Download or read book Ions in Solution and their Solvation written by Yizhak Marcus and published by John Wiley & Sons. This book was released on 2015-08-03 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods
Download or read book Ion Solvation written by Y. Marcus and published by John Wiley & Sons. This book was released on 1985 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical reactions generally take place in solution and often involve ions. The behaviour of ions in solution, manifested through ion solvation, is therefore of prime interest in chemistry. This book considers in depth the phenomenology of ion solvation and the models and interpretations that have been proposed as the physical causes for the observed phenomena. It contains a thorough discussion of the statistical thermodynamic background of the solvation process from which a discussion of the actual thermodynamics is developed. This, in turn, serves as a background to the structural and kinetic features of ion solvation.
Download or read book Ions in Solution and their Solvation written by Yizhak Marcus and published by John Wiley & Sons. This book was released on 2015-06-18 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods
Download or read book Ions in Solution and Their Solvation written by and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the s.
Download or read book Metal Ions in Solution written by John Burgess and published by . This book was released on 1978 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Single Ion Solvation written by Philippe Hunenberger and published by Royal Society of Chemistry. This book was released on 2015-10-20 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ions are ubiquitous in chemical, technological, ecological and biological processes. Characterizing their role in these processes in the first place requires the evaluation of the thermodynamic parameters associated with the solvation of a given ion. However, due to the constraint of electroneutrality, the involvement of surface effects and the ambiguous connection between microscopic and macroscopic descriptions, the determination of single-ion solvation properties via both experimental and theoretical approaches has turned out to be a very difficult and highly controversial problem. This unique book provides an up-to-date, compact and consistent account of the research field of single-ion solvation thermodynamics that has over one hundred years of history and still remains largely unsolved. By reviewing the various approaches employed to date, establishing the relevant connections between single-ion thermodynamics and electrochemistry, resolving conceptual ambiguities, and giving an exhaustive data compilation (in the context of alkali and halide hydration), this book provides a consistent synthesis, in depth understanding and clarification of a large and sometimes very confusing research field. The book is primarily aimed at researchers (professors, postgraduates, graduates, and industrial researchers) concerned with processes involving ionic solvation properties (these are ubiquitous, eg. in physical/organic/analytical chemistry, electrochemistry, biochemistry, pharmacology, geology, and ecology). Because of the concept definitions and data compilations it contains, it is also a useful reference book to have in a university library. Finally, it may be of general interest to anyone wanting to learn more about ions and solvation. Key features: - discusses both experimental and theoretical approaches, and establishes the connection between them - provides both an account of the past research (covering over one hundred years) and a discussion of current directions (in particular on the theoretical side) - involves a comprehensive reference list of over 2000 citations - employs a very consistent notation (including table of symbols and unambiguous definitions of all introduced quantities) - provides a discussion and clarification of ambiguous concepts (ie. concepts that have not been defined clearly, or have been defined differently by different authors, leading to confusion in past literature) - encompasses an exhaustive data compilation (in the restricted context of alkali and halide hydration), along with recommended values (after critical analysis of this literature data) - is illustrated by a number of synoptic colour figures, that will help the reader to grasp the connections between different concepts in one single picture
Download or read book Ions in Solution written by Ronald Wilfrid Gurney and published by . This book was released on 1962 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ions in Solution written by J Burgess and published by Elsevier. This book was released on 1999-10-01 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. - Inorganic solution chemistry is treated thoroughly - Emphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics
Download or read book Ions in Solution written by J. Robbins and published by CUP Archive. This book was released on 1972 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Ion Solvation written by Yizhak Marcus and published by . This book was released on 1996 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Thermodynamics of Solvation written by Gennadiĭ Alekseevich Krestov and published by Prentice Hall. This book was released on 1991 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aimed at scientists interested in the structure and dynamics of aqueous electrolyte solutions, this work examines the concept of the chemical nature of solutions. It shows quantitatively in tabulations of thermodynamic data for metal ions and anions the role of solvents as chemical reagents.
Download or read book Ion Properties written by Yitzhak Marcus and published by CRC Press. This book was released on 1997-07-29 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considering the properties of inorganic and organic ions pertaining directly, as well as indirectly, to their behaviour in solutions, this work aims to enable the specialist and non-specialist alike to comprehend ion behaviour in ongoing and developing studies and applications. The companion disk is for use with Microsoft Access 2.0.
Download or read book Ions in Solution 1 written by John Burgess and published by . This book was released on 1984-01-01 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book An Introduction to Aqueous Electrolyte Solutions written by Margaret Robson Wright and published by John Wiley & Sons. This book was released on 2007-06-05 with total page 603 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.
Download or read book Ions in Solution written by John Burgess and published by Ellis Horwood. This book was released on 1988-01-01 with total page 191 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Volume 1 Modern Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 1998-06-30 with total page 814 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book had its nucleus in some lectures given by one of us (J. O’M. B. ) in a course on electrochemistry to students of energy conversion at the University of Pennsyl- nia. It was there that he met a number of people trained in chemistry, physics, biology, metallurgy, and materials science, all of whom wanted to know something about electrochemistry. The concept of writing a book about electrochemistry which could be understood by people with very varied backgrounds was thereby engendered. The lectures were recorded and written up by Dr. Klaus Muller as a 293-page manuscript. At a later stage, A. K. N. R. joined the effort; it was decided to make a fresh start and to write a much more comprehensive text. Of methods for direct energy conversion, the electrochemical one is the most advanced and seems the most likely to become of considerable practical importance. Thus, conversion to electrochemically powered transportation systems appears to be an important step by means of which the difficulties of air pollution and the effects of an increasing concentration in the atmosphere of carbon dioxide may be met. Cor- sion is recognized as having an electrochemical basis. The synthesis of nylon now contains an important electrochemical stage. Some central biological mechanisms have been shown to take place by means of electrochemical reactions. A number of American organizations have recently recommended greatly increased activity in training and research in electrochemistry at universities in the United States.
Download or read book Investigating Ion Solvation in Electrolyte Solutions Via X ray Absorption Spectroscopy written by Jacob W. Smith and published by . This book was released on 2016 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: X-ray Absorption Spectroscopy (XAS) is a powerful atom-selective probe of the local chemical environment of a target atom. Streaming liquid microjets, created by forcing liquid at high pressures (ca. 20-100 atm.) through a capillary tube of inner diameter 30-100 μm, allow for liquids to be introduced into a vacuum chamber and interrogated with soft X-rays generated by synchrotron light sources. This technique has enabled the study of many liquids and solutions. In this dissertation, the use of soft X-ray XAS for the study of the solvation of ions in electrolyte solutions is discussed. The majority of chemical reactions occur in the solution phase. The thermodynamics and kinetics of these reactions are explicitly dependent upon the local chemical environments of the reactants. Consequently, knowledge of the solvation of ions in solution is critical to understanding their chemistry in this phase. By interpreting XAS measurements with ab initio Density Functional Theory (DFT)-based electronic structure calculations, it is possible to acquire valuable knowledge about the local chemical environment of ions and molecules in solution, such as the solvation number and geometry and propensity to form ion pairs. Commercial lithium ion batteries typically contain a liquid electrolyte comprising a lithium salt dissolved in a mixture of alkyl carbonates such as propylene carbonate, dimethyl carbonate, and ethylene carbonate. The solvation environment of the lithium ion in these solutions is thought to direct the formation of the Solid Electrolyte Interphase (SEI), which in turn is believed to play a critical role in determining essential cell properties including power output, recharging rate, and cycle life. Consequently, understanding this solvation environment is of critical importance. Here I report the a study of the solvation of Li+ in solutions of LiBF4 in alkyl carbonates via XAS on the carbon and oxygen K-edges. In collaboration with Dr. David Prendergast, we have performed electronic structure calculations within the eXcited electron and Core Hole (XCH) approximation and extracted a solvation number for Li+ in propylene carbonate. I also report the study of aqueous solutions sodium nitrate and nitrite on the nitrogen K-edge utilizing similar experimental and theoretical methods. Aqueous nitrate and nitrite salts are important commercial reagents and play a critical role in the global nitrogen cycle. A detailed understanding of their chemical environment of solution would be beneficial in understanding and modeling reactivity. Unfortunately, the nitrogen K-edge XAS spectra of these species are found to be largely insensitive to ion pairing and solvation geometry around the anion, such that limited chemical information was extracted from this study.
