Download or read book Isotope Separation by Selective Photodissociation of Glyoxal written by and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissociation products, mainly formaldehyde and carbon monoxide, enriched in a desired isotope of carbon, oxygen, or hydrogen are obtained by the selective photodissociation of glyoxal wherein glyoxal is subjected to electromagnetic radiation of a predetermined wavelength such that photon absorption excites and induces dissociation of only those molecules of glyoxal containing the desired isotope.
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1976 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration. Technical Information Center and published by . This book was released on 1976 with total page 962 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on 1976 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Exchange as a Versatile Isotope Separation Process written by G. H. Clewett and published by . This book was released on 1950 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Official Gazette of the United States Patent and Trademark Office written by and published by . This book was released on 1976 with total page 3340 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Isotope Separation by Selective Unimolecular Photoisomerization written by Stanford University. Microwave Laboratory and published by . This book was released on 1974 with total page 2 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Experimental and Computer Modeling Studies of Isotopically Selective Two step Laser Photodissociation of Small Molecules written by and published by . This book was released on 1992 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: The approach to laser isotope separation taken in this study is based on isotopically selective, two-step, laser photodissociation of small molecules. A primary goal of this study is the measurement of fundamental molecular processes which control the two-step, photodissociative isotope enrichment process. This objective has led to experimental measurements of uv photodissociation cross sections for vibrationally excited states of several small molecules, including the first cross section reported for any neutral molecule in a specific, excited vibrational state. A second goal of this study has been the laboratory demonstration of isotope enrichment for isotopes of practical interest and for processes with a potential for larger scale production. Where possible, efforts have focussed on the separation of middle isotopes, such as 17O and 33S, which are expensive and difficult to separate using other techniques. Considerable success has been achieved in demonstrating the enrichment of isotopes of bromine, carbon, oxygen and a third goal of this study has been the application of computer modeling to the two-step enrichment process. Experimental measurements define as many as possible of the critical photophysical and chemical parameters required by an ab initio computer model of the enrichment process. Progress toward these goals has been documented in detail in a variety of journal articles and technical reports. It is not the objective of this final report to discuss each aspect of the work done under this contract/grant in detail. A general overview of the program, touches briefly on each of the problems addressed by the study and provides references to more detailed discussions. 19 refs.
Download or read book Isotope Separation and Isotope Exchange written by and published by . This book was released on 1953 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Separation of Isotopes of Biogenic Elements in Two phase Systems written by Boris Mikhailovich Andreev and published by Elsevier. This book was released on 2006-12-01 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: Separation of Isotopes of Biogenic Elements provides a detailed overview of this area of research covering all aspects from the value of isotope effects to their practical use (equilibrium single-stage isotope effect - kinetics and mass transfer – multiplication of the single-stage isotope separation factor - technological peculiarity of processes) with the purpose of extraction from the natural mixture of the enriched and highly concentrated isotopes. In contrast to traditional books on the theory of isotope separation, the theoretical part of the book describes separation in two-phase processes in counter-flow columns. The experimental part of the book presents systematic analysis of specialists in the field of isotope separation in counter-flow columns. This book will be of interest to scientists, engineers and technical workers engaged in isotope separation processes and isotope application in nuclear physics, medicine, agro-chemistry, biology and other areas. This book may also be used in teaching theory and practical aspects in courses on physical chemistry and Isotope separation of light elements by physicochemical methods. * summarises current state of isotope research, especially biogenic elements* covering all aspects from the value of isotope effects to their practical use* of interest to scientists, engineers and technical workers engaged in isotope separation processes and isotope application
Download or read book Experimental and Computer Modeling Studies of Isotopically Selective Two step Laser Photodissociation of Small Molecules Final Report written by and published by . This book was released on 1992 with total page 25 pages. Available in PDF, EPUB and Kindle. Book excerpt: The approach to laser isotope separation taken in this study is based on isotopically selective, two-step, laser photodissociation of small molecules. A primary goal of this study is the measurement of fundamental molecular processes which control the two-step, photodissociative isotope enrichment process. This objective has led to experimental measurements of uv photodissociation cross sections for vibrationally excited states of several small molecules, including the first cross section reported for any neutral molecule in a specific, excited vibrational state. A second goal of this study has been the laboratory demonstration of isotope enrichment for isotopes of practical interest and for processes with a potential for larger scale production. Where possible, efforts have focussed on the separation of middle isotopes, such as 17O and 33S, which are expensive and difficult to separate using other techniques. Considerable success has been achieved in demonstrating the enrichment of isotopes of bromine, carbon, oxygen and a third goal of this study has been the application of computer modeling to the two-step enrichment process. Experimental measurements define as many as possible of the critical photophysical and chemical parameters required by an ab initio computer model of the enrichment process. Progress toward these goals has been documented in detail in a variety of journal articles and technical reports. It is not the objective of this final report to discuss each aspect of the work done under this contract/grant in detail. A general overview of the program, touches briefly on each of the problems addressed by the study and provides references to more detailed discussions. 19 refs.
Download or read book Laser Isotope Separation in Atomic Vapor written by Petr Artemovich Bokhan and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by leading Russian scientists, including Nobel laureate, A.M. Prokhorov (1916-2002), this first book on this important technology allows an understanding of the physics of atomic vapor laser isotope separation and new photochemical methods of laser isotope separation. One entire chapter is devoted to chemical reactions of atoms in excited states, while further chapters deal with the separation of isotopes by one photon isotope-selective and coherent isotope-selective two photon excitation of atoms. A final chapter looks at the prospects for the industrial production of isotope products by laser isotope separation. The whole is rounded off by six appendices.
Download or read book Isotope Separation by Photoselective Dissociative Electron Capture written by and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A method of separating isotopes based on photoselective electron capture dissociation of molecules having an electron capture cross section dependence on the vibrational state of the molecule. A molecular isotope source material is irradiated to selectively excite those molecules containing a desired isotope to a predetermined vibrational state having associated therewith an electron capture energy region substantially non-overlapping with the electron capture energy ranges associated with the lowest vibration states of the molecules. The isotope source is also subjected to electrons having an energy corresponding to the non-overlapping electron capture region whereby the selectively excited molecules preferentially capture electrons and dissociate into negative ions and neutrals. The desired isotope may be in the negative ion product or in the neutral product depending upon the mechanism of dissociation of the particular isotope source used. The dissociation product enriched in the desired isotope is then separated from the reaction system by conventional means. Specifically, .sup. 235 UF.sub. 6 is separated from a UF.sub. 6 mixture by selective excitation followed by dissociative electron capture into .sup. 235 UF.sub. 5 - and F.
Download or read book Separation of Carbon and Nitrogen Isotopes by Selective Photodissociation Azo Or Diazo Compounds written by and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Separation of isotopes, particularly of carbon or nitrogen, is achieved by the selective photodissociation of an azo compound or a diazoalkane, particularly azomethane or diazomethane.
Download or read book Government Reports Annual Index written by and published by . This book was released on 1977 with total page 920 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Laser Isotope Separation by Selective Excited State Photochemistry Progress Report June 1 1975 February 29 1976 written by and published by . This book was released on 1976 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress has been made on the development of a low-temperature source for the generation of uranium atoms, and the use of laser-induced predissociation in Rb2* for isotope separation. However, our main efforts have concentrated on understanding and improving the laser isotope separation of 35Cl and 37Cl by photochemical means. The gas-phase reaction ICl* with 1,2-dibromoethylene produces both cis-1-bromo-2-chloroethylene and cis-1,2-dichloroethylene stereospecifically. Selective excitation of I37Cl with a tunable cw dye laser causes identical degrees of isotope enrichment in both products. By the use of an I35Cl cell placed inside the cavity of the dye laser, the 35Cl:37Cl ratio may be changed from 3:1 (natural abundance) to greater than 1:15. A competing pathway, cis-trans isomerization of starting material, also occurs and is the fastest reaction. The stereospecificity of the reaction and the relative rate of geometrical isomerization to substitution are the same when chlorine atoms, formed by the photodissociation of ICl or Cl2, are scavenged by dibromoethylene. We conclude that, kinetically, ICl* acts as a free chlorine atom. That isotope separation is achieved by a free-radical scavenging mechanism is indeed remarkable and owes its success to the structure of the scavenger and the choice of initial conditions.
Download or read book Chemical Problems in Stable Isotope Separation written by Arthur J. Miller and published by . This book was released on 1947 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:
