combines the extensive industrial and teaching experience of the authors Introduces the user to the concept of "Good Manufacturing Practice" Presents experiments that are representative of a wide variety of polymerization and characterization methods Includes numerous references for more advanced students, technicians, and researcher

Book The Diels Alder Reaction

    Book Details:
  • Author : Francesco Fringuelli
  • Publisher : John Wiley & Sons
  • Release : 2002-01-21
  • ISBN : 9780471803430
  • Pages : 364 pages

Download or read book The Diels Alder Reaction written by Francesco Fringuelli and published by John Wiley & Sons. This book was released on 2002-01-21 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: 70 Jahre Forschung an der Diels-Alder-Reaktion: Dieses Buch fasst die wichtigsten und beeindruckendsten Ergebnisse in einzigartiger Weise zusammen! Zunächst werden die Grundprinzipien der Reaktion klar und verständlich anhand übersichtlicher Graphiken erläutert. Spezielle Vorschriften und gegebenenfalls ihre industrielle Umsetzung werden anschließend erklärt. Einen Schwerpunkt bilden auch physikalische und katalytische Verfahren zur Steigerung der Selektivität der Reaktion. Cycloadditionen in konventionellen und unkonventionellen Medien werden vorgestellt. Mit über 1.000 Literaturverweisen!

Book Polymer Chemistry

    Book Details:
  • Author : Timothy P. Lodge
  • Publisher : CRC Press
  • Release : 2020-07-14
  • ISBN : 1466581662
  • Pages : 609 pages

Download or read book Polymer Chemistry written by Timothy P. Lodge and published by CRC Press. This book was released on 2020-07-14 with total page 609 pages. Available in PDF, EPUB and Kindle. Book excerpt: A well-rounded and articulate examination of polymer properties at the molecular level, Polymer Chemistry focuses on fundamental principles based on underlying chemical structures, polymer synthesis, characterization, and properties. It emphasizes the logical progression of concepts and provide mathematical tools as needed as well as fully derived problems for advanced calculations. The much-anticipated Third Edition expands and reorganizes material to better develop polymer chemistry concepts and update the remaining chapters. New examples and problems are also featured throughout. This revised edition: Integrates concepts from physics, biology, materials science, chemical engineering, and statistics as needed. Contains mathematical tools and step-by-step derivations for example problems Incorporates new theories and experiments using the latest tools and instrumentation and topics that appear prominently in current polymer science journals. The number of homework problems has been greatly increased, to over 350 in all. The worked examples and figures have been augmented. More examples of relevant synthetic chemistry have been introduced into Chapter 2 ("Step-Growth Polymers"). More details about atom-transfer radical polymerization and reversible addition/fragmentation chain-transfer polymerization have been added to Chapter 4 ("Controlled Polymerization"). Chapter 7 (renamed "Thermodynamics of Polymer Mixtures") now features a separate section on thermodynamics of polymer blends. Chapter 8 (still called "Light Scattering by Polymer Solutions") has been supplemented with an extensive introduction to small-angle neutron scattering. Polymer Chemistry, Third Edition offers a logical presentation of topics that can be scaled to meet the needs of introductory as well as more advanced courses in chemistry, materials science, polymer science, and chemical engineering.

Book The Combinatorial Index

Download or read book The Combinatorial Index written by Barry A. Bunin and published by Elsevier. This book was released on 1998-04-15 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the explosion of combinatorial solid-phase methods, access to information has become one of the main barriers facing a synthetic chemist who is contemplating a combinatorial approach to a medicinal chemistry problem. The Combinatorial Index is an answer to that problem. This compendium of methods from the primary literature provides quick and convenient access to reliable synthetic transformations as well as information on linkers and analytical methods. Each synthetic procedure is preceded by a section entitled"Points of Interest,"which highlights the strengths and weaknesses of the various studies. The index also covers the use of solution-based synthesis for the generation of molecular diversity. Organized for rapid retrieval of published information on classes of synthetic transformations, linkers, and analytical methods Serves as a laboratory manual for bench chemists Includes a chapter on linkers to assist in choice of linking strategy Discusses strengths and limitations of the various methods Contains a structural index showing functional group transformations in solid-phase synthesis

Book Microwave assisted Polymer Synthesis

Download or read book Microwave assisted Polymer Synthesis written by Richard Hoogenboom and published by Springer. This book was released on 2016-09-02 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science.The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics.Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned.Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students

Book Advanced Organic Synthesis

Download or read book Advanced Organic Synthesis written by Richard Monson and published by Elsevier. This book was released on 2012-12-02 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Organic Synthesis: Methods and Techniques presents a survey and systematic introduction to the modern techniques of organic synthesis. The book attempts to acquaint the reader with a variety of laboratory techniques as well as introduce chemical reagents that require deftness and care in handling. Chapters are devoted that discuss the techniques of organic synthesis; apparatus and terminology used in the description of synthetic procedures; the scope and mechanism of chemical reactions; and technical procedures on how to perform chemical experiments. The text will be of vital importance to advanced undergraduate student or beginning graduate student of chemistry.

Book Engineering Index

Download or read book Engineering Index written by and published by . This book was released on 1969 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Book Polysaccharide Based Graft Copolymers

Download or read book Polysaccharide Based Graft Copolymers written by Susheel Kalia and published by Springer Science & Business Media. This book was released on 2013-05-23 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Renowned experts give all essential aspects of the techniques and applications of graft copolymers based on polysaccharides. Polysaccharides are the most abundant natural organic materials and polysaccharide based graft copolymers are of great importance and widely used in various fields. Natural polysaccharides have recently received more attention due to their advantages over synthetic polymers by being non-toxic, biodegradable and available at low cost. Modification of polysaccharides through graft copolymerization improves the properties of polysaccharides. Grafting is known to improve the characteristic properties of the backbones. Such properties include water repellency, thermal stability, flame resistance, dye-ability and resistance towards acid-base attack and abrasion. Polysaccharides and their graft copolymers find extensive applications in diversified fields. Applications of modified polysaccharides include drug delivery devices, controlled release of fungicides, selective water absorption from oil-water emulsions, purification of water etc.

Book Bio Based Polymers and Composites

Download or read book Bio Based Polymers and Composites written by Richard Wool and published by Elsevier. This book was released on 2011-08-30 with total page 641 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-Based Polymers and Composites is the first book systematically describing the green engineering, chemistry and manufacture of biobased polymers and composites derived from plants. This book gives a thorough introduction to bio-based material resources, availability, sustainability, biobased polymer formation, extraction and refining technologies, and the need for integrated research and multi-disciplinary working teams. It provides an in-depth description of adhesives, resins, plastics, and composites derived from plant oils, proteins, starches, and natural fibers in terms of structures, properties, manufacturing, and product performance. This is an excellent book for scientists, engineers, graduate students and industrial researchers in the field of bio-based materials. * First book describing the utilization of crops to make high performance plastics, adhesives, and composites * Interdisciplinary approach to the subject, integrating genetic engineering, plant science, food science, chemistry, physics, nano-technology, and composite manufacturing. * Explains how to make green materials at low cost from soyoil, proteins, starch, natural fibers, recycled newspapers, chicken feathers and waste agricultural by-products.

Book Bioconjugate Techniques

    Book Details:
  • Author : Greg T. Hermanson
  • Publisher : Academic Press
  • Release : 2010-07-26
  • ISBN : 0080568726
  • Pages : 1233 pages

Download or read book Bioconjugate Techniques written by Greg T. Hermanson and published by Academic Press. This book was released on 2010-07-26 with total page 1233 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioconjugate Techniques, 2nd Edition, is the essential guide to the modification and cross linking of biomolecules for use in research, diagnostics, and therapeutics. It provides highly detailed information on the chemistry, reagent systems, and practical applications for creating labeled or conjugate molecules. It also describes dozens of reactions with details on hundreds of commercially available reagents and the use of these reagents for modifying or cross linking peptides and proteins, sugars and polysaccharides, nucleic acids and oligonucleotides, lipids, and synthetic polymers. A one-stop source for proven methods and protocols for synthesizing bioconjugates in the lab Step-by-step presentation makes the book an ideal source for researchers who are less familiar with the synthesis of bioconjugates More than 600 figures that visually describe the complex reactions associated with the synthesis of bioconjugates Includes entirely new chapters on the latest areas in the field of bioconjugation as follows: Microparticles and nanoparticlesSilane coupling agentsDendrimers and dendronsChemoselective ligationQuantum dotsLanthanide chelatesCyanine dyesDiscrete PEG compoundsBuckyballs,fullerenes, and carbon nanotubesMass tags and isotope tagsBioconjugation in the study of protein interactions

Book Analytical Determination of Nicotine and Related Compounds and their Metabolites

Download or read book Analytical Determination of Nicotine and Related Compounds and their Metabolites written by J.W. Gorrod and published by Elsevier. This book was released on 1999-11-02 with total page 773 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides for the first time a single comprehensive source of information on the analytical chemistry of nicotine and related alkaloids. The editors have brought together scientists from academia and the tobacco industry to describe the state-of-the-art of the chemistry and analytical methods for measurement of nicotine. Both the scope and detail of the book are impressive. Chapters describe the history, pharmacology and toxicology of nicotine, the biosynthesis of nicotine and other alkaloids in the tobacco plant, the general chemistry of nicotine and the analytical methodologies that have been used to measure nicotine and related alkaloids in biological specimens, in tobacco and pharmaceutical products and in tobacco smoke. There is also a comprehensive review of the chemistry and toxicology of nicotine-derived nitrosamines, an important class of tobacco carcinogens.